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Metals and Non-metals: Reaction Guide

Chapter 3 covers the reactivity series of metals and non-metals, detailing their chemical properties and reactions with oxygen, water, acids, and salt solutions. It includes methods for the extraction of metals, emphasizing electrolytic reduction for highly reactive metals and roasting followed by reduction for medium and least reactive metals. Additionally, the chapter discusses corrosion, prevention methods, and the formation of alloys to enhance desirable properties.
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0% found this document useful (0 votes)
6 views6 pages

Metals and Non-metals: Reaction Guide

Chapter 3 covers the reactivity series of metals and non-metals, detailing their chemical properties and reactions with oxygen, water, acids, and salt solutions. It includes methods for the extraction of metals, emphasizing electrolytic reduction for highly reactive metals and roasting followed by reduction for medium and least reactive metals. Additionally, the chapter discusses corrosion, prevention methods, and the formation of alloys to enhance desirable properties.
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

Yes, Chapters 1 and 2 responses contain everything requested, following all your

strict formatting rules:


1. Word-file pastable font: Plain running text used.
2. Simplified formulas: H2O, CO2, etc., used (no superscripts).
3. No special formatting: No boxes, no tables, no arrows ($\to$).
4. Reaction/Symbol arrow: Replaced with (==>).
5. Full explanation: Details on precipitate (color, type), reaction type, heat info
(Exothermic/Endothermic) are included.
6. Squeezed NCERT: All core NCERT reactions are present.
7. More reactions: Additional relevant reactions (like the excess CO2 test) were
added.
8. Important reactions marked: Key reactions are marked with Board Exam
Importance and potential questions/years mentioned.
I will now proceed with Chapter 3: Metals and Non-metals, which will include the
reactivity series and extraction details as requested.

Chemistry Chapter 3: Metals and Non-metals - Detailed Reaction Sheet


This section covers the essential chemical properties, reactions, the reactivity
series, and the extraction processes of Metals and Non-metals from NCERT Class 10
Chapter 3.
1. Reactivity Series
The arrangement of metals in the decreasing order of their reactivity:
K (Potassium) ==> Na (Sodium) ==> Ca (Calcium) ==> Mg (Magnesium) ==> Al
(Aluminum) ==> Zn (Zinc) ==> Fe (Iron) ==> Pb (Lead) ==> H (Hydrogen) ==> Cu
(Copper) ==> Hg (Mercury) ==> Ag (Silver) ==> Au (Gold)
• Highly Reactive: K, Na, Ca, Mg (React vigorously, even with cold water/air).
• Medium Reactive: Al, Zn, Fe, Pb (React with steam/hot water, react with
acids).
• Least Reactive: Cu, Hg, Ag, Au (Do not react easily).
2. Chemical Properties and Reactions
2.1 Reaction of Metals with Oxygen (Air)
General: Metal + Oxygen ==> Metal Oxide
1. Potassium/Sodium: React so vigorously that they catch fire if kept in the open.
o Reaction: 4Na (Sodium) + O2 (Oxygen) ==> 2Na2O (Sodium Oxide).
o Details: These are stored in Kerosene oil to prevent reaction with air
and moisture.
2. Magnesium: Burns with a dazzling white flame (as seen in Chapter 1).
o Reaction: 2Mg (Magnesium) + O2 (Oxygen) ==> 2MgO (Magnesium
Oxide).
3. Aluminum, Zinc, Lead: Form a thin oxide layer on the surface that prevents
further oxidation (self-protecting).
o Details: Aluminum oxide is Amphoteric (reacts with both acids and
bases).
Amphoteric Oxide Reactions:
4. Aluminum Oxide with Acid
o Reaction: Al2O3 (Aluminum Oxide) + 6HCl (Acid) ==> 2AlCl3 + 3H2O
5. Aluminum Oxide with Base
o Reaction: Al2O3 (Aluminum Oxide) + 2NaOH (Base) ==> 2NaAlO2
(Sodium Aluminate) + H2O
6. Copper: Does not burn but forms a black coating when heated.
o Reaction: 2Cu (Copper) + O2 (Oxygen) + Heat ==> 2CuO (Copper(II)
Oxide).
o Details: The black substance formed is Copper(II) Oxide.
2.2 Reaction of Metals with Water
General: Metal + Water ==> Metal Hydroxide/Oxide + Hydrogen Gas.
1. Potassium and Sodium (Highly Reactive): React violently with cold water.
o Reaction: 2Na (Sodium) + 2H2O (Cold Water) ==> 2NaOH (Sodium
Hydroxide) + H2 (Hydrogen Gas) + Heat
o Details: The reaction is so Exothermic that the Hydrogen gas produced
catches fire instantly.
o Board Exam Importance: Frequently asked observation.
2. Calcium (Reactive): Reacts less violently with cold water.
o Reaction: Ca (Calcium) + 2H2O (Cold Water) ==> Ca(OH)2 (Calcium
Hydroxide) + H2 (Hydrogen Gas)
o Details: Calcium starts floating because the bubbles of H2 gas stick to
its surface.
3. Magnesium (Medium Reactive): Reacts only with hot water.
o Reaction: Mg (Magnesium) + 2H2O (Hot Water) ==> Mg(OH)2
(Magnesium Hydroxide) + H2 (Hydrogen Gas)
4. Aluminum, Zinc, Iron (Medium Reactive): React only with steam.
o Reaction: 2Al (Aluminum) + 3H2O (Steam) ==> Al2O3 (Aluminum Oxide)
+ 3H2 (Hydrogen Gas)
o Reaction: 3Fe (Iron) + 4H2O (Steam) ==> Fe3O4 (Iron(II,III) Oxide) +
4H2 (Hydrogen Gas)
5. Lead, Copper, Silver, Gold: Do not react with water or steam.
2.3 Reaction of Metals with Acids
General: Metal + Dilute Acid ==> Salt + Hydrogen Gas.
1. Zinc with Hydrochloric Acid (Review from Ch 2)
o Reaction: Zn (Zinc) + 2HCl (Acid) ==> ZnCl2 (Zinc Chloride) + H2
(Hydrogen Gas).
o Details: Vigorous reaction, H2 gas evolved.
2. Reaction with Nitric Acid ($HNO3$)
o Details: $HNO3$ is a strong Oxidizing Agent. It oxidizes the $H2$
produced to $H2O$. Therefore, $H2$ gas is usually not liberated when
a metal reacts with $HNO3$.
o Exception: Magnesium (Mg) and Manganese (Mn) react with very dilute
$HNO3$ to produce $H2$ gas.
o Reaction: Mg (Magnesium) + 2HNO3 (very dilute) ==> Mg(NO3)2 + H2
2.4 Reaction of Metals with Salt Solutions (Displacement)
General: More Reactive Metal + Less Reactive Metal Salt Solution ==> More Reactive
Metal Salt Solution + Less Reactive Metal.
1. Iron with Copper Sulphate (Review from Ch 1)
o Reaction: Fe (Iron) + CuSO4 (Copper Sulphate, Blue) ==> FeSO4
(Ferrous Sulphate, Green) + Cu (Copper, Red-brown deposit).
o Details: Iron displaces Copper because Iron is higher in the reactivity
series.
2.5 Reaction between Metals and Non-metals (Ionic Compound Formation)
Ionic Bonds: Formed by the transfer of electrons from a metal (loses electrons to
form cations) to a non-metal (gains electrons to form anions).
1. Formation of Sodium Chloride (NaCl)
o Process: Sodium (Valence 1) loses 1 electron. Chlorine (Valence 7)
gains 1 electron.
o Reaction: 2Na (Metal) + Cl2 (Non-metal) ==> 2NaCl (Sodium Chloride).
2. Formation of Magnesium Chloride (MgCl2)
o Process: Magnesium (Valence 2) loses 2 electrons. Two Chlorine
atoms each gain 1 electron.
o Reaction: Mg (Metal) + Cl2 (Non-metal) ==> MgCl2 (Magnesium
Chloride).
3. Formation of Magnesium Oxide (MgO)
o Process: Magnesium (Valence 2) loses 2 electrons. Oxygen (Valence 6)
gains 2 electrons.
o Reaction: 2Mg (Metal) + O2 (Non-metal) ==> 2MgO (Magnesium Oxide).
o Details: Ionic compounds are generally solid, have high melting/boiling
points, and are good conductors of electricity in molten state or in
aqueous solution, but not as a solid.
3. Metallurgy (Extraction of Metals)
Ore: Naturally occurring mineral from which a metal can be profitably extracted.
Gangue (Matrix): Impurities (like soil, sand, rocks) present in the ore.
3.1 Highly Reactive Metals (K, Na, Ca, Mg, Al)
• Method: Electrolytic Reduction (Extraction by electricity).
• Example: Extraction of Sodium/Magnesium:
o Process: Electrolysis of their molten chlorides (e.g., $NaCl$).
o At Cathode (-ve electrode): Metal ions are reduced (Gain electrons).
▪ Reaction: Na+ + e- ==> Na
o At Anode (+ve electrode): Non-metal ions are oxidized (Loss electrons).
▪ Reaction: 2Cl- ==> Cl2 + 2e-
• Example: Extraction of Aluminum: Electrolysis of molten $Al2O3$ mixed with
cryolite.
3.2 Medium Reactive Metals (Zn, Fe, Pb, Cu)
• Ores: Usually found as Sulphide ores or Carbonate ores.
• Step 1: Conversion to Oxide (Easier to reduce metal oxides).
o A. Roasting (For Sulphide ores): Heating strongly in the presence of
air.
▪ Reaction (Zinc Sulphide): 2ZnS (Zinc Sulphide) + 3O2 (Oxygen) +
Heat ==> 2ZnO (Zinc Oxide) + 2SO2 (Sulphur Dioxide).
o B. Calcination (For Carbonate ores): Heating strongly in limited/no air.
▪ Reaction (Zinc Carbonate): ZnCO3 (Zinc Carbonate) + Heat ==>
ZnO (Zinc Oxide) + CO2 (Carbon Dioxide).
• Step 2: Reduction to Metal
o Method: Using Carbon (Coke) as a reducing agent (Smelting).
▪ Reaction: ZnO (Zinc Oxide) + C (Carbon/Coke) + Heat ==> Zn
(Zinc) + CO (Carbon Monoxide).
o Alternative (Highly Reactive Metal Displacement): For very reactive
metals like Manganese, Aluminum can be used for reduction (highly
Exothermic reaction).
▪ Reaction (Thermite Reaction - for Fe): Fe2O3 (Iron Oxide) + 2Al
(Aluminum) + Heat ==> 2Fe (Molten Iron) + Al2O3 (Aluminum
Oxide).
▪ Details: The heat generated is so high that the iron is produced
in a molten state. Used for joining railway tracks or cracked
machine parts.
▪ Board Exam Importance: The Thermite reaction is very
frequently asked for its equation, use, and nature (highly
Exothermic).
3.3 Least Reactive Metals (Cu, Hg, Ag, Au)
• Ores: Usually found as Sulphides (often easily reduced by simple heating).
• Example: Cinnabar (HgS - Mercury Sulphide)
o Step 1: Roasting:
▪ Reaction: 2HgS (Mercury Sulphide) + 3O2 (Oxygen) + Heat ==>
2HgO (Mercury Oxide) + 2SO2 (Sulphur Dioxide).
o Step 2: Reduction (by heat alone):
▪ Reaction: 2HgO (Mercury Oxide) + Heat ==> 2Hg (Mercury) + O2
(Oxygen).
• Example: Copper Sulphide (Cu2S)
o Details: Can be reduced by heating the Sulphide ore in air.
▪ Reaction: 2Cu2S + 3O2 ==> 2Cu2O + 2SO2
▪ Reaction: 2Cu2O + Cu2S ==> 6Cu + SO2
3.4 Refining of Metals
• Method: Electrolytic Refining (Most common for Cu, Zn, Sn, Ni, Ag, Au).
• Process: Impure metal is made the anode (+ve terminal). A thin strip of pure
metal is made the cathode (-ve terminal). The electrolyte is a solution of the
metal salt (e.g., $CuSO4$ for Copper refining).
o At Anode: Impure metal dissolves: M ==> M(n+) + n e-
o At Cathode: Pure metal is deposited: M(n+) + n e- ==> M
o Anode Mud: Soluble impurities go into the solution, and insoluble
impurities (like Gold and Silver) settle at the bottom near the anode.
4. Corrosion and Prevention
Corrosion (Review from Ch 1): Eating up of metals.
• Rusting (Iron): Hydrated Iron(III) Oxide (Fe2O3 $\cdot$ xH2O).
• Silver: Tarnishes black due to Silver Sulphide ($Ag2S$).
• Copper: Acquires a green coating of Copper Carbonate ($CuCO3$).
Prevention: Painting, oiling, greasing, galvanization, chrome plating, anodizing,
making alloys.
Galvanization: Coating Iron/Steel with a thin layer of Zinc. Zinc is more reactive than
Iron, so it protects the Iron even if the coating is broken (sacrificial protection).
Anodizing: A method of thickening the oxide layer on Aluminum (makes it more
corrosion resistant and allows it to be dyed).
Alloys: Homogeneous mixtures of two or more metals or a metal and a non-metal.
• Purpose: Enhance desirable properties (e.g., corrosion resistance,
hardness).
• Examples:
o Steel: Iron + Carbon (C).
o Stainless Steel: Iron + Carbon + Nickel (Ni) + Chromium (Cr) (highly
corrosion resistant).
o Brass: Copper (Cu) + Zinc (Zn).
o Bronze: Copper (Cu) + Tin (Sn).
o Amalgam: An alloy of Mercury (Hg) with any other metal.

(This completes Chapter 3. Please confirm if you want me to proceed with Chapter 4:
Carbon and its Compounds).

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