17-11-2025

4602CJA101801250004 JM

PART-1 : PHYSICS

SECTION-I

1) A length L of flexible tape is tightly wound. It is then allowed to unwind as it rools down a steep
incline that makes an angle θ with the horizontal, the upper end of the tape being tacked down.
Then, the tape unwinds completely in time equal to :-

(A)

(B)

(C)

(D) None of the above

2) A uniform rod AB of mass m and length l is suspended by means of two light inextensible strings
as shown in figure. Tension in one string immediately after the other string is cut is :-

(A)

(B) mg

(C)

(D) 2mg

3) A ball of radius r rolls inside a hemispharical shell of radius R. It is released from rest from point
A as shown. The angular velocity of centre of the ball in position B about the centre of the shell is :
(A)

(B)

(C)

(D)

4) Assuming that the mass m of the largest stone that can be moved by a flowing river depends upon
the velocity v of the water, its density ρ and the acceleration due to gravity g. Then m is directly
proportional to which dimension of velocity :-

(A) 3
(B) 4
(C) 5
(D) 6

5) A triangular set square of negligible mass is suspended freely from the right angled corner and
weights are hung at the two corners. If the hypotenuse of the set square sets horizontally, then the
ratio of the weights W1/W2 is :

(A) 3 : 1
(B) 1 : 3
(C) :1
(D) 1 :

6) A hollow cylinder with inner radius R, outer radius 2R and mass M is rolling without slipping with
speed of its centre v. Its kinetic energy is :
(A)

(B)

(C)

(D) None of these

7) A ring of mass m and radius R has three particles attached to the ring as shown. The centre of the
ring has a speed v0 (there is no slipping). Then kinetic energy of the system is:-

(A)
(B)
(C)
(D)

8) One stick leans on another as shown in figure. A right angle is formed where they meet, and the
right stick makes an angle θ with the horizontal. The left stick extends infinitesimally beyond the end
of the right stick. The coefficient of friction between the two sticks is μ. The sticks have the same
mass density per unit length and are both hinged at the ground. What is the minimum value of tan θ
for which the sticks do not fall? (Take μ = 0.04)

(A) 5
(B) 3
(C) 8
(D) 12

9) The radii of the front and the rear wheel of a carriage is 0.5m and 1m. The horizontal distance
between two axle centres is 3m. A particle of dust driven from the highest point of the rear wheel is
observed to land on the highest point of front wheel. The velocity of carriage is (g = 10 ms–2)
(A) 3 ms–1

(B) 6 ms–1

(C) 3 /2 ms–1

(D) 5 ms–1

10) A sphere of mass m and radius R is kept on a rough horizontal surface and pulled with a
horizontal force F = αt where α is a constant and t is time. The coefficient of static friction is μs and
coefficient of kinetic friction is μ[Link] of the following graph correctly shows the variation of
acceleration of sphere with time ?

(A)

(B)

(C)

(D)

11) A horizontal wheel with buckets on its circumference revolves about a frictionless axis. Water
falls into the buckets at a uniform rate of mass m per unit time. Treating the buckets as small
compared with the wheel, find the angle turned through by the wheel in time t. The moment of
inertia of the wheel and buckets about the vertical axis is I and r is the radius of the circumference
on which the buckets are placed. Initial angular velocity of the wheel system is Ω.

(A)

(B)

(C)

(D)

12)

The moment of inertia about x-axis of uniform thin plate of density ρ kg/m2 as shown in the figure is

, then find the value of N.

(A) 1
(B) 2
(C) 4
(D) 5

13) Velocity and acceleration of a particle at some instant of time are m/s and
m/s . Then, the speed of the particle is .............. at a rate of ............ m/s2. Which of
2

the following sets of information best suits for the blank spaces?

(A) increasing, 2
(B) decreasing, 2
(C) increasing, 4
(D) decreasing, 4

14) A large number of particles are moving each with velocity v having directions of motion
randomly distributed. What is the average relative velocity between any two particles averaged over
all the pairs?
(A) V
(B) (π/4)v
(C) (4/π)v
(D) Zero

15) A ball is projected in the vertical x-y plane from a train moving in horizontal x direction with
constant positive acceleration. The trajectory of the ball as seen from frame of train cannot be :
(Point of projection is origin)

(A)

(B)

(C)

(D)

16) A particle is projected from a point O on the horizontal surface OA with speed u and angle of
projection θ. It just grazes the plane BC which makes an angle α with the horizontal. The time taken
by the projectile to reach P from the instant of projection is, if θ = 2α.

(A)

(B)

(C)

(D)
17) In the given arrangement, mass of the block is M and the surface on which the block is placed is
smooth. Assuming all pulleys to be massless and frictionless, strings to be inelastic and light, R1, R2
and R3 to be light supporting rods, then acceleration of point ‘P’ will be :

(A) 0
(B) ∞

(C)

(D)

18) A particle of mass m is initially situated at the point P inside a hemispherical surface of radius r
as shown in figure. A horizontal acceleration of magnitude a0 is suddenly produced on the particle in
horizontal direction. If gravitational acceleration is neglected, the time taken by particle to touch the

sphere again is

(A)

(B)

(C)

(D) None of these

19) In a water park there is a circular river in which the flow is at a speed u along a circular path. A
small toy beat is steered radially with speed v relative to water. If reaches a diametrically opposite
point B to the other bank in half round (180°). The time to cross the river and reach B is. (r0
is radius of central circle.)

(A)

(B)

(C)

(D) None of these

20) A small mass slides down an inclined plane of inclination θ with the horizontal. The co-efficient
of friction is μ = μ0 x where x is the distance through which the mass slides down and μ0 is a
constant. Then the distance covered by the mass before it stops is:

(A)

(B)

(C)

(D)

SECTION-II

1) Figure shows a bar of mass 'm' moving with a constant speed v0 on horizontal surface around a
semi-circular fence of radius R. The average normal force acting on the bar due to contact with the

fence is given by . Fill the value of α in OMR sheet. Consider all surface to be smooth.
2) Two uniform thin rods A and B of length 0.6m each and masses 0.01kg and 0.02kg respective are
rigidly joined and to end. The combination is pivoted at the lighter end P as shown in fig. such that
it can freely rotate about the point P in a vertical plane. A small object of mass 0.05kg moving
horizontally hits the lower end of the combination and sticks to it. What should be the speed of the
object (in m/s) so that the system could just be raised to the horizontal position?

3) A particle is moving with uniform acceleration along x-axis with initial velocity along positive x.

At the magnitude of displacement becomes the total distance travelled. By this time
the x coordinate of particle is still positive. The instant (in sec) at which displacement becomes zero
is :

4) The small marble is projected with a velocity of 10 m/s in a direction 45° from the y-direction on
the smooth inclined x-y plane. Calculate the magnitude v of its velocity (in m/s) after 2 seconds. Take

g = 10 m/s2.

5) A bird is at a point P (4m, –1m, 5m) and sees two points P1 (–1m, – 1m, 0m) and P2 (3m, – 1m, –
3m). At time t = 0, it starts flying in a plane of the three positions, with a constant speed of 1 m/s in
a direction perpendicular to the straight line P1 P2 till it sees P1 and P2 collinear at time t. Find the
time t. (in s)

PART-2 : CHEMISTRY

SECTION-I

1) Which of the following option is correct :

Time period of electron in the nth orbit for 'H' atom is proportional to n2 (n-principal quantum
(A)
number)
The maximum possible number of spectral lines in visible region when electron jumps from 7th
(B)
excited state to ground state in a 'H' atom are five.
The maximum number of electrons in Cr atom which have set (m = – 1 and s = – 1/2, n ≠ 2) are
(C)
'3'
When 28.6 eV of energy is given to 'H' atom in ground state the debroglie wave length of
(D)
ejected electron is Å

2) For a 3s-orbital, value of ψ is given by following relation, one of radial node may be at radial

distance :

(A)

(B)

(C)

(D)

3) Which of the following is a wrong order with respect to the property mentioned against each ?

(A) (NO)– > (NO) > (NO)+ [bond length]

+ +
(B) H2 > H2 > He2 [ Stability ]
2– ++
(C) O2 > O2 > O2 [ Magnetic moment ]
+ –
(D) NO2 > NO2 > NO2 [ bond angle ]

4)

Number of molecule or ions having lone pairs ≥ 2 for central atom are :
HClO4, HClO3, HClO2, H2O, NH2–1, ClF3, XeF2, XeF4, XeF6, I3–1, N3–1, O3, ICl4–, ICl2+, XeO3, XeF5–1

(A) 10
(B) 21
(C) 25
(D) 30

5) A sample of FeSO4 and FeC2O4 is dissolved in H2SO4. The complete oxidation of sample required
8/3 eq. of KMnO4. After oxidation, the reaction mixture was reduced by Zn. On again oxidation by

KMnO4 required eq. The mole ratio of FeSO4 and FeC2O4 is

(A)

(B)

(C)

(D)

6) Density of water varies with temperature as shown. ;

where = density at t°C and is density at 0°C = 1gm/ml. Calculate % change in molarity and
molality respectively of pure water due to change in temperature from 0°C to 100°C.

(A) 10%, no change

(B) no change, 20%
(C) 20%, no change
(D) 20%, 20%

7) In which of the following reactions, the equivalent mass of the underlined species is equal to its
molecular mass ?

(a)

(b)

(c)

(d)
Correct code is :-

(A) a, c
(B) b, c
(C) a, c, d
(D) a, b, d

8) When a equimolar mixture of Cu2S and CuS is titrated with KMnO4 in acidic medium, the final
product contains Cu2+, SO2 and Mn2+. If molar masses of compounds Cu2S, CuS and KMnO4 are M1,
M2 and M3 respectively then incorrect statement is
(A)
Equivalent mass of Cu2S is

(B)
Equivalent mass of CuS is

(C)
Equivalent mass of KMnO4 is
(D) Cu2S and CuS both have same number of equivalents in mixture

9) Thiosulphate reacts differently with iodine and bromine in the reaction given below:

Which of the following statement justifies the above dual behavior of thiosulphate?

Bromine undergoes oxidation and iodine undergoes reduction by thiosulphate in these

(A)
reactions.
(B) Thiosulphate undergoes oxidation by bromine and reduction by iodine in these reaction
(C) Bromine is a stronger oxidant than iodine
(D) Bromine is a weaker oxidant than iodine

10) 2 mol of He gas is undergoing through following process - work during the process ABCD is –

(A) + 100 R
(B) + 200 R
(C) + 300 R
(D) + 400 R

11)

(A) V
(B) S
(C) – S
(D) –V

12) The given figure shows a polytropic process ABC for one mole of an ideal gas. Calculate the
polytropic index (x) for the process-

(A) 1/2
(B) –1/2
(C) 3/2
(D) None

13) Calculate ΔfHº (in kJ/mol) for Cr2O3 from the ΔrGº and the Sº values provided at 27ºC
4Cr(s)+3O2(g) → 2Cr2O3(s) ;
ΔrGº = – 2093.4 kJ/mol
Sº (J/K mol) :
Sº(Cr, s) =24 ; Sº (O2, g) =205 ;
Sº (Cr2O3, s) = 81

(A) –2258.1 kJ/mol

(B) –1129.05 kJ/mol
(C) – 964.35 kJ/mol
(D) None of these

14) Two blocks of the same metal having same mass and at temperature T1 and T2, respectively, are
brought in contact with each other and allowed to attain thermal equilibrium at constant pressure.
The change in entropy, ΔS, for this process is :

(A)

(B)

(C)

(D)

15) Find the value of ΔrHº for the following process X(g) Y(g), if van't hoff equation for the

same is given as lnKp = 3 – (Assume R = )

(A) 4 kcal mol–1

(B) 2 kcal mol–1
(C) 6 kcal mol–1
(D) 3 kcal mol–1

16)

Fraction of oxygen molecules (dN/N) in the range Umps to Umps + fUmps where f < < < 1

(A)

(B)

(C)

(D) 1

17) The correct set of paramagnetic, polar and planar species is :

(A)
(B) NO, CO, NO2
(C) NO, NO2, ClO2
(D) ClO3, N2O, NO2

18) Which of the following order is correct for Hydrated radius?

(A)
(B)
(C)
(D)

19) The type of overlap in the bridge bond existing in Al2(CH3)6 is :-

(A) sp3–sp3d–sp3
(B) sp3–sp2–sp3
(C) sp3–s–sp3
(D) sp3–sp3–sp3

20) The correct order of increasing C—O bond length of CO, CO32—, CO2 is :

2–
(A) CO3 < CO2 < CO
2–
(B) CO2 < CO3 < CO
2–
(C) CO < CO3 < CO2
2–
(D) CO < CO2 < CO3

SECTION-II
1) For electron is hydrogen atom wave function is given :

Find the ratio of probability density of electron at (r = a0) to the probability density of electron at
nucleus (r = 0).

[Given : = 2]

2) An element undergoes a reaction as shown:

x + e– → x–, energy released = 30.87 eV
If the energy released, is used to dissociate 12 g of H2 molecules, equally into H+ and H*, where H*
is an excited state, in which the electron travels a path length equal to four times it’s Debroglie
wavelength.
Determine the least amount (in moles) of ‘x’ that would be required.
Given: I.E. of H = 13.6 eV/atom, Bond energy of H2 = 4.526 eV/molecule.

3) The number of paramagnetic species among following is ________ .

4) Count the number of pairs in which radius of first specie is greater than the second specie
(H+, H–), (Mg2+, Li+), (F–, O2–), (S2–, Ca2+), (Na+, Al3+), (Cu, Zn), (Y, La)

5) An electron is accelerated from rest, by 'V' volts. Uncertainty in position (Δx) is plotted against
minimum uncertainty in de-broglie wavelength (Δλ) as following -

The value of 'V' is -

PART-3 : MATHEMATICS

SECTION-I

1)

Number of values of x satisfying the equation

(log(1 – x))3 – 6(log(1 – x))2 log(2 + x) + 11log(1 – x)(log(2 + x))2 – 6(log(2 + x))3 = 0
(where base of log is 5)
(A) 3
(B) 4
(C) 5
(D) 6

2)

If then sum of integral values of x is

(A) 30
(B) 45
(C) 35
(D) 40

3)

Let and sin θ + cos θ = . If x + y = , where p & q are coprime then (p + q) is

equal to

(A) 96
(B) 97
(C) 0
(D) 98

4)

If ( + tan kº) = ab (where a is prime & b N), then (b – 13a) is equal to

(A) 0
(B) 1
(C) 2
(D) 3

5)

If α & β are roots of equation x2 – 2x – 7 = 0 and Sr = , for all r ϵ N then is

equal to

(A) 1
(B) 1/4
(C) 7/2
(D) 2/7

6)

Consider three sequences an A.P, a G.P. and a H.P. as follows

a, A1, A2, A3, ........., A9, b (A.P.)
a, G1, G2, G3, ........., G9, b (G.P.)
a, H1, H2, H3, ........., H9, b (H.P.)

If a, b are the roots of the equation x2 – (p + 1)x + 16 = 0, p R, then the value of (ArH10–r G10–r Gr)

is

(A) 416
(B) 64
(C) 49
(D) 412

7)

The value of is –

(A) 1/5
(B) 1/25
(C) 4/5
(D) 24/25

8) If number of solution of

is

(A) 0
(B) 1
(C) 2
(D) 4

9) If (b2 – 4ac)2(1 + 4a2) < 64a2, a < 0, then maximum value of quadratic expression ax2 + bx + c is
always less than

(A) 0
(B) 2
(C) -1
(D) -2
10) Let point 'P' be (5, 3) and a point 'R' on y = x and Q on x-axis such that PQ + QR + RP is
minimum, then co-ordinates of point Q is -

(A) (17, 0)

(B)

(C)

(D)

11) Suppose P is an interior point of a ΔABC with general notation such that the ratio

, (where d(P, AB) denotes perpendicular distance of AB from

'P') then

(A) P is orthocenter and p1 : p2 = 4 :1

(B) P is incenter and p1 : p2 = r : Δ
(C) P is centroid and p1 : p2 = 3 :1
(D) P is circumcentre and p1 : p2 = 4 :1

12)

Coefficient of x65 in expansion of (i + x)i+1 is -

(A) 650
(B) 325
(C) 440
(D) 66

13)

The value of 505C5 – 5. 404C5 + 10. 303C5 – 10. 202C5 + 5. 101C5 is equal to-

101 5
(A) ( C1)
101
(B) C1
201
(C) ( C1)5
101
(D) C5

14)

Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II
 The number of terms in the expansion of ( + 51/4)92, which are integer
P 17
is λ, then λ is equal to
If 540 is divided by 11, then remainder is α and when 22003 is divided by
Q 21
17, then remainder is β, then the value of β + α is
If (8 + 3 )n = α + β, where n and α are positive integers and β is a
R 3 24
positive proper fraction, then (1 – β) (α + β) is
If Tk is the numerically greatest term in the expansion of (3 – 5x)11 when
S 49
x = , then sum of values of k is equal to

(A) P-3 Q-4 R-1 S-2

(B) P-4 Q-3 R-2 S-1
(C) P-3 Q-4 R-2 S-1
(D) P-3 Q-1 R-4 S-2

15) All the pairs (x, y) that satisfy the inequality

also satisfy the equation:

(A) sinx = |siny|

(B) 2|sinx| = 3siny
(C) sinx = 2siny
(D) 2sinx = 2siny

16) If r & s be the positive integers and f(r, s) be the function which gives number of ordered
quadraples (a, b, c, d) of positive integers such that 3r7s = LCM (a, b, c) = LCM(a, b, d) = LCM(a, c,
d) = LCM(b, c, d) then

(A) f(1, 1) = 122

(B) f(2, 1)= 364
(C) f(1, 2) = 364
(D) f(3, 3) = 4489

17) The number of ways in which all the letters of the word 'TANATAN' can be arranged so that no
two alike letters are together

(A) 24
(B) 36
(C) 38
(D) 40

18) The total number of positive integral solution of 15 < x1 + x2 + x3 ≤ 20 is equal to:

(A) 685
(B) 785
(C) 1125
(D) None of these

19) You walk up 12 steps, going up either 1 or 2 steps with each stride. There is a snake on the 8th

step, so you can not step there. Number of ways you can go up is λ then is

(A) 10
(B) 9
(C) 11
(D) 12

20)

If ‘m’ denotes the number of 5 digit numbers when each successive digits are in their descending
order of magnitude and ‘n’ is the corresponding figure when the digits are in their ascending order
of magnitude, then (m – n) has the value

10
(A) 2· C5
10
(B) C4
9
(C) C3
9
(D) C5

SECTION-II

1) Let ABC be a triangle and A ≡ (1, 2), y = x be the perpendicular bisector of AB and x – 2y + 1 = 0
be the angle bisector of ∠C. If the equation of BC is given by ax + by – 5 = 0, then the value of a – 2b
is :

2) The students S1, S2, ......, S10 are to be divided into 3 groups A, B and C such that each group has
at least one student and the group C has at most 3 students. Then if total number of possibilities of
forming such groups is 10P then P is equal to ________.

3) There are 'n' lines in a plane, no two of which are parallel and no three are concurrent. Let the

plane is divided into xn parts then value of is equal to

4) Let an be a sequence such that a1 = 3, an+1 = 3an+1 (n = 1, 2, 3,....). If the value of

(where p and q are in their lowest form), then find the value of

5) Let (xi, yi) for i = 1, 2, 3 satisfies x3 - 3xy2 = 2025 & 3x2y - y3 = 2024, Then find value of
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B C B D B C A A A C C B B C A C C C A A

SECTION-II

Q. 21 22 23 24 25
A. 4.00 6.30 to 6.50 12.00 10.00 7.00

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D C C A B C B D C B A C B C A A C A D D

SECTION-II

Q. 46 47 48 49 50
A. 0.14 6.00 4.00 2.00 75.00

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A B B D B A A C B C C C A C A D C A B D

SECTION-II

Q. 71 72 73 74 75
A. 5.00 3165.00 5.00 07.00 4049.00
 SOLUTIONS

PART-1 : PHYSICS

1)

2)

3)
 4)

Explanation Question:
A largest stone can be moved by flowing river depends on water velocity density and
acceleration due to gravity

Concept:
This question is based on dimensional analysis

Solution:
m = vxρygz
0 0
M1L T = (LT–1)x (ML–3)y (LT–2)z
1=y
0 = x – 3y + z ⇒ x + z = 3y
0 = –x – 2z ⇒ x + 2z = 0
∴x=6

Final Answer :

The correct option is (4)

5)

6)

7)
8)

9)

10)
11)

12)

13)

Speed changes due to tangential acceleration. Tangential acceleration is the component of

acceleration along velocity vector

Therefore speed decreases at 2m/s2.

14)
15)

In x dirn
VBT = Vcosθ – at {Decreasing with time}
(A) Not Possible
{As velocity is decreasing so ball can't cover more distance (x dirn) in second half}
(B) Possible
{As velocity is decreasing so ball can cover less distance (x dirn) in second half}
(C) Possible

If projected velocity of ball w.r.t. train is in opp direction to aBT.

(D) Possible
If VBT becomes –ve when ball is in air only.

16)

17)

F.B.D of the mass M :

T=F
ma = 2T = 2F ⇒ a =

so, acceleration of point P is 2a = (From constraint relation)

18) Let the particle touches the sphere at the point A.

Let

In

or

But

19)

20) (mg sin q) x – dx = 0

sinθ x = m cosθ
x tanθ = μ0 , x=

21)

<F>=m<a>

= =

22) Angular momentum conservation about hinge and work energy theorem.

23)
t1 + t2 = t

⇒ t12 + (t – t1)2 =

⇒ t1 = 6 for t =
so answer is 2t1 = 12

24)
T = 2 sec
or particle will strike plane at 2 sec
Hence speed will be 10 m/s

25) Let bird flying along PQR

component of PP1 along P1P2 (PP1x)

 = =1

and =
From triangle PP1 Q
50 = (1)2 + (PQ)2
PQ = 7m

time = = 7 s
Ans. 7 s.

PART-2 : CHEMISTRY

26) (1)

The maximum number of electrons in Cr atom which have m = – 1 and s = – 1/2

where n ≠ 2 are '2' i.e., one electrons from 3p (m = – 1, s = – ) and one electron from 3d (m =

– 1, s = – )
(4)

27)

σ2 – 6σ + 6 = 0

are roots
28) NO– > NO > NO+ (bond length)
Bond order 2.0 2.5 3

H2 > H2+ > He2+ (stability)

Bond order 1 0.5 0.5
(more antibonding)

NO2+ > NO2 > NO2–

Bond angle 180° 133° 115°

O22– = O22+ < O2 (magnetic moment)

No. of unpaired e–
0 0 2

29)

Fact Based

30)
Number of eq. of FeSO4 + Number of eq. of FeC2O4 = number of eq. of KMnO4

...(1)

By solving (1) and (2),

and

31) For molarity

20% decrease in molarity

32)

Fact Based

33) Cu2S —→ Cu2+ + SO2

nF = 8
CuS —→ Cu2+ + SO2
nF = 6

34) (Change in O.N. of S = +2 to +2.5)

(Change in O.N. of S = +2 to +6)
Br2 is a stronger oxidising agent than I2.

35) =– nRΔT = –nR × 100 = – 2 × R × 100 = – 200 R

=0
= – nRΔT = + nR × 200 = 2 × R × 200 = + 400 R

36)

Fact Based

37)

TA = 600K, VA =1L
PA × VA = 1 × RTA
PA = 600R
TB = 300K
VB = 4L
PBVB = 1×R×300

PAVAx = PBVBx
(600R)(1)x = (75R)(4)x
600R´1 = 75R´ (4)x
x
4 =8
22x = 23
2x = 3

38)

ΔrGº = ΔrHº – T × ΔrSº

ΔrSº = 2 × 81 – 4 × 24 – 3 × 205 J/mol
∴ ΔrHº = – 2258.1 kJ/mol
ΔrHº = 2 × ΔfHº (Cr2O3, s)

∴ ΔrHº (Cr2O3, s) = –
= – 1129.05 kJ/mol

39)
40) ⇒ ΔrHº = 4000 cal

41)

Fraction of oxygen molecule in the range Umps to Umps + fUmps +

42)

Fact Based

43) Li+ has highest degree of hydration.

44) In Al2(CH3)6 each carbon is sp3 hybridised and each Al is also sp3 hybridised.

Therefore Al and carbon will use sp3 hybridised orbitals in the overlapping during bridge bond
formation.
Thus bridge bond Al–C–Al will be formed by sp3–sp3–sp3 overlapping.

45) CO CO2 CO32–

B.O. = 3 2 4/3

Bond length ∝

46) Question Explanation: Ratio of

Concept : This question is based on Schrodinger wave equation.

Solution:
Probability density = ψ2
 0

ψ at(r = a ) =
2

ψ2at(r = 0) =

Final Answer = 0.14

47)

(i) H – H H+H
Now After dissociation of Bond
One process is H → H+ + e–
Second process is H → H* (excitation)
Both process equally happened
Now e– travels a path of 4 time of debroglie wave tength i.e. n = 4
So H-atom Excitation Energy Required for 4th shell Excitation
is ΔE = 13.6 – 0.85 = 12.75 ev
Total 12 g H2 Molecules i.e.

mole H2 molecules
Now Assume a mole "X" used
So total energy released = a × NA × 30.87
Now This Energy used in whole process
So total Energy of process is equal to released energy.

a × NA × 30.87 =
∴ a × NA × 30.87 = 6 × NA × 4.526 + 6 × NA ×13.6 + 6 × NA × 12.75
⇒ a = 6 moles

48)

Fact Based

49) (S–2, Ca+2), (Na+, Al+3) pairs have radius of first specie greater than the second specie.
 50)

PART-3 : MATHEMATICS

51)

52)
53)

54)
55)

56)

57)
58)

59)

60) Let A and B are images of (5, 3) about line y = x and x-axis
∴ A(3, 5) and B(5, –3)
Equation joining AB is y + 3 = –4(x – 5)

& is

61) ∴
Similarly

∴ Area of ΔABC = Ar(ΔAPB) + Ar(ΔBPC) + Ar(ΔAPC)

∴ d(A, BC) = 3d(P, BC)

ar(ΔAPB) = ar(ΔBPC) = ar(ΔAPC) =

∴ P is the centroid

62)

63)
64)
65)

66)
Case Exactly 3 gets r & other can be filled with 1, 2, ........r - 1.

67)

A — A — A
Separate A's by gap method

...(1)

A — A — A N N
 ...(2)

(1) – (2) ⇒ A – A –A and N – N = 60 – 12 = 48

T T A – A –A

...(3)

T T A – A –A N N

..(4)

(3) – (4) ⇒ T T A – A –A N N
12 – 2 = 10
⇒ 48 – 10 = 38

68)

15 < x1 + x2 + x3 ≤ 20
⇒ x1 + x2 + x3 = 16 + r, r = 0, 1, 2, 3, 4
13+r+3–1
Now, the number of positive integral solutions of x1 + x2 + x3 = 16 + r is C13+r, i.e.,
15+r
C13+r = 15+rC2.
Thus, the total number of solutions is

= 685

69)

Let an denote number of ways in which you can walk n-steps going either 1 or 2 steps with
70)

n = 9C5

71) Here, B is the image of A w.r.t. line y = x

∴ B ≡ (2, 1) and C is the image of A w.r.t. line x – 2y + 1 = 0

If C ≡ , then or and

Equation of BC is

or 3x – y – 5 = 0 ( Eq. of BC is ax + by – 5 = 0)
Here a = 3, b = – 1 ∴ a – 2b = 5
72)

73)

74)
75)