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Sustainable Metal Recovery from E-Waste

Pratheep Kumar Vijayan is applying for a PhD in Materials Science and Engineering, focusing on sustainable recycling processes for recovering valuable metals from e-waste and spent batteries, under the supervision of Professor Veena Sahajwala. He has a Master's degree and relevant research experience, demonstrating proficiency in key characterization techniques and a strong capability for high-quality research. The project aims to develop efficient, low-emission recycling methods that contribute to resource security and sustainability in Australia.

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0% found this document useful (0 votes)
6 views4 pages

Sustainable Metal Recovery from E-Waste

Pratheep Kumar Vijayan is applying for a PhD in Materials Science and Engineering, focusing on sustainable recycling processes for recovering valuable metals from e-waste and spent batteries, under the supervision of Professor Veena Sahajwala. He has a Master's degree and relevant research experience, demonstrating proficiency in key characterization techniques and a strong capability for high-quality research. The project aims to develop efficient, low-emission recycling methods that contribute to resource security and sustainability in Australia.

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pratheepvijayan
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Applicant Name: PRATHEEP KUMAR VIJAYAN

Degree/Program: 1045- Materials Science and Engineering

Title of Research Project: Advanced Recovery of Critical and Valuable Metals from E-Waste and
Spent Batteries Using Sustainable Recycling Processes

Primary Supervisor: Professor Veena Sahajwala

Joint/Secondary Supervisor(s): Dr Rumana Hossain

Outline how you are eligible for admission to the program.

I am eligible for PhD admission as I hold a Master of Materials Science and Technology from
UNSW, where I completed a research thesis under Prof. Veena Sahajwalla at the SMaRT Centre.
I also worked for a year at the SMaRT Centre under Mr. Anirban Ghose, gaining hands-on
research experience in sustainable materials processing, recycling, and waste-derived product
development. I am proficient in key characterisation techniques including SEM/EDS, XRD, FTIR,
TGA, and associated fabrication processes relevant to metal recovery and advanced recycling. My
current industry role has strengthened my skills in process optimisation and materials quality
control. With supervisory support secured and strong academic referees available, I meet the
academic, research, and capability requirements to undertake a PhD in this field.

Describe your capability to carry out high quality research.

I have developed strong research capability through my Master’s thesis at UNSW and my
subsequent work at the SMaRT Centre, where I contributed to experimental design, materials
fabrication, and analysis across multiple sustainability-focused projects. I am highly proficient in
core characterisation techniques such as SEM/EDS, XRD, FTIR, and TGA, and have practical
experience with thermal processing, mechanical separation, and electrochemical testing—skills
essential for advanced recycling and metal recovery research. During my time at SMaRT, I
independently handled sample preparation, data interpretation, troubleshooting, and
documentation, demonstrating initiative, accuracy, and scientific discipline. My current industry
role leading production and quality workflows has further strengthened my ability to manage
complex processes, maintain precision, and work systematically toward defined outcomes. I am
confident in my ability to conduct rigorous experiments, analyse results critically, and contribute
original insights to high-quality research in sustainable materials engineering.

Provide a rationale for why you chose this project and this supervisory team.

I chose this project because it aligns directly with my academic training, research experience, and
long-term goal of contributing to sustainable materials innovation. My Master’s thesis and
subsequent research work at the SMaRT Centre exposed me to micro recycling science, waste
valorisation, and materials transformation—areas where UNSW leads globally. Working closely
with research teams at SMaRT gave me an appreciation for the centre’s unique approach of
combining fundamental materials science with practical, scalable recycling technologies.

The proposed project on metal recovery from e-waste and spent batteries fits naturally with my
skills in materials characterisation, thermal processing, electrochemical analysis, and waste-
derived material development. It also aligns with my interest in circular economy solutions that can
be implemented at both local and industrial scales.

I chose this supervisory team because of their internationally recognised expertise in advanced
recycling, micro recycling, and sustainable materials engineering. Their ongoing work in
recovering metals, creating waste-derived ceramics and carbon materials, and developing fit-for-
purpose recycling technologies directly complements the direction I hope to pursue. I have
previously worked within the SMaRT ecosystem, and I value their rigorous research culture,
innovative mindset, and commitment to translating laboratory results into real-world impact.
Working under this team will provide the ideal environment for me to contribute meaningfully and
develop as an independent researcher in the field of sustainable materials.

Project Title:

Advanced Recovery of Critical and Valuable Metals from E-Waste and Spent Batteries Using
Sustainable Recycling Processes

Project Description:

The rapid global expansion of electronic devices and lithium-ion batteries has led to an
unprecedented accumulation of end-of-life e-waste and spent batteries, both of which contain
significant quantities of critical and valuable metals such as lithium (Li), cobalt (Co), nickel (Ni),
manganese (Mn), copper (Cu), and rare earth elements. Current recycling approaches are either
inefficient, environmentally burdensome, or fail to recover metals at sufficient purity levels for
reuse in advanced manufacturing. This project proposes to develop next-generation, sustainable
recycling processes capable of recovering these metals through integrated thermal, chemical, and
materials-engineering-based pathways.

The proposed research aims to explore and optimise low-emission, energy-efficient recovery
routes, including selective thermal treatment, microstructure-controlled fragmentation, green

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chemical leaching, and advanced separation processes. By leveraging materials-characterisation
techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier-
transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and UV–Vis
spectroscopy, the study will closely investigate phase transformations, bonding environments, and
morphological changes that govern metal liberation and recovery efficiency. This multi-technique
analytical framework will enable a deep mechanistic understanding of how waste-derived
feedstocks behave under controlled reaction environments.

A core component of the project involves designing sustainable fabrication pathways for
converting recovered metals into high-value secondary resources suitable for re-entry into
manufacturing chains. By integrating principles of process intensification, circular economy
engineering, and waste valorisation, the research will seek to achieve metal recovery with minimal
reagent consumption, reduced energy input, and significantly lower environmental impact
compared to conventional hydrometallurgical or pyrometallurgical routes. The aim is to develop
scalable processes with commercial feasibility, enhanced selectivity, and improved lifecycle
performance.

This research aligns closely with UNSW’s pioneering work in sustainable materials and micro
recycling, particularly in advanced waste-to-resource transformation and the development of
environmentally responsible processing technologies. The project’s outcomes have the potential to
contribute significantly to Australia’s resource security, reduce reliance on primary mining, and
position the country as a leader in critical-metal recovery and circular manufacturing. Ultimately,
the project seeks to create practical, science-driven solutions capable of closing the loop on e-
waste and spent battery materials, helping industry transition toward a more resilient and
sustainable materials economy.

Expected Outcomes:

The project will employ an integrated, multi-stage experimental methodology designed to optimise
the recovery of critical and valuable metals from end-of-life e-waste and spent batteries while
minimising environmental impact.

The first phase will focus on material pre-processing and feedstock characterisation, involving
systematic dismantling, mechanical separation, and particle-size optimisation to obtain
representative fractions of battery black mass and e-waste components. Advanced analytical tools
—XRD, SEM–EDS, FTIR, TGA, and ICP-OES—will be used to assess elemental composition,
crystalline phases, thermal stability, and morphological features. These data will guide the design
of targeted recovery pathways.

In the second phase, the project will investigate selective thermal treatment and controlled phase
transformation to enhance metal liberation. Low-energy thermal pretreatment strategies, such as
reductive roasting, microstructure softening, or organics removal, will be optimised to minimise
decomposition by-products and energy consumption. This will be complemented by green
hydrometallurgical routes using mild leaching agents (organic acids, deep eutectic solvents, or
alternative ionic media) to achieve selective dissolution of target metals, while reducing chemical
waste generation.

The third phase will develop advanced metal-separation and purification strategies, including
solvent extraction, precipitation, electrodeposition, and ion-exchange processes. These methods
will be refined to maximise purity, yield, and selectivity. Process integration principles will be

Page 3
applied to ensure that recovered metal salts or powders meet specifications for secondary
manufacturing applications.

The final phase will focus on materials re-fabrication, converting recovered metals into usable
products such as battery-grade cathode precursors, conductive metal powders, or functional
alloys. Material performance will be validated through structural, electrochemical, mechanical, and
thermal property evaluations. Lifecycle assessment (LCA) and process-mass-intensity (PMI)
calculations will be incorporated to quantify environmental and economic advantages over
traditional recycling routes.

The project is expected to deliver (1) a scientifically validated understanding of the key
physicochemical mechanisms governing metal liberation and recovery from complex waste
matrices; (2) a set of optimised, low-emission recycling processes that significantly reduce reagent
consumption, energy usage, and secondary waste generation; (3) high-purity recovered metal
products suitable for reintegration into manufacturing supply chains; and (4) a scalable recycling
framework with demonstrable circular-economy benefits. These outcomes aim to contribute
directly to Australia’s resource resilience and support the development of sustainable, industry-
ready metal recovery technologies.

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Common questions

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The project proposes several key techniques and processes to achieve low-emission, energy-efficient metal recovery. These include selective thermal treatment and controlled phase transformation to enhance metal liberation with minimal energy consumption . It also involves the use of green hydrometallurgical routes, such as mild leaching agents—including organic acids and deep eutectic solvents—to achieve selective dissolution of target metals, reducing chemical waste generation . Advanced separation and purification strategies, such as solvent extraction and ion-exchange processes, are also refined to maximize purity and efficiency .

The project aims to improve metal recovery processes from e-waste and spent batteries through an integrated methodology that minimizes environmental impact and optimizes efficiency. It involves systematic dismantling, mechanical separation, and particle-size optimization to obtain representative fractions, followed by advanced analytical assessments to guide the design of targeted recovery pathways . This methodology includes selective thermal treatment to enhance metal liberation and green hydrometallurgical routes to achieve selective dissolution of target metals, while minimizing waste . Ultimately, the project seeks to create scalable, low-emission recycling processes that reduce energy usage and chemical waste generation, delivering high-purity metal products for reuse .

The research project is expected to contribute significantly to Australia's resource resilience by reducing reliance on primary mining and promoting the re-entry of recovered metals into manufacturing supply chains . It anticipates delivering scalable recycling frameworks with circular-economy benefits and low environmental impact, positioning Australia as a leader in critical-metal recovery and circular manufacturing . This could enhance the nation's capacity to manage its resources sustainably and transition towards a more resilient materials economy .

The project aims to advance beyond conventional recycling technologies by integrating principles of process intensification, circular economy engineering, and waste valorisation . It proposes novel recycling processes that are low-emission, energy-efficient, and capable of achieving high selectivity and purity levels in metal recovery, compared to traditional hydrometallurgical and pyrometallurgical routes . These advanced methods include selective thermal treatments, green hydrometallurgical processes, and optimized separation strategies, which aim to significantly reduce chemical use, energy consumption, and secondary waste generation . The project's focus on practical, scalable solutions positions it as a leader in innovative recycling technologies.

The project integrates the concept of a circular economy by focusing on waste-to-resource transformation techniques and strategies that convert recovered metals into high-value secondary resources, such as battery-grade cathode precursors and functional alloys . By emphasizing low-energy, low-emission recycling processes and efficient use of resources through novel fabrication pathways, the project aims to reduce reliance on virgin materials, effectively closing the loop on e-waste and spent battery materials . The outcomes align with circular economy principles, supporting sustainable manufacturing and reducing the environmental footprint of material recovery processes .

Pratheep Kumar Vijayan possesses several capabilities that qualify him for high-quality research in the proposed project. He holds a Master of Materials Science and Technology and has practical experience from his work at the SMaRT Centre, where he contributed to sustainability-focused projects involving experimental design and materials analysis . He is proficient in core characterisation techniques such as SEM/EDS, XRD, FTIR, and TGA, and has skills in thermal processing and electrochemical testing, essential for metal recovery research . His industry experience in managing production and quality workflows further strengthens his ability to handle complex processes and produce rigorous, high-quality research .

The expected outcomes of the project include the development of efficient, low-emission recycling processes that minimize reagent consumption and energy usage, thereby significantly reducing the environmental impact compared to conventional methods . The project aims to deliver a scientifically validated understanding of the physicochemical mechanisms governing metal recovery, enabling high-purity recycling capable of integration into manufacturing supply chains . It also anticipates creating a scalable recycling framework with demonstrable circular-economy benefits, thus contributing directly to sustainable practices and industry-ready technologies .

The supervisory team is suitable for the metal recovery project due to their internationally recognized expertise in advanced recycling, micro recycling, and sustainable materials engineering . Their work directly complements the project's goals, as they focus on recovering metals, creating waste-derived ceramics and carbon materials, and developing purpose-fit recycling technologies . Moreover, the applicant has prior experience working within the SMaRT ecosystem, appreciates their rigorous research culture, and is keen to contribute meaningfully under their guidance .

The main techniques used in the project to assess and guide the design of metal recovery pathways include a comprehensive suite of advanced analytical tools like X-ray diffraction (XRD), scanning electron microscopy with energy dispersive spectroscopy (SEM/EDS), Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), and inductively coupled plasma optical emission spectrometry (ICP-OES). These techniques enable detailed feedstock characterization, assessment of elemental composition, crystalline phases, thermal stability, and morphological features, which are critical for optimizing recovery processes such as selective thermal treatments and green chemical leaching . This analytical framework supports the development of efficient recycling strategies with high recovery rates and minimal environmental impact .

The project emphasizes an integrated, multi-stage experimental methodology that focuses on achieving high-purity metal products from recycled materials. This approach begins with detailed pre-processing and characterisation of feedstocks using advanced analytical techniques like XRD, SEM-EDS, FTIR, and TGA . It proceeds with selective thermal and chemical treatments to optimize metal liberation and separation processes. Separation includes solvent extraction, precipitation, and ion-exchange techniques. This holistic method ensures that the recovered metals meet specifications for secondary manufacturing applications, ultimately producing high-purity, usable metal products .

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