02-12-2025

4602CJA101821250021 JM

PART-1 : PHYSICS

SECTION-I

1) Four Ts are made from two identical rods of equal mass and length. If I represents the moment of
inertia about the axis shown in figure.

(1) (2)

(3) (4)

(A) Ι1 > Ι4 > Ι2 > Ι3

(B) Ι1 > Ι2 > Ι4 > Ι3
(C) Ι1 > Ι2 > Ι3 > Ι4
(D) Ι1 > Ι3 > Ι4 > Ι2

2) The linear speed of a homogeneous solid sphere after rolling down an inclined plane of vertical
height h, from rest without sliding is :-

(A)

(B)

(C)

(D)

3) A small disk is attached to the end of a light inextensible string, which passes through a hole in a
frictionless horizontal tabletop. Initially the disk moves on a circle of radius R with kinetic energy K0.

The string is then slowly pulled so that the disk finally rotates on a circle of radius What is the
work (W) done in pulling the string?

(A) W = η K0
2

2
(B) W = (η – 1)K0
(C) W = (η – 1)K0
(D) W = 0

4) A ring of mass M and radius R is rotating about its axis with angular velocity ω. Two identical
bodies each of mass m are now gently attached at the two ends of a diameter of the ring. Because of
this, the kinetic energy loss will be :

(A)

(B)

(C)

(D)

5) Mass per unit area of a circular disc of radius a depends on the distance r from its centre as σ(r)
= A + Br. The moment of inertia of the disc about the axis, perpendicular to the plane and passing
through its centre is :

2πa4
(A)

(B)
πa4
2πa4
(C)

2πa4
(D)

6) A right triangular plate ABC of mass m is free to rotate in the vertical plane about a fixed
horizontal axis through A. It is supported by a string such that the side AB is horizontal. The reaction
at the support A in equilibrium is:

(A)

(B)

(C)

(D) mg

7) A uniform rod of length l is placed symmetrically on two walls as shown in figure. The rod is in
equilibrium. If N1 and N2 are the normal forces exerted by the walls on the rod then :-

(A) N1 > N2
(B) N1 < N2
(C) N1 = N2
(D) N1 and N2 would be in the vertical directions

8) A rod of length 50 cm is pivoted at one end. It is raised such that it makes an angle of 30º from
the horizontal as shown and released from rest. Its angular speed when it passes through the
horizontal (in rad s-1) will be (g = 10 m s-2)

(A)

(B)

(C)

(D)
9) Two uniform rods of equal length but different masses are rigidly joined to form an L-shaped
body, which is then smoothly pivoted about O as shown. If in equilibrium the body is in the shown

configuration, ratio M/m will be :

(A) 2
(B) 3
(C)
(D)

10) A particle moving on a circular path with a constant speed v, light is thrown from a projectors
placed at the centre of the circular path. The shadow of the particle is formed on the wall. The

velocity of shadow up the wall is:

(A)
(B)
(C)
(D) None of these

11) A uniform rod of length ℓ is being rotated in a horizontal plane with a constant angular speed
about an axis passing through one of its ends. If the tension generated in the rod due to rotation is
T(x) at a distance x from the axis, then which of the following graphs depicts it most closely?

(A)

(B)
(C)

(D)

12) Consider a body, shown in figure, consisting of two identical balls, each of mass M connected by
a light rigid rod. If an impulse J = MV is imparted to the body at one of its ends, what would be its

angular velocity:-

(A) V/L
(B) 2V/L
(C) V/3L
(D) V/4L

13)

Find the minimum height of the obstacle so that the sphere can stay in equilibrium.

(A)

(B)

(C)
(D)

14) A small fish 0.4m below the surface of a lake , is viewed through a simple converging lens of
focal length 3m. The lens is kept at 0.2 m above the water surface such that fish lies on the optical

axis of the lens. The image of the fish which become object for lens is at
(A) A distance of 0.2m from the water surface.
(B) A distance of 0.6m from the water surface.
(C) A distance of 0.3m from the water surface.
(D) The same location of fish.

15) Two plane mirrors are inclined at an angle of 60°. A light ray is incident at an angle 60° at point
A on mirror M1. Total deviation suffered by ray after all possible reflections is :

(A) 100°
(B) 180°
(C) 40°
(D) 240°

16) You are given a parabolic mirror whose inner surface is silvered. The equation of the curve

formed by its intersection with x–y plane is given by y = . A ray travelling in x–y plane along line y
= x + 3 hits the mirror in second quadrant and gets reflected. The unit vector in the direction of

reflected ray is :-

(A)

(B)
(C)

(D) None of these

17) A fish rising vertically up towards the surface of water with speed 3 ms–1 observes a bird diving

vertically down towards it with speed 9 ms–1. The actual velocity of bird is (µ of water is )

(A) 4.5 ms–1

(B) 5.0 ms–1
(C) 3.0 ms–1
(D) 3.4 ms–1

18) In the given figure an object 'O' is kept in air in front of a thin plano convex lens of radius of
curvature 10 cm. It's refractive index is 3/2 and the medium towards right of plane surface is water
of refractive index 4/3. What should be the distance 'x' of the object so that the rays become parallel

finally.

(A) 5 cm
(B) 10 cm
(C) 20 cm
(D) None of these

19) A plane mirror and a spherical mirror of focal length f is arranged as given. A point object O is
placed between them, the value of x so that final image coincide the object (d > 2f) is :
(A)

(B)
(C)
(D)

20)

For the given incident ray as shown in figure, the condition of total internal reflection of the ray will
be satisfied if the minimum value of refractive index of block will be :

(A)

(B)

(C)

(D)

SECTION-II

1) A convex lens of focal length 20 cm is cut into two equal parts so as to obtain two plano-convex
lenses as shown in fig(B). The two parts are then put in contact as shown in fig (C). Find focal length
of combination (in cm) _______ .

2) A quarter cylinder of glass of radius R and refractive index 1.5 is placed on a table. A point object
P is kept at a distance of mR from it. Find the value of 3m for which a ray from P will emerge parallel

to the table as shown in the figure.

3) Bottom of a glass beaker is made of a thin equi-convex lens having bottom side silvered as shown
in figure. Water is filled in the beaker up to a height [Link] image of a point object O, floating at
middle point of beaker at the surface of water coincides with it. Find out the radius (in cm) of

curvature of the lens. Given that refractive index of glass is and that of water is .

4) The focal lengths of the objective and eye-lens of a microscope are 1 cm and 5 cm respectively. If
the magnifying power for the relaxed eye (take final image at infinity) is 45, then the length of the
tube is (in cm):

5) A cylindrical drum, pushed along by a board, rolls forward on the ground. There is no slipping at
any contact. If the distance moved by the man who is pushing the board is nL, when axis of the

cylinder covers a distance L, then n is :

PART-2 : CHEMISTRY

SECTION-I

1) A solution contain 8 g of a carbohydrate in 100 g of solution has a density 1.025 g/ml and an
osmotic pressure of 5 atm at 27°C. What is the molar mass of the carbohydrate :-

(A) 387
(B) 404
(C) 3740
(D) None

2)

Which of the following has the lowest freezing point ?

(A) 0.1 m sucrose solution

(B) 0.1 m urea solution
(C) 0.1 m K2SO4 solution
(D) 0.1 m glucose solution
3) Two liquids X and Y form an ideal solution. At 300 K, vapour pressure of the solution containing 1
mole of X and 3 mole of Y is 550 mm Hg. At the same temperature, if 1 mole of Y is further added to
this solution, vapour pressure of the solution increases by 10 mm Hg. Vapour pressure (in mm Hg) of
X and Y in their pure states will be, respectively :-

(A) 200 and 300

(B) 300 and 400
(C) 400 and 600
(D) 500 and 600

4) The vapour pressure of CS2 at 50°C is 854 torr and a solution of 2.0 gm sulphur in 100 gm of CS2
has vapour pressure 848.9 torr. If the formula of sulphur molecule is Sn, then calculate the value of
"n" (approx) (At. mass of S = 32) :-
[Assume very dilute solution]

(A) 2
(B) 4
(C) 8
(D) 6

5) Liquid 'M' and liquid 'N' form an ideal solution. The vapour pressures of pure liquids 'M' and 'N'
are 450 and 700 mm Hg, respectively, at the same temperature. Then correct statement is:
(xM = Mole fraction of 'M' in solution ;
xN = Mole fraction of 'N' in solution ;
yM = Mole fraction of 'M' in vapour phase ;
yN = Mole fraction of 'N' in vapour phase)

(A) (xM – yM) < (xN – yN)

(B)

(C)

(D)

6) For a general reversible reaction; 3A + 2B 2C + D, the initial moles of A are double of B. At

equilibrium moles of A and D are equal. The percentage dissociation of A is :-

(A) 50%
(B) 25%
(C) 75%
(D) None of these

7) The standard free energy change of a reaction is ΔG° = –115 kJ at 298 K. Calculate the value of
log10Kp
(Given : R = 8.314 JK–1 mol–1) :-

(A) 20.16
(B) 2.303
(C) 2.016
(D) 13.83

8) A 0.010 M solution of ZrO(NO3)2 was found to have a pH of 3.80 [Antilog (–3.8) = 1.6 × 10–4]. What
is the value of Kb for ZrO(OH)+ ?

(A) 1.0 × 10–6

(B) 3.9 × 10–8
(C) 3.9 × 10–9
(D) 3.9 × 10–10

9) The pH of a solution obtained by mixing 100 ml of 0.2 M CH3COOH with 100 ml of 0.2 M NaOH
would be : (pKa for CH3COOH = 4.74)

(A) 4.74
(B) 8.87
(C) 9.10
(D) 8.57

10) The number of moles of Ca(OH)2 required to prepare 250 mL of solution with pH 14 (assuming
complete ionization) is :-

(A) 0.25
(B) 1.0
(C) 0.125
(D) 10.0

11) The gas A2 in the left flask allowed to react with gas
B2 present in right flask as A2(g) + B2(g) 2AB(g); Kc = 4 at 27°C. What is the concentration of AB
when equilibrium is established?

(A) 1.33 M
(B) 2.66 M
(C) 0.66 M
(D) 0.33 M

12) pH of a mixture of 1 M HA (pKa = 4.2) and 1 M NaA is 4.5. In 300 ml of buffer volume of HA is
[log 2 = 0.3]
(A) 200 ml
(B) 150 ml
(C) 100 ml
(D) 600 ml

13) The equilibrium constant for the reaction

H2(g) + S (s) H2S(g) ; is 18.5 at 925 K
and 9.25 at 1000 K respectively. The enthalpy of the reaction will be :
(Given log 2 = 0.301)

(A) – 68000.05 J mol–1

(B) –71080.57 J mol–1
(C) – 80071.75 J mol–1
(D) 57080.75 J mol–1

14) The effect of addition of helium gas at constant pressure to the following reaction in equilibrium
state, is :
PCl5(g) ⇌ PCl3(g) + Cl2(g)

the equilibrium will shift in the forward direction and more of Cl2 and PCl3 gases will be
(A)
produced
(B) the equilibrium will go backward due to suppression of dissociation of PCl5
(C) helium will deactivate PCl5 and reaction will stop
(D) addition of helium will change the equilibrium constant

15) The solubility of AgCN in a buffer solution of pH = 3 is x. The value of x is:

[Assume : No cyano complex is formed;
Ksp(AgCN) = 2.2 × 10–16 and Ka(HCN) = 6.2 × 10–10]

(A) 0.625 × 10–6

(B) 1.9 × 10–5
(C) 2.2 × 10–16
(D) 1.6 × 10–6

16) Two solids dissociate as follows

A(s) ⇌ B(g) + C(g) ; atm2
D(s) ⇌ C(g) + E(g) ; atm2
The total pressure when both the solids dissociate simultaneously is :-

(A) (x + y) atm
(B) x2 + y2 atm
(C)
(D)

17) For the following reaction :

N2O3(g) ⇌ NO(g) + NO2(g) the degree of dissociation is 50 % at total pressure of P then Kp would be :

(A)

(B)

(C) 2P
(D) 3P

18) The correct increasing order of solubility of the following substances in g/100 ml is :
PbSO4(Ksp = 2 × 10–9), ZnS(Ksp = 1× 10–22),
AgBr(Ksp = 4× 10–13) and CuCO3(Ksp = 1× 10–8).
(Atomic masses : Pb = 208, Zn = 65, Ag = 108, Br = 80, Cu = 63)

(A) PbSO4 < ZnS < AgBr < CuCO3

(B) PbSO4 < CuCO3 < AgBr < ZnS
(C) ZnS < AgBr < CuCO3< PbSO4
(D) ZnS < AgBr < PbSO4 < CuCO3

19) When H2S gas is passed through an ammonical salt solution X, a white precipitate is formed. The
X can be.

(A) Cobalt salt

(B) Lead salt
(C) Zinc salt
(D) Silver salt

20) [X] + H2SO4 → [Y] a colourless gas with irritating smell, [Y] + K2Cr2O7 + H2SO4 → green solution.
[X] and [Y] is :-

(A) , SO2
(B) Cl–, HCl
2–
(C) S , H2S

(D) , CO2

SECTION-II

1) A 5% (w/V) solution of cane sugar (molecular weight = 342) is isotonic with 1% (w/V) solution of a
substance X. The molecular weight of X is :-

2) 100 gm of C6H12O6 (aqueous) solution has vapour pressure is equal to 40 torr. If this solution is
cooled to –0.93° C. What mass (in gram) of ice will be separated out :
(Round off to nearest integer)

Given torr, Kf = 1.86 K. kg mol–1

3) The pH of 0.5 M NaCN solution is
(Ka of HCN = 5 × 10–10)

4) Sulphurous aid (H2SO3) has Ka1 = 1.7 × 10–2 and Ka2 = 6.4 × 10–8. The pH of 0.588 M H2SO3 is
........... (Round off to the Nearest Integer)

5) In the following how many will produce NO2 gas on decomposition ?

Pb(NO3)2, Hg(NO3)2, AgNO3, Mg(NO3)2, LiNO3, NaNO3

PART-3 : MATHEMATICS

SECTION-I

1) A unit vector in the plane of and is such that it is equally inclined to and
where The unit vector is

(A)

(B)

(C)

(D)

2) Consider the set of eight vectors

V= . Three non-coplanar vectors can be chosen from V in 2p

ways. Then p is _______ .

(A) 2
(B) 3
(C) 5
(D) None

3) Let , , and a vector satisfies ,

, then the value of is

(A) 1
(B) 2
(C) 3
(D) 4

4) If and are such that = 1, , and , then the

angle between and is

(A)

(B)

(C)

(D)

5) Let be a unit vector and is a nonzero vector not parallel to . The angles of the triangle, two

of whose sides are represented by and are

(A)

(B)

(C)

(D) None

6)

The plane = 1 cuts the axes in A, B, C then the area of the ΔABC is

(A)
(B)
(C)

(D) 2

7)

The planes x = cy + bz, y = az + cx, z = bx + ay pass through one line, if

(A) a + b + c = 0
(B) a + b + c = 1
(C) a2 + b2 + c2 = 1
(D) a2 + b2 + c2 + 2abc = 1

8) If (α, β, γ) is a point on the line = z at distance 2 from the point (1, –1, 0), then

the coefficient of xα+β+γ in the expansion of is

(A) –84
(B) 84
(C) 672
(D) –672

9)

If the projection of the line on a plane P is . Then the distance of

plane P from origin is

(A)

(B)

(C)

(D)

10) Let P1 : x + y + 2z – 3 = 0 and P2 : x – 2y + z = 4 be two planes. Also, let A(1, 3, 4) and B(3, 2, 7)
be two points in space. The equation of plane which passes through line of intersection of P1 and P2
and upon which length of projection of the line segment AB is the least, is

(A) x + 3y + z + 2 = 0
(B) 3y + z + 1 = 0
(C) 2x – y + 3z – 7 = 0
(D) 3x – 3y + 4z – 11 = 0

11)

If f(x) = sin2x + sin2(x + ) + cosx cos (x + ) and g = 1 then

(A)

(B)

(C) go f(x) is an identity function

(D)

12) Let and be defined as

Then the number of possible functions such that is:

(A)
(B)
(C)
(D)

13)

For a R if |x + a – 3| + |x – 2a| = |2x – a – 3| is true for x R then exhaustive set of a is

(A) [–4, 4]
(B) [–3, 2]
(C) {–2, 2}
(D) {1}

14) If the function f : R–{(2n + 1) } → R be defined by f(x) = x3 – 3x2 + 21x + tan x ; where n I
then f(x) is

(A) Many-one and into

(B) Many-one and onto
(C) One-one and into
(D) One one and onto

15)

Let A = {1, 2, 3}. The total number of distinct relations that can be defined on A is

(A) 29
(B) 6
(C) 8
(D) (29 - 1)

16)

Let R be the relation on the set R of all real numbers defined by aRb if |a – b| ≤ 1. Then R is

(A) Reflexive and Symmetric

(B) Symmetric only
(C) Transitive only
(D) Anti-symmetric only

17) is equal to

(A) tan–1(2n)
(B) tan–1(2n + 1)
(C) tan–1(2n) – π/4
(D) None of these

18)
If α, β and γ are the three angles with
α = 2 tan–1 ( – 1);

β = 3 sin–1 + sin–1 and

γ = cos–1 , then

(A) α > β > γ

(B) β > γ > α
(C) γ > α > β
(D) α = β > γ

19)

Consider the following relations.

R = {(x, y)|x, y are real numbers and x = wy for some rational number w}
S= m, n, p, q are integer such that n·q ≠ 0 and qm = pn}
Statement-1 : S is an equivalence relation but R is not an equivalence relation.
Statement-2 : R and S both are symmetric.

Statement–1 is true, Statement–2 is true; Statement–2 is not the correct explanation of

(A)
Statement–1.
(B) Statement–1 is false, Statement–2 is true.
(C) Statement–1 is true, Statement–2 is false.
Statement–1 is true, Statement–2 is true; Statement–2 is the correct explanation of
(D)
Statement–1.

20) Let S = is
The value of [5 tan–1(cos(tan–1{S}))] equals, (where {.} denotes fractional part function and [.]
denotes greatest integer function)

(A) 3
(B) 0
(C) 2
(D) 1

SECTION-II

1) If (cos–1x)2 + (cos–1y)2 = 2π2 Then value of x5 + y5 is

2)

Let . If the vectors , are

coplanar then is
3) Let are non-zero vectors such
that . If and then value of is

4) The distance of the point (1, –2, 3) from the plane x – y + z = 5 measured parallel to the line

is

5)

Given A = . The total number of bijective functions f : A → A such that

f(x) = x, if x is an odd integer
and f(x) ≠ x , if x is an even integer,

is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A A B C A B C B D A D A D C D A A C B C

SECTION-II

Q. 21 22 23 24 25
A. 20.00 4.00 5.00 15.00 2.00

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. B C C C C C A C B C C C B A B C B C C A

SECTION-II

Q. 46 47 48 49 50
A. 68.40 48.00 11.50 1.00 5.00

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B C B B C C D C B C B B D B A A C B C A

SECTION-II

Q. 71 72 73 74 75
A. -2.00 3.00 4.00 1.00 9.00
 SOLUTIONS

PART-1 : PHYSICS

1)

Ι1 > Ι4 > Ι2 > Ι3

2) V =

3)

Torque by tension force is zero

⇒ angular momentum conservation
Ι1w1 = Ι2w2
Let w1 = w0

0
⇒ w2 = w η2

Here change in K.E. = (WD)

WD = kf – ki =
= k0(η2 – 1)
4)

5) dI = dmr2
dI = σ2πr dr r2
dI = 2π(A + Br) r3 dr

I = 2πa4

6) N only ↑ because no other Horizontal component

τB = 0 ⇒ Nℓ =

∴N=

7)
∴ N1 = N2

8) Question Explanation:
We need to find the angular speed of the rod when it passes through the horizontal.

Concept:
This question is based on principle of conservation of energy.

Solution:
Work done by gravity from initial to final position is

Final Answer:
The correct option is (2)

9) Torque about O

mgsin60º × = Mg sin30º ×

= M⇒

10)

= Rsec2θ
= vsec2θ
11)

12) Given system of two particles will rotate about its centre of mass.

Initial angular momentum = MV

Final angular momentum = 2Iω = 2M ω

By the law of conservation of angular momentum

13)

The sphere is one the verge of toppling when a line of action of weight passes through the
edge.

14)

15)
s = 2 × 60 + 2 × 60 = 240
16)

Point of intersection of two curves, y = and y = x + 3 is, (–2, 1)

i.e.,
tan β = slope of incident ray
RP =1 or β = 45°

and
From geometry we can show that i.e., the ray is incident normally.
Hence, the desired unit vector :

A=

17)

Explaining the Question :-

We are given a fish observes a bird moving vertically downwards with speed 9 m/s, Find the
actual velocity of bird
Concept:-
This question is based on Refraction from plane surface.
Solution :-
(i) Position of bird as observed by the fish
XIF = y' + µy
VIF = VF + µVB

–9 = – 3 + × VB

VB = – = – 4.5 m/s
Diff [Link] 't'
VIF = vel. of bired as observed by fish
VF = velcoity of fish
VB velocity of Bird
∴ Speed = 4.5 m/sec

18)
19) For any reflection pattern we can say that

20) (r = 90° – θ)
sin(45°) = µ sin(90 – θ)

= µ cos θ

21)

22) Use refraction formula at both surfaces

Refraction at 1st surface

Refraction at 2nd surface

by solving for m
3m = 4

23) If image formed at pt. o then it act as centre of curvature of find equivalent mirror

24)
 25)

Velocity of axis = V
Velocity of topmost point = 2V
so distance covered = 2L

PART-2 : CHEMISTRY

26)

27)
i = 3, for K2SO4
28)

29)
(for very dilute solution )

(mol. wt)solute = 254.5

mol. wt of Sn = 32 × n
∴ 32 × n = 254.5
n = 7.95
=8

30) According to Raoult's law;

PM = ; PN =
According to Dalton's law;
PM = [Link]; PN = [Link]
Þ = [Link] … (1)
& = [Link] … (2)
Divide (1) & (2);

Given; = 450 mm Hg & = 700 mm Hg

⇒ ; as when multiplied by a number less than 1 gives .

31) 3A+ 2B 2C + D
initially 2a a 0 0
at equilibrium (2a–3x) (a – 2x) 2x x
At equation moles of A = moles of D (given)
(2a – 3x) = x
 4x = 2a ⇒
∴ number of moles of A consumed in the reaction

% age of A dissociated =

32) ΔG° = –2.303 RT × log10 KP

–115 × 1000 = –2.303 × 8.314 × 298 × log10 KP
log10 KP = 20.16

33)

34) CH3COOH + OH– → CH3COO– + H2O

t=0 20 20
t = eq – – 20

So, [CH3COO–] = = 0.1 M

pH = 7 + pKa + log C = 7 + 2.37 +

log 10–1 = 7 + 2.37 – 0.5 = 8.87

35)

pH = 14 means [H+] = 10–14

0
or [OH–] = 10 = 1M
1 mole Ca(OH)2 gives 2 moles of OH– ions.
∴ Ca(OH)2 required = 0.5 mol L–1

= mole for 250 mL = 0.125 mole

36)

⇒ mole

[AB(g)] =

37)
⇒ 4.5 = 4.2 + log

⇒ 0.3 = log

⇒ log 2 = log

⇒ 2x = 300 – x
⇒ 3x = 300 ⇒ x = 100 ml

38) H2(g) + S(s) H2S(g)

log

log

– 0.3010 =
ΔH = – 71080.57 J/mole

39) PCl5(g) ⇌ PCl3(g) + Cl2(g)

At constant Pressure, Volume will increase so reaction will shift in forward direction then
answer will be A

40)

AgCN(s) Ag+ + CN–, ksp = S[CN–] ..........(i)

CN– + H2O HCN + OH–,

Considering the hydrolysis of CN–
[CN–]o = [CN–]eq + [HCN]eq
 S = 1.9 × 10–5 M

41) A(s) ⇌ B(g) + C(g) KP1 = x = PB×PC

P1 P1 x = P1(P1 + P2) ...(1)
D(s) ⇌ C(g) + E(g) KP2 = y = PC × PE
P2 P2 y = (P1+P2) (P2) ...(2)
Adding (1) and (2)
x + y = (P1 + P2)2
Now total pressure
PT = PC + PB + PE
= (P1 + P2) + P1 + P2 = 2(P1 + P2)
PT =

42)
total moles = 1 + x

mole fraction = , ,

Partial pressure = , ,

kP =

kP =

x=

∴ Kp =

43)

PbSO4 ZnS AgBr CuCO3

Ksp 2 × 10 –9
1 × 10 –22
4 × 10 –13
1 × 10–8
S(in Mole/L) 4.47 × 10–5 1× 10–11 6.32× 10–7 1 × 10–4
S(in g/ml) 1.36 × 10–3 9.7 × 10–10 1.18 × 10–4 1.23× 10–3

44) Zn+2 + H2S → Zn S↓ (white) + 2H+

45)

46)

Mw = = 68.4

47) molality (m) of solution,

m = 0.25

∵ m = 0.25 =
45(100 – w) = w × 1000
4500 = 104500

H2O = 100 – 4.31 = 95.69 g H2O

∴ ΔTF = Kf × m

×
= 47.88 g (liquid)
So ice = 95.69 – 47.88 = 47.8 g 48.00 g

48) pH = 7 + (pka + log C)

=7+

=7+ [10 – log5 + log5 – log 10]

= 7 + [9]
pH = 11.5

49) H2SO3 [Dibasic acid]

c = 0.588 M
⇒ pH of solution due to First dissociation only since Ka1 >> Ka2
⇒ First dissociation of H2SO3
 Therefore pH of sol. is : pH = –log

50) Pb(NO3)2 → PbO + NO2 + O2

Hg(NO3)2 → Hg + 2NO2 + O2
AgNO3 → Ag + NO2 + O2
Mg(NO3)2 → MgO + NO2 + O2
LiNO3 → Li2O + NO2 + O2
NaNO3 → NaNO2 + O2

PART-3 : MATHEMATICS

51) Let
is equally inclined to and , where .

=
or λ(4 + 1) + μ(2–1) = λ (1) + μ(–1+2)
or 4λ = 0, i.e., λ = 0

52) Let are (1, 1, 1), (–1, 1, 1)

(1, –1, 1), (–1, –1, 1) and rest of the vector are

Here 3 vectors will be coplanar if two will be collinear (anti parallel)

Number of ways of selecting two anti parallel pair = 4
Number of ways of selecting third vector = 6
Total number of ways = 24
Total number of ways of non coplaner selection
= 8C3 – 24 = 32 = 25

53)

⇒
⇒ (–38)

54)

or
Also

⇒ =

or sin2 θ =

or θ =

55)
here
∠ABC = 90°

θ = π/3
∠ ABC = π/2 : ∠BAC = π/6
∠ ACB = π/3
56)

57)

58)

59)

Projection of line on a plane P is .

∴ Plane through these lines is perpendicular to the plane P.

Normal to the plane determined by the given lines is

∴ Direction ratios normal to the required plane is

∴ Equation of the plane is x + y + 2z – 3 = 0 as it passes through (0, 1, 1).

Its distance from origin is .

60) Equation of family of planes containing line of intersection of planes P1 and P2 is given bY
(x + y + 2z – 3) + λ(x – 2y + z – 4) = 0
or (1 + λ)x + (1 – 2λ)y + (2 + λ)z – 3 – 4λ = 0
Projection of length of line segment is least if AB is perpendicular to read plane.

∴ ⇒λ=1
∴ Equation of plane P is 2x – y + 3z – 7 = 0
61)

62)

In function should be mapped to respectively. Each of

remaining elements can be mapped to any of 10 elements.
Number of possible is

63)

64)

increasing piece wise (because tanx is discontinuous)

f is many one
odd power polynomial onto

65)

n(A × A) = n(A).n(A) = 32 = 9
So, the total number of subsets of A × A is 29 and a subset of A × A is a relation over the
set A.
66)

67)

68)

69)
70)

71)

cos–1x = π cos–1y
x = y = -1
So x5 + y5 = –2

72)
= α(i + j) + β(j + k)
= αi + (α + β) j + βk
Given that i – 2j + k, 3i + 2j – k,

Are coplanar so =0
2β + α + β + 2(3β + α) + 3α + 3β – 2α = 0
12β + 4α = 0

73)
74)
eq of line PQ is

If PQ = r

then Q ≡
8 lies on plane x – y + z = 5

1+ r+2– r+3– r=5

⇒r=1
∴ PQ = 1

75)

Using given information

f(1) = 1, f(3) = 3, f(5) = 5, f(7) = 7, f(9) = 9
and f(2) ≠ 2, f(4) ≠ 4, f(6) ≠ 6, f(8) ≠ 8
so using method of disarrangement total number of bijective functions