28-11-2025

6001CJA10102225011GRIP JA

PHYSICS

SECTION-I

1) Two plane mirrors M1 and M2 each have length 1 m and are separated by 2cm. A ray of light is
incident on one end of mirror M1 at angle 45°. How many reflections the ray will have before going

out from the other end ?

(A) 50
(B) 51
(C) 100
(D) 101

2) A plane mirror is moving with velocity . A point object in front of the mirror moves with
a velocity . Here is along the normal to the plane mirror and facing towards the object.
The velocity of the image is:

(A)
(B)
(C)
(D)

3) A short linear object of length b lies along the axis of a concave mirror of focal length f at a
distance u from the pole of the mirror. The size of the image is approximately equal to

(A)
b

(B)
b

(C)
b

(D)
b

4) At what distance from a concave mirror of focal length 10 cm must an object be placed in order
that an image double of its size may be obtained ?
(A) 5 cm only
(B) 15 cm only
(C) either 5 cm or 15 cm
(D) at 10 cm

5) Liquid is filled in a vessel of height H. At the bottom of the vessel there is a spot P and a hole from
which liquid is coming out. Let d be the distance of image of P from an eye at height H from bottom
at an instant when level of liquid in the vessel is x. If we plot a graph between d and x, it will be like
:-

(A)

(B)

(C)

(D)

6) Velocity of image of fish in the mirror with respect to ground is

(A) zero
(B) 2 m/s towards mirror
(C) 2 m/s away from mirror
(D) 4 m/s towards mirror

7) The angle of a prism is 'A'. One of its refracting surfaces is silvered. Light rays falling at an angle
of incidence 2A on the first surface returns back through the same path after suffering reflection at
the silvered surface. The refractive index µ, of the prism is :-

(A) 2sinA
(B) 2cos A

(C)
cosA
(D) tanA

8) A ray is incident on the first prism at an angle of incidence 53º as shown in the figure. The angle
between side CA and B'A' for the net deviation by both the prisms to be double of the deviation

produced by the first prism, will be :-

(A)
2 sin–1

(B)
sin–1

(C)
cos–1

(D)
sin–1

9) Consider a glass slab of refractive index kept in air. An equilateral prism is cut from the slab
as shown in figure. This space is filled by liquid of refractive index . Two narrow beams P and Q
are incident as shown in figure. The angle between two emergent beams is . Select incorrect

statement.

(A) If

(B)
If

(C)
If
(D) If
10)

Choose the correct ray diagram of an equi convex thin lens which is cut as shown
(paraxial condition satisfied) :-

(A)

(B)

(C)

(D)

11) A point object is placed at a distance of 3R from point P on glass hemisphere of radius R. If
refractive index of hemisphere is 1.5 then position of its image from C is

(A)
to the right

(B)
to the right
(C) 7.5R to the left

(D)
R to the left

12)

The graph shows how the magnitude of magnification produced by a thin plano-convex lens for a
real image varies with image distance v. Which of the following is correct ?

(A) focal length of lens is b/c.

(B) if the refractive index of the lens material is µ. then the radius of curved surface will be
.

if the lens is placed in contact with another thin lens of focal length , the focal length of
(C)
combination will be .
(D) None of these

13) A point like object is placed at a distance of 1m in front of a convex lens of focal length 0.5 m. A
plane mirror is placed at a distance of 2 m behind the lens. The position and nature of the final
image formed by the system is :

(A) 1 m from the mirror, virtual

(B) 1 m from the mirror, real
(C) 2.6 m from the mirror, real
(D) 2.6 m from the mirror, virtual

14) A concave mirror is placed in a medium of refractive index μ1 = 1.2. An object placed at 30 cm
from pole of the mirror and its image coincide. Now a liquid of refractive index μ is placed in the
concave mirror in the shaded region and it is found that object needs to be shifted by 7.5 cm below
O for the object and image to coincide. The refractive index of the liquid μ is

(A)

(B) 1.2
(C) 1.6
(D) None of the above

15) An astronomical telescope has an eyepiece of focal-length 5 cm. If the angular magnification in
normal adjustment is 10, when final image is at least distance of distinct vision (25cm) from eye
piece, then angular magnification will be :

(A) 10
(B) 12
(C) 50
(D) 60

16) An astronomical telescope has magnifying power 6 for distance objects. The separation between
objective and the eye piece is 42 cm and the final image is formed at infinity. The focal length f0 of
objective and focal length fe of eye-piece are (in cm) :-
(A) f0 = 36, fe = 6
(B) f0 = 50, fe = 8
(C) f0 = 20, fe = 10
(D) f0 = 40, fe = 8

17) A beam of light consisting of red, green and blue and is incident on a right angled prism. The
refractive index of the material of the prism for the above red, green and blue wavelengths are 1.39,

1.44 and 1.47 respectively. The prism will

(A) separate part of the red color from the green and blue colors
(B) separate part of the blue color from the red and green colors
(C) separate all the three colors from the other two colors
(D) not separate even partially, any colors from the other two colors

18) When a ray of light is incident at angle of 35° on an equilateral prism. Then it passes
symmetrically. Calculate the deviation of the ray. (Symmetrically means parallel to base)

(A) 30°
(B) 15°
(C) 10°
(D) 45°

19) In the cross-section of thin slice of atmosphere in vertical plane, the thickness of the layer is d.

The refracting index of air varies as with the ray entering at origin at angle 30° with y
axis. n0 and a are constant (d>>a). Calculate value of y at which ray becomes parallel to x–axis

(A)

(B)

(C) y = d
(D) y = a

20) Four identical lenses are kept one beside the other on the same optical axis as shown in the
figure. The right surface of rightmost lens is silvered. Focal length of each lens is 20 cm and radius
of the silvered surface is 20 cm. The focal length of the combined system is

(A) 2 cm
(B) –2 cm
(C) 5 cm
(D) –5 cm

SECTION-II

1) A concave mirror produces an image of an object such that the distance between the object and
image is 20 cm. If the magnification of the image is '-3', then the magnitude of the radius of
curvature of the mirror is: (in cm)

2) Two light beams fall on a transparent material block at point 1 and 2 with angle θ1 and θ2 ,
respectively, as shown in figure. After refraction, the beams intersect at point 3 which is exactly on
the interface at other end of the block. Given : the distance between 1 and 2, and θ1 =

θ2 = , where refractive index of the block n2 > refractive index of the outside medium

n1, then the thickness of the block is ________ cm.

3) A light ray in medium enters another medium at an angle 30°. The angle in other

medium is . How many minimum degrees the incident angle must be increased such that
the ray is completely reflected.

4) Two point sources of light are placed 24 cm apart in air. A converging lens of focal length 9 cm is
so placed between the sources that their images coincide. Find the nearest distance of source from
lens :-
5) An insect at point 'P' sees its two images in the water mirror system as shown in the figure. One
image is formed due to direct partial reflection from water surface and the other image is formed
due to refraction, reflection & again refraction by water mirror system in order. The separation
between the two images is 6x cm. Find x. (mirror M has focal length 60 cm.) .)[Take ]

CHEMISTRY

SECTION-I

1) 1 g of non–volatile non-electrolyte solute is dissolved in 100g of two different solvents A and B

whose ebullioscopic constants are in the ratio of 1 : 5. The ratio of the elevation in their boiling
points, is :

(A) 5 : 1
(B) 10 : 1
(C) 1 : 5
(D) 1 : 0.2

2) Calculate the amount of water required to saturate a vessel of volume 82 litre as 300 K. Vapour
pressure of water is 38 torr.

(A) 3 gm
(B) 6 gm
(C) 9 gm
(D) None of these

3) Total vapour pressure of mixture of 1 mol X and 2 mol Y is 240

torr. In this case :

(A) There is a negative deviation from Raoult's law

(B) There is a positive deviation from Raoult's law
(C) There is no deviation from Raoult's law
(D) Can not be decided

4) If Mnormal is the normal molecular mass and is the degree of ionization of K3[Fe(CN)6], then the
abnormal molecular mass of the complex in the solution will be :
(A)
(B)
(C)
(D) equal to Mnormal

5) The freezing point of 1 molal NaCl solution assuming NaCl to be 100% dissociated in water is :
(Kf = 1.86 K kg mol–1) :

(A) –1.86°C
(B) –3.72°C
(C) +1.86°C
(D) +3.72°C

6) An azeotropic solution of two liquids has boiling point lower than either of them when it:

(A) shows a negative deviation from Raoult’s law

(B) shows no deviation from Raoult’s law
(C) shows positive deviation from Raoult’s law
(D) is saturated

7)

Which of the following shows positive deviation from Raoult's law?

(A) Benzene + Toluene

(B) Aniline + Phenol
(C) Acetone + Chloroform
(D) CHCl3 + CCl4

8) Vapour pressure of chloroform (CHCl3 ) and dichloromethane (CH2Cl2 ) at 298 K are 200 mm Hg
and 415 mm Hg respectively. Then calculate the vapour pressure of the solution prepared by mixing
25.5 g of CHCl3 and 40 g of CH2Cl2 at 298 K is

(A) 347.9 mm Hg
(B) 287.3 mm Hg
(C) 328.5 mm Hg
(D) 358.3 mm Hg

9) At 25°C, the vapour pressure of pure liquid A (mol. wt. = 40) is 100 torr, while that of pure liquid
B is 40 torr, (mol. wt. = 80). The vapour pressure at 25°C of a solution containing 20 g of each A and
B is:

(A) 80 torr
(B) 59.8 torr
(C) 68 torr
(D) 48 torr
10)

For which of the following vant' Hoff's factor is correctly matched -

Degree of
Salt i
dissociation (α)

(1) Na2SO4 80% 2

(2) K3[Fe(CN)6] 75% 3.25

(3) [Ag(NH3)2]Cl 50% 1.8

(4) [Cr(NH3)5Cl]SO4 90% 2.8

(A) 1
(B) 2
(C) 3
(D) 4

11) At a given temperature, the vapour pressure in mm of Hg of a solution of two volatile liquids A
and B is given by the equation:
PS = 120 – 80XB (XB = mole fraction of B)
Vapour pressures of pure A and B at the same temperature are respectively:

(A) 120, 80
(B) 120, 200
(C) 120, 40
(D) 80, 40

12) Which of the following has been arranged in order of decreasing freezing point?

(A) 0.05 M KNO3 > 0.04 M BaCl2 > 0.140 M sucrose > 0.075 M CuSO4
(B) 0.04 M BaCl2 > 0.140 M sucrose > 0.075 M CuSO4 > 0.05 M KNO3
(C) 0.075 M CuSO4 > 0.140 M sucrose > 0.04 M BaCl2 > 0.05 M KNO3
(D) 0.075 M CuSO4 > 0.05 M KNO3 > 0.140 M sucrose > 0.04 M BaCl2

13) The vapour pressure of an aqueous solution is found to be 750 torr at certain temperature 'T'. If
'T' is the temperature at which pure water boils under atmospheric pressure
(Kb = 0.52 K kg mol–1)

(A) 777
(B) 779
(C) 782
(D) 746

14) The osmotic pressure of 10%(w/v) aqueous solution of urea (π1) is related to that of 10%(w/v)
aqueous solution of glucose (π2)

(A) π1 = π2
(B) π1 > π2
(C) π1 < π2
(D) π1 = 1 – π2

15) When 12.2 g of benzoic acid is dissolved in 100 g of water, the freezing point of solution was
found to be –0.93°C (Kf(H2O) = 1.86K kg mol–1). The number (n) of benzoic acid molecules associated
(assuming 100% association) is ____.

(A) 2
(B) 4
(C) 6
(D) 8

16) A 5% solution (by mass) of cane sugar in water has freezing point of 271 K and freezing point of
pure water is 273·15K. The freezing point of a 5% solution (by mass) of glucose in water is –(Nearest
Integer)

(A) 271 K
(B) 273·15 K
(C) 269·07 K
(D) 277·23 K

17) The Henry's law constant for the solubility of N2 gas in water at 298 K is 8 × 105 bar. The mole
fraction of N2 in air is 0.8. The number of moles of N2 from air dissolved in 10 moles of water at 298
K and 1 bar pressure is :-

(A) 4 × 10–4
(B) 4 × 10–5
(C) 5 × 10–4
(D) 4 × 10–6

18) Which of the following graph correctly represents the plots of KH at 1 bar gases in water versus
temperature ?

(A)
(B)

(C)

(D)

19) Match List-I with List-II

List-I List-II

Solution of chloroform and Minimum boiling

(A) (I)
acetone azeotrope

(B) Solution of ethanol and water (II) Dimerizes

Solution of benzene and Maximum boiling

(C) (III)
toluene azeotrope

Solution of acetic acid in

(D) (IV) ΔVmix = 0
benzene
Choose the correct answer from the options given below :
(A) (A)-(III), (B)-(I), (C)-(IV), (D)-(II)
(B) (A)-(II), (B)-(IV), (C)-(I), (D)-(III)
(C) (A)-(III), (B)-(IV), (C)-(I), (D)-(II)
(D) (A)-(II), (B)-(I), (C)-(IV), (D)-(III)

20) The vapour pressure of CS2 at 50°C is 854 torr and a solution of 2.0 gm sulphur in 100 gm of
CS2 has vapour pressure 848.9 torr. If the formula of sulphur molecule is Sn, then calculate the value
of "n" (approx) (At. mass of S = 32) :-
[Assume very dilute solution]

(A) 2
(B) 4
(C) 6
(D) 8

SECTION-II

0 0
1) Two liquids A and B have, PA and PB = 1 : 3 at a certain temperature. Assume A and B form an
ideal solution, and the ratio of mole of A to B in the liquid phase are 1 : 3, then mole fraction of A in
vapour phase in equilibrium with the solution -

2) The osmotic pressure of blood is 7.47 bar at

300 K. To inject glucose to a patient intravenously, it has to be isotonic with blood. The
concentration of glucose solution in gL–1 is _____
(Molar mass of glucose = 180 g mol–1
R = 0.083 L bar K–1 mol–1) (Nearest integer)

3) Number of correct statements are-

(i) Azeotrope obey Raoult's law
(ii) Minimum boiling point azeotrope is formed if ΔHmix < O
(iii) ΔHvap for ideal aqueous solution containing non-volatile solute is same as ΔHvap for pure water
(iv) When azeotrope is vapourised, composition of vapour formed is same as solution.

4) How many of the following statement(s) is/are correct?

(i) Minimum boiling azeotropic mixture boils at temperature lower than either of the two pure
components.
(ii) Maximum boiling azeotropic mixture boils at temperature higher than either of the two pure
components.
(iii) Minimum boiling azeotropic mixture shows (+) ve deviation.
(iv) Maximum boiling azeotropic mixture shows (–) ve deviation.

5) The Van't Hoff factor (i) for a dilute solution of K3[Fe(CN)6] is: (Assuming 100% ionsation)

MATHEMATICS

SECTION-I

1) The vectors , . If c is a vector such that and , angle

o
between a × b and c is 45 , then is

(A) 3
(B)

(C)

(D) None of these

2) Position vector of a point which divides line joining points A and B whose position vectors are
and externally in the ratio 5 : 2 is

(A)

(B)

(C)
(D)

3) The area of a parallelogram whose diagonals represent the vectors and is

(A)
(B)
(C) 8
(D) 4

4) Let be unit vectors such that . Which one of the following is correct?

(A)
(B)
(C)
(D) are mutually perpendicular

5) If the vectors are non-coplanar and ,m,n are distinct real numbers, then

= 0 implies -

(A) m + mn+ n = 0
(B) +m+n=0
2
(C) + m2+ n2 = 0
3
(D) + m3 + n3 = 0

6) Let , and be three vectors such that

, , then is equal to :

(A) 10
(B) 5
(C) 15
(D) 12

7) If the components of along and perpendicular to respectively, are

and , then α2 + β2 + γ2 is equal to :

(A) 23
(B) 18
(C) 16
(D) 26

8) Let and be two given vectors where vectors and are non-
collinear. The value of λ for which vectors and are collinear, is:

(A) –3
(B) 4
(C) 3
(D) –4

9) Let , and be a vector such that and

= 168. Then the maximum value of is :

(A) 77
(B) 462
(C) 308
(D) 154

10) Let and be coplanar vectors. Then the non-

zero vector is :

(A)
(B)
(C)
(D)

11) Let and be three vectors. A vectors of the type +λ

for some scalar λ, whose projection on is of magnitude , is :

(A)
(B)
(C)
(D)

12) If the vector is collinear with the vector & = 10, then :

(A) =0
(B) =0
(C) =0
(D) None

13) If and being non-

collinear then

(A)

(B)

(C)

(D)

14) If are vectors of length 3, 4 & 5 respectively such that is perpendicular to

, is perpendicular to and is perpendicular to , then the length of

equals

(A)

(B)

(C)

(D)

15) A rigid body rotates with constant angular velocity ω about the line whose vector equation

is, = λ . The speed of the particle at the instant it passes through the point with p.v.
is :

(A) ω
(B) 2ω

(C)

(D) none

16) Let and Then is equal

to
(A) –12
(B) –10
(C) –13
(D) –15

17) Let and be two vectors such that and

If , then the angle between and is equal to :

(A)

(B)

(C)

(D)

18) Let be a unit vector which follows the equation, Also, and
then

(A)

(B)

(C)

(D)

19) Points and are coplanar and . Then the least

value of is

(A)

(B) 14
(C) 6

(D)

20) Let the plane contain the line of intersection of two planes and

If the plane P passes through the point then the value of is

equal to

(A) 90
(B) 93
(C) 95
(D) 97

SECTION-II

1) Let be three vectors having magnitude 1, 2, 3 units respectively such that

If is unit vector coplanar with and and then the value of
is equal to :

2) Consider three vectors , and . If × = ,

then (u + v + w) equals to

3) Let and be three non-coplanar unit vectors such that the angle between every pair of them

is . If = , where p, q and r are scalars, then the value of is :

4) Let and . If for some real numbers α,β and γ, we have

then the value of γ is

5) Let be three mutually perpendicular vectors of the same magnitude and equally inclined at
an angle θ, with the vector . Then 36 cos2 2θ is equal is _______.
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B B D C C A B A C B B C C C B A A C D B

SECTION-II

Q. 21 22 23 24 25
A. 15 6 7 6 4

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C A A B B C D A A B C A A B A C A D A D

SECTION-II

Q. 46 47 48 49 50
A. 0 54 2 4 4

MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C A A B B B D D C C A C D B A A C C A B

SECTION-II

Q. 71 72 73 74 75
A. 9 2 4 2 4
 SOLUTIONS

PHYSICS

1)
In 4 cm = 2 reflection
In 100 cm = 50 reflection
Total reflection = 50 + first reflection = 51

2) Question Explanation: Calculating the velocity of an image in a moving mirror.

Concept: Reflection from a Plane Mirror.
Solution: The velocity of the image is related to the velocity of the object and the mirror. The
components of velocity parallel to the mirror are the same for the image and object. The
component perpendicular to the mirror is reversed relative to the mirror.
Let v0, vi and vm be the velocities of the object, image, and mirror.
The normal direction is
Components parallel to the mirror

Components perpendicular to the mirror:

So,
Total velocity of image
Final Answer:

3)

4)

m = +2 =

m = –2 =

5)

y=H–x+
 y=x +H

6) Velocity of image due to motion of fish =

Velocity of image due to motion of mirror = 2 m/s

7)

µ = 2cosA

8)

Let be the angle of emergence from the first prism be 'e'

calculating step by step we get e = sin–1

Then for net deviation to be double, the incident ray on side A'B' of second prism should make
angles i or e with normal.

Hence the angle between the given then will be 2e or i + e.

9)
At I surface

r2 = 30o
e = 60o

(B)

10)

As the upper half will have focal length twice that of lower half, rays coming from upper half of
planoconvex will be focused at more distance from lens.
11)

12) ,

,
So f = c/b

13)
Object is at 2f. So image will also be at '2f'. (I1).
Image of I1 will be 1m behind mirror.
i.e. ⇒ I2
Now I2 will be object for lens.
∴ u ⇒ – 3m
f ⇒ +0.5 m

So total distance from mirror ⇒ 2 + 0.6

⇒ 2.6 m and real image

14)
and

This

Also,

15) For normal adjustment

m=–
When final image is at least distance of distinct vision from eyepiece,

m' = – = = 12

16)

f0 + fe = 42

17) 45° > θC 45° ≤ θC

sin 45° > sin θC sin 45° ≤ sin θC

red green & blue

18) Given
for equilateral prism A = 60°
& i = 35°
∵ δmin = 2i – A = 2 × 35° – 60°
⇒ δmin = 10°
19)

20)

21) and

22)
n1sin(90 – θ1) = n2sinθ3
n1cosθ1 = n2sinθ3

, θ3 = 30

23)
 24) ...(i)

...(ii)
By adding (i) & (ii)

24x – x2 = 108
x = 6, x = 18

25)

For direct reflection distance of image from surface = 12cm

For reflection at mirror

For refractions and reflections image directed from surface = = 36 cm

CHEMISTRY

26) ΔTb = Kb × m

as mA = mB

27)

v = 82 L
T = 300 K

= PMax
PV = nRT

28)
PT = 50 + 200 = 250
PT > Pobs
Negative deviation.

29)
n=4

30) Tf = i × Kf × m = 2 × 1.86 × 1 = 3.72

Tf =

31) Question Explanation: Boiling point of an azeotrope.

Concept: Azeotropes

Solution: An azeotropic mixture that boils at a lower temperature than either of its
components is called a minimum boiling azeotrope. This occurs when the solution's vapor
pressure is higher than expected, which happens when the solution shows positive deviation
from Raoult's law.

Final Answer: shows positive deviation from Raoult's law

32)

Conceptual.

33) (i) Molar mass of CH2Cl2 =

Molar mass of CHCl3 =

Moles of CH2Cl2 =

Moles of CHCl3 =
Total number of moles = 0.47 + 0.213 = 0.683 mol

Using equation (2.16),

= 200 + 147.9 = 347.9 mm Hg

 34) Ps = . xA + = 100 = 100 × + 40 ×
= 80 torr

35)

K3[Fe(CN)6] —→ 3K+ + [Fe(CN)6]–3

1–α 3α α

i=

i = 1 + 3(0.75) ⇒ 3.25

36) Ps = 120 – 80 XB
For pure B, XB = 1, Ps = p°B = 40
For pure A, XB = 0, Ps = p°A = 120

37) Higher is (i × c); higher will be ΔTf, So, lower will be Tf

i × c for KNO3 = 2 × 0.05 = 0.1
BaCl2 = 3 × 0.04 = 0.12
Sucrose = 1 × 0.140 = 0.14
CuSO4 = 2 × 0.075 = 0.15

38) ΔTb = Kb . m

m= = 2 mole/kg

also

– 1 = 2(18) × 10–3

= 1 + 36 × 10–3
= 1.036
P° = 777 torr

39)

Question is Asking About :-

To determine π1 of 10% aqueous solution of area and π2 of 10% aqueous solution of

glucose.

Concept :- π1 = i1 C1 R T
 – (1)
π2 = i2 C2RT

– (2)
So, π1 > π2

Hence, option (2) is correct.

40) ΔTf = i × kf × m

0 – (–0.93) = i × 1.86 ×

i= ⇒
n=2

41) ΔTf = i·Kf · m [for sugar]

(273.15 – 271) = 1 × Kf × ....(1)

(ΔTf)glucose = i · Kf · m

= 1 × Kf × .....(2)

=
(ΔTf)glucose = 4.082
∵ (F.P.)glucose = 273.15 –4.082 = 269.07

42)
It means :
1 mole of solution, contains
4 × 10–5 mole N2
10 mole of solution 4 × 10–5 × 10 mole N2
4 × 10–4 mole N2

43) As temperature increases solubility first decrease then increase hence KH first increase
than decrease also at moderate temperature KH value He > N2 > CH4.

44) (A) Solution of chloroform and acetone shows –ve deviation, so maximum boiling
azeotrope.
(B) Solution of ethanol & water shows +ve deviation. So minimum boiling azeotrope.
(C) Solution of benzene and toluene form ideal solution. ΔVmix = 0.
(D) Acetic acid in benzene form dimer.

45)
(for very dilute solution )

(mol. wt)solute = 254.5

mol. wt of Sn = 32 × n
∴ 32 × n = 254.5
n = 7.95
=8

46)

Pt = = =
PT . YA =

⇒ yA =

47)

π = C.R.T
7.47= C × 0.083 × 300
C = 0.3 M
= 0.3 ×180 gL–1
= 54 gL–1

48) (i) Incorrect : → Azeotropes are non-ideal solutions so do not obey Rault’s law.
(ii) Incorrect : → for minimum boiling azeotropes ΔHmix > 0.
(iii) Correct : → addition of non-volatile solute decreases vapour pressure However ΔHvap
remains unaffected.
(iv) Correct : → In case of azeotropes, composition of vapours formed is same as solution after
vapourisation.
Correct statement =

49)

(i), (ii), (iii), (iv)

 50)

MATHEMATICS

51)

52)

53) Area =

54)

For a triangle

= = ≠

55)
R1 → R1 + R2 + R3
⇒

⇒
R2 → R2 – lR1; R3 → R3 – nR1

⇒ (m2 + n2 + 2 – mn – n – m) = 0
⇒ + m + n = 0 or m2 + n2 + 2 – mn – n – m = 0
⇒ + m + n or =m=n
But ≠ m ≠ n
So, + m + n = 0

56) Let's assume

and
So,

–29 + 2 = λ(14 + 40)

57)

let

= component of along

= component of perpendicular to

=
∴ =

α=4 β=1 γ = –3

α2 + β2 + γ2 = 16 + 1 + 9 = 26

58)

3λ – 6 = 4λ – 2

∴ Option (4)

59)

=0

⇒
....(1)

using equation (1)

+ 77λ2 = 154
77λ + 77λ2 – 154 = 0
λ2 + λ – 2 = 0
λ = –2, 1
∴ Maximum value of occurs when λ = –2

= 77×4
= 308

60)
so, (as is parallel to for )

Hence

61) ∵ ; ;

Given Magnitude of projection of vector on the vector =

⇒
⇒ λ = 1 or – 3

62) Explain Question: In this question we have given a vector is collinear with vector

and choose the correct option

Concept: (1) This question is based on collinearity condition of vectors
(2) If is collinear with vector then
Solution: Given is collinear with
...(1)

where

put in (1)

correct answer is (3)

Final Answer: Option (3)
63)

64) Given:

Similarly
..........(2)

Adding (1), (2) and (3) we get

.............(4)
65)

Angular velocity =

⇒ ...(1)
where

66)

67) Given

Dot product with on both sides

…..(1)
Dot product with on both sides
…..(2)
68)

69)

Because of coplanarity

by Cauchy Schwarz inequality

70) Equation of plane passing through line of intersection of

planes and is

and it passes through point

⇒
⇒λ=1

Equation of plane is
 ; d = 13

Value of

71)
are mutually perpendicular vectors

72)

Thus
v = 5, μ = – 3, w=0
μ+v+w=2
Hence B.

73) = cos
Given = , we get

=p

=p+ ...(i)

Given that = 0 ...(ii)

and = ...(iii)
From (i) and (iii), p = r, Using (ii) q = –p
∴ = =4

74)
taking dot with

= 0 + 0 + γ(p2q2 –
⇒ 52 = 26 γ
∴γ=2

given
b2 – b3 = –3 also
2 2
b2 + b3 – 2b2b3 = 9 b2b3 > 0
b22 + b32 = 9 + 2b2b3
b22 + b32 = 9 + 2b2b3 > 9
b22 + b32 > 9

75) Given
Let =λ
now = a2 + b2 + c2 + 2

now = cosθ

cosθ =

⇒ cosθ = ⇒ cos2 2θ =

⇒ 36cos22θ = 36 × =4