SAKTHI TUITION CENTRE
Date : 10.10.24 UNIT TEST –CHAPTER 3: PERIODIC CLASSIFICATION OF ELEMENTS and 50 marks
CHAPTER 12: BASIC CONCEPTS OF ORGANIC CHEMISTRY
Section A (ONE MARK) 10*1=10 7)Hyper Conjugation is also known as
(a) no bond resonance (b) Baker - nathan effect (c) both (a)and (b)
1) What would be the IUPAC name for an element with atomic number (d) none of these
222? a) bibibiium b) bididium c) didibium d)bibibium
8)Which of the group has highest +I effect?
2) Which of the following elements will have the highest electronegativity? (a) CH3 - (b) CH3 -CH2 - (c) (CH3 )2 -CH- (d) (CH3 )3 -C
a) Chlorine b) Nitrogen c) Cesium d) Fluorine
9)What is the hybridisation state of benzyl carbonium ion?
3) In the third period the first ionization potential is of the order. (a) sp2 (b) spd2 (c) sp3 (d) sp2 d
a) Na > Al > Mg > Si > P b) Na < Al < Mg < Si < P
c) Mg > Na > Si > P > Al d) Na< Al < Mg < P < Si 10)For the following reactions
(A) CH3– CH2 –CH2 Br + KOH ––→ CH3 –CH= CH2 + KBr +H2 O
4) Identify the wrong statement. (B) (CH3 ) 3 CBr + KOH ––→ (CH3 ) 3 COH + KBr
a) Amongst the isoelectronic species, smaller the positive charge on cation,
smaller is the ionic radius
b) Amongst isoelectric species greater the negative charge on the anion, Which of the following statement is correct?
larger is the ionic radius (a) (A) is elimination, (B) and (C) are substitution
c) Atomic radius of the elements increases as one moves down the first (b) (A) is substitution, (B) and (C) are elimination
group of the periodic table
(c) (A) and (B) are elimination and (C) is addition reaction
d) Atomic radius of the elements decreases as one moves across from left to
right in the 2nd period of the periodic table. (d) (A) is elimination, B is substitution and (C) is addition reaction
5) In a given shell the order of screening effect is Section A (2 MARK)[answer any 4 ] 4*2=8
a) s > p > d > f b) s > p > f > d c) f > d > p > s d) f > p > s > d
11) What is modern periodic law?
6)Homolytic fission of covalent bond leads to the formation of 12) What are isoelectronic ions? Give examples.
(a) electrophile (b) nucleophile (c) Carbo cation (d) free radical
"The elements whisper secrets to those who listen." ◔‿◔
SAKTHI TUITION CENTRE
Date : 10.10.24 UNIT TEST –CHAPTER 3: PERIODIC CLASSIFICATION OF ELEMENTS and 50 marks
CHAPTER 12: BASIC CONCEPTS OF ORGANIC CHEMISTRY
13) Why the first ionization enthalpy of sodium is lower than 22)Explain inductive effect and their properties with suitable
that of magnesium while its second ionization enthalpy is higher example.
than that of magnesium? 23) Mention the following substitution reactions i) Nucleophilic
14)What are Nucleophiles and electrophiles? Give suitable ii) Electrophilic iii) Free radical
examples each 24) explain the pauling method for determination of ionic radii
15)What are homolytic and heterolytic cleavages with examples ,By using paulings method calculate the ionic radii of K+ and Cl-
ions in the potassium chloride crystal. Given that dK + -Cl- = 3.14 Å
Section C(3mark) [answer any 4] 4*3=12
25)i) Define electronegativity.
16) Define Ionization enthalpy and explain the trend in the
variation in groups and periods. ii) State the trends in the variation of electronegativity in group
and periods.
17) What is the screening effect and effective nuclear charge
iii) Briefly give the basis for pauling's scale of electronegativity
18) Explain the following, give appropriate reasons.
(i) The ionisation potential of N is greater than that of O
(ii)the diagonal relationship.
19)What is the hybridization and shape of carbon in carbocation,
carbanion, free radical?
20)Explain electromeric effect.
SECTION D(5mark) [answer any 4] 4*5=20
21) Write short notes on (a) Resonance (b) Hyperconjucation
"The elements whisper secrets to those who listen." ◔‿◔