07-12-2025

9610WJA801928250022 JA

PART 1 : PHYSICS

SECTION-I (i)

1) Radius of cylinder is increasing at the rate of 2 cm/sec and height of cylinder is increasing at the
rate of 5 cm/sec.

(A) Rate of change of volume is at R = 10 cm, H = 10 cm is 900π cm3/sec

(B) Rate of change of curved surface area at R = 10, cm H = 10 cn is 140π cm2/sec
(C) Rate of change of one of plane surface area at R = 10 cm, H = 10 cm is 40π cm2/sec
(D) Change in volume in 4 sec is 1000π cm3 at R = 10, H = 10

2) Figure shows a block of mass m projected with velocity v0 towards a wedge. Consider all the
surfaces to be smooth. Block does not have sufficient energy to negotiate (over come) wedge. Mark

the correct option(s).

When block is at the maximum height on wedge, block and wedge have velocity equal to
(A)
velocity of centre of mass of block wedge system
Wedge acquires maximum speed with respect to ground when block returns to lowest point on
(B)
wedge.
(C) Momentum of wedge and block is conserved at all times
(D) Centre of mass of wedge and block remains stationary

3) Two blocks A and B, each of mass m, are connected by an ideal spring of stiffness k and placed on
a smooth horizontal surface. A ball of mass m moving with a velocity v0 strikes the block A and gets

embedded to it. Then,

(A) velocity of block A just after collision is v0/2

(B) velocity of block B just after collision is zero
the maximum compression produced in the spring is
(C)
 the kinetic energy lost during collision is
(D)

4) Consider a sphere of mass 'm' radius 'R' doing pure rolling motion on a rough surface having
velocity as shown in the figure. It makes an elastic impact with the smooth wall and moves back

and starts pure rolling after some time again :-

(A) Change in angular momentum about 'O' in the entire motion equals 2mv0R in magnitude.
(B) Moment of impulse provided by the wall during impact about O equals 2mv0R in magnitude.

(C)
Final speed of ball will be

(D)
Final speed of ball will be

5) A disc of mass 3 m and a disc of mass m are connected by massless spring of stiffness k. The
heavier disc is placed on the ground with the spring vertical and lighter disc on top. From its
equilibrium position, the upper disc is pushed down by a distance δ and released. Then

(A) if >3mg/k, the lower disc will bounce up

(B) if =2 mg/k, maximum normal reaction from ground on lower disc = 6 mg
(C) if =2 mg/k, maximum normal reaction from ground on lower disc = 4 mg
(D) if >4mg/k, the lower disc will bounce up

6) The wires A and B shown in the figure are made of the same material, and have radii rA and
rB respectively. The block between them has a mass m. When the force F is mg/3, one of the wires

breaks–

(A) A will break before B if rA = rB

(B) A will break before B if rA < 2rB
(C) Either A or B may break if rA = 2rB
(D) The lengths of A and B must be known to predict which wire will break
 SECTION-II (i)

Common Content for Question No. 1 to 2

In the treatment of moments of inertia, introductory textbooks often present two theorems, generally
called the parallel axis theorem and the perpendicular axis theorem. There is another theorem of
this same genre, which is not usually included, but which is interesting and useful. It is

Here, Ix, Iy and Iz are the moments of inertia about three mutually perpendicular intersecting axes, mi
is the mass of the ith particle and ri is the distance from the intersection. The proof is simple: Taking
the three axes as coordinate axes, we have :
Ix + Iy + Iz

One important application is the calculation of the moment of inertia Id of a uniform thin-walled
spherical shell, of mass M and radius R, about a diameter. Taking the centre as the origin of
coordinates, we have Ix = Iy = Iz = Id, and ri =R. The theorem gives 3Id =

= 2MR2, where Id = .

1) If inertia of ring of mass m and radius R about an axis passing through its centre and making an
angle 45° with its plane is nMR2/4 find the value of n.

2) Consider a solid cube of mass m and side L. The value of MI for this body when the point of
intersection of axes is the centre of the cube is n mL2/4 then 'n' is.

Common Content for Question No. 3 to 4

When a cyclist turns on a circular path, the necessary centripetal force is provided by friction
between the tyres and the road. If centripetal force is not provided by friction, then for the vehicle to
move on circular path, the track is banked.

3) The minimum value of friction coefficient µ for turning on road of radius 120 m for a speed of 108
km/h (g = 10 m/s2) is :-

4) The correct angle (in degree) of banking for a curved smooth road of radius 120 m for a speed of
108 km/h (g = 10 m/s2) is

Common Content for Question No. 5 to 6

A particle is moving along a straight line, whose displacement time equation is given by
x = 2t2 – 12 t (S. I. units)

5) The velocity of particle will be zero at t = sec. what will be the value of .

6) Acceleration of particle will be at t = 3 sec. will be m/s2, What will be the value of

SECTION-I (ii)

Common Content for Question No. 1 to 2

A uniform ring of radius 1m is performing rolling motion on the horizontal surface as shown in the
figure. At t = 0 acceleration of COM of ring is m/s2 while angular acceleration & angular velocity
are rad/s2 and rad/s where x-z plane is horizontal and y is vertical axis. A is in contact with
surface and C is at 2m above the surface. B and D are 1m above the surface.

1) Magnitude of acceleration of point A is :

(A) 0 m/s2
(B) 2 m/s2
(C) 4 m/s2
(D) 3 m/s2

2) Acceleration of point B with respect to point D is:

(A) m/s2
(B) m/s2
(C) m/s2
(D) m/s2

Common Content for Question No. 3 to 4

A boat travels, between two points A and B on the opposite banks of a river (figure), always following
the line AB. The distance S between points A and B is 240 m. The velocity of the river flow vr =
m/s is constant over the entire width of the river. The line AB makes an angle α = 45° with the
direction of the current. The boat moves to cover the distance AB and back in a time t = min.
The angle β remains the same during the passage from A to B and from B to A.
3)

With what velocity ub should the boat travel ?

(A) m/s
(B) 4 m/s
(C) 0 m/s
(D) 2 m/s

4)

At what angle β to the line AB should the boat travel ?

(A) 30°
(B) 0°
(C) 15°
(D) 23°

SECTION-II (ii)

1) Consider an elliptically shaped rail PQ in the vertical plane with OP = 3 m and OQ = 4m. A block
of mass 1 kg is pulled along the rail from P to Q with a force of 18 N, which is always parallel to line
PQ (see the figure given). Assuming no frictional losses, the kinetic energy of the block when it
reaches Q is (n × 10) Joules. The value of n is (Take acceleration due to gravity = 10 ms–2)

2) A spring block system is placed on smooth horizontal surface as shown. Initially spring is in

0
natural length (ℓ ). Maximum expansion (in cm) in spring in subsequent motion is cm. Value of x
will be ?

3) In the figure shown, the block A collides with the block B and after collision they stick together.

The amplitude of resultant vibration is u. Find the value of x

PART 2 : CHEMISTRY

SECTION-I (i)

1) Choose the option in which given pairs of compunds having Ist weaker base than IInd

+
(A) H2O , H3O
(B) Cl¯ , SH¯
(C) H2O, NH3
(D) OH¯, SH¯

2) Re-orient the molecule at the left to match the partially drawn perspective at the right. Find the
two missing substituents at their correct positions.

(A)

(B)

(C)
(D)

3) Possible functional isomer of CH3COOCH3 is/are :

(A) CH3CH2COOH
(B) HOCH2–CH2CHO
(C) CH3COCH2OH
(D) H–COO–CH=CH2

4) Which type of isomerism is/are exhibited by hexanoic acid.

(A) Chain isomerism

(B) Position isomerism
(C) Functional isomerism
(D) Metamerism

5) The number of species which are not perfectly planar.

(A)

(B)
(C)
(D)

6) Select incorrect order out of given options:

(A) covalent character

(B) BeO > SrO : lattice energy
(C) Hydration energy
(D) Ionic mobility

SECTION-II (i)

Common Content for Question No. 1 to 2

Entropy is a state function and its value depends on two or three variables temperature (T), Pressure
(P) and volume (V). Entropy change for an ideal gas having number of moles (n) can be determined
by the following equation.

ΔS = 2.303 nCV log + 2.303 nR log

ΔS = 2.303 nCp log + 2.303 nR log

Since free energy change for a process or a chemical equation is a deciding factor of spontaneity,
which can be obtained by using entropy change (ΔS) according to the expression, ΔG = ΔH – TΔS at
a temperature T.

1) What would be the entropy change involved in thermodynamic expansion of 2 moles of a gas from
a volume of 5 L to a volume of 50 L at 25°C [Given R = 8.3 J/mole – K]

2) An isobaric process having one mole of ideal gas has entropy change 23.03 J/K for the
temperature range 27°C to 327°C. What would be the molar specific heat capacity (CV) ?

Common Content for Question No. 3 to 4

In a balance redox reaction, net gain of electron(s) is equal to net loss of electrons(s). nfactor is a
reaction specific parameter and for inter molecular redox reaction nfactor of oxidising or reducing
agent is the no. of moles of electron gained / loss by one mole of compound, respectively.

3) 50 ml 0.1M CuSO4 is mixed with 50 ml of 0.1M KI. Then number of moles of K2SO4 produced (as
per above reaction) is x × 10–3. The value of x is

4)

Consider the following reaction :

CrO5 + H2SO4 → Cr2(SO4)3 + H2O + O2
One mole of CrO5 will librate how many moles of O2

Common Content for Question No. 5 to 6

Bohr proposed his atomic model based on Planck’s quantum theory and derived following relations
for one electron system in C.G.S units :
For H-atom :

; E1 = –13.6eV
For 1 electron systems, other than H

Later on de Broglie proposed the dual nature of electron and put forward his wave concept. The
wavelength of electron in an orbit was given by

5) The potential energy of electron in 3rd Bohr orbit of H-atom is x × 10–12 erg. The value of x is
(magnitude only)

6) The circumference (in m) of 3rd Bohr orbit in H-atom is z × 10–2 m. The value of z is (Nearest
integer)

SECTION-I (ii)

Common Content for Question No. 1 to 2

81gm mixture of MgCO3(s) and NH2COONH4(s) in equimolar ratio is heated in open to constant
mass.
MgCO3(s) MgO(s) + CO2(g)
NH2COONH4(s) 2NH3(g) + CO2(g)

1)

Mass % of MgCO3 in original sample -

(A) 50%
(B) 51.9 %
(C) 70.9%
(D) 59.1 %

2)

Mole % of CO2 in the resulting gaseous mixture is

(A) 50%
(B) 51.9
(C) 48.17
(D) 33.33 %

Common Content for Question No. 3 to 4

A container is divided into two compartment. One compartment contains 2 mole of N2 gas at 1 atm
and 300 K & other compartment contains H2 gas at the same temperature and pressure. Volume of
H2 compartment is four times the volume of N2 compartment.
[Assuming no reaction under these condition]

3) If the container containing N2 & H2 are further heated to 1000 K, forming NH3 with 100% yield.
Calculate the final total pressure.

(A) 2.22 atm

(B) 3 atm
(C) 2 atm
(D) 3.33 atm

4) Calculate the final total pressure if partition between two compartments is removed.

(A) 2 atm
(B) 3 atm
(C) 1 atm
(D) 1.5 atm

SECTION-II (ii)
1) Amongst the following, the total number of compounds soluble in aqueous NaOH is:

2) How many of the following are tertiary amines ?

3) Total number of amphoteric compounds among given is :

BeO, Al2O3, ZnO, PbO, NO2, N2O5, SO3, SnO, MgO, Na2O, P4O10.

PART 3 : MATHEMATICS

SECTION-I (i)

1) Select the correct option(s) from the following:

(A)
If sin3 x cos 3x + cos3 x sin 3x = , then the value of 8 sin 4x is 4.
(B) If A = tan2 θ + 2 cot2 θ, then for all real values of θ, A ∈ [1, 3].

(C)
If cos α + cos β=1/2 and sin α + sin β=1/3, then =

(D)
cos 0° + cos + =1

2) For two events A & B, which of the following is/are correct -

(A) (A ∪ B) ∩ B = B
(B) (A ∪ B)C ∩ BC = (A ∪ B)C
(C) AC ∩ (A ∩ B) ∩ BC = ϕ
(D) (AC ∩ B) ∩ (A ∪ B) = B
3) If A, B, C are angle of a triangle ABC and [Link] = 3; [Link] = 6; then which of the
following is/are correct ?

(A)

(B) [Link] = 2

(C)

(D) tanB = 2tanA

4) Choose the correct statement(s)

(A) There are 45 ways in which one can post 4 distinct letters in 5 distinct letter boxes.
A person can invite his six friends in 63 ways, if he has three domestic helpers to carry
(B)
the cards.
There are 32 ways to answers (every question must be attempted), out of five true-false
(C)
type questions.
There are 30 ways in which five distinct balls can be put into three distinct boxes so that no box
(D)
remains empty.

5) Element in set of values of r for which, is

(A) 9
(B) 5
(C) 7
(D) 10

6) A triangle is formed by the lines x – 3y – 6 = 0 ; 3x – y + 6 = 0 and 3x + 4y – 24 = 0. If the points

P(α, 0) and Q(0, β) always lie on or inside the ΔABC, then range of α & β are [a, b] and [c, d] then

(A) a + b = 4
(B) c + d = 1
(C) a + b = 2
(D) c + d = 4

SECTION-II (i)

Common Content for Question No. 1 to 2

Given x, y, z are respectively sines and p, q, r are respectively cosines of the angles α, β, γ which are

in A. P. with common difference then

1) p + q + r is equal to

2) x + y + z is equal to

Common Content for Question No. 3 to 4

Consider the number N = 24 34 52 72 112.

3) The number of ways in which 'N' can be resolved as the product of 2 divisors is

4) The number of divisors of 'N' which are divisible by 60 is

Common Content for Question No. 5 to 6

Consider the expansion of (1 – x3)5 (1 + x2)4 (1 + x4)8 in power of x then

5) Coefficient of x6 is

6) The coefficient of term independent of 'x' is

SECTION-I (ii)

Common Content for Question No. 1 to 2

Let sinA + cosB = p and sinB + cosA = q.

1) If and , then numerical value of sin(A + B) is

(A)

(B)

(C)

(D)

2) Number of possible integral value of p + q is

(A) 3
(B) 5
(C) 7
(D) 9

Common Content for Question No. 3 to 4

Consider a line L which passes through the point (1, 4).

3) The equation of line L which cuts equal and positive intercept on the co-ordinate axes is

(A) x + y = 3
(B) x + y = 5
(C) y – x = 3
(D) 2y – x = 7
4) If gradient of the the line L is –2 then the area of triangle formed by L and co-ordinate axes is

(A) 18 sq unit
(B) 6 sq unit
(C) 12 sq unit
(D) 9 sq unit

SECTION-II (ii)

1) Two sides of a rhombus ABCD are parallel to the lines y = x + 3 and y = 7x + 7. If the diagonals
of the rhombus intersect at the point (19, 15) and the vertex A(0, α) is on the y-axis, then α1 and α2
are two possible values of α, then 2(α1 + α2) is equal to

2) Tangents to x2 + y2 = r2 having inclinations α and β with x-axis intersect at P. If cotα + cotβ = 0,

such that the locus of P is xy = λ, then the value of λ is

3) The value of · is
 ANSWER KEYS

PART 1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. A,B,C A,B A,B,C,D A,B,D B,D A,B,C

SECTION-II (i)

Q. 7 8 9 10 11 12
A. 3.00 1.00 0.75 37.00 3.00 4.00

SECTION-I (ii)

Q. 13 14 15 16
A. C C B A

SECTION-II (ii)

Q. 17 18 19
A. 5 4 2

PART 2 : CHEMISTRY

SECTION-I (i)

Q. 20 21 22 23 24 25
A. B,C A,B A,B,C A,C B,C,D A,C,D

SECTION-II (i)

Q. 26 27 28 29 30 31
A. 38.00 to 39.00 24.50 to 25.50 2.50 1.75 4.80 to 4.90 3.00

SECTION-I (ii)

Q. 32 33 34 35
A. B A C C

SECTION-II (ii)

Q. 36 37 38
A. 4 3 5

PART 3 : MATHEMATICS
 SECTION-I (i)

Q. 39 40 41 42 43 44
A. A,C,D A,B,C A,B,D C,D A,C,D A,D

SECTION-II (i)

Q. 45 46 47 48 49 50
A. 0.00 0.00 338.00 216.00 46.00 1.00

SECTION-I (ii)

Q. 51 52 53 54
A. A B B D

SECTION-II (ii)

Q. 55 56 57
A. 3 0 1
 SOLUTIONS

PART 1 : PHYSICS

1) Explain Question: Since both radius and height change with time, volume and surface
areas also change with time.
Concept: Related rates + differentiation of cylinder formulas
Solution:
Rate of change of volume

Final Answer: (A,B,C)

2)

Explain Question: Horizontal momentum is conserved; at maximum height, the block and
wedge momentarily share the COM velocity.
Concept: Conservation of horizontal momentum + Energy
Solution:
(i) in horizontal direction momentum is conserved. when block is at maximum height it would
be stationary w.r.t. plank.
So vblock = vplank = vcm
(ii) PE + KE = constant
(iii) momentum is not conserved at all time.
(iv) vcm ≠ 0
Final Answer: (A,B)

3) Question Explanation:
We have to choose correct options for the inelastic collision between ball and block 'A' as
shown.
Concept:
Collision.

Solution:

During the collision impulse is not transferred to B :

Just after collision

and at the time of maximum compression

Loss in KE =

Final Answer:
Correct options are (1), (2), (3) and (4).

4) Explain Question: The wall gives an impulse that changes angular momentum; after
rebound the sphere returns to pure rolling.
Concept: Rolling motion + impulse+ angular momentum.
Solution:

Final Answer: (A,B,D)

5) Question Explanation: Find condition for lower block to bounce up in vertical SHM with
two masses.
Concept: Vertical SHM, Normal Force, and Equilibrium. Solution:
Solution: From energy conservation

kδ12 = mg (d1 + x1) + kx12

⇒ If δ the lower disk will bounce up.

Now If then maximum normal reaction from ground on lower disk

N = 3mg + k(x0 + δ) = 6 mg
Final Answer: (B,D)

6)

Explaining the Question :-

Two wire A + B are made of the same material and have radii rA and rB. The block between
them as a mass m. When the force F is mg/3, then we need to compare the breaking conditions
for different radii.
Concept:- This question is based on Stress, strain, breaking force.
Solution :-
When force F = mg/3 is applied at the lower end then

stress in wire B = and

Stress in wire
(i) If rA = rB = r (let), then

Stress in wire B = and

stress in wire A =
i.e. stress in wire A > stress in wire B
So, the wire A will break before B.
(ii) If rB = r1 (let), then rA = 2r

Stress in wire B = and stress in wire A =

i.e. stress in wire A = stress in wire B. It means either A or B may break.
(iii) If rA < 2rB then stress in wire A will be more than B.
i.e. A will break before B.
Final Answer :- (A), (B) & (C)

7) Explain Question: The moment of inertia about an inclined axis is found by resolving Ml
along perpendicular axes.
Concept: Axis transformation of MI.
Solution:

= 2MR2

Final Answer: (3.00)

8) Explain Question: A cube is symmetric, so Ml about three perpendicular axes through its
center is equal.
Concept: Symmery + Ml relation.
Solution:

Ans. is
Final Answer: (1.00)

9)

Explain question : To safely a turn, the static friction between the car's tires and the road
provides the necessary inward pull, known as centripetal force. This force prevents the car
from skidding out of its circular path.
Concept : This question is based on The minimum friction required is when the maximum

static frictional force, fs,max =μN, equals the centripetal force, Fc = . On a flat road, the
normal force n is equal to the gravitational force mg.
Solution :-
First, convert the speed to m/s
v = 108 km / h = 30m/s

By equating the centripetal force to the frictional force , we can solve

for μ :
μ=

m=
Final answer :- 0.75

10)

Explain question : Banking a road means tilting the surface so the normal force helps
provide the centripetal force required to make a turn safely.
Concept : This question is based on The ideal banking angle (θ) is found using the formula

Solution :-
Given : r = 120m, υ = 108km/h, g = 10m/s2

speed in m/s v =
Calculation :

tan(θ) =

θ = tan–1
Final answer :- The correct angle of banking is 37°

11)

Explaining the Question :-

The problem describes a particle moving along a straight line and its displacement (x) is given
by the equation : x = 2t2 – 12 t. The question asks for the value of α when the particle's velocity
is zero.
Concept:- This question is based on Kinematics
Solution :-
x = 2t2 – 12t

t = 3 sec
∴ α = 3 sec

Final Answer :- Therefore, the value of a is 3 seconds.

12)

Explaining the Question :-

We need to find the value of α when acceleration of particle at t = 3 sec will be α m/s2.
Concept:- This question is based on
Kinematics, Acceleration
Solution :-
x = 2t2 – 12t
 ∴ α = 4 m/s2
Since, the acceleration equation is a constant (a = 4), the acceleration at t = 3 seconds will
also be 4 m/s2.
Final Answer :- Hence, the value of α is 4 m/s2.

13)

Question Explanation : The problem describes a uniform ring of radius 1m performing

rolling motion on a horizontal surface. At a certain instant the acceleration of COM of the ring
angular acceleration and angular velocity are given. We need to find the magnitude of the
acceleration of point A, which is in contact with the surface.

Concept: “This question is based on rolling motion ”

Solution:

condition of pure rolling

a = Rα
aA = (2)2 × 1 = 4 m/s2

Final Answer: The correct option is (3)

14)

Explanation Question : A uniform ring is performing rolling motion on horizontal surface

and we have to find acceleration of point B with respect to point D.
Concept : This question is based on rolling motion.
Solution :

=
2
= m/s

Final Answer : The correct option is (3)

15) Explain Question: For the boat to follow line AB, the perpendicular velocity components
of boat and river must cancel.
Concept: Relative velocity vector components.
Solution:
ub = 4 m/s; β = 30° The velocities of the river flow and of the boat should be resolved into
components along the line AB and perpendicularly to it (figure). In order that the moving boat
is always on the straight line AB the components of the velocity of the river flow and of the

boat in the direction perpendicular to AB should be equal, i.e.,

ub sin β = vr sin α (1) When the boat moves from A to B its velocity relative to the
ground
will be ub cos β + vr cos α and the time of motion will be determined from the equation S = (ub
cos β + vr cos α) t1 (2) The time of motion from B to A (figure) can be found from the

equation
S = (ub cos β – vr cos α) t2 (3) From the known conditions, t1 + t2 = t (4) Solving the system

of the four equations we found and

Final Answer: (B)

16) Explain Question: The boat adjusts its angle so its perpendicular component exactly
balances the river current.
Concept: Relative velocity
Solution:
ub = 4 m/s; β = 30°
The velocities of the river flow and of the boat should be resolved into components along the
line AB and perpendicularly to it (figure). In order that the moving boat is always on the
straight line AB the components of the velocity of the river flow and of the boat in the direction
perpendicular to AB should be equal, i.e., ub sin β = vr sin α
(1) When the boat moves from A to B its velocity relative to the ground
will be ub cos β + vr cos α and the time of motion will be determined from the equation S = (ub
cos β + vr cos α) t1 (2) The time of motion from B to A (figure) can be found from the

equation S = (ub cos β – vr cos α) t2 (3) From the known

conditions, t1 + t2 = t (4) Solving the system of the four equations we found

and Final Answer: (A)

17) Question Explanation: Find the final kinetic energy of a block pulled along an elliptical
rail by a constant force parallel to the line PQ.
Concept: Work-Energy Theorem and Work Done by a Constant Force.
Solution

Calculation:

Final Answer: (5)

18) Explain Question: Maximum expansion occurs when both blocks reach the same velocity
(relative velocity zero).
Concept: COM frame + spring energy.
Solution:

m/s2
Taking COM as reference frame
 From work-energy theorem in COM frame

20x1 – 2acmx1 + 1 × acmx2 – k (x1 + x2)2 = 0

Final Answer: (4)

19) Question Explanation: Finding the amplitude of oscillation after an inelastic collision.
Concept: Conservation of momentum and energy.
Solution:
Common velocity after collision be v then by COLM

Hence, kinetic energy = (2M)

It is also the total energy of vibration because the spring is unstretched at this moment, hence
if A is the amplitude, then

KA2 = Mu2 ⇒ A =

Final Answer : 2

PART 2 : CHEMISTRY

20) Question Explanation: Identifying the pair where

the 1st compound is a weaker base than 2nd.

Concept: Basicity (Acidity of Conjugate Acid)

Solution: Weaker base ⟹ Stronger conjugate acid. We seek Acidity(I) > Acidity(II).

A. A(H2​Ovs H3O⊕): H3​O⊕ is the strongest acid. Incorrect.

B. C(H2O​ vs NH3​): H2​O > NH3​. Correct.

Final Answer: (B,C)

21) Question Explanation: To find the two missing substituents at their correct positions
Concept: Optical isomerism
Solution:
Final Answer: (AB)

22)

Explaining the Question :- To identify functional isomer of given compound.

Concept : This question is based on Functional isomerism.

Solution : Given compound is C3H6O2

(1) CH3 – CH2 – COOH C3H6O2 carboxylic acid
(2) HO – CH2 – CH2 – CHO C3H6O2 Aldehyde and alcohol.

(3) C3H6O2 Ketone and alcohol.

(4) C3H4O2 Ester with different molecular formula.

Final Answer : (A,B,C)
23) Question Explanation: To find which type of isomerism is/are exhibited by hexanoic acid
Concept: Isomerism
Solution:

It will show chain isomerism and functional isomerism.

Final Answer: (A,C)

24)

Question Explanation: To find the number of species which are not perfectly planar
Concept: odd electron species
Solution:

(A) →sp2 → Trigonal planar (planar)

(B) → sp3 → non planar

(C) → sp3 → Tetrahedral(non planar)

(D) → sp3 → Tetrahedral (non planar)

Final Answer: (BCD)

25) Question Explanation: To find select incorrect order out of given options
Concept: Fajan's Rule
Solution:
(A) Smaller size of cation, greater will be covalt character.
(B)
(C)

(D)
Final Answer: (ACD)

26) Question Explanation: To find what would be the entropy change involved in
thermodynamic expansion of 2 moles of a gas from a volume of 5 L to a volume of 50 L at 25°C

Concept: ΔS = 2.303 nCV log + 2.303 nR log

Solution:

ΔS = 2.303 x 2 x 8.3 log = 38.23 J/K

Final Answer: (38.00-39.00)

27)
Question Explanation: To find what would be the molar specific heat capacity (CV)

Concept: ΔS = 2.303 nCP log

Solution:

ΔS = 2.303 × 1 × CP log = 23.03 CP =

CV = CP – R = – 8.3
Final Answer: (24.50 - 25.50)

28) Question Explanation: To find number of moles of K2SO4 produced

Concept: equivalent KI = equivalent of electron
Solution:
milli equation of CuSO4 = 0.1 × 50 × 1 milli equivalent of KI = 0.1 × 50 × 1/2
hence KI is limiting reactant
equivalent KI = equivalent of electron

=n×1
n = 2.5 × 10–3 moles.
Final Answer: (2.50)

29) Question Explanation: To find one mole of CrO5 will librate how many moles of O2
Concept: Redox Balancing
Solution:

2CrO5 + 3H2SO4 → Cr2(SO4)3 + 3H2O + O2

One mole of CrO5 will produce 7/4 moles of O2
Final Answer: (1.75)

30) Question Explanation: To find the potential energy of electron in 3rd Bohr orbit of H-
atom
Concept: P.E. = 2 × T.E.
Solution:

P.E. = 2 × T.E. = 2 × – 21.8 × 10–19 ×

= – 4.84 × 10–12 erg/atom.

Final Answer: (4.80-4.90)

31)

Explain the question : Find the circumference of the 3rd orbit in a hydrogen atom
Concept : This question is based on Bohr model.
Explanation :
 Circumference of Bohr orbit of n orbit number = 2πr

r = 0.529 × × 10–10 m

So, circumference =
= 2.989 × 10–9

Final answer : (3.00)

32) Question Explanation: To find Mass % of MgCO3 in original sample

Concept: Heating Effect
Solution:
MgCO3(s) → MgO(s) + CO2(g)
(a mole) – –
– – (a mole)

NH2COONH4(s) → 2NH3(g) + CO2(g)

(a mole) – –
– (2a mole) (a mole)

84a + 78a = 81
a = 0.5

Mass % MgCO3 =
Final Answer: (B)

33) Question Explanation: To find mole % of CO2 in the resulting gaseous mixture
Concept: Mole Percent
Solution:

Mole % of = 50%
Final Answer: (A)

34) Question Explanation: To find the final total pressure

Concept: PV = nRT
Solution:
At 1000 K
N2 + 3H2 → 2NH3
2 8
- 2 4
nT = 6 mole

PT =
Final Answer: (C)

35) Question Explanation: To calculate the final total pressure if partition between two
compartments is removed
 Concept: Dalton's law
Solution:
nT = 2 + 8 = 10 moles
As volume of H2 compartment is four times that of N2 compartment
Final Answer: (C)

36) Question Explantion :

To identify the total number of compounds soluble in aqueous NaOH.

Concept:
This question is based on acid base reaction.

Solution :
Those compounds which are stronger acid than H2O are soluble in NaOH.
Carboxylic acids and phenols are soluble in NaOH

Acidic strength order →

Total (4) compound are more acidic than H2O hence they are soluble in NaOH.

Final answer : 4

37) Question Explanation: To find how many of the following are tertiary amines
Concept: Degree of amines
Solution:

Final Answer: (3)

38) Question Explanation: To find total number of amphoteric compounds among given is :
Concept: Types of oxides
Solution:
Amphotesic compounds are - BeO, Al2O3, ZnO, PbO, SnO
Final Answer: (5)

PART 3 : MATHEMATICS

39)

Explain Question : We have to check correct options

Concept : Basic trigonometric formulas
 Solution :

(A)

⇒ (3sinx – sin3x)cos3x + (3cosx + cos3x)sin3x =

⇒ 3[sinx cos 3x + cosx sin3x] =

⇒ sin 4x =
⇒ 8 sin4x = 4

(B) = +
(C)

…(i)

…(ii)
Dividing Eq. (ii) by Eq.(i). we get

(D) cos0° + cos +

= + +

= + +
=1+0+0+0=1
Final Answer : (A,C,D)

40) Question Explanation: Multiple choice question to determine correct set operations.
Concept: Set identities.
Solution:

Option Statement Law/Simplification Result Status

1 Absorption Law LHS = B Correct

2 De Morgan's Law Correct

3 Associative Law Correct

4 Distributive Law Incorrect

Final Answer: Option (1, 2, 3)

41) Explain Question : From given information we have to chose correct options
Concept : tanA + tanB + tanC = tanA tanB tanC
Solution :
tanA tanC = 3 and tanB tanC = 6
∴ tanA + tanB + tanC = tanA tanB tanC

⇒ α=1
tanA = 1, tanB = 2, tanC = 3
Final Answer : (A,B,D)

42) Explain Question : We have to choose correct options

Concept : Fundamental principle of counting
Solution :
Use fundamental principle of counting. Correct answer of (A) and (B) are 54 and 36 respectively
Final Answer : (C,D)

43) Explain Question : We have to find value of r which satisfy given inequality
Concept : nCr + nCr–1 = n+1Cr
Solution :

or
or
r = 7,8,9,10,11,12,13
Final Answer : (A,C,D)

44) Explain Question : We have to find range of α, β so that point P & Q lie on or inside
triangle
Concept : Position of point
(i) 4β – 24 < 0 ⇒ β<6
3α – 24 < 0 ⇒ α<8
(ii) –β + 6 > 0 ⇒ β < 6.
3a + 6 > 0 ⇒ α > –2
(iii) α – 6 < 0 ⇒ α<6
–3β – 6 < 0 ⇒ β > –2
From cases (i), (ii) & (iii)
 & Final Answer : (A,D)

45) Explain Question : From the given information we have to find value of p + q + r

Concept : cosC + cosD =

Solution :

p + q + r = cosα +

= cosα + 2cos(π + α).cos

= cosα – cosα
=0
Final Answer : (A)

46) Explain Question : From the given information we have to find value of x + y + z

Concept : sinC + sinD =

Solution :

x + y + z = sinα + sin + sin

= sinα + 2sin(π + α).cos

= sinα – sinα
=0
Final Answer : (0.00)

47) Explain Question : We have to find number of ways in which 'N' can be resolved as the
product of 2 divisors

Concept : if N is perfect square

Solution :
Total divisors = 675

∴
Final Answer : (A)

48) Explain Question : We have to find the number of divisors of 'N' which are divisible by 60
Concept : Divisors
Solution :
Number should be divisible 4, 3 and 5.
at least two 2's can be taken in 3 ways
at least one 3's can be taken in 4 ways
at least one 5's can be taken in 2 ways
7's can be taken in 3 ways
11's can be taken in 3 ways
∴ No. of divisors = 216
Final Answer : (216.00)

49) Explain Question : We have to find coefficient of x6

Concept : Binomial expansion
Solution :
(1 – x3)5 (1 + x2)4 (1 + x4)8
[5C0 – 5C1x3 + 5C2x6 ...] [4C0 + 4C1x2 + 4C2x4 + 4C3x6 + 4C4x8]
[8C0 + 8C1x4 + ...]
Coefficient of x6
= 5C0 4C3 8C0 + 5C0 4C1 8C1 + 5C2 4C0 8C0
= 4 + 32 + 10 = 46
Final Answer : (46.00)

50) Explain Question : We have find term independent of x

Concept : Binomial expansion
Solution :
(1 – x3)5 (1 + x2)4 (1 + x4)8 [5C0 – 5C1x3 + 5C2x6 ...] [4C0 + 4C1x2 + 4C2x4 + 4C3x6 + 4C4x8]
[8C0 + 8C1x4 + ...]
0
Coefficient of x
= 5C0 4C0 8C0 = 1
Final Answer : (1.00)

51) Explain Question : We have to find value of sin(A + B) from given information
Concept : sin(A + B) = sinAcosB + cosAsinB
Solution :

sinA + cosB = .....(1)

sinB + cosA = ......(2)

squaring and add

sin2A + cos2B + 2sinAcosB = ......(3)

sin2B + cos2A + 2 sinB cosA = ......(4)

add (3) & (4)

2 + 2 sin(A + B) =

2 sin(A + B)
sin(A + B) =
Final Answer : (A)

52) Explain Question : We have to find possible value of p + q

Concept : Range of trigonometric function
Solution :
p + q = (sinA + cosB) + (sinB + cosA)
= (sinA + cosA) + (sinB + cosB)

∴ Possible integral values = –2, –1, 0, 1, 2

Final Answer : (B)

53) Explain Question : We have to find equation of line which have equal & positive
intercepts on co-ordinate axis
Concept : Equation of line
Solution :
L cut’s equal and non zero intercept then equation of L is
(y – 4) = – (x – 1)
⇒ x+y=5
Final Answer : (B)

54) Explain Question : We have to find area of triangle formed by line and co-ordinate axes
Concept : Equation of line
Solution :
gradient = –2
⇒ (y – 4) = –2(x – 1)
⇒ y + 2x = 6

Δ = |3| |6| = 9 sq. unit

Final Answer : (D)

55) Explain Question : From the given information we have to find values of α
Concept : Angle bisector
Solution :
Diagonals are parallel to the angle bisectors between given lines
∴ Diagonals are
D1 : x + 2y + λ = 0 which passes through (19, 15)
∴ 49 + λ = 0 ⇒ λ = –49

x + 2y – 49, at x = 0, y = = α1
D2 : 2x – y + µ = 0
38 – 15 + µ = 0 ⇒ µ = –23
2x – y – 23 = 0 at x = 0, y = –23 = α2 ∴ 2(α1 + α2) = 49 – 46 = 3
Final Answer : (3)

56) Explain Question : Tangent to circle intersect at P. We have to find locus of P.

Concept : Tangent to circle
Solution :
cotα + cotβ = 0 ⇒ m1 + m2 = 0
equation of tangent is
y = mx +
it passes through P(h, k)
k = mh +

Now, m1 + m2 = 0

xy = 0
⇒ Locus of P is xy = 0 ⇒ λ = 0
Final Answer : (0)

57) Explain Question : We have to find value of given expression

Concept : Basic algebra

Solution :

Hence
Final Answer : (1)