NATIONAL UNIVERSITY OF CALLAO

PREUNIVERSITY CENTER
Chemistry
WEEK 8 B) It is a chemical unit of
CHEMICAL UNITS OF dough.
C) Contains the same number of
DOUGH
atoms that 12 g of C12
D) It is the mass of one mole of
1. Starting from 1962, the standard atom
taken as a reference for molecules.
measure the atomic masses of the E) It is numerically equal to the
isotopes of an element is: atomic mass expressed in
grams.
A) 8 O16 B) 1 H1
SOLUTION
C) 20 Ca40 D) 6 C14 One mole of atoms is its mass
E) 6 C 12 atomic expressed in grams, no
it is the chemical unit of mass.
SOLUTION RPTA.: B
The pattern taken as a reference
to measure atomic masses is the
4. Identify the incorrect statement
12
Being the unit of mass
6 regarding the mass one mole of
atomic the twelfth part of the molecules.
mass of said isotope.
A) It is the mass of 6.02 1023
RPTA.: E molecules.
B) Contains the same number of
2. The atomic mass (A.M.) of a molecules that number of
element is the average atoms in 12g of C12 .
weighted average of atomic masses C) Contains Avogadro's number
relatives of the........ del 6,022.1023of atoms in
12
element, compared to theC
a molecule.
to which the value has been assigned D) It is numerically equal to the
De……………..Units of mass molecular weight expressed in
atomic. grams.
E) It is a chemical unit of
A) isotopes -16 dough.
B) isotopes -14
C) atoms -12
D) isobars -12
SOLUTION
E) isotopes -12 One mole of molecules is not a
chemical mass unit.
SOLUTION
RPTA.: E
RPTA.: E

3. Mark the incorrect about the

5. The following samples are available
mass of one mole of atoms.
chemicals:
I. 1 10 10 moles of N
A) It is the mass of a 6.02 1023 11
II. 1 10 moles of NH3
of atoms.

CYCLE 2007-II Page 413 Reproduction and Sale Prohibited

 NATIONAL UNIVERSITY OF CALLAO
PRE-UNIVERSITY CENTER
Chemistry
III. 17 1010 g.deNH3 A) VVV B) FFV C) VFF
D) FFF E) VFV
It is correct to state:
SOLUTION
A) They contain the same number of I. O2……….(V)
20 moles of HNO330 mol
atoms.
B) In II there is a greater number of 60 at-g (0) 60 at-g (0)
atoms.
C) II and III contain an equal number II. 5 molO2..... 2.4 mol P4.......(F)
of atoms.
D) In III they contain a larger number
10 at-g 9.6 at-g
of atoms.
E) There is a greater number of
III. 10 mol
Calcium hydroxide
A COH 2.....(F)
atoms. 2
There is no contribution from Al
M.A. (u.m.a): N = 14, H = 1

SOLUTION RPTA.: C
Comparing the atoms in each
case: 7. Calcium has two isotopes, Ca40
N atom y Ca44, if the atomic mass is
I. 10 10 mol N A 1010NA 40.08 and. What is the % of
1mol
abundance of the light isotope?
4N Aatom
II. 10 11
molNH3 4 1011NA
molNH3 A) 88% B) 90% C) 35%
D) 98% E) 60%
4NAatom
III. 17 1010 gNH3 4 1010NA
17gNH3
SOLUTION
It is observed that in II contains
Isotopes:
greater number of atoms. 40
Ca............a %
44
Ca... 100%
RPTA.: D
100 %
6. Dad the following 40 a 44 100 a
PA here
assertions: 100
I. From 20 moles of HNO3 himself
obtains 30 moles of O2 . 40.08

II. 5 moles of O2 contains the same (40.08) (100)=40a+4 400-44a

number of atoms in 2.4 moles
de P4 . 392
Ca(OH)of 4a = 392
III. Starting from 10 moles 2
a = 98%
520 g is obtained fromAl(OH)3 . RPTA.: D

It is (they are) true 8. To determine the mass of a

M.A. (u.m.a): Al = 27, O = 16, molecule of a certain element, must
H=1 divide by 6.02 x10 23, the

CYCLE 2007-II Page 414 Reproduction and Sale Prohibited

 NATIONAL UNIVERSITY OF CALLAO
PREUNIVERSITY CENTER
Chemistry
value corresponding to the mass IV. The mass of one mole of atoms is
de: numerically equal to the mass
atomic expressed in units of
A) one mole of atoms atomic mass
B) one mole of molecules
C) one gram of element A) FFVV B) FVVV C) FVVF
D) 22.4 moles of atoms of D) VVVF E) FFFF
element
E)6.022x1023atoms of the element SOLUTION
I. 98 g is the mass of one mole of
SOLUTION molecules
To determine the mass of a II. One mole of Na weighs 23 g.
III. if they are relative, as it is compared
molecule, we divide one mole of
molecules between 6.02 1023 with theC………………………………..(V)
´12

IV. false a mole of atoms is

express in grams………….………(F)
RPTA.: B
RE: C
9. 40 g of Argon (M.A.= 40 u.):
23 11. Indicate the incorrect statement.
A) contains 6.02 x 10 atoms of
Argon O
A) 5 moles of 2order double
B) contains 6.02x1023 molecules
what 5 moles of CH4
of Argon
B) In 3 moles of acetic acid
C) contains one mole of atoms of
Ar CH3COOH there are 6 moles of
D) contains 1 mole of molecules carbon atoms.
of Ar C) 54g of H2 O , contains
E) all are correct
approximately 18 x 1023
SOLUTION molecules.
As Argon is a noble gas, the In 63 g of HNO3 there are 48 g of

an individual uncombined atom can oxygen.

to consider oneself as a molecule E) In 12 x 1023 molecules of
monatomic, then.
40gAr 6.02 1023atoms
C6H12O6 they contain 72 g
of carbon.
6.02 1023molecules
M.A. (u.m.a): O = 16 C = 12
RPTA.: E N = 14

10. Indicate true (T) or false (F)

SOLUTION
I. The mass of a molecule of acid 180gC6H12O6
12 1023molecule6H12O6
sulfuric is 98 g. 6 1023 CílopeM6H12O6
II. The mass of one mole of atoms of
72gC
It is 23 g. 144gC
III. The atomic mass and mass 180gC6H 12
O6
Molecular weights are relative masses.
RPTA.: E
CYCLE 2007-II Page 415 Reproduction and Sale Prohibited
 NATIONAL UNIVERSITY OF CALLAO
PRE-UNIVERSITY CENTER
Chemistry
C) 33.33% D) 66.66%
E) 44.44%
12. Find the molecular mass of a
composed monochlorinated, yes SOLUTION
contains 25% by weight of chlorine. x 3y 2
M.A.: Cl = 35,5
3x = 60% (x = 20)
2y………….. 40 %(y = 20)
A) 170 u. B) 142 u. C) 71 u.
D) 284 u. E) 340 u.
x 4y5

SOLUTION 5 (x) = 4(20) 80

Mcl 5 (y) = 5(20) 100
180
35.5……….25% 80
% mx 100 44.44%
M ………….100% 180
35.5 100
M 142 RPTA.: E
25

RPTA.: B 10 g of NiCl were heated.2

hydrated, NiCl2XH2O , he/she
13. A mixture contains only
the pure substances: A and B thus obtained an anhydride residue of
the total mass of the mixture is 3.72 g; NiCl2 which weighed 5,456 g. Calculate
the total number of moles is 0.06; the value of 'X'
the mass of one mole of B is 48 g and M.A. (u.m.a): Ni = 58,7 Cl = 35,5
In the mixture, there are 0.02 moles of A. O = 16
What is the molecular mass of A?
A) 7 B) 5 C) 4
A) 60 pcs. B) 90 units. C) 70 pcs. D) 6 E) 3
D) 80 units. E) 120 pcs.
SOLUTION
SOLUTION
I. wAwB3.72g N/A 2H2O
wB
II. 0.02 0.06wB1.92 18 x
48
wA1.8g 71
58.7
wA 1.8 NaCl2
Finally: MA 90
nA 0.02
129.7 + 18 x 129.7
10 g 5,456 g
RE: B
About the problem:
14. The percentage of Y is 40% in 5,456(129.7) + 18x = 129.7(10)
X 3 Y2What is the percentage in x=6
X's mass in X 4 Y5 ?
RPTA.: D
A) 60% B) 40%
CYCLE 2007-II Page 416 Reproduction and Sale Prohibited
 NATIONAL UNIVERSITY OF CALLAO
PRE-UNIVERSITY CENTER
Chemistry
16. A given substance shows the A)C8H16O4 B)C4H10O2
next weight analysis:
C)C6H12O3 D)C4H8O2
C = 57,2%, H = 4,79% y
S = 38.01%. If 5 grams of this E)C2H4O8
material they produce in the
molar properties the same SOLUTION
effect that 1.8 x 1022 molecules CxHyO2O2 CO2H2O
What is the molecular formula of
the substance? 7.49 g 14.96 6.13 g
P.A.(u.m.a): C = 12 H =1 S = 32

A)C4H4S B)C8H8S2
2gH
C) C4H8S2 D) C2H6S2 6.13gH2O 0.68
18gH2O
E) C3H8S3
12gC
SOLUTION 14.96gCO2 4,08
44gCO2
Calculating the empirical formula:
CxHySw
C = 4.08
57,24,77 CxHyOz H = 0.68
x 4
12 1,188 7.49 g O = 2.73
4,794,79
y 4 C4H4S M 84
1 1,188 Calculation of the empirical formula
38,011,188
w 1 4.08 0.34
321,188 X 2
12 0.17
Furthermore: 0.68 0.68
H 4 C2H4O M 44
1.8x1022molecules …………………5g 1 0.17
6.02 1023molecules............M 2,730,17
O 1
M 167
16 0.17
k 2
MC4H4S 84
Molecular weight calculation:
Finally: FM = KFE 2 molecules 5,866 1022g
FM 2 C4H4S C8H8S2
6.02 1023 M
M
176.56
RE: B 176.56
K 4
44
17. The combustion of 7.49 g of a
FM = k (FE)
compound that contains C, H, and O
FM C8H16O4
produced 14.96 g of CO2 and 6.13 g
RE: A
of water. Furthermore, two molecules
from this
compound weigh
18. In the combustion of a sample
5,866 times g.10
22
Establish the from a hydrocarbon are formed
molecular formula of the compound. 1,026 g of H2O and 11.40 g of
Calcium (when
Carbonate
absorbing
3 CO2in
the

CYCLE 2007-II Page 417 Reproduction and Sale Prohibited

 NATIONAL UNIVERSITY OF CALLAO
PRE-UNIVERSITY CENTER
Chemistry
dissolution of Ca(OH)2 Additionally C) SnF2Sn2F2
2.5 moles of the compound weigh 195 D) SnF2SnF 6
g. Find the molecular formula of
E) SnF2Sn2F8
hydrocarbon.

A)C3H8 B)C2H2 C)C4H4 SOLUTION

D)C6H6 E)C5H10 Snx Fx

0,578 0.366
SOLUTION
CxHyO2 CO2H2O 0.578
x 4.85 103/0.00485 1
119
0.366
2gH y 0.01926/0.00485 4
1,026gH2O 0.114gH 19
18gH2O
SF4
CaOH 2
RPTA.: B
12gC
Calcium Carbonate311.4g CaCO3 1,368gC
100g of CaCO3 20. A mixture of 1.00 g of oxide
coppery Cu2O and cupric oxide
1,368 0,114 CuO was quantitatively
x 1
12 0.114 reduced to 0.839 g of copper
CH M 13 metallic. What was the weight of the
0.114 0.114
y 1 CuO in the original sample?
1 0.114
M.A. (a.r.): Cu = 63.5
* In addition: 2.5 moles 195 g
A) 0.61 g B) 0.54 g
1 mol M C) 0.32 g D) 0.41 g
M 78 E) 0.81 g
78
* k 6
13 SOLUTION
FM k(FE) 6 CH C6H6 x 1-x
* wWith2O wCuO1g ……………..
RPTA.: D 127 63.5
* x 1 x 0.839…..
143 79.5
It is 0.578 g of pure tin.
with gaseous fluorine until the
2 Cu + O Cu + O
weight of the resulting compound
have a constant value of 0.944 127 63,5
g. What is the synthesis equation?
of this process? 143 79.5
M.A.(u.m.a): Sn = 119 F = 19
Solving x wWith 2O 0.4515
A) SnF2SnF2 wCuO1 0,4515 0,5485
B) SnF2SnF4
CYCLE 2007-II Page 418 Reproduction and Sale Prohibited
 NATIONAL UNIVERSITY OF CALLAO
PREUNIVERSITY CENTER
Chemistry
RPTA.: B
RPTA.: B
22. A type of sugar, substance
21. A sample of 1.483 g of white that is used a lot as
composed of K, Cr, and O gives rise to binder in manufacturing
through appropriate treatment to pills and tablets, contains C, H
0.581 g of Cr2O3by 1,609 g and in its composition. For
analyze one preparation
transform 2,296 g of KClO4 . commercial a sample is burned
Find the F.E. of the compound. of 0.5604 g. The weight increase
M.A. (u.m.a) : K = 39, Cr = 52 of the water absorber is
Cl = 35,5 0.3267 g and the absorbent of
Co2It is 0.832 g. Find the F.E. of
A)K2Cr2O7 B)K2CrO4 composed
CK2CrO3 D)K2CrO2
E)KCrO3 A)C6H12O6 B) C12H22O11
C) CH2O D) C6H10O5
SOLUTION E)C5H12O5
k xCryOw
1,483 SOLUTION
CxHyOwO2 CO2 H2O

104gCr 0.5604 g 0,822 g 0,3267g

0.581gCr2O3 0.395gCr
152gCr2O3
2gH
0.3267gH2O 0.0363
k 2CryOw 18gH2O
1,069
12gC
0.832gCO2 0.2269g
44gCO2
39gK
2,296gkClO4 0.6465gk wH0.0363g
138.5g KClO4
wC0.2269g
wThe0.5602 0.0363 0.2269 0.2972g
* 1,483 kgxCryOw 0.3975Cr1.08496
0.2269
1,609 kgxCryOw 0.4313gCr x 0.0189/0.0186 1
12
* 1,609 kgxCryOw 0.6465gk 0.0363
y 0.0363/0.0186 2 CH2O
wThe1.6091, 0778g, 0.5312gO 1
k xCryOw 0.2972
w 0.0186/0.0186 1
16
0.6465
x 0.016577/0.008294 2
39 RPTA.: C
0.4313
y 0.008294/0.008294 1 k 2CrO4
52
0.5312
w 0.0332/0.008294 4
16

CYCLE 2007-II Page 419 Reproduction and Sale Prohibited

 NATIONAL UNIVERSITY OF CALLAO
PRE-UNIVERSITY CENTER
Chemistry
23. Starting from 6.827 g of oxide of a total of 4.8 millimoles.
24.6 g of sulfate is obtained from iron. How many grams of carbon are there?
ferrous heptahydrate. Find the in the mix?
formula of iron oxide. M.A. (u.m.a): C = 12 H = 1
M.A. (u.m.a): Fe = 55,85 S = 32
O = 16 A) 0.112 g B) 0.098 g
C) 0.171 g D) 0.067 g
A) FeO B)Fe2O3 E) 0.152 g
C)Fe3O4 D)Fe2O4
E) FeO2
SOLUTION
MC2H6 30 MC3H8 44
wC2H6 wC3H8 0.187
SOLUTION
FexOyFeSO47H2O wC2H6 wC3H8
0.0048
30 44
6,827 g 24.6g (*) so:thC H a wC3H8 b
2 6

Calculation of: a + b = 0.178

MF eSO74H2O a b
0.0048 ………………….…
30 44
7 x 18 =126
16 x 4 = 64 a + b = 0.187
32 30
55.85 g Fe - 30 x -a - b 0.144
44
0.043
277.85 g of salt b 0.135g
0.318

55.85g Fe a = 0,187–0,135 = 0,052

(*)24.6g of Iron(II) Sulfate47H 2O
277.85g FeSO47H 2O
4.9457 gFe Calculating carbon weights
In the formula in each case
FexOy 24c
wC2H6: 0 . 0 5 2 g C 2H6 0.0416 gC
1.8813 g O 30
4.9457 g Fe 36gC
wC3H8:0,135C3H8 0.1104 gC
44C3H8
4.9457
x 0.0885/0.0885 1 3 3 wC0.152 g
55.85
1.8813
y 0.1176/0.0885 1.33 3 4 RPTA.: E
16

Fe3O4
RPTA.: C

24. A mixture consisting of the

compounds of formulas C2H6 y
C3H8 weighs 0.187 g and includes

CYCLE 2007-II Page 420 Reproduction and Sale Prohibited