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Short Notes Maths

The document discusses various thermodynamic processes involving ideal gases, including adiabatic and isothermal expansions, and their associated heat capacities and enthalpies. It presents problems related to the heat of combustion, enthalpy of neutralization, and the relationship between thermodynamic quantities. Additionally, it includes assertions and reasoning regarding enthalpy changes and the heat of formation for specific substances.

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46 views10 pages

Short Notes Maths

The document discusses various thermodynamic processes involving ideal gases, including adiabatic and isothermal expansions, and their associated heat capacities and enthalpies. It presents problems related to the heat of combustion, enthalpy of neutralization, and the relationship between thermodynamic quantities. Additionally, it includes assertions and reasoning regarding enthalpy changes and the heat of formation for specific substances.

Uploaded by

aarohisri2802
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF or read online on Scribd
21, 22. One mole of an ideal monoa Teversible proc: given figure: itomic gas undergoes two s (A > B and B > C) as shown in the [JEE Ady 2023] Temperature (K) Volume (m*) A — B is an adiabatic process. If the total heat absorbed in the entire process (A — B and B — C) is RT, In 10, the value of 2 log V, is _ 1 [Use, molar heat capacity of the gas at constant pressure, Com = 5/2R] An ideal gas undergoes a reversible isothermal expansion from state | to state II followed by a reversible adiabatic expansion from state II to state III. The correct plot(s) representing the changes from state I to state III is (are) (p:pressure, V:volume, T:temperature, H:enthaln’ © era state. 23. One mole of an ideal gas at 900 K, undergoes two reversible processes, I followed by II, as shown below. If the work done by the gas in the two process are same, the value of In i V; SS [JEE Adv 2021] f the Vy oy (U: internal energy, S: entropy, P: pressure, V: volume, R: gas constant) cao (Given: molar heat capacity at constant volume, C,,,, of the 5 gas is —R) 2 7 ae a kJ respectively is - _! V ekTs a {04 April, 2024 (shift-D] 7. Given below are two statements: One is labelled as Assertion (A) and the other is labelled as Reason (R) Assertion (A): Enthalpy of neutralisation of strong monobasic acid with strong monoacidic base is always 57 kJ mol! Reason (R): Enthalpy of neutralisation is the amount of heat liberated when one mole of F I' ions furnished by acid combine with one mole of OH ions furnished by base to form one mole of water. In the light of the above statements, choose the correct answer from the options given below. [05 April, 2024 (Shift-D] (a) (A) is true but (R) is false SPY Both (A) and (R) are true and (R) is the correct explanation of (A) (c) (A) is false but (R) is true (@) Both (A) and (R) are true but (R) is not the correct explanation of (A) 28. The heat of combustion of solid benzoic acid at constant volume is -321.30 kJ at 27°C. The heat of combustion at constant pressure is (321.30 —xR) kJ, the value of x is [05 April, 2024 (Shift-1)] 29. Combustion of 1 mole of benzene is expressed at 1 CoHe(l) + Boxe) — CO,(g) + 3H20(/) ‘The standard enthalpy of combustion of 2 mol of benzene is kK. ree (1) Standard Enthalpy of formation of | mol of CH), for the reaction 6C(graphite) + 3H,(g) 7 © [05 April, 2024 (Shift-ID] oH) is 48.5 kJ mol! a 33. 34. ase 36. QT NC a ore 12% ‘olume ui 19,/An thermodynamics the p Vv (my (a) P A WM w=—fave,,. Work done is given by aoe v e” For a system under, Oi gemenee Ff Song a particular Process, the work t uu RT ye | = ‘| J vane [JEE Ady 2020] 1 Mi Eohes This equation is applicable to a: s YS System that satisfies the van der Waals equation of state. 23. One mole of an ide: Process that is reversible and isothermal. processes, | follow Ay ‘ocess that is reversible and adiabatic. done by the gas in| a 20. Fora rocess that is irreversible and at constant isothermal. V sé diatomic ideal gas ina closed system, which of the | V3 following plots does not correctly describe the relation | w: intra ens between various thermodynamic quantities: | R: gas constant) ray tan 2010 (Shift-DI | (Given: malar hea 4 i 3 % An ideal gas undergoes isothermal compression from 5 m gt. While performing a 4, made the following HCI + NaOH - y, CH,COOH + NaOH ~ CH. The enthalpy of joni, the student is MEAS: hermodyn; ‘amics experiment, as servation, a aCl +10 AH 57.3 kJ mol! sCOONa +H. 0 AH =-55.3 kJ mot! ation of CH. 3COOH as calculated by | — kJ mot - (Nearest integer) [25 July, 2022 (Shitt-11)) At 298.2 K the relationship b, ceca KI mol fei? between enthalpy of bond ) for hydro; EI deuterium (ED), is best described by: a iim ies July, 2021 (Shift-I] ED (6) & (2) Ey=2E, d) E, of the final solution is aoe (Round off to the Nearest Integer). [Use: H* (aq) + OH (aq) > H,0 : AH =-57.1 kImol-] Specific heat of H,O = 4. 185K ig! Density of H,O = 1.0 gem [Assume no change in volume of solution on mixing] [27 July, 2021 (Shift-I1)] 4, Lattice enthalpy and enthalpy of solution of NaCl are 788 kJ mol and 4 kJ mol", respectively, The hydration enthalpy of NaCl is: [5 Sept, 2020 (Shift-I1)] (a) 784 kJ mol! (b) -784 kJ mol! | (c) 780 kJ mol (d) ~780 kJ mol ! | 41. The standard heat of formation(A,H®,,) of ethane (in ki/mol), if the heat of combustion of ethane, hydrogen and graphite are ~1560, -393.5 and -286 kJ/mol respectively is : {7 Jan, 2020 (Shift-I1)] to | m3 against a constant external pressure of 4 Nm, Heat released in this process is used to increase the temperature of . rie 1 mole of Al. If molar heat capacity of Al is 24 J mol! K, 44. ( 45. 46. 47. 48. 49. 50. ; TRIGONOME TRIC ‘ EQUATION Be, aud canting, weapacoit4 | S wae * ete, Guava OluLLOws gh TE Pp Aout squasang yoo = go | dD SOL: Wut congter fy qvocct camcetralion |Germelityy en | =] it muplt sol: O Lo, ot Fy Qowunir,, Range eed 100 w | Pascticul gol: © unr ginern cinthval | Nove mul SOLLLLOK fe Q Se re | no of SOL = NO Of | ua beaut oh dents WY Sa O= Seael Pe o aa 4 SraquolLon CO quad. 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