Atomic Structure

. In absence of Pauli exclusion principle, the i 11. The elements in which electron enters to 3d
electronic configuration of-Li in ground statee orbitals have their atomic number from:
may be:
(a21 to 30 (b) 21 to 29
(a) 1s2, 2s (b) 1s3
(c) 21 to 31 (d) 21 to 32
(c) 1s', 2s2 (d) 1s2, 2s 2p
2 The sub atomic particle not found in the |
12. For an atom with atomic number-14, the
nucleus is: number of orbits and orbitals in which
(a) Neutrons (b) Protons electrons are present respectively are
(c) Electrons (d) None (a)3,6 (b)6,3
3 The number of
electrons in HD* ion is (c)7,3 (d) 3, 8
(a) 1 (b) 2 (c) 3 (d) 4
13 H has two natural isotopes of ,H' and ,H2
A. The missing particle in the reaction, and O has two isotopes O16 and O18. Which

N14+? 017+,H is of the following mol. wt. of H,O will not be

(a)n (b),He4 possible ?

(c)e (d) (a) 19 (b) 20

(c) 24 (d) 22
A and
5. AXan
emission Y-10B-32,
the number of a
and B emitted are 14. Which one is odd man ?
(a) 8a and 6 (b) 6a and 7ß (a) 4f (b) 5d
() 5a and 8 (d) 7a and 10ß (c) 3s (d) 6p
6 During neutron transformation, the particles I 15 The values of m for 3d,, are
ejected out are (a)-2 (b)+2
(a) ,p (b)n (c)e (d).e (c) Both (a) and (b) (d) None
1 Which does not exist ?
(a) 1C35 (b) O18 16 Nucleus always contains:
(d) (a) Neutrons(n) (b) Electrons (e)
(c),H3 (c) n and pP (d) Proton (p)
Heavy water molecule made from ,H and|
of 17 If n and I are respectively the principal and
08 has a mol. wt.
(a) 18 (b) 20 (c) 22 (d) 24 azimuthal quantum numbers, then the
The possible form of H, molecule on the i expression for calculating the total number
9
basis of three isotopes can be; of electrons in any energy level is
(c) 8 (d) 19 =n
(a) 3 (b) 6 =n-1
(a) 22(21+1) (b) =121+
10. The atomic orbital not allowed in quantumi
theory is : =n+1 =n-1
(a) 1s (b) 2p (c) 3f (d) 5 (c)22(21+1) (d) 22(21+1)
18. When a polyelectronic atom has a total spin | 24. In how many elements does the last elec-
tron have the quantum numbers of n = 4 and
s , it gives rise to (2s+ 1) spin quantum
states, known as spin multiplicity. what is the 1?
spin multiplicity of nitrogen atom in its ground (a)4 (b)6 (c) 8 (d) 10
state?
25. Which electron configuration is not allowed
(a) 4 (b) 3
for either a neutral atom or an ion in its ground
(c) 2 (d) 5
state ?
A 5g orbital has (a) 1s2 2s2 2p3
19
(a) zero angular node and zero radial ñode (b) 1s2 2s2 2p
(b) zero radial node and two angular nodes (c) 1s2 2s 2p 3d5
(c) 4 radial nodes and 4 angular nodes ( 1s2 2s2 2p 3s2 3p 3d3
(d) zero radial node and 4 angular nodes
26 An orbital in an atom is represented by quan
The number of radial nodes and the value of tum number (s)
20 (a) n
orbital angular momentum of the 28th elec- (b) n and
tron added in Ni(28) atom are respectively (c) n, f and m (d) n, f, m and m,

(a) 1 and v2 h/2T 27. Hund's rule deals with the distribution of elec-
(b) 2 and 6 h/27t trons in
(a) quantum shell
a
(c) zero and 6 h/2
(b) an orbit
(d) zero and v2 h/2t (C) an orbital

Which of the pair of orbitals have electronic (d) degenerate orbitals

21
density along the axis 28. Which of the following orbitals has zero prob-
ability of finding the electron in yz plane?
(a) [Link] (b)dyd
(a) Px (6) Py (c) P2 (d) dy
(C) dy dyz (d) dxy d
29. Non-directional orbital is:
22. Which of the following pair of electrons (c) 4 d (d) 4 p
(a) 3s (b) 4 f
excluded from an atom ?
(a) n =
2, l= 0, m =
0, s =
+% and n 2, f =
30 Suppose a completely filled or half filled set
0, m = 0 , s = +% of p or d-orbitals is spherically symmetrical
(b) n 2, l= 1, m =+1, s =+% and n =2, Point out the species which is spherical sym-
metrical:
=
1, m= -1, s =
+%
+% and n 1, =| (a) O (b) C (c) Ci (d) Fe
(c) n 1, I=0, m =0, = =
s

0, m = 0, S = * *
Which one of the following diagrams is in
d)n=3, I =2,m =-2-s =+%and n =3, 31
accordance with Hund's rule:
0 , m =0, s* +
(1L
23 What would be the expected magnetic mo-
ment in Bohr magnetons for atoms with 1 L
atomic numbers 26 and 32 ?
(a)4.9;2.42 (b) 2.83; 2.42
(c) 4.9; 2.83 (d) 3.87; 2.42
 The total pin resulting from a d configura- | 39 The correct set of quantum numbers of the
tlon ls outermost electron of the potassium atom is
a) 1 (b) 2 (c) 5/2 +1/2 (b) 4, 1, 0, +1/2
(d) 3/2 (a) 3. 2, 2,
1, +1/2
(c) 4, 0, 0, +1/2 (d) 4, 1,
33 Which of the following electronic configura- |
tions of oxygen atom does not have same The nucleus of CI contains
energy as
40
(a) 35 protons and 17 electrons.
(b) 35 neutrons and 17 protons.
(c) 17 protons and 18 neutrons

( (d) 17 protons and 17 neutrons.

The maximum number of electron in atom
t 41
that can have the value for its [Link]-
an

bers as n = 4, I= 3 and s = +1/2 is

(d) 14
(a) 5 (b)7 (c) 9
( 42 Which ot the following sets of quantum
An atom has a mass of 2Z+ 12, where Z is numbers is not allowed ?
the number of extra-nuclear electron in the
(a) n =
3, /= 1, m = +2
atom, then the number of neutrons in the (b) n = 3, /= 1, m = +1
nucleus is
(c) n =
3, /= 0, m =0

(a) Z (b)Z+6 (d) n= 3, / = 2, m =t2

) Z+ 12 (d) 12.
43 The energy of electrepin Li2* species de-
35. Which among the following pairs is iso
pends on
conelectronic?
(a) Principal quantum e r
(a)Arand Ca2 (b) K and Ca2 (b) principal and Azituthal quantum
(c)Ar and K (d) Ca and K
numbers
number determines (c) principal, Azimuthal and magnetic quan-
36 Theprincipal quantum
tum numbers
(a) shape of the electron cloud
(b) the orjentation of electron around the || (d) principal, Azimuthal, magnetic and spin
quantum numbers
nucles
distance of the
(c) energy and probable 44 The angular momentum produced by the
elecron from the nucleus
spin of electron is given by
(d) none of these
h 3 h
31 The maximum pumber of electrons
n3 and I3 is
wit:
(a)27 ()2
(a)14 (6).10
(c) 6 (d) 0 (d) 27t

Atoms with same mass but having differert 45 The number of orbital in a sub-shell is equal
nuclear charges are
to
(a) Isobars (b) Isotones (a) n2 (b) 2/
( lsotopes (d) Isochores (d) m
(c)2/+1
46) Thepossible set of quantum numbers for the 53. Which of the following represent the correct
lastelectron of Gallium atom (Z = 31) in its set of four quantum numbers of a 4d
ground state is electron ?
m S (a) 4, 3. 2, +1/2 (b) 4, 2, 1 +1/2
(a) 1 +1/2 (c) 4, 3,-2, +1/2 (d) None
(b) 4 0 0 -1/2
(c) 3 2 +2 +1/2 b54 A 3d electron having s =
+1/2 can have
(d) 3 0 -1/2 magnetic quantum number
(a) +2 (b) +3 (c)-3 (d) 4
47 The maximum number of electrons possible
in sub level is equal top 55, Which set of quantum number represents
(b) 2n2 the electron of lowest energy
(a)2/+1 (a)n =2, I = 0, m = 0, s = +1/2
(c) 2P (d)4/+2 (b) n = 2, I= 1, m =0, s = *1/2
The maximum number of atomic orbitals (c) n = 4, 1= 0. m = 0, s = +1/2
associated with a principal quantum (d) n = 4, /= 0, m =0, s = -1/2
number 4 is
56 The electron idintified by quantum numbers
(a) 9 (b) 12 (c) 16 (d) 18 n and /.

49 (1) n = 4, /=T (2) n

The correct set of quantum number for the
(3) n = 3, I = 0
=4,1=0 -

unpaired electron of chlorine atomis (4)n=3, l=1

can be placed in order of increasing energy
(a) n 2 , l = 1, m = 0 (b) n = 2.11, m =0
from lowest to
highest
(c) n = 3,=1, m = 1 (d) n 3, L= 0, m =0 (a) iip*(iv)<(i)<() (b) (i)<(iv)<(i)<(ii)
(c) ()<(ii)<(i)<(iv) (d) (ii))<(iv)<(i)
50 A transition element X has
configuration(Ar)d in its +3 oxidation state. 57 Which orbital has two
angular nodal planes
Its atomic number is (a) s (b) p (c) d (d)f
(a) 22 (b) 25 (C) 26 (d) 19 58. Which have the same number of s-electrons
51 The statement which is/are correct as the d-electrons in Fe2*
(a) Number of total nodes in an orbital = (a) Li (b) Na (c) N (d) P
(n-1). 59 Which ion has the maximum
(b) Number of radial nodes in an orbital =
moment
magnetic
n-/-1
(a) Mn3 b)Cu2 (c) Fe3 (d)v3
(c) Number of angular nodes in an orbital =
Ad) All 60 Predict the total spin in Ni2* ion
(a) +5/2 (b) £3/2 (c) 1/2 (d) 1
52 Which
ment
represents an impossible arrange
61 The number of electrons in
phosphorous
m S atom having n+/= 3?
(a) 3 2 -2 1/2 (a) 2 (6) 4 (c) 6 (d)'8
(b) 4 1/2 which atóm contains an electron
(c) 3 2 3 1/2 with
quantum numbern 3, =
2, m = -1,
(d) 5 3 0 1/2 S-1/2
(a) Ne (6) Co (c) CI (d) K
 A compound of Vanadium has a magnetic 72. Which of the following has more number of
moment of 1.73 BM. Find the
configuration of Vanadium ion in the
electronic 1 unpaired d-electrons
(a) Zn2 (b) Fe2 (c) N3 (d)Cu
compound ?
34. Find the orbital angular momentum of
[Link] configuration of calcium atom may
a
an be written as
electron in the following orbital:
(a) 3p
(a)[Nej2s2 (b) [Ne]3s2
(b) 3d (c)3s (d) 4d (d)[Xe]Bs
(c) Arl4?
65. Arrange the electrons represented by the 74 An electron has magnetic quantum number
following sets of quantum bumber in as-3what is its principal quantum number?
decreasing order of energy. (a) 1 (b) 2 (c) 3 (d) 4
(a) n =4, l=0, m = 0, s = +1/2
(b) n 3,1= 2, m = 0, s = -1/2 I 75. Which of the following explains the sequence
(c) n = 3,l= 1, m = 1, s = -1/2 of filling of the electrons in different shells ?
(d) n = 3,I= 0, m =0, S = -1/2 (a) Hund's rule (b) Octet rule
(c) Aufbau principal (d) All of these
66. How many 7s electrons are there in an atom
with Z 104 ? 76.
76. Magnetic quantum number specifies
(a) size of orbitals
67 If X species emity firstly a positron,
then (6) shape of orbital
two a and two ß and in last one a is also (c) nuclear stability
emitted and finally converted in dY species (d) orientation of orbitals
so correct relation is

(a) c = a -5, d = b - 12 77. The number of electrons in 19K is

(b) c = a - 4 , d = b - 12
(a) 18 (b) 19 (c) 20 (d) 40
(c) c a-6, q= b-8
(a) c a-5, d = b-8
78 Aufbau principle is obeyed in which of the

68. The given quantum numbers are possible for

following electronicconfiguration?
(a) 1s2 2s2 2p (b) 1s2 3s2 3p3
howmany orbitals n =3, /= 2, m = +2?
(c) 1s2 3p3 3s2 (d) 1s22s 3s2
(a) 1 (b) 2 (c) 3 (d)4

69 Which of the following is not paramagnetic 79 The electronic configuration of Gadolinium

(Atomic Number = 64) is
(a) N (6) N
(c) CO (d) NO
(a) [Xej41® 5d® 6s2 (b) [Xe]4f 5d5 6s2
(a) [Xe]4f 5d2 6s2 (b) [Xe]4f7 5d' 6s2
Number of neutrons in a parent nucleee X, an
The maximum number of electrons in a
which gives ,N14 nucleus after twa subshell corresponding to the Azimuthal
successive B-emmission would be
(a) 9 (b) 8 quantum number |=3 would be
()7 (d)6
(a)6 (b) 14 (c) 2 (d) 10
Among the following which one is. not1
81 The principle that no two electrons of an atom
paramagnetic?
(a) Cl have the same set of four quantum numbers
(b) Be was first
() Ne2 (d)As proposed by
(a) Dalton (b) Pauli
 (c) Einstein (d) Avogadro 90 The atomic number (Z) of an element is 25.
In its
ground state how many
After the emission of one a - particle followed electrons are
82 present in the N - shell ?
by B-particle from the atom of 256Xg2 the
(a) 13 (6) 2 (c) 15 (d) 3
number of neutrons in the atom will be
(a) 148 (b) 146 91. Rutherford's a-particle scattering experiment
(c) 144 (d) 143 proved that atom has
Which one of the following is not isoelectronic (a) electrons (b) neutrons
83.
with O-2 ?
(c) nucleus (d) orbitals
(a) N3- (b) Ti (c)F (d) Na 92. Which of the following has maximum
number of unpaired electrons (atomic num-
84. Ifan isotope of hydrogen has two neutrons berof Fe is 26)?
in its atoms, its atomic number and atomic
(a) Fe (b) Fe(i)
mass number will respectively be
(a) 1 and 1 (6) 1 and 3 (c) Feçii) (d) Fe(iv)
(c) 2 and1 (d) 3 and1 Which of the following quantum numbers is
not possible ?
85 The order of illing of electrons in the orbitalss | (a) n 3, I= 2, m - 2 , s = +1/2
of an atom will be
(b) n = 2, I = 0, m 0, s = +1/2
(a)4s, 3d, 4p, 5s, 4d (b) 3d, 4s, 4p, 4d, 5s
(c)n = 3, / = 2, m =-3, s = +1/2
(c)4s, 3d, 4p, 5s, 4d (d) 3d, 4p, 4s, 4d, 5s (d) n = 2,/= 1, m =-1, s = -1/2
o 86. Which of the following oxides of nitrogen is |.94 The last three electrons of nitrogen differs in
paramagnetic (a) n (c) m (d)s
(b)
(a) NO (b) N,O5
(c) NO, (d) N,O3 95. Which of the following is isoelectronics and

87 The oribital diagram in which the Aufbaul isostructural NO, Co, CIO;,sO
principle is violated (a) [Link] (b) SOg. NO
(c) Co SO, (d) NO CIO;
96. The electronic configuration of an element is
1s2 2s 2p 3s 3p5 3ds 4s'. This represent
88 The number W,X,Y and Z of a naturally | its
Occuring series are related as (a) excited state (b) ground state
(C) cationic form (d) anionic form
wW- x Y-2.
The isotopes among the above are 97. Which of the following has maximum
(a) Y &Z (b) W &XK magnetic moment
(c)X &Z (d) W& Z* (a) Mn2 (b) Fe2 (c) Ti2 (d) Cr2
The radius of an atomic nucleus is generally98 Which of the following is violation of pauli's
89
expressed in únits of exclusion principle
(b) Coulomb
(a) Debye
(c) Fermi (d) Tesla (aUN
 99 the orbital diagram in
which have no classical analogue.
is violated is
Aufbau principlee
[Link] the nitrogen atom had electronic
configuration 1s', it would have lower energy

than that of the normal ground state

configuration 1s2 2s2 2p3 because the
100 The quantum number not obtained from the electrons would be closer to the nucleus
schrodinger wave equation is Yet, 1s7 is not observed because it violates.
(a) n (b) (c) m (d) s (a) Heisenberg uncertainty principle
(b) Hund's rule
101 The outer shell
configuration of most (c) paulis exclusion principle
electronegative element is
(a) ns2 np3 (d) Bohr postulate of stationary orbit
(b) ns2 np4
(c) ns nps 108 Rautherford's experiment which established
(d) ns np5
the nuclear model of the atom, used a beam
102. Which combination of quantum
numbers n, of
, m, s for the electron in an atom doesnot
(a) B-particles, which impinged on a metal
provide a permissible solution of the wave
foil and got absorbed.
equation?
(b)y-raýs which impinged on a metal foil and
(a) 3, 2,-2, 1/2 (6) 3, 3, 1,-1/2 ejected electrons.
(c) 3, 2, 1, 1/2 (d)3,1,1, -1/2 (C) helium atoms, which impinged on a metal
103. Pick out isoelectronic structures from the foil and got scattered.
|
following (d) helium nuclei, which impinged on a metal
(i) CH, (ii) HO* (ii) NH (iv) CH foil and got scattered.
(a) i) & (i) (b) (i) & (iv)
109. Any p-robital can accordate up to
(c))& (i) (d) (n), (i) & (iv) (a) four electrons
104 The orbital angular momentum of an | (b) two electrons with parallel spin
electron in 2s orbital is (c) six electrons
(d) two electrons with opposite spin
(a) 2 2T (b) zero
() ()2
v22T110 A3p-orbital has
nodal (a) only one plane no spherical node
105
105p An element has an atomic mass 19 and
(b) only one spherical node and no nodal
atomic number 9, its ion is represented by
(c) m- (d) m2-
plane
(a) m* (b) m c) one nodal plane and one spherial node
106/ The quantum number +1/2 and -1/2 for (d) one nodal plane and two spherical nodes.
electron spin represents
| 111 Which d-orbital has its four lobes
along the
(a) rotation of electron in clockwise and
axis
anticlockwise direction respectively
(a) dy (b) Oyz
6)rotation of elecrton in anticlockwise and
clockwise direction respectively. (c) dx d)
(c) magnetic moments electrons pointingg
up and down espectively.
(d) two quantum mechaical spin states which