ANION ANALYSIS
Physical
STEP-1Y State
(like face-powder)
s Powder : Carbonate
icg
Grystalline
Nitrate
reliable
*
not
STEP . 1.
2 Salt +
dil . HzS0q .
Cost (C024)
Effervescence
is :
is Rotten small : So (H2S4)
egg
ii) Brown :
NO (NO M
gas
,
(iv) solourless S (502)
purgent
smell : So
,
smell. whithesulphur
Suffoliating re
stand
forba
sout,solution
- nad /
warmed mayaction
of
gas
.
Test
Step-2
Confirmatory
.
2 :
list - always
with solutiona
If
preliminary
done
salt in water
of OR
Sodium carbonate
↑
extract-the salt
is insoluble in water
Preparation of Sodium sarbonate extract
(i) Take salt and sodium carbonate in 1 : 3
ratio in porcelain
a dish and add 5
mill
:
(in 10 it.
parks
in stir and boil the content . Then cool it,
itter it collect the
filtrate
and
filtrate the carbonate
This is sodium
extract .
(cos)
Confirmatory for
is Carbonate
lime water turns
pass through
· -
milky
.
Nas 203 > Na
-
SOg + H20 +
202
>
H2SOq
-
, -
(salt)
凶
affervesanc .
SaCOHIc 2
+ -
Calos + H20
Clima) Cinsoluble)
if O2 is the milkiness
passed
excess
,
dis
appears
.
Calon
+
cO2 + 420 -
Ca(Hcon)2
(soluble)
* Use
ion
water-solution
of
salt
for carbonate
i
confirmatory for Sulphite (
SO,
dichromaté
in
paper potassim
·
pipa dil .
Haso
green
NazSOz + H2S0q >
-
NazSOg + HeO + SO2
pungent
small .
KryOf +
H2SO4 + 350 >
-
KeSOg +
Cre (only + H20
(green)
3
. Salt + Conc. H2SOn
look a is colorless :
a (404)
gas
is Brown : Br (BV24)
his Violet (21)
-
: I
sus CH3E
Vinegav
:
small (CH3 COOH4)
if is evolved asks
=> I as a
gas
no
.
meducing agent
of
Add +
piece
·
paper
a
ii , Black
coloration
iis Brown
gas : Not
Sofor
t
,
tet
ring
Confirmaliry
stse
foractatrion
iis test
achacotnt +
H2SOn
-
CHycooH +
Nazsoq
testy
(a) spreliminary ·
.
CHzcNH CeNgOH
↓ -
CHzlocH5 + H2
sfruity
small) .
Llike vicks)
(b)
3t
3 Pe 2 H 20
CH3 200 t
^
t D
Snenbral
ferric chlorice Fecls)
(Fee
ナ +
(or) (CH3 cools) + 2H
4 H 20
3(Feg(onl2 (ycoof] +
3cNzcook + h
loon (I1I) dihydroxy acelato
(rown-red ppt .
)
.
ii) test i
Confirmatory
sodium carbonati
of
AgNos Agel
>
-
+
extrate while
Gwrdyppt )
NH90H
γ
Soluble
ii Salt
Guenish-
+ >
-
+
MrOp conc My son
Yellow gsTts
U2
Nacl +
MnOz + MySOn -NazSO ,
Salt 2H20 + ¢2
.
i i
Confirmatory
test
for
ins Sodium carbonat
AgNos Agr
>
-
+
extrate
Ipale-yellow
precipitate)
NHqOH .
very difficulty
in
dissolving
iis Salt MnOz +
HeSOa >
-
-
+ cone . Intense
NaBr
MnOz H2SOn >
-
brow
fumes .
(Salt)
+ +
NazS0 + MrsOq +
H2O + Bra
ritrate (NUz1
Confirmatory fou
iv tet
Salt solution-> corso -
mixed "I cooled under
tap
·
freshly prepared (ferrousFaso
n
Sulphate
· Feson I shoulo be dripped·slowlby along
,
shaking
~
Dark-brown ormed at the
ringthe
is
solutions
junction two .
NaNO3 +
H2SOq >
NaHSOn + HNOz .
(salt)
6FeSOq + 3HeSOa +
2HNOz >
-
Srez(SOals +
4H20 + 2NO
FeSOa + NO >
(Fo(Nol] So a
Nitroso
ferrous sulphate
(Brown-ring) .
4 Test
for Sulphate and
Phosphate
nirmalöry
cony
Original
solution
isdro
-> Add post
t
tes
·
Salt +120
Cdo not use
dry salt)
wbite
ppt
ssentii ,
cone .
He .
√ pPtuble
son
conf
.S
0 . + conc . HzSOg + Δ irmed .
+ 1mL ammonium
sol
Na
, SOq
+ Back -
BaSO4
molybdate (salt) ppty
cwhite2NaCl .
Canary
lamon .
yellow ppt
= like
pool
pos-confirmed .
dissolved whilea
should be completely
* salt
making
CATION ANALYSIS
Prepare transparent
Step-1) a clear and
solution the salt
Order
of solven
Distilled > heat a dil .
sheat
water H¢
heat dil .
< heat <
conc .
HNOz .
HC
( Agua Refine. No1