Shell Rimula RT4 15W-40

Version 1.3
Effective Date 12/05/2011

Safety Data Sheet

Chemical Product
1. Identification of the product and the company

Material Name Shell Rimula RT4 15W-40

Recommended use / Motor oil.
Usage Restrictions

Product Code 001C8448

Manufacturer/Supplier Shell Brazil Petroleum Ltd.

Avenida das Américas
4200 - Block 6 - 1st floor (part)
Barra da Tijuca
ZIP code 22640-102
Rio de Janeiro
Brazil

Telephone : +55 (11) 2171-0440

Fax : +55 (11) 2171-0444
Emergency Phone +55 0800 0 251120
Contato de e-mail para a : fale@[Link]
FISPQ

2. Hazard Identification
GHS Classification NOT DANGEROUS

GHS Label Elements

Symbol(s) :
Without symbol
Words of Indication No signaling word

Danger statements PHYSICAL DANGER:

Not classified as a physical hazard under GHS criteria.

HEALTH HAZARDS:
Not classified as a health hazard under the criteria
GHS.

ENVIRONMENTAL HAZARDS:
Not classified as an environmental hazard under the criteria
GHS.

GHS Warnings
Prevention No warning phrases.

Reaction No warning phrases.

Storage No warning phrases.

Discard No warning phrases.

January 9
Print Date 12/05/2011
 Shell Rimula RT4 15W-40
Version 1.3
Effective Date 12/05/2011

Safety Data Sheet of

Chemical Product

Other dangers that are not Not classified as flammable, but burns.
result in
Classification
Prolonged or repeated contact with the skin without cleaning
suitable can clog the pores of the skin, resulting in
disorders such as acne/folliculitis. The oil used may contain
harmful impurities.

3. Composition and information about the ingredients

Description of the preparation Highly refined mineral oils and additives.

Classification of components according to the GHS

Chemical Identity CAS Class of Declarations of Conc.

danger danger
(category)
Alkyl diethylphosphate of 68649-42-3 Eye Dam., 1; H318; H411; 1,00 - 2,40 %
zinc Aquatic
Chronic, 2;
Calcium sulfonate Skin Sensitivity, 1; H317; H413; 0.10 - 0.90 %
Aquatic
Chronic, 4;

UN No. Not applicable.

Additional Information The highly refined mineral oil contains < 3% (m/m) of
DMSO extract, according to IP 346.

Refer to chapter 16 to read the full text of sentences H-.

4. FIRST AID MEASURES

General Information It is not expected to be a health hazard when used in

normal conditions.
Inhalation Under normal conditions of use, no treatment is necessary.
If symptoms persist, seek medical advice.
Contact with the Skin Remove the contaminated clothing. Wash the exposed area with
water and then with soap if available. If it occurs
persistent irritation, seek medical attention.
Contact with the Eyes Wash the eye with large amounts of water. If it occurs
persistent irritation, seek medical attention.
Ingestion In general, no treatment is necessary unless
large quantities should be swallowed, however, obtain
medical guidance.
More Symptoms The signs and symptoms of acne/folliculitis may include
Important/ Effects, In formation of pustules and blackheads on the skin of the areas

2/9
Print Date 12/05/2011
 Shell Rimula RT4 15W-40
Version 1.3
Effective Date 12/05/2011

Safety Data Sheet

Chemical Product
Short Term and Delayed exposed. Ingestion may result in nausea, vomiting and/or
diarrhea.
Immediate medical attention: Provide symptomatic treatment.
special treatment

5. Firefighting measures

Remova todo o pessoal não emergencial da área do fogo.

Specific dangers of Hazardous combustion products may include: A mixture

combustion of products complex of gases and airborne solid and liquid particles
chemicals (smoke). Carbon monoxide. Organic compounds and
unidentified inorganic materials.
Means of Extinction Foam, spray, or water mist. Dry chemical powder, dioxide of
appropriate carbon, sand, or soil can only be used for
small fires.
Extinction Material Do not use jet water.
Inadequate
Protective Equipment: To approach a fire in a confined space,
Precaution for appropriate protective equipment should be used,
Firefighters including self-contained breathing apparatus.

6. Control measures for spills or leaks

Avoid contact with spilled or released material. For guidance in the selection of
personal protective equipment refer to Chapter 8 of this information sheet
chemical product safety - SDS. See disposal information in Chapter 13.
Obey all relevant local and international regulations.

Personal Precautions Avoid contact with skin and eyes.

Protective Equipment
and Procedures of
Emergency
Environmental Precautions Use proper containment to avoid environmental contamination.
Avoid spreading or entering drains, ditches, or rivers
using sand, soil, or other suitable barriers.
Methods and Materials for Slippery when spilled. Avoid accidents, clean up.
Storage and immediately.
Cleaning Avoid spreading by making a barrier with sand, earth.
or another containment material. Recover the liquid
directly or in a tampon. Soak a tampon
como a argila, areia ou outro material adequado no resíduo e
dispose of properly.
Additional Alerts Local authorities should be notified of leaks.
significant ones could not be contained.

7. Handling and storage

3/9
Data de Impressão 05/12/2011
 Shell Rimula RT4 15W-40
Version 1.3
Effective Date 12/05/2011

Safety Data Sheet

Chemical Product

General Precautions Use local exhaust ventilation if there is a risk of inhalation

of vapors, mists, or aerosols. Dispose of properly.
any contaminated cloths or cleaning materials for
prevent fires. Use the information from this form
information as input for a risk assessment of the
local circumstances, to help determine the controls
adequate
Precautions for the Avoid prolonged or repeated contact with the skin. Avoid inhaling the
Safe Handling vapor and/or mists. When handling the product in
drums, safety footwear should be worn and
own equipment.
Conditions for Keep the container hermetically sealed, in a location
Secure Storage cool and well-ventilated. Use identified containers and that
close properly. Storage Temperature: 0 -
50 °C / 32 - 122 °F
Recommended Materials For containers or coatings of these use mild steel or
high density polyethylene.
Inadequate Materials PVC.
Other Advice Polyethylene containers should not be exposed to high temperatures.
temperatures due to the possible risk of deformation.

8. Exposure control and personal protection

If the value of the American Conference of Governmental Industrial Hygienists (ACGIH) is

available in this document is for information only.

Occupational Exposure Limits

Material Source Type ppm mg/m3 Notation

Oil fog, ACGIH TWA 5 mg/m3
mineral Fraction
unbreathable.

Biological Exposure Index (BEI) - refer to the reference for complete details

Data not available.

Engineering Controls The level of protection and the types of control needed will
appropriate vary depending on the potential exposure conditions.
Select controls based on a risk assessment
the local circumstances. Appropriate measures include: A
adequate ventilation to control air concentrations.
Where the material is heated, pulverized, or in the form of
fog, there is a great potential for generation of
air concentrations.
Protection Measures Personal protective equipment (PPE) must

4/9
Print Date 12/05/2011
 Shell Rimula RT4 15W-40
Version 1.3
Effective Date 12/05/2011

Safety Information Sheet

Chemical Product
Individual to obey the recommended rules in the country, which must be
verified with the PPE suppliers. The equipment of
personal protective equipment (PPE) must comply with the regulations
recommended in the country, which should be verified with the
suppliers of PPE.
Respiratory Protection Under normal usage conditions, it is not usually necessary.
respiratory protection. According to good practices of
industrial hygiene, precautions must be taken to avoid
breathe the material. If the engineering controls do not
they maintained air concentrations at a level that is
suitable to protect the health of workers, select
appropriate respiratory protection equipment for the
specific conditions of use that comply with the legislation
relevant. Check with the equipment suppliers
protective respirators. Where the respirators with filters of
If suitable, select an appropriate combination.
with mask and filter. Select a suitable filter for
combination of particulates/gases and organic vapors [point
>65 °C (149 °F) boiling point.
Hand Protection Where hand contact with the product can occur, use
approved gloves according to relevant standards (e.g. Europe:
EN374, USA: F739) made with the following materials can
provide adequate chemical protection: Rubber gloves of
PVC, neoprene or nitrile. The utility and durability of
a glove depends on its use, e.g. frequency and duration of
contact, chemical resistance of the glove material, thickness of the
glove, skill. Always check the recommendations of
glove manufacturer. Contaminated gloves must be
replaced. Personal hygiene is a key element for care
effective of the hands. Gloves should be worn only over
clean hands. After using gloves, hands should be washed and
completely dry. Applying a cream does not
fragrant is recommended.
Eye protection Use protective goggles or a full face mask if available
possibility of splashes.
Skin and sun protection Normally, no skin protection is needed other than the
body normal items of professional dressing room.
Thermal Hazards Not applicable.
Methods of Monitor the concentration of substances in the area of
monitoring breathing of workers or throughout the workplace
it may be necessary to confirm compliance with the LEO
(Operational Exposure Limit). For some substances
biological monitoring may also be appropriate.
Exposure Controls Minimize the release into the environment. It should be done in a...
Environmental environmental assessment to ensure compliance with the
local environmental legislation.

9. Physicochemical properties

Appearance Orange. Liquid at room temperature.

Odor Hydrocarbon level

5/9
Printing Date 05/12/2011
 Shell Rimula RT4 15W-40
Version 1.3
Effective Date 12/05/2011

Safety Data Sheet of

Chemical Product
Odor limit Data not available.
pH Not applicable.
Initial Boiling Point > 280 °C / 536 °F Estimated value(s)
The Boiling Range
Flow point Typical -36 °C / -33 °F
Flash point Typical 230 °C / 446 °F (COC)
Limits of Typical 1 - 10 % (V) (based on mineral oil)
inflammability or
inferior explosions
/superiores
Self-temperature : > 320 °C / 608 °F
ignition
Vapor pressure < 0.5 Pa at 20 °C / 68 °F (Estimated value(s))
Relative Density Typical 0.888 at 15 °C / 59 °F
Density Typical 888 kg/m3 at 15 °C / 59 °F
Solubility in water Negligible.
Solubility in others Data not available.
solvents

Partition coefficient: > 6 (based on information from similar products)

n-octane/water
Dynamic viscosity Data not available.
Kinematic viscosity 109 mm2/s at 40 °C / 104 °F
Vapor density Estimated value(s)
(ar=1)
Speed of Data not available.
evaporation (nBuAc=1)
Temperature of Data not available.
decomposition
Flammability Data not available.

10. STABILITY AND REACTIVITY

Chemical Stability Stable.

Possibility of Reactions: Data not available.
Dangerous
Conditions to Avoid Extreme temperatures and direct sunlight.
Incompatible Materials Strong oxidizing agents.
Dangerous products from It is not expected that hazardous products will form from
decomposition decomposition during normal storage.

11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Base for Assessment The information provided is based on data from

components and in the toxicology of similar products.
Probable Routes of Contact with the skin and with the eyes are the main means
Exhibition of exposure, although exposure can also occur
after accidental ingestion.
Acute oral toxicity Considered of low toxicity: LD50 > 5000 mg/kg, Rat

6/9
Print Date 12/05/2011
 Shell Rimula RT4 15W-40
Version 1.3
Effective Date 12/05/2011

Safety Data Sheet

Chemical Product

Dermal Toxicity Considered to have low toxicity: LD50 > 5000 mg/kg, Rabbit
Sharp
Inhalation Toxicity Under normal usage conditions, it is not considered a danger.
Sharp of inhalation.

Corrosion/Irritation of the Considered slightly irritating. Prolonged contact or

Pele repeated with skin without proper cleaning can block the
skin pores, resulting in disorders such as acne/folliculitis.

Serious Harm/Irritation of Considered slightly irritating.

Eyes
Respiratory Irritation The inhalation of vapors or mists can cause irritation.

Skin Sensitization or It is not expected to be a skin sensitizer.

Respiratory
Danger of aspiration Aspiration is not considered dangerous.

Mutagenicity in It is not considered a mutagenic hazard.

germ cells
Carcinogenicity The product contains mineral oils of the types that have shown to be
non-carcinogenic in animal skin painting studies.
Highly refined mineral oils are not classified.
as carcinogens by the International Agency for
Cancer Research (IARC). The other components are not
known for being associated with carcinogenic effects.

Reproductive toxicity and It is not expected to be a risk.

of development
Specific toxicity of: It is not expected to be a risk.
target organs after
unique exhibition
Target organ toxicity It is not expected to be a risk.
specific - exposure
repeated
Additional Information Used oils may contain harmful impurities that
accumulated during use. The concentration of these impurities
it will depend on the use and may present health risks
environment in disposal. All used oil must be
handled with caution and contact with skin avoided
whenever possible. Continuous contact with motor oil
used caused skin cancer in animal tests.

12. ECOLOGICAL INFORMATION

Evaluation Basis Ecotoxicological data have not been specifically

determined for this product. The information provided
are based on knowledge of the components and of the
ecotoxicology of similar products.

7/9
Print Date 05/12/2011
 Shell Rimula RT4 15W-40
Version 1.3
Effective Date 12/05/2011

Safety Data Sheet of

Chemical Product

Acute Toxicity Slightly soluble mixture. May cause physical pollution of

aquatic organisms. Considered practically non-toxic:
LL/EL/IL50 > 100 mg/l (for aquatic organisms)
(LL/EL50 expressed as the nominal quantity of the product
necessary to prepare the aqueous test extract). Not se
do you believe that mineral oil causes any chronic effects to
aquatic organisms in concentrations lower than 1 mg/l.
Microorganisms Data not available.
Mobility It is liquid under most environmental conditions. It floats in
water. If it enters the soil, it will be absorbed by the particles of
alone and it will not remain mobile.
Persistence/degradation Considered not immediately biodegradable. It is expected
that the main components are inherently
biodegradable, but the product contains components that
they can remain in the environment.
Potential Bioaccumulative Contains components with potential for bioaccumulation.
Other adverse effects The product is a mixture of non-volatile components, which
it is not expected to be released into the air in quantities
significant. It is not believed to have consumer potential
of ozone, photochemical ozone creation potential or
potential for global warming.

13. Considerations on treatment and disposal

Material Disposal Recover or recycle if possible. It is the responsibility of

waste generator determine the toxicity and properties
physical properties of the generated material, to determine the classification and
appropriate disposal methods, in compliance with the
applicable regulations. Do not dispose of in the environment, in
drains or watercourses.
Packaging Disposal Disposal according to prevailing regulations, of
preference with a recognized collector or supplier. A
the competence of the collector or supplier must be established
in advance.
Local Legislation The disposal must comply with laws and regulations.
regional, national and local applicable.

14. Information about transportation

ADR
This material is not classified as hazardous under ADR regulations.

RID
This material is not classified as hazardous by RID regulations.

IMDG

8/9
Print Date 12/05/2011
 Shell Rimula RT4 15W-40
Version 1.3
Effective Date 12/05/2011

Safety Data Sheet

Producto Químico
This material is not classified as hazardous by IMDG regulations.

IATA (there may be variations by country)

This material is not classified as hazardous by IATA regulations.

15. Regulations

It is not intended for the regulatory information to be complete. Other regulations may
it applies to this material.

Situation of Chemical Product Inventories

EINECS All
components
listed or
exempt from
polymers.
TSCA All
componentes
lists.
Sensitizer no Contains calcium sulfonate. May produce a reaction.
sufficient for allergic.
classification

16. OTHER INFORMATION

Danger declarations
May cause an allergic
It can cause
skin reaction
a skin allergic reaction.
H318 Causes serious eye injuries.
H411 Toxic to aquatic life with long-lasting effects.
H413 It can cause lasting harmful effects on aquatic organisms.

Version number of 1.3

Safety Data Sheet
Effective Date of the Safety Data Sheet : 05/12/2011

MSDS revisions A vertical bar (|) on the left margin indicates a

alteration of the previous version.
Safety Data Sheet Regulations The content and format of this Information Sheet
Chemical Product Safety is in accordance with the
requirements of ABNT 14725-1:2009.
Distribution of the Safety Data Sheet (SDS) The information contained in this document must be
made available to everyone who can handle the product
Resignation This information is based on our current knowledge, and
is intended solely to describe the product regarding the requirements
in terms of health, safety, and environment. It should not put
both to be interpreted as a guarantee of any property
specific to the product.

9/9
Print Date 12/05/2011