28-09-2025

1001CJA101033250009 JA

PART-1 : PHYSICS

SECTION-I

1) Point charge Q is placed at point P in the plane of circular face of sphere. The electric flux passing

through the spherical part shown in the figure is :-

(A)

(B)

(C)

(D) Can not be calculated.

2)

An electric dipole moment μC. m is placed in a uniform electric field

5 –1
× 10 N C .

(A) The torque that exerts on is Nm.

(B) The potential energy of the dipole is –0.6 J.
(C) The potential energy of the dipole is 0.6 J.
(D) None of these

3)

A hollow closed conductor of irregular shape is given some charge. Which of the following
statements is/are correct?

(A) The entire charge will appear on its outer surface.

(B) All points on the conductor will have the same potential.
(C) All points on its surface will have the same charge density.
(D) All points near its surface and outside it will have the same electric intensity.

4) In circular orbit of a satellite of mass m, revolving around a planet of mass M in an orbit of radius
r and having the period of revolution T, we have :-
(A)
orbital speed equals
(B) T2 ∝ r3

(C)
kinetic energy equals

(D)
potential energy equals

5) For the given circuit, select the correct alternative(s)

(A)
The equivalent capacitance between points 1 & 2 is

(B)
The equivalent capacitance between points 3 & 6 is

(C)
The equivalent capacitance between points 1 & 3 is

(D)
The equivalent capacitance between points 3 & 5 is

6) Four capacitors and a battery are connected as shown. The potential drop across the 7μF

capacitor is 6V. Then the

(A) potential difference across the 3μF capacitor is 10V

(B) charge on the 3μF capacitor is 42μC
(C) e.m.f. of the battery is 30V
(D) potential difference across the 12μF capacitor is 10V.

SECTION-II

1) Two blocks of masses 9 kg & 18 kg are attached with springs as shown in figure. Find the time
period for small oscillations of the two blocks (in sec). Take π2 = 10.
2) Calculate the amount of charge (in μC) on capacitor of 4μF. The internal resistance of battery is

1Ω :-

3) The ratio of magnitude of electric field due to +q and –2q at a point between the charges where
net potential is zero on x-axis is z : 1, then z will be :-

4) In the circuit shown, the energy (in µJ) stored in 1µF capacitor is :-

5) A parallel plate capacitor has two layers of dielectric as shown in figure. If this capacitor is
connected across a battery & the ratio of potential difference across the dielectric layer is x, then

value of 2x is :

6) On a planet which has the same density as that of earth, we construct a frictionless inclined plane
of inclination 53° with the horizontal. When a block is released on the inclined plane, it is seen to
accelerate at 1 m/s2. What is the radius of planet (in 105 m) ? (Take radius of Earth = 6400 km)

SECTION-III
1) An object of mass 0.2 kg executes simple harmonic along X-axis with frequency of Hz. At the
position x = 0.04 m, the object has kinetic energy of 0.5 J and potential energy of 0.4 J. The
amplitude of oscillation in meter is equal to.

2) In the figure shown, short electric dipole is placed at a distance x from an infinitely long rod of

uniform linear charge density λ. Then magnitude of force acting on dipole is found to be ,

then find the value of N.

3) A solid conducting sphere of radius 'a' having charge q is surrounded by a concentric conducting
spherical shell of inner radius 2a and outer radius 3a as shown in figure. If the amount of heat

produced when switch is closed is , fill the value of α.

4) For the circuit shown in the figure the reading of the voltmeter (in V) will be......

5)

Find the current shown by ammeter (ideal) in ampere.

6) If in steady state the energy stored in the capacitor (as shown in figure) is N × 10–8 J, then find the

value of N.

PART-2 : CHEMISTRY

SECTION-I

1)
Correct statement about product P1, P2 & P3 is/are

(A) Product P1 is 3º alcohol

(B) Product P2 is 2º alcohol
(C) Product P3 is 1º alcohol
(D) All products are structural isomers of each other

2) Which of the following compounds can show positive Br2/H2O test.

(A)

(B)

(C)

(D)

3) Which of the following molecules have following : ionic bond, covalent σ-bond, covalent π-bond?
(A) CaC2
(B) NH4Cl
(C) NH4NO3
(D) CH3CN

4) Pick out the INCORRECT statement(s) :

4+
(A) MnO2 dissolves in conc. HCl, but does not form Mn ions.
(B) Decomposition of acidic KMnO4 solution is not catalysed by sunlight.
MnO42– is quite strongly oxidising and stable only in very strong alkalies. In dilute alkali, water
(C)
or acidic solutions it disproportionates.
(D) KMnO4 does not act as oxidising agent in alkaline medium.

5) One mole of an ideal gas in initial state A undergoes a cyclic process ABCA, as shown in the
figure. Its pressure at A is P0. Choose the correct option from the following.

(A) Internal energies at A and B are different

(B) Work done by the gas in process AB is P0V0 ℓn 4

(C) 0
Heat liberated in process BC is CP T .

(D)
Pressure at B is

6) At 90oC pure water has [H+] = 10−6 M. Based on this correct statement is (are) :

(A) Increasing the temperature, increases degree of ionization of water

(B) At 60oC, pH of pure water will be less than 6
(C) At 90oC, pH of a 10−6 M HCl solution will be less than 6
o −12
(D) Ionization constant (Ka) of H2O at 90 C is 10

SECTION-II
1) Products. (If 96% racemisation takes place)
Find out the percentage of product having 'R' configuration.

2) Number of products are (X)

Number of products are (Y)

Report your answer as (3X + Y)?

3) Consider the following reaction sequence.

Find the sum of number of stereoisomers of complexes P, Q and R.

4) Find the correct configuration of metal ion in given complexes.

(i) [Ni(en)3]2+ – (ii) [Cr(NH3)6]3+ –

(iii) [Co(NO2)6]3– – (iv) [Fe(CN)6]4– –

(v) [Mn(H2O)6]2+ – (vi) [FeF6]3– –

5) In a hypothetical elementary reaction X → Y at 500 K. and .

0
Assume that catalyst is used and it lowers the activation energy by 20% then what is |ΔG | for the

reaction after use of catalyst (in kJ mol–1) is:

6) If first dissociation of triacidic base X(OH)3 is 100% whereas second dissociation is 50% and third
dissociation is negligible then the pH of 4 × 10–3 M X(OH)3 is :
(log 6 = 0.78)

SECTION-III

1)
Number of hyper conjugable hydrogen in (P) = x
Number of DU in (P) = y
Number of sp2 hybridised carbon in (P) = z
Value of [x – (y × z)] is

2)

Total number of stereoisomers possible for (x)

3)

How many moles of ions will form on decomposition of Pentaamminechloroplatinum (IV) chloride in
aqueous solution.

4)

How many of the following are low spin & paramagnetic ?

[Co(H2O)6]3+, K4[Fe(CN)6], K3[Fe(CN)6], [Cr(NH3)6]3+, [NiF6]2–

5) Osmotic pressure of an aqueous solution of a nonelectrolyte solute is 300 mm of Hg at 27°C. If

certain volume of this solution is diluted by adding water and temperature is raised to 54°C then its
osmotic pressure is found to be 300 mm of Hg. Find % increase in volume of solution after dilution.

6) The enthalpy of vapourization of a liquid is 30 kJ mol–1 and entropy of vapourization is 75 J

mol–1 K–1. The boiling point (in K) of the liquid at 1 atm T, then T × 10–2 is.

PART-3 : MATHEMATICS

SECTION-I
1) Let ƒ(x) = 2014tan2015x + 2014tan2013x – 2010tan2011x – 2010tan2009x for all . Then the
correct expression(s) is(are)

(A)

(B)

(C)

(D)

2) Which of the following statement(s) is/are true ?

(A)

(B)

(C)

(D)

3) If where x > 0, then-

(A)

(B)

(C) ƒ(1) > 0

(D) ƒ(1) < 0

4) If Rolle's theorem is applicable for ƒ(x) = x3 + ax2 + bx in [1,2], then a, b are respectively -
(A) –2, –1
(B) 0, –7
(C) 5, 2
(D) –5, –6

5) Let ƒ(x) is a function such that ƒ′′(x) exists and ƒ′(x) is not a constant and ƒ(1), ƒ(2), ƒ(3), ƒ(4) are in
A.P. If domain of ƒ(x) is [1,4], then -

(A) ƒ′′(x) = 0 for at least two values of x.

(B) ƒ′(x) increases in its domain
(C) ƒ′(x) decreases in its domain
(D) ƒ′(x) is non-monotonic

6) Let , then -

(A) ƒ(x) has two local maxima and one local minima
(B) ƒ(x) has one local maxima and two local minima
(C) Global minimum value of ƒ(x) is zero

(D)
Global minimum value of ƒ(x) is

SECTION-II

1) A curve y = ƒ(x) which passes through (4,0) satisfy the differential equation xdy + 2ydx = x(x –
3)dx. The area bounded by y = ƒ(x) and line y = x (in square unit) is-

2) Let y = f(x) be a curve which satisfies the differential equation ex dy + (x – 1) dx = 0 and f(0) = 0.
If area enclosed by the curve , the x-axis and a line x = c where is the point of inflection on

the curve is then (m + n) is equal to

[Note: e denotes napier's constant.]

3) If area of the region bounded by & , λπ,

then is

4) Let and , then value of is

5) Given ƒ(x) = tan–1(cotx) + cot–1(tanx), , then is equal to

6) Value of n for which exists finitely and is non zero, is

SECTION-III

1) Given and y = 0 for . If maximum value of y is , then 'k' is equal to

2) Let the curve y = ƒ(x) satisfies and the curve passes through (0, 0), then the
value of |ƒ(–2)| is

3) Let y = ƒ(x) be a real- valued differentiable function on R (the set of all real numbers) such that
ƒ(1) = 1. If ƒ(x) satisfies xƒ′(x) = x2 + ƒ(x) – 2, then the area bounded by ƒ(x) with x-axis between
ordinates x = 0 and x = 3 is equal to

4) Let the area bounded by the curve ƒ(x) = max{x2, x3} & x-axis is λ, when 0 ≤ x ≤ 2, then is

5) Area bounded by & y = 7–|x| is A, then value of is

6) If = ,
where C is constant of integration , then is equal to
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6
A. B A,B A,B A,B,C A,B,C B,C,D

SECTION-II

Q. 7 8 9 10 11 12
A. 6.00 8.00 2.00 32.00 3.00 8.00

SECTION-III

Q. 13 14 15 16 17 18
A. 6 1 6 9 1 6

PART-2 : CHEMISTRY

SECTION-I

Q. 19 20 21 22 23 24
A. A,B,C,D B,C,D A,C B,D B,C,D A,C

SECTION-II

Q. 25 26 27 28 29 30
A. 52.00 14.00 6.00 4.00 45.00 11.78

SECTION-III

Q. 31 32 33 34 35 36
A. 2 8 4 1 9 4

PART-3 : MATHEMATICS

SECTION-I

Q. 37 38 39 40 41 42
A. B,C A,C B,C A,B A,D B,C

SECTION-II

Q. 43 44 45 46 47 48
A. 21.33 to 21.34 5.00 4.50 8.00 0.00 4.00
 SECTION-III

Q. 49 50 51 52 53 54
A. 8 0 6 2 8 0
 SOLUTIONS

PART-1 : PHYSICS

1)

Only half of field lines would pass.

2)

Find the torque and potential energy of electric dipole when it is placed in electric field.
Torque experienced by a dipole placed in an E.F. is given by and potential energy
is given by .

,
Option (1), (2)

3)

Property of conductor.

4)

For a satellite

So, all (A), (B) and (C) are correct.

5) (A)
(B)

(C)

6) Total potential
drop across 3.9μF = 20V
Charge on 7μF

Capacitor = 7 × 6 = 42 μC Hence, Potential drop across 3μF is

Charge given by battery = 6 × 20 = 120 μF

Hence potential drop across 12μF =

∴ E = 10 + 20 = 30V

7) Both springs are in series.

Reduced mass = µ

= 6 sec.

8)
ΔV = VA – VP = 5 – 3 = 2 Volt
Q = CV = 4 × 10–6 × 2 = 8 µC

9)

VA = VB

x = 2d – 2x
3x = 2d

x=

10)

11)

12) On earth
g sin 53° = 8

... (i)
On other planet

... (ii)
Put value of (i) in (ii) & solve
R' = 8 × 105 m

13)
Putting we obtain,
14) here ;

15)

So, Ui – Uf = H =

16)

V = IR ⇒

reading of voltmeter is

17)
Find equivalent

18)

VB = 4 volt
VD = 4.2 volt
PART-2 : CHEMISTRY

19) The correct answer option is (A), (B), (C) and (D)

20) The correct answer is option (B,C, D)

Br2 / H2O shows test with unsaturated compounds.

21)

The correct answer is (A) and (C)

22) (A) MnO2 + 4HCl → MnCl2 + Cl2 + 2H2O

(B) Decomposition of acidic KMnO4 is catalysed by sunlight

(C)

(D) KMnO4 also acts as on oxidizing agent in alkaline medium :

23) AB : Isothermal expension

0 0
WAB = –1 × R × T ℓn = –RT ℓn 4
∴ P0V0 = RT0
∴ WAB = –P0V0 ℓn 4
BC : V ∝ T

TC =
q = n CP ΔT

0
= 1 × CP × = – CP T

24)

Explaining the Question :- Find correct statement

Concept:- This question is based on properties of water

Solution :-
(1) If temperature then ∝ of water (correct)
(2) when temp. of water decreases from 90°C to 60° C, ∝ of water ↓ [H+] ↓ and pH therefore
pH will be more than 6 (Incorrect)
(3) At 90°C, for 10–6 M HCl, [H+] water can't neglect therefore pH will be less than 6
(correct)
(4) At 90° C H2O H+ + OH–
t=0 55.5
t = teq 55.5 – 10–6 10–6 10–6
≈ 55.5

(Incorrect)
Final Answer : options (1, 3)

25) Product 96% racemization

So,
48% 52%
SN1 SN2
Retention inversion
So, Among the product 48%S configuration and 52% R configuration

26) X = 4 products

Y = 2 products
3 × 4 + 2 = 14

27) P = [Pt(Py)2Cl2] Q = [Pt(Py)2(NH3)Cl]+

cis + trans cis + trans
+
R = [Pt(NH3)2(Py)Cl]
cis + trans

28)

The correct answer is 4.00

0
29) ΔrH = Eaf – Eab = 15 – 10 = 5 kg mol–1
 0
ΔrS = 150 – 50 = 100 Jk–1
0 0 0
ΔG = ΔH – TΔS
= 5 – 500 × 100 × 10–3
= – 45 KJ mol–1.

30) First dissociation :

Second dissociation :
Total [OH–] = 4 × 10–3 + 2 × 10–3 = 6 × 10–3
pOH = 3 – log 6 = 2.22
pH = 11.78

31)
x=8
y=3
z=2
Thus x – (yz) = 8 – (3 × 2) = 8 – 6 = 2

32)
Total eight stereoisomers are possible

33)

34)

The correct answer is 1

35) ....(1)

....(2)

% increases in volume =
 36) Given that,

We know that,

PART-3 : MATHEMATICS

37) ƒ(x) = 2014tan2013x sec2x – 2010tan2009x.sec2x

⇒ ...(B)

...(C)

38) ∵ –x2 + x + 1 > 0

∴ (A) true

∵ If
sin–1x > cos–1x
∴ (C) true.

39) ƒ′(x) =

(LH rule)

ƒ(1) =
 (et – 1)

40) For Rolle's theorem ƒ(1) = ƒ(12)

1 + a + b = 8 + 4a + 2b
3a + b + 7 = 0

41) ƒ′(C1) = ƒ(2) – ƒ(1) & ƒ′(C2) = ƒ(3) – ƒ(2);

ƒ′(C3) = ƒ(4) – ƒ(3)
ƒ′(C1) = ƒ′(C2) = ƒ′(C3)
ƒ′′(C) = 0 for at least two values
ƒ′(x) is non monotonic

42)
Global minimum value of ƒ(x) is zero

43)

by (4,0) ⇒ c = 0

so area

44)
∴ y = xe–x + λ
As f(0) = 0 ⇒ λ = 0

Also,
⇒ x = 2 is point of inflection.
∴ Required area
=.

45)
(|x| – 3)2 + (|y| – 3)2 ≤ 9

⇒ full circle.
⇒ area = 9π
k=9

46)

= x(1 – x5)10 –
= x(1 – x5)10 + 50I9 – 50I10

⇒
⇒ n = 50; m = 51

47)

⇒ ƒ′(x) = –2 = constant

48)

for finite, non zero limit, n = 4

49)
I.F. =
so solution is
⇒ y = cosx + α cos2x put
⇒ α = –2
∴ y = cosx – 2cos2x

∴ ymin =

50) ⇒

51) (Linear differential equation)

⇒ ƒ(x) = (x – 1)2 + 1
∴ Required area

52)

53)
54) =
∴ α = – 9, β = 3
⇒ (α + 3β) = 0