Work Sheet PW VIDYAPEETH Kothapet center
Subject: CHEMISTRY Topic : Quantum Numbers Date of Distribution : 16.08.25
NAME: BATCH : PRAYAS
1. The two electrons have the following sets of quantum numbers:
n l m s
x 3 2 2 ½
y 3 0 0 ½
Which of the following is true?
(A) x and y have same energy (B) x has greater energy than y
(C) x has less energy than y (D) x and y represent same electron
2. Of the following quantum state designations which is/are not allowed state for an electron in an atom.
n l m
I 3 1 -2
II 3 1 0
III 3 0 -1
IV 3 3 0
V 3 0 1/2
(A) I, II (B) III, IV (C) I, III, IV, V (D) I, II, III, IV
+
3. Which set of quantum numbers in possible for the last electron of Mg ?
(A) n = 3, = 2, m = 0, s = + ½ (B) n = 2, = 3, m = 0, s = + ½
(C) n =13, = 0, m = 0, s = + ½ (D) n = 3, = 0, m = 0, s = + ½
4. The correct set of four quantum numbers for the valence electron of rubidium (Z = 37) is:
(a) n = 5, l = 0, m = 0, ms = +1/2 (b) n = 5, l = 1, m = 0, ms = +1/2
(c) n = 5, l = 1, m = 1, ms = +1/2 (d) n = 6, l = 0, m = 0, m s = +1/2
5. Correct the arrangement of the energies of orbitals given 4f, 6p, 4d and 5s is
(A) 4d < 5s < 4f < 6p (B) 5s < 6p < 4f < 4d (C) 4d < 4f < 5s < 6p
(D) 5s < 4d < 4f < 6p
2 2 4
6. If the electronic cofiguration of oxygen atom is written as 1s ,2s ,2p
It would violate
(a) Hund's rule (b) pauli's exclusion principle (c) both Hund's and Pauli's principles (d) none of these
7. What are the values of the orbital angular momentum of an electron in the orbitals 1s, 3s, 3d and 2p-
(A) 0 , 0 , 6 , 2 (B) 1,1, 4 , 2 (C) 0 ,1, 6 , 3 (D) 0 , 0 , 20 , 6
8. The value of the magnetic moment of a particular ion is 2.83 Bohr magneton. The ion is-
(A) Fe 2 (B) Ni 2 (C) Mn 2 (D) Co 3
9. Which of the following sets of quantum numbers is correct for an electron in 4f orbital?
(A) n = 4, l = 3, m = +3, s = +1/2 (B) n = 4, l = 4, m = –4, s = –1/2
(C) n = 4, l = -3, m = +1, s = +1/2 (D) n = 4, l = 4, m = -3, s = +1/2
10. Which one of the following sets of ions represents the collection of isoelectronic species?
+ 2+ 3+ – + 2+ 3+ – + – 2+ 3+ + 2+ 3+ –
(A) K , Ca , Sc , Cl (B) Na , Ca , Sc , F (C) K , Cl , Mg , Sc (D) Na , Mg , Al , Cl
11. The orbital diagram in which both the pauli’s exclusion principles and Hund’s rule are violated is
(A) (B)
(C) (D)
n+
12. Magnetic moment of X (Z = 26) is 24 B.M. The no. of unpaired electron and the value of ‘n’ respectively are
(A) 4, 2 (B) 3, 6 (C) 2, 1 (D) 0, 2
PW VIDYAPEETH-KOTHAPET, Victoria Memorial, 8-116, MH 65,Narsimha Puri Colony, Huda Colony, [Link], Hyderabad,
Telangana 500 035.
Work Sheet Page 2 of 2
13. Orbit angular momentum and orbital angular momentum of 3s electron are respectively
h h 1.5h 1.5h
(A) 1.5 ,0 (B) 0,1.5 (C) , 2 (D) 2,
2 2 2
14. Which of the following statements is not correct ?
(A) The shape of an atomic orbital depends on the azimuthal quantum number.
(B) The orientation of an atomic orbital depends on the magnetic quantum number
(C) The energy of an electron in an atomic orbital of multi–electron atom depends on principal quantum number.
(D) The number of degenerate atomic orbitals of one type depends on the values of azimuthal and magnetic quantum
numbers.
a+
15. An ion Mn has the magnetic moment equal to 4.9 B.M. The value of a is :
(A) 3 (B) 4 (C) 2 (D) 5
16. The number of electrons with the azimuthal quantum number l = 1 and 2 for 24Cr in ground state are:
(A) 16 and 5 (B) 12 and 5 (C) 16 and 4 (D) 12 and 4
One or More than one option CORRECT:
17. Which of the following set of quantum number(s) is / are correct?
(A) n = 4, l = 2, m = +2, s = 0 (B) n = 5, l = 4, m = 0, s = +½ (C) n = 3, l = 3, m = +3, s +½ (D) n = 3, l = 2, m = 1, s =
+½
18. Which of the following statements is/are correct?
5 1
(A) The electronic configuration of Cr(z = 24) is [Kr] 3d 4s (B) The magnetic quantum number may have a negative
value
(C) In silver atom (z = 47), 23 electrons have a spin of one type and 24 of opposite type
(D) The azimuthal quantum number may have a negative value
19. Ground state electronic configuration of nitrogen atom can be represented by
(A) (B)
(C) (D)
20. In which of these options do both constituents of the pair have the same magnetic moment?
2 2 2 4 2 2
(A) Zn and Cu (B) Co and Ni (C) Mn and Co (D) Mg and Sc
21. Which of the following set of quantum numbers are incorrect.
(A) n = 3; l = 3; m = 0; s = ½ (B) n = 1; l= 2; m = 2; s= –1/2 (C) n = 4; l= 0; m= –1;s = ½ (D) n = 4; l = 2; m = –2; s= –
1/2
22. When 2 electrons are lost by Cr (Chromium), then
(A) the ‘n’ value changes for the last electron (B) the ‘l’ value changes for the last electron
(C) the Spin Magnetic Moment is 4.89 BM (D) the spin multiplicity of the species is 4
ANSWERS
1. B 2. B 3. D 4. A 5. D
6. A 7. C 8. B 9. A 10. A
11. A 12. A 13. A 14. C 15. A
16. B 17. BD 18. AC 19. AD 20. AD
21. AB 22.
PW VIDYAPEETH-KOTHAPET, Victoria Memorial, 8-116, MH 65,Narsimha Puri Colony, Huda Colony, [Link], Hyderabad,
Telangana 500 035.