26

vnpun puss ws calonoteaw (enc) aud dichlaro

25 5 9

C=12,
H-)

NDO,X =-XA

xAA-+fe
 24

40
8%

11915-!

Total w

,(h-R) o, o.6 82
4ofa f+(R-)
 28
SoluBjon fant 3

Aud 46-8 Kpa spetlively wht wil be th yapbes phus uA

ue)") wkick should be dissolved iv

in 149
was 40 9
tlaw to
Dy fnasla

11

(W-)

vaue
Jes volaile as toupa#
to toup0uund euel
ole-aioy
 t0 ol

1H4 weble inaeioy nnoa toutoiut devn,s es to

qnellea

laled
total pVapbus pasue over te Bouiou tan be

vapeun prusWe ouer -lue solutiou vanits fiuasly

Total
toi!4 the wcole Sracion | toupount 2
Note

toupousuda

1 aud 2
prsss
y=X
 idral aed NDyjal solfi on
AHneioy toaves
0 vaudh waal nthniou digthe- dipole athaeti ou
ydhogen atinelity

(weak)

webaBod

Voudn wd alvaioy

CH4

toiyole dipole foue)

H,0
(E.N

eliut
(E,O N)
 Nole!

(ED,N)
(EN')
Catagpaieu
0sdnoug auda waal faee
-

ig waleules (H) is Braug

C6’Ca (weas vauls wanl forve)
2 we Kk vatvdr waal toAe
vaudA wwaal toave auowg ball uoleules tHc) is weak

vudin waal torye

ton waliou oluion by uiwiag bezdut awd toluee

CHa

S. W.y.F S-W:VF

A+B ’ Soluion
iduol sluHoy
 33
ielval atlzli ou'
A noltio havig aiwilaa prepeaties s the prepenli
Haviw) solete zud stlveut
zoluioy
Fonwaitu olution by waiciwg beuzeus awed adeoal:
| CHg0H-CHOHCH,OH
SV wF

boud

A ouion
prupenties
Te piapenlies haviw salade
Achivty -
CH2 CHa

CHa

AcctouCKaloui) Soluioy

dipole-diynle

(uon- idoad slaien)

 34

Tu sollionk wlice obey hatuHs law oveh Aw eudin

CH2 CHe

S"VWF
idral ilion
= 200 wm
Hear,

vlalike coupiunds

to aoutl, Iaw A total vapou pusua

soluiou uale harieu
4 dleand vwlalle Toufaands
touuasds
 (eE RT)

idnl solutioy

OH"Ono

(S-V oF)

Herl

+P
OH

Couelueiout
(idal soldrou)- follaso Aasolls Jaxo
(NOM idlml solutiu)
 36

Iyvessly
Subatae

duity =
Voluut x duity
dnsity
note!

in vemt
AN= V- V
For idoal owtou,

AHvaeliou'
vdluut less (dausity
 Foa (Aclividy)
CHg
0-0-0-0
(A 6)
Sy:wF Solulioy
SV:w F
Tetal velnut d Anetaut

FA paaciee

CH

Soluliou

Total wos Aaetaut

Avfo
Ayo
 CHa
soluhdu
Diyale-bipsle at'
bipile-Dipele
roduet
 39
losilive dvialioy - (solutiou)
Vayous

AN>0
Negdive drvialion! (solali ou)
Law te solaiou txlübils pae dvialious

|Av <o
Cnaph shoswL poziive dovj adipu i- (Solulieu)
Ma

E-
MixeaAs elhauol ad
note-iautitu
Acetone b'ehavel prsilive
devinion

Xp=1
(acctoa)
 iaypad aud eiuds'

but
NDle!
Acetoe Aeclea (aiybe- diole eo idAaeio)

etlhaol ellaauol -

krgakive duialitu's

M)M

(CHela) ad toetou
Mole haeton>
duiaie0
iugpaBavd poiut

vapouh pusUAL toill be lo

 CHa

Fözazidal isillaion
bisry soluio, o2
Tetiany solualioy at dilend tewehaus heon)n as
taritieal xilatidy

soluliou

walta

NDÀe vaoun geta tondbusod

Azeotiogeb O% Azeotaopie wixtuAN': (binnay solutioy)
 Azeolaopeut

Couditiow'
soluioy uwbieh boilug potd
Have dleote tougoiliu

lasge goithue. dvialiou fhom

EHhouol

80

beiliq yond

naviuuw boiliug aeotopei"

 3425 K
Iwtexi bmsiou'
Tu

digeuda
Sueh popeties au talled

selute+oles Solute
solvent
Nole!
Seule Nacl gu volalile
 to flow

Lel, NDM- vblaile oolwle A' nud

etolie olveud '

Seluliou duto s0lved A

(A-L)
Ausadiug to sapulk law
A XA

A
 solultou

pfi-a-0 (-a lawiq iu vapua)

iaial psnsuN

A- ckonge
 In vapoua fhsue is equal to

<<« nA

NDW,

MM:3
wt A
MM A

Teuipeaatun baa. Awon ubberlile

elhriaelate
boiliug peiut
foid

AcHivity

45 c
1
Heat

|wader
Hoat Teuptintua

Heat
Teugesatusn
 (1 adu)
1

20c

760 mwM

fop
Teuf
Elevakios in boilig poind :
Cowdition st

feit

fus valaile solveut

Ha0
Heat
 C

Soluiou
A+ B A- solte (NDy volatle)
L- Solvedlvojalile)-’ watta

we m hove to lwAase

boiliog yoisd polution

 So
Nuete'

EIle vabitn in

14
ieling pit(theatitn,ie)
|peid

F
solved

salutioy

Tnupendu A