Polysaccharides
▪ Polysaccharides contain a large number of monosaccharide
units joined together by glycosidic linkages.
▪ These are the most commonly encountered carbohydrates in
nature. For example, starch, cellulose and glycogen.
▪ They mainly act as the food storage or structural materials.
Starch
▪ Starch is the main storage polysaccharide of plants.
▪ It is the most important dietary source for human beings.
▪ High content of starch is found in cereals, roots, tubers and
some vegetables.
▪ It is a polymer of α-glucose and consists of two components—
Amylose and Amylopectin.
Amylose
▪ Amylose is water soluble component which constitutes
about 15-20% of starch.
▪ Chemically amylose is a long unbranched chain with
200-1000 α-D-(+)-glucose units held together by C1– C4
glycosidic linkage.
Amylopectin
▪ Amylopectin is insoluble in water and constitutes
about 80 – 85% of starch.
▪ It is a branched chain polymer
of α-D-glucose units in which
chain is formed by C1–C4
glycosidic linkage whereas
branching occurs by C1–C6
glycosidic linkage.
Cellulose
▪ Cellulose occurs exclusively in plants and it is the most
abundant organic substance in plant kingdom.
▪ It is a predominant constituent of cell wall of plant cells.
Cellulose
▪ Cellulose is a straight chain polysaccharide composed only of β-D-glucose units
which are joined by glycosidic linkage between C1 of one glucose unit and C4 of the
next glucose unit.
Glycogen
▪ The carbohydrates are stored in animal body as glycogen.
▪ It is also known as animal starch because its structure is similar to
amylopectin and is rather more highly branched.
▪ It is present in liver, muscles and brain.
▪ When the body needs glucose, enzymes break the glycogen down to
glucose.
▪ Glycogen is also found in yeast and fungi.
Importance of Carbohydrates
▪ Carbohydrates are essential for life in both plants and animals.
▪ They form a major portion of our food.
▪ Honey has been used for a long time as an instant source of energy
by ‘Vaids’ in ayurvedic system of medicine.
▪ Carbohydrates are used as storage molecules as starch in plants and
glycogen in animals.
▪ Cell wall of bacteria and plants is made up of cellulose.
▪ We build furniture, etc. from cellulose in the form of wood
Importance of Carbohydrates
▪ We build furniture, etc. from cellulose in the form of wood and
clothe ourselves with cellulose in the form of cotton fibre.
▪ They provide raw materials for many important industries like
textiles, paper, lacquers and breweries.
▪ Two aldopentoses viz. D-ribose and 2-deoxy-D-ribose are present in
nucleic acids.
▪ Carbohydrates are found in biosystem in combination with many
proteins and lipids.