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Chemistry Solutions and Properties Guide

The document outlines various chemistry problems related to solutions, including calculations involving concentrated nitric acid, molality, colligative properties, and Raoult's Law. It also covers concepts such as osmotic pressure, Henry's Law, and azeotropic mixtures, along with specific numerical problems for determining molecular mass and solubility. Additionally, it discusses the behavior of non-ideal solutions and the importance of osmotic pressure measurements.

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3 views1 page

Chemistry Solutions and Properties Guide

The document outlines various chemistry problems related to solutions, including calculations involving concentrated nitric acid, molality, colligative properties, and Raoult's Law. It also covers concepts such as osmotic pressure, Henry's Law, and azeotropic mixtures, along with specific numerical problems for determining molecular mass and solubility. Additionally, it discusses the behavior of non-ideal solutions and the importance of osmotic pressure measurements.

Uploaded by

aadyaaahna77
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as DOCX, PDF, TXT or read online on Scribd

DELITE COACHING CENTRE

G-98, SEC-25, NOIDA mob. – 9810717005


SOLUTION
1. Concentrated Nitric Acid is 69% by mass of HNO3 .Calculate the vol. of this [Link]
contains 19.9gms. of HNO3 ( Density of concentrated nitric acid soln.= 1.4 gm cm-3 )
2. Calculate the molality of a 1 M soln. of NaNO3 .The density of the soln. is 1.25 gm/cm3
3. Explain the following terms:
(a)Colligative properties (b)Osmosis & Osmotic pressure (c)Reverse osmosis (d)Ideal &
Non ideal behavior of soln. (e)Vant’ Hoff factor & abnormal M .
4. State Raoult’s Law. How is it formulated for a solution where solvent alone is volatile.
5. Why is molality more accurate than molarity?
6. What is Henry's law?'Raoult's law is a special case of Henry's law, Explain. How is the
solubility of a gas in liq affected by KH a)at constant pressure b )with increase in
temp.
7. What is called azeotropic mixture ? Give one example each for the two types of
azeotropic mixture.
8. Show that. the following are colligative properties of a solution. (a) Osmotic pressure
(b)Depression of freezing point (c) Lowering of vapour pressure. How would you
determine molecular mass of a solute with each of the above?
9. What type of non- ideality will be exhibited by each of cyclohexane + ethanol & acetone
+chloroiorm mixtures? Give reasons for your answer.
10. Why is osmotic pressure measurement better than the elevation of B. P. method for
determination of molecular mass.
What is reverse osmosis? Give its one of the important uses.
11. When 18 gms solute having the empirical formula CH2O is dissolved in 300 gms water,
it freezes at -0.93 degree C. What is the molecular formula of the solute?
Kf = 1.86 K kg mol-1
12. The osmotic pressure of blood is 8.21 atm at 37 degree C. How much glucose should be
used per litre for an intravenous injection that is at the same osmotic pressure as blood?
13. The freezing point of a solution composed of 5.85 gms of NaCI in 100 gms water is -
3.348°c. Calculate the VAN'T HOFF factor for this solution, Kf =1.86 K kg mol-1.
14. An electrolyte MgCl2 is 50 percent ionised in aqueous solution. Calculate the freezing
point of 1 m of this aqueous solution. Kf = 1.86 K Kg mol-1.
15. Acetic acid associates in benzene to form a dimmer. 1.65 gm of acetic acid when
dissolved in 100gm of benzene raised the b.p. by 0.360 [Link] the Van’t Hoff factor
and degree of association of acetic acid. (Kf = 2.570C/m)
16. If N2 gas is bubbled through water at 293 K, how many millimoles of N2 gas would
dissolve in 1 litre of water. Assume that N2 exert a partial pressure of 0.987 bar. Given
that Henry’s Law constant for N2 at 293 K is 76.48 Kbar.
17. The Henry’s Law constant for the solubility N2 gas in water is 1.0 x 105 atm. The mole
fraction of N2 is 0.8 . What is the no moles of N2 from air dissolved in 10 moles of water
at 298 K and 5 atm pressure.

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