15-11-2025

6001CJA10102225002ADV JA

PHYSICS

SECTION-I(i)

1) The particle of mass m and charge q is thrown with initial velocity v0 at an angle α with the
horizontal. In space there exists an electric field of strength E at angle β with the downward vertical

away from the point of projection. The time of flight is :

(A)

(B)

(C)

(D)

2) A car starting from rest is accelerated at constant rate until it attains a speed of 16m/s. It moves
with the constant speed 16 m/s for some time and then it is retarded at other constant rate until it
comes to rest. Considering that the car moves with constant speed for half of the time of total
journey, what will be the average speed of the car for the whole journey (in m/s) ?

(A) 18
(B) 12
(C) 9
(D) 15

3) Which of the following is TRUE regarding non-uniform circular motion ?

(A)

(B)

(C)

(D)
4) A ball of mass 3 kg and radius 3cm moving with velocity of 10 m/s collides obliquely with another
ball of mass 2 kg & radius 2 cm, kept at rest. The impact parameter is 3 cm. It is found that after
collision, the 3 kg ball has a velocity component of 2 m/s along the common normal. Find the

coefficient of restitution.

(A)

(B)

(C)

(D)

SECTION-I(ii)

1) Two spherical planets have the same mass but densities in the ratio 1: 8. For these planets, the :-

(A) Acceleration due to gravity will be in the ratio 4 : 1.

(B) Acceleration due to gravity will be in the ratio 1 : 4.
(C) Escape velocities from their surfaces will be in the ratio .
(D) Escape velocities from their surfaces will be in the ratio .

2) A bead slides on a fixed frictionless wire bent into a horizontal semicircle of radius R0 as shown in
figure. In addition to any normal forces exerted by the wire, the bead is subjected to an external
force that points directly away from origin and depends on distance r from the origin according to

the formula :-

(A) Given force is a central force.

(B) Given force is a conservative force.

(C)
Work done by external force as bead leaves the track is .
(D)
Speed of bead as it leaves the wire is .

3) A point charge +Q is kept at a distance 3a from the centre of a spherical conducting shell of
charge -3Q and radius a.

Assuming , mark the CORRECT statements(s):-

Before closing switch the electric field at C due to the spherical shell is
(A)

(B)
Before closing switch the potential of the shell is

(C)
After closing the key,the charge on the shell is
(D) After closing the key, the charge of the shell is zero

SECTION-I(iii)

1)

Three ants are sitting on the vertices of an equilateral triangle of side of a. At t = 0, ant 1 starts
approaching ant 2 with a speed v, ant 2 starts approaching ant 3 with a speed v and ant 3 start
approaching ant 1 with a speed v. If a = 1m, v = 1m/s match the following

List–I List–II

The three ant meet at the centroid of

(P) (1)
the triangle at time (in s)

The angular velocity (in rad/s) of ant 2

(Q) (2)
with respect to ant 1 at t = 0 is

The angular acceleration (in rad/s2) of

(R) (3)
ant 2 with respect to ant 1 at t = 0 is

The area of the equilateral triangle (in

(S) m2) formed by the three ants at any (4)
time t = a/4v will be
(A) P → 1;Q → 4;R → 2;S → 3
(B) P → 3;Q → 1;R → 4;S → 2
(C) P → 4;Q → 3;R → 1;S → 2
(D) P → 3;Q → 1;R → 1;S → 4

2) A block of mass m is stationary with respect to a rough wedge as shown in figure. The system
travels for time 't' with acceleration 'a' starting from rest. All terms of List-II are wrt ground frame.

List-I List-II

(P) 144 J (1) Magnitude of work done by the gravity on the block

(Q) 32 J (2) Work done by the normal reaction on the block

(R) 48 J (3) Work done by the friction between block and wedge on block

(S) 160 J (4) Work done by all the forces on the block

(5) Change in kinetic energy of the block

(A) P → 2;Q → 4,5;R → 3;S → 1
(B) P → 4,5;Q → 1;R → 3;S → 2
(C) P → 2;Q → 4,5;R → 1;S → 3
(D) P → 3;Q → 4,5;R → 1;S → 2

3) List I describes four systems, each with two particles A and B in relative motion as shown in figure. List II gives possible

magnitudes of then relative velocities (in ms–1) at time

List-I List-II

A and B are moving on a horizontal circle of radius 1 m with uniform angular speed ω = 1 rad s . The
–1

initial angular positions of A and B at time t = 0 are θ = 0 and θ = respectively.

(I) (P)
 Projectiles A and B are fired (in the same vertical plane) at t = 0 and t = 0.1 s respectively, with the

same speed m s–1 and at 45° from the horizontal plane. The initial separation between A and

(II) (Q)

B is large enough so that they do not collide, (g = 10 m s–2 ).

Two harmonic oscillators A and B moving in the x direction according to xA = x0 sin and xB = x sin

0 0

respectively, starting from t = 0. Take x = 1 m, t = 1 s.

(III) (R)

Particle A is rotating in a horizontal circular path of radius 1 m on the xy plane, with constant angular
speed ω = 1 rad s–1. Particle B is moving up at a constant speed 3 m s–1 in the vertical direction as

(IV) (S)

shown in the figure. (Ignore gravity.)

(T)

Which one of the following options is correct?

(A) I → R;II → T;III → P;IV → S
(B) I → S;II → P;III → Q;IV → R
(C) I → S;II → T;III → P;IV → R
(D) I → T;II → P;III → R;IV → S

4) Two men of mass 60 kg and 80 kg stand on a plank of mass 20 kg. Both of them can jump with a
velocity of 1 m/s relative to the plank. In each event shown in List-I, find the velocity of plank after
the event. Sign of right direction is (+ve) and (–ve) for left direction.

List-I List-II
 (I) Ram alone jumps to the left (P)

(II) Shyam alone jumps to the right (Q)

Ram jumps to left and Shyam

(III) (R)
jumps to right simultaneously

Ram jumps to left and after that

(IV) (S)
Shyam jumps to right.

(T)

(A) I → R;II → Q;III → S;IV → P

(B) I → R;II → Q;III → P;IV → S
(C) I → P;II → Q;III → T;IV → P
(D) I → S;II → T;III → P;IV → Q

SECTION-II

1)

A solid sphere of radius R has a charge Q distributed in its volume with a charge density ρ = kra,

where K and a are constants and r is the distance from its centre. if the electric field at r = is
times that at r = R, find the value of a.

2) A satellite is projected into space from a point ‘P’ at a distance ‘r0’ from the centre of the earth

with an initial velocity at an angle α = 37° with the horizontal at point 'P' as shown in
the figure. It is found that the satellite is propelled into an elliptical orbit. If the eccentricity of the
elliptical orbit is e, then value of 5e is ?

3) Two balloons A and B are released simultaneously from two buildings of different heights and
250 m apart. Balloon A rises with constant velocity 10 m/s and balloon B rises with constant velocity
of 20 m/s
he wind imparts them a horizontal velocity Vx = 0.5 y where y is the height from the point of
release. Find the time after which the balloons Collide (in deca second)

4) A pair of wedges are located on a horizontal surface. the coefficient of friction (both sliding and
static) between the wedges is µ, the coefficient of friction between the bottom wedge B and the
horizontal surface is µ, and the angle of the wedge is θ. The mass of the top wedge A is m, and the
mass of the bottom wedge B is M = 2m. A horizontal force F directed to the left is applied to the
bottom wedge as shown in the figure. Maximum value (in N) of F for which top wedge does not slip

on wedge is 15 x. Value of x is (Take m = 1kg, θ = 45°, µ = 1/2)

5) A heavy particle is attached to one end of a light string of length ℓ whose other end is fixed at O.
The particle is projected horizontally with a velocity v0 from its lowest position A. When the angular
displacement of the string is more than 90°, the particle leaves the circular path at B. The string

again becomes taut at C such that B,O,C are colinear. If , find the value of n.

6) A simple pendulum of inextensible string of length l and mass m is hinged at point A in a vertical
plane as shown in the figure. The ball is released from the same horizontal level as that of A and at a

distance from point ‘A’. At the lowest point bob hits a block of identical mass m elastically. Find

the maximum compression in the spring ( and ground is smooth)

 CHEMISTRY

SECTION-I(i)

1) Which of the following complexes show six coordination number

2–
(A) [Zn(CN)4]
3+
(B) [Cr(H2O)6]
2–
(C) [Cu(CN)4]
2+
(D) [Ni(NH3)4]

2) The refining method used when the metal and the impurities have low and high melting
temperatures, respectively, is -

(A) zone refining

(B) liquation
(C) vapour phase refining
(D) distillation

3)

Given below are two statements

Statement-I : Acetaldehyde and Benzaldehyde can be differentiated using Tollens test.
Statement-II: Lassaigne's test for the detection of nitrogen will fail in case of NH2 – NH2.
In the light of above statements, choose the correct answer from the following.

(A) Both Statement-I and Statement-II are correct

(B) Both Statement-I and Statement-II are incorrect
(C) Statement-I is correct but Statement-II is incorrect
(D) Statement-I is incorrect but Statement-II is correct

4) Which of the following is correct statement?

(A)

+ 2HCHO

(B)

(C)

(D) All of these

SECTION-I(ii)

1) The correct statement(s) regarding the binary transition metal carbonyl compounds is (are)
(Atomic numbers : Fe = 26, Ni = 28)

(A) Total number of valence shell electrons at metal centre in Fe(CO)5 or Ni(CO)4 is 16
(B) These are predominantly low spin in nature
(C) Metal - carbon bond strengthens when the oxidation state of the metal is lowered
(D) The carbonyl C–O bond weakens when the oxidation state of the metal is increased

2) Which of the following amines after diazotization will form deeply coloured azodye with alkaline
solution of b–Naphthol?

(A)

(B)

(C)
(D)

3) Which of the following tests will be given by (Squaric acid) ?

(A) Br2 water test

(B) 2, 4-DNP test
(C) Neutral FeCl3
(D) Tollen’s test

SECTION-I(iii)

1) Match the four starting materials (P , Q, R, S) given in List I with the corresponding reaction
scheme (I, II, III, IV) provided in List - II and select the correct answer using the code given below in
lists.

List-I List-II

Scheme I

(P) (1)

(2) Scheme II
(Q) (2)

(3) Scheme III

(R) (3)

Scheme IV

(S) (4)

Code:
(A) P → 1;Q → 4;R → 2;S → 3
(B) P → 3;Q → 1;R → 4;S → 2
(C) P → 3;Q → 4;R → 2;S → 1
(D) P → 4;Q → 1;R → 3;S → 2
2) Match List – I with List – II.

List – I List – II
Natural Amino acid One Letter Code

(A) Arginine (I) D

(B) Aspartic acid (II) N

(C) Asparagine (III) A

(D) Alanine (IV) R

Choose the correct answer from the options given below :-

(A) A → IV;B → I;C → III;D → II

(B) A → I;B → III;C → IV;D → II
(C) A → III;B → I;C → II;D → IV
(D) A → IV;B → I;C → II;D → III

3) Match items of Row I with those of Row II.

Row I Row I

(P) (i) α-D-(-)Fructofuranose.

(Q) (ii) β-D-(-)Fructofuranose

(R) (iii) α-D-(-) Glucopyranose.

(S) (iv) β-D-(-)Glucopyranose

Correct match is
(A) P → iv;Q → iii;R → i;S → ii
(B) P → i;Q → ii;R → iii;S → iv
(C) P → iii;Q → iv;R → ii;S → i
(D) P → iii;Q → iv;R → i;S → ii

4) Match List I with List II:

 List I-(Monomer) List II-(Polymer)

(A) Tetrafluoroethene (I) Orlon

(B) Acrylonitrile (II) Natural rubber

(C) Caprolactam (III) Teflon

(D) Isoprene (IV) Nylon-6

Choose the correct answer from the options given below : [JEE (Main) 2023]
(A) A → (III);B → (I);C → (IV);D → (II)
(B) A → (III);B → (IV);C → (II);D → (I)
(C) A → (IV);B → (I);C → (II);D → (III)
(D) A → (II);B → (III);C → (IV);D → (I)

SECTION-II

1) Consider the following reaction sequence.

Find the sum of number of stereoisomers of complexes P, Q and R.

2) Scheme 1 and 2 describe the conversion of P to Q and R to S, respectively. Scheme 3 describes

the synthesis of T from Q and S. The total number of Br atoms in a molecule of T is ________

Scheme 1 :

Scheme 2 :

Scheme 3 :
3) The number of reducing sugars among the following is -

4) The total number of distinct naturally occurring amino acids obtained by complete acidic
hydrolysis of the peptide shown below is

5) Number of compounds giving (i) red colouration with ceric ammonium nitrate and also (ii) positive

iodoform test from the following is _______

6) In the given reaction The number of sp2 hybridised

carbon present in the product 'X' is _____.

MATHEMATICS

SECTION-I(i)
1) The slope of the line which belongs to family of lines (1 + λ)x + (λ – 1)y + 2(1 – λ) = 0 and makes
shortest intercept on x2 = 4y – 4 is-

(A)

(B) 0

(C)

(D)

2) Which of the following points lies on the locus of the foot of perpendicular drawn upon any

tangent to the ellipse, from any of its foci ?

(A)

(B)

(C)

(D) (1,2)

3) Given p,q,r are three distinct real numbers such that

, then roots of above equation are-

(A)

(B)

(C)

(D) roots depends on values of p,q,r

4) There is a certain sequence of positive real numbers. Beginning from the third term, each term of
the sequence is the sum of all the previous terms. The seventh term is equal to 1000 and the first
term is equal to 1. The second term of this sequence is equal to

(A) 246

(B)

(C)

(D) 124

SECTION-I(ii)

1) The tangent PT and the normal PN to the parabola y2 = 4ax at a point P on it meet its axis at
points T and N, respectively. The locus of the centroid of the triangle PTN is a parabola whose
(A)
vertex is
(B) directrix is x =0

(C)
latus rectum is
(D) focus is (a, 0)

2) Let the eccentricity of the hyperbola be reciprocal to that of the ellipse x2 + 4y2 = 4. If
the hyperbola passes through a focus of the ellipse, then -

the equation of the hyperbola is

(A)

(B) a focus of the hyperbola is (2,0)

(C)
the eccentricity of the hyperbola is
(D) the equation of the hyperbola is x2–3y2=3

3) If and cosA + cosB = 1, then -

(A) cos(A – B) = 1/3

(B)
| cosA – cosB | =

(C)

(D)

SECTION-I(iii)

1) Suppose a parabola has vertex and equation y = ax2 + bx + c (where a > 0 and a + b +
c is integer). Let 'a' takes its minimum possible value under given condition, then

Match List-I with List-II and select the correct answer using the code
given below the list.

List-I List-II

(P) 2(latus rectum of parabola) is (1) 9

 (Q) If equation of directrix is 4y + λ = 0, then 4λ2 is (2) 81

(R) If the value of a is (where p & q are relatively prime), (3) 11

then p + q is

(S) (4) 36
If (α, 0) lies on parabola, then is
(A) P → 1;Q → 2;R → 3;S → 4
(B) P → 3;Q → 1;R → 2;S → 4
(C) P → 1;Q → 4;R → 3;S → 2
(D) P → 4;Q → 1;R → 2;S → 3

2)

List-I List-II

If α, β, γ, δ are the solutions of the equation

(P) (A)
, no two of which have equal
tangent then tanα + tanβ + tanγ + tanδ is equal to

In a ΔABC are in H.P., then minimum

(Q) (B)
value of is:

(R) (C) 0
is equal to

(S) (D)
is equal to
(A) P → A;Q → B;R → C;S → D
(B) P → D;Q → C;R → B;S → A
(C) P → C;Q → D;R → A;S → B
(D) P → B;Q → D;R → C;S → A

3) Match List-I with List-II and select the correct answer using the code given below the list.
List-I List-II
(P) Numbr of solution of equation sgn({x}) = |1 –x|, is (1) 30
(where sgn(.) and {.} denote signum funtion and (2) 1
fraction part function respctively)

(Q) is equal to (3) 3

rd th th
(R) If the 3 , 6 and 10 terms of a non-constant A.P. are in G.P, (4) 4
then the common ratio of G.P is (5) 35

(S) If α,β,γ are roots of the equation x3 + ax + 10 = 0, then value of (6)

 (α + β)3 + (β + γ)3 + (γ + α)3 is

(A) P → 2;Q → 5;R → 6;S → 1

(B) P → 2;Q → 1;R → 6;S → 3
(C) P → 3;Q → 5;R → 4;S → 1
(D) P → 3;Q → 1;R → 4;S → 3

4) Match the column

Column - I Column - II

(A) A tangent drawn to hyperbola2

at (p) 17
forms a triangle of area 3a square units, with coordinate
axes, then the square of its eccentricity is equal to

If the eccentricity of the hyperbola x2 – y2 sec2θ = 5 is

times the eccentricity of the ellipse x2sec2θ + y2 = 25
(B) (q) 8

then smallest positive value of θ is , value of 'p' is

(C) For the hyperbola , angle between its (r) 16

asymptotes is then value of ' ' is

For the hyperbola xy = 8 any tangent of it at P

(D) meets co-ordinate axes at Q and R then area of triangle (s) 24
CQR where 'c' is centre of the hyperbola is
(A) P → 1;Q → 4;R → 2,3;S → 3
(B) P → 1;Q → 3;R → 2;S → 1
(C) P → 4;Q → 1,2;R → 3,4;S → 4
(D) P → 1;Q → 2;R → 2,3,4;S → 4

SECTION-II

1) From a point A common tangents are drawn to the circle and parabola y2 = 4ax. If
the area of the quadrilateral formed by the common tangents, the chord of contact of the circle and

the chord of contact of the parabola is . Find m.

2) Common tangents are drawn to the parabola y2 = 4x & the ellipse 3x2 + 8y2 = 48 touching the

parabola at A & B and the ellipse at C & D. If the area of the quadrilateral is m. Find .

3) If the tangent at the point (h, k) to the hyperbola cuts the auxiliary circle in points
whose ordinates are y1 and y2 then if . Find m.

4) If ƒn(θ) = then ƒ29 is

5) If α is a root of x3 – x – 1 = 0, then the value of α10 + 2α8 – α7 – 3α6 – 3α5 + 4α4 + 2α3 – 4α2 – 6α +
2 is :

6) Let tn be nth term of a G.P. with common ratio r. If r < 0, and t2 + t5 = 216 and , then
the value of (a + b – 110) is (a and b are coprime numbers)
 ANSWER KEYS

PHYSICS

SECTION-I(i)

Q. 1 2 3 4
A. C B D C

SECTION-I(ii)

Q. 5 6 7
A. B,D A,B,C A,B,C

SECTION-I(iii)

Q. 8 9 10 11
A. B A C A

SECTION-II

Q. 12 13 14 15 16 17
A. 2 3 1 7 3 7

CHEMISTRY

SECTION-I(i)

Q. 18 19 20 21
A. B B D D

SECTION-I(ii)

Q. 22 23 24
A. B,C B,D A,B,C

SECTION-I(iii)

Q. 25 26 27 28
A. C D D A

SECTION-II

Q. 29 30 31 32 33 34
A. 6 4 3 1 3 8

MATHEMATICS
 SECTION-I(i)

Q. 35 36 37 38
A. B A B B

SECTION-I(ii)

Q. 39 40 41
A. A,D B,D B,C

SECTION-I(iii)

Q. 42 43 44 45
A. C C A A

SECTION-II

Q. 46 47 48 49 50 51
A. 5 5 2 4 4 5
 SOLUTIONS

PHYSICS

1) =

2)

m/s

3) (A) always perpendicular to motion plane

so

(B) (Not correct)

as, α ≠ 0

(C) [ not constant]

(D) for non uniform notion

So option (D) is correct.

4)
From figure

sin θ =
θ = 37°
by momentum conservation along the line of impact.
3×8=3×2+2×v
v=9

∴e=
5)

The correct option is (4) escape velocities from their surfaces will be in the ratio 1:√2
Given:
ρ1:ρ2 =1:8 and m1 = m2

We know that, ρ =
⇒ρ1V1 = ρ2V2

As we know that the acceleration due to gravity, g =

Now escape velocity,

6) is a central force, because direction of force is always away from the fix

point origin & work done by this force is zero in any close loop force is
conservative

Work done by the force on bead = =

7)

'S' i s open
'S' i s closed

8) (P) Approaching velocity of 1 and 2 towards each other is V + Vcos60º and they cover distance a time =

= = =

(Q) w21 = (V⊥/r)

⇒ (Vsin60°)/a = = rad/sec

(R) w21 =
r21 = a – (V + vcos60º)t

w21 = a = 1, V = 1
 α=

w21 =

α= ⇒
α at t = 0

0
a =

= rad/sec2
(S) Area of equilateral triangle

⇒ (side)2
side at any time t = a – [(V + Vcos60º)t]

at t = ⇒ sec

side = 1 – ⇒

Area ⇒

= m2

9)

...(1)

So, f = 6N
10) (I)
As remains constant.
Also, vA = vB = 1 m/s
So,

(II)

(III) xA = sin t

xB = cost

(IV) are always perpendicular

So,

11) (I)
Pi = Pf ⇒ 60(1 – V) = 100 V

opposite to velocity of Ram i.e. m/s towards right.

(II) 80 V = 80 (1 – V)

⇒ V = m / sec left.
(III) 80(1 + V) + 60(–1 + V) + 20V = 0

V= m/s

(IV) After jump of Ram 3/8

Now (80 + 20) = 80(1 + V) + 20 V

12)

Calculating charge contained inside sphere of radius "r"

dQ = ρdv
dQ = kra, 4pr2dr

Q(r) =

Q(R) =

Electric field at

Electric field at R = E(R)

E(R) =

2a + 3 = 32 = 25
a+3=5
a=2

13) Total mechanical energy

∴ Length of semi-major axis, a = r0
Hence point 'P' must be an extreme
Point of the minor axis of the elliptical orbit
∵ α sin α = ae
e = sin α = sin 37° = 0.6
Hence the eccentricity of the elliptical orbit
e = 0.60

14) YA = 10 t
Horizontal distance covered by A in time t

Vertical distance by B in time t

YB = 20 t
Horizontal distance covered by B in time t

XB = 5t2
At the time of collision
XB – XA = the seperation between the buildings = 250 m

15)

Assume the block does not slip. Considering the horizontal forces on the entire system gives

F – 3 µmg = 3ma ⇒ a = .
When F is small, the top wedge wants to slide downward, so static friction points up the ramp.
Considering the horizontal and vertical forces on the block gives
N cos θ + f sin θ = mg, N sin θ – f cos θ = ma.
When the minimal force is applied, the friction is maximal, f = µN. Eliminating N gives

ma = mg
and plugging in our first equation gives

Fmin = 3mg = 3mg .

When F is large, the top wedge wants to slide upward, so static friction points down the ramp,
and
N cos θ – f sin θ = mg, N sin θ + f cos θ = ma.
Now setting f = µN gives

Fmax = 3 mg = 3mg
Therefore naively the range of forces so that the block will not slip is
F ∈ [Fmin, Fmax]

Fmax = 3 × 10

= 30 = = 15 × 7
Fmax = 135 N

16)
Let v = speed at B.
Tension in the string at B = 0

....(i)
After B, the motion of particle is that of a projectile. One can consider it a projectile thrown
down the incline B.
The particle hits the incline at C.

∴ 2ℓ = 2ℓ cot2θ
 ∴ cot2θ = 1
Or, θ = 45°
Now we can use conservation of energy between points A and B, which gives

Using (i)

[∵ θ = 45°]

17)

⇒ ℓ = 7m

CHEMISTRY

18)

Ans : (B)
[Cr(H2O)6]3+ ⇒ C.N. = 6

19)

Explanation Question: Name the refining method in which the metal & impurities have law
& high M.P. temperature
 Concept: This question is based on refining process
Solution:

Liquation method is used when the melting point of metal is less compare to the melting point of the
associated impurity.

Final Answer
The correct option is (2)

20)

Both Aliphatic and aromatic aldehyde gives positive tollent test.

NH2 – NH2 not gives lassaigne's test.

21) The correct answer is option (D)

22) (A) Electronic configuration of central metal atom in both cases is [Ar]3d10 4s24p6 (8
electrons in outermost shell and 18 valence electrons respectively).
(B) These are low spin in nature due to the presence of strong field ligand
(C) As density of electron increases on the metal, extent of Synergic bonding increases hence
strengthen the metal- carbon bond
(D) As M-C bond order , CO bond length

23)

24) Squaric acid gives bromine water, 2, 4-DNP and Neutral FeCl3 test.

25)
26)

Question Explanation:
Match the common names of amino acids with their one-letter codes.

Concept: Amino acid nomenclature: one-letter codes.

Solution:
A (Arginine): →R (IV).
B (Aspartic acid): →D (I).
C (Asparagine): →N (II).
D (Alanine): →A (III).

Final Answer:
The correct option is (4).

27) Explanation of Question: Question is asking to match the given cyclic forms of glucose
and fructose from row (i) with their correct names in row (II).
Concept: “This question is based on cyclic structure of glucose and fructose”.
Solution: In cyclic structures, the configuration at the anomeric carbon decides whether the
sugar is α or β. If the –OH group at the anomeric carbon is opposite to the –CH2OH group on
the reference carbon, it is α; if it is on the same side, it is β.

(P) (iii) α–D–Glucopyranose

(Q) (iv) β–D–Glucopyranose

(R) (i) α–D–Fructofuranose

(S) (ii) β–D–Fructofuranose

Final Answer: The correct option is (4)

28)

Question Explanation:
The question requires matching the given list of monomers in List I to the specific polymers
they form in List II.

Concept: This is based on the polymers and name of their monomers.

Solution:
 A. Tetrafluoroethene (CF2​=CF2​) undergoes addition polymerization to form Teflon
(Polytetrafluoroethene).

B. Acrylonitrile (CH2​=CHCN) polymerizes to form Orlon (Polyacrylonitrile or PAN).

C. Caprolactam undergoes ring-opening polymerization to yield Nylon-6.

D. Isoprene (2-methyl-1,3-butadiene) is the monomer of Natural rubber.

The correct matching is: A→(III), B→(I), C→(IV), D→(II).

Final Answer:
option (1)

29) P = [Pt(Py)2Cl2] Q = [Pt(Py)2(NH3)Cl]+

cis + trans cis + trans
+
R = [Pt(NH3)2(Py)Cl]
 cis + trans

30)

Explaining the Question :- Question is asking about the number of bromine atoms in a
molecule of final product.
Concept :- This Question is based on multiple concept
Solution :-

(1)

(2)

Number of bromine atoms in (T) = 4

Final Answer :- (4)

31)

Explaining the Question :-

Question is asking about the number of reducing sugar among the following
Concept:-
 This question is based on those sugar having hemiacetal linkage present an anomeric carbon
atom are called reducing sugar
Solution :-
(a), (e) and (f) are reducing sugar because they have hemiacetal linkage on anomeric carbon
atom.
Final Answer :- (3)

32) Only one naturally occuring amino acid glycine is present.

33)

34)

MATHEMATICS

35) Since each line of family of line passes through the focus of given parabola hence shortest
intercept is L.R.

36) Let foot of perpendicular is (h, k)

(Given)

a =2 , ,

∴ Focus (ae,0)
Equation of tangent
 Passes throguh (h,k)
(k – mh)2 = 4m2 + 2 ...(1)

line perpendicular to tangent will have slope

y–0=

(h + mk)2 = 2 ...(2)
Add equaiton (1) and (2)
k2(1 + m2) + h2(1 + m2) = 4(1 + m2)
h2 + k2 = 4
x2 + y2 = 4 (Auxilary circle)

∴ lies on the locus.

37) Let
∴ ƒ(p) = p2, ƒ(q) = q2, ƒ(r) = r2
consider an equation ƒ(x) = x2 ....(1)
equation has roots p,q,r
but equation (1) is quadratic equation and it has more than two roots so equation (1) is an
identity.
hence in order to solve ƒ(x) = x + 1 it is sufficient to solve

x2 = x + 1 ⇒ x2 – x – 1 = 0 ⇒

38) sequence is t1 + t2 + t3 + t4 + ........

t3 = t1 + t2 ; t7 = 1000
t1 = 1
but t7 = t1 + t2 + t3 + t4 + t5 + t6
1000 = 2(t1 + t2 + t3 + t4 + t5)
(as t6 = t1 + t2 + t3 + t4 + t6)
= 4(t1 + t2 + t3 + t4)
(t4 = t1 + t2 + t3)
= 8(t1 + t2 + t3)
1000 = 16(t1 + t2)

t1 + t2 =

⇒ t2 = –1= –1=
39) Let centroid of Δ PTN is R (h. K)

∴ h= &k=

⇒ 3h = 2a + a .

⇒ 3h = 2a +
⇒ 9k2 = 4 a (3h – 2a)
locus of centroid is

y2 =

∴ vertex

directric

⇒ x=

Latus rectum =

focus
i.e. (a, 0)

40) Question Explanation: Find properties of a hyperbola related to a given ellipse.

Concept: Eccentricity and Foci of Conics.
Solution: First, find the eccentricity and foci of the given ellipse. Use the reciprocal relation
to find the eccentricity of the hyperbola. Since the hyperbola passes through the focus of the
ellipse, we can find its parameters and check the given statements.
Calculation:

Given hyperbola is

ellipse is

eccentricity of ellipse =

eccentricity of hyperbola =

⇒ ⇒ 3b2 = a2 ... (1)

also hyperbola passes through foci of ellipse

⇒ a2 = 3 ... (2)
from (1) & (2)
b2 = 1

equation of hyperbola is
⇒ x2 – 3y2 = 3

eccentricity of hyperbola

focus of hyperbola =
Final Answer: Options 2, and 4 are correct.

41) & cos A + cos B = 1

Also cos(A – B) + cos (A + B)

(cos A – cos B)2 = (cos A + cos B)2 – 4 cos A . cos B

42)
a = –2b

a = 18 + 16c
Hence parabola is

Now check options.

43)

44) (Q)
(R) (a + 5d)2 = (a + 2d) (a +9d)
⇒ a = 7d(∵ d ≠ 0)

c.d
(S) α + β + γ = 0 and αβγ = –10
∴ Given expression = –α3 – β3 – γ3 = 30

45)

46)

Equation of any tangent to the parabola, y2 = 4ax is .

This line will touch the circle

if

⇒
⇒ 2 = m 4 + m2
⇒ m4 + m2 – 2 = 0
⇒ m4 + 2m2 – m2 – 2 = 0
⇒ m2(m2 + 2) – 1 (m2 + 2) = 0
⇒ (m2 – 1) (m2 + 2) = 0
⇒ m2 – 1 = 0, m2 –2 (which is not possible).
⇒ m = ±1
Therefore, two common tangents are
y = x + a and y = – x – a
These two intersect at A(–a, 0)

The chord of contact of A(–a, 0) for the circle is

or
and chord of contact of A(–a, 0) for the parabola y2 = 4ax is
0 · y = 2a(x – a) or x = a
Again length of BC = 2KB
=

= = =a
and we know that DE is the latus rectum of the parabola so its length is 4a.
Thus area of the trapezium

BCDE = (BC + DE) (KL)

47) y2 = 4x & 3x2 + 8y2 = 48

Let be a tangent to the parabola.

It is common to the ellipse if

16m4 + 6m2 – 1 = 0

∴ &
Coordinates of A

(x + 8)2 = 32x
x2 + 16x + 64 = 32x
x2 – 16x + 64 = 0
(x – 8)2 = 0
x=8
∴ y2 = 4 × 8
∴
Co-ordinate of C

3x2 + (x + 8)2 = 48
4x2 + 16x + 16 = 0
x2 + 4x + 4 = 0
(x + 2)2 = 0
x = –2
3 × 4 + 8y2 = 48
8y2 = 36

Area ABCD (CD + AB) × h

48)

Tangent at (h, k)
x2 + y2 = a2 Auxiliary circle

⇒ ⇒

Now

⇒ Proved
∵ (h, k) lies an hyperbola.

49) ƒn(θ) =
 , n = 29

50) Given a3 = a + 1 ⇒ α6 = (α2 + 1 + 2α)

α7(α3 + 2α – 1) – α3(3α3 – 4α – 2) – 3α5 – 4α2 – 6α + 2
= α7(α + 1 + 2α – 1) – α3(3α + 3 – 4α – 2) – 3α5 – 4α2 – 6α + 2
= 3α8 + α4 – α3 – 3α5 – 4α2 – 6α + 2
= 3α5(α3 – 1) + α4 – α – 1 – (4α2 + 6α – 2)
= 3α6 + αα3 – α – 1 – 4α2 – 6α + 2
= 3(a2 + 1 + 2α) + α(α + 1) – α – 1 – 4α2 – 6α + 2
= 3 + 2 – 1 = 4.

51)
⇒ r = –2 as r < 0
t2 + t5 = 216
ar + ar4 = 216
–2a + 16a = 216
14a = 216

t1 = a