Pearson Edexcel IGCSE Chemistry Mark
Scheme Bank
Contents
Principles of Chemistry
1. States of Matter
2. Elements, Compounds and Mixtures
3. Atomic Structure
4. The Periodic Table
5. Chemical Formulae, Equations and Calculations
6. Ionic Bonding
7. Covalent Bonding
8. Metallic Bonding
9. Electrolysis
Inorganic Chemistry
10.Group 1 - Alkali Metals
11.Group 7 - Halogens
12.Gases in the Atmosphere
13.Reactivity Series
14.Extraction and Uses of Metals
15.Acids, Alkalis and Titrations
16.Acids, Bases and Salt Preparations
17.Chemical Tests
1. States of Matter
Topic 1.1: Particle Theory
Question Type: Describe the arrangement of particles
Mark Scheme:
● Solid: particles are closely packed / touching (1)
● Particles in regular arrangement / pattern / lattice (1)
● Liquid: particles are close together but not in regular arrangement (1)
● Gas: particles are far apart / widely spaced (1)
Question Type: Describe particle movement
Mark Scheme:
● Solid: particles vibrate about fixed positions (1)
● Liquid: particles can move/slide past each other (1)
● Gas: particles move randomly / in all directions / rapidly (1)
Question Type: Describe particle energy
Mark Scheme:
● Solids have least energy (1)
● Liquids have more energy than solids (1)
● Gases have most energy (1)
Topic 1.2: State Changes
Question Type: Name state changes
Mark Scheme:
● Solid → Liquid: melting (1)
● Liquid → Gas: boiling / evaporation (1)
● Gas → Liquid: condensing / condensation (1)
● Liquid → Solid: freezing / solidification (1)
● Solid → Gas: sublimation (1)
Question Type: Explain state changes in terms of energy
Mark Scheme:
● Heating increases particle energy (1)
● Particles vibrate more / move faster (1)
● Particles overcome forces of attraction between them (1)
● Particles become more spread out (1)
Topic 1.3: Diffusion
Question Type: Explain diffusion
Mark Scheme:
● Movement of particles (1)
● From region of high concentration to low concentration (1)
● Until evenly distributed / equilibrium reached (1)
● Due to random movement of particles (1)
Question Type: Factors affecting rate of diffusion
Mark Scheme:
● Temperature: higher temperature increases rate (1)
● Because particles have more energy / move faster (1)
● Molecular mass: smaller/lighter molecules diffuse faster (1)
Topic 1.4-1.7: Solutions and Solubility
Question Type: Define key terms
Mark Scheme:
● Solvent: liquid that dissolves a solute (1)
● Solute: substance that dissolves in a solvent (1)
● Solution: mixture formed when solute dissolves in solvent (1)
● Saturated solution: solution containing maximum amount of solute at that temperature
(1) / no more solute will dissolve (1)
● Solubility: mass of solute that dissolves in 100g of solvent (1) at a specific temperature
(1)
Question Type: Interpret solubility curves
Mark Scheme:
● As temperature increases, solubility increases (for most solids) (1)
● Point on curve shows solution is saturated (1)
● Point below curve shows solution is unsaturated (1)
● Point above curve is impossible / supersaturated (1)
2. Elements, Compounds and Mixtures
Topic 1.8: Classification of Matter
Question Type: Define element/compound/mixture
Mark Scheme:
● Element: substance made of one type of atom only (1)
● Compound: two or more elements chemically combined / bonded (1) in fixed
proportions (1)
● Mixture: two or more substances not chemically combined (1)
Question Type: Distinguish pure from impure
Mark Scheme:
● Pure substance has sharp/fixed melting point (1)
● Pure substance has sharp/fixed boiling point (1)
● Mixture melts/boils over a range of temperatures (1)
● Impurities lower melting point (1)
● Impurities raise boiling point (1)
Topic 1.10-1.13: Separation Techniques
Question Type: Describe simple distillation
Mark Scheme:
● Heat the mixture (1)
● Liquid with lowest boiling point evaporates first (1)
● Vapour condenses in condenser (1)
● Pure liquid collected as distillate (1)
● Thermometer shows boiling point of substance being collected (1)
Question Type: Describe fractional distillation
Mark Scheme:
● Mixture heated (1)
● Vapours rise up fractionating column (1)
● Column has temperature gradient / hotter at bottom (1)
● Liquid with lowest boiling point reaches top first (1)
● Condenses and collected (1)
● Used to separate liquids with different boiling points (1)
Question Type: Describe filtration
Mark Scheme:
● Separates insoluble solid from liquid (1)
● Mixture poured through filter paper (1)
● Residue remains on filter paper (1)
● Filtrate passes through (1)
Question Type: Describe crystallisation
Mark Scheme:
● Heat solution to evaporate some solvent (1)
● Until solution becomes saturated (1)
● Allow to cool (1)
● Crystals form as solubility decreases (1)
● Filter to collect crystals (1)
● Wash crystals with cold distilled water (1)
● Dry crystals (1)
Question Type: Describe paper chromatography
Mark Scheme:
● Spot of mixture placed on pencil baseline (1)
● Paper placed in solvent (1)
● Solvent must be below baseline (1)
● Solvent rises up paper (1)
● Different components travel different distances (1)
● Based on their solubility in solvent (1)
Question Type: Calculate Rf values
Mark Scheme:
● Rf = distance moved by substance ÷ distance moved by solvent (1)
● Measure from baseline to center of spot (1)
● Rf value has no units (1)
● Component with same Rf as reference is identified as that substance (1)
3. Atomic Structure
Topic 1.14-1.15: Structure of Atoms
Question Type: Define atom and molecule
Mark Scheme:
● Atom: smallest particle of an element (1)
● Molecule: two or more atoms chemically bonded together (1)
Question Type: Describe atomic structure
Mark Scheme:
● Protons: in nucleus (1), relative mass = 1 (1), relative charge = +1 (1)
● Neutrons: in nucleus (1), relative mass = 1 (1), relative charge = 0 / neutral (1)
● Electrons: in shells/energy levels around nucleus (1), relative mass = 1/1840 / negligible
(1), relative charge = -1 (1)
Topic 1.16-1.17: Atomic Number and Mass
Question Type: Define key terms
Mark Scheme:
● Atomic number: number of protons (1) in nucleus of atom (1)
● Mass number: total number of protons + neutrons (1) in nucleus (1)
● Isotopes: atoms of same element (1) with same number of protons (1) but different
number of neutrons (1) / different mass numbers (1)
● Relative atomic mass (Ar): average mass of isotopes (1) compared to 1/12 mass of
carbon-12 (1)
Question Type: Calculate relative atomic mass
Mark Scheme:
● Multiply mass of each isotope by its abundance (1)
● Add these values together (1)
● Divide by total abundance / 100 (1)
● Ar = Σ(mass × abundance) ÷ total abundance (1)
Example calculation (3 marks):
● Correct multiplication shown (1)
● Values added correctly (1)
● Final answer correct (1)
4. The Periodic Table
Topic 1.18-1.19: Organization of Periodic Table
Question Type: Describe arrangement
Mark Scheme:
● Elements arranged in order of atomic number (1)
● Groups: vertical columns (1)
● Periods: horizontal rows (1)
● Group number = number of electrons in outer shell (1)
● Period number = number of electron shells/energy levels (1)
Question Type: Write electronic configuration
Mark Scheme:
● First shell holds maximum 2 electrons (1)
● Second shell holds maximum 8 electrons (1)
● Third shell holds maximum 8 electrons (for first 20 elements) (1)
● Written as numbers separated by commas, e.g., 2,8,1 (1)
Topic 1.20-1.24: Metals and Non-metals
Question Type: Properties of metals vs non-metals
Mark Scheme:
Metals:
● Conduct electricity (1)
● Oxides are basic / alkaline (1)
● Left side / Groups 1, 2, 3 of Periodic Table (1)
Non-metals:
● Do not conduct electricity (except graphite) (1)
● Oxides are acidic (1)
● Right side of Periodic Table (1)
Question Type: Explain similar properties in groups
Mark Scheme:
● Elements in same group have same number of outer electrons (1)
● Chemical properties depend on number of outer electrons (1)
● Therefore have similar reactions (1)
Question Type: Explain noble gas unreactivity
Mark Scheme:
● Noble gases have full outer shell (1)
● This is a stable electronic configuration (1)
● No need to gain/lose/share electrons (1)
● Therefore unreactive / inert (1)
5. Chemical Formulae, Equations and Calculations
Topic 1.25: Chemical Equations
Question Type: Write balanced equations
Mark Scheme:
● Correct formulae for all substances (1 per formula)
● Balanced equation (1)
● State symbols correct (s, l, g, aq) (1)
● Word equation correct (1)
Common state symbols:
● (s) = solid
● (l) = liquid
● (g) = gas
● (aq) = aqueous / dissolved in water
Topic 1.26-1.28: The Mole
Question Type: Calculate Mr
Mark Scheme:
● Add together Ar values of all atoms in formula (1)
● Multiply Ar by number of atoms of each element (1)
● Correct answer (1)
Question Type: Calculate moles
Mark Scheme:
● Moles = mass ÷ Mr (1)
● Correct substitution (1)
● Correct answer with units (mol) (1)
Alternative:
● Mass = moles × Mr (1)
● Mr = mass ÷ moles (1)
Topic 1.29-1.30: Reacting Masses and Yield
Question Type: Calculate reacting mass
Mark Scheme:
● Write balanced equation (1)
● Calculate moles of known substance (1)
● Use mole ratio from equation (1)
● Calculate moles of required substance (1)
● Calculate mass using mass = moles × Mr (1)
Question Type: Calculate percentage yield
Mark Scheme:
● Percentage yield = (actual yield ÷ theoretical yield) × 100 (1)
● Correct substitution (1)
● Correct answer with % sign (1)
Topic 1.31-1.33: Empirical and Molecular Formulae
Question Type: Define formulae types
Mark Scheme:
● Empirical formula: simplest whole number ratio of atoms (1) of each element in
compound (1)
● Molecular formula: actual number of atoms (1) of each element in molecule (1)
Question Type: Calculate empirical formula from data
Mark Scheme:
● Divide mass of each element by its Ar to get moles (1)
● Divide all values by smallest number of moles (1)
● If necessary, multiply to get whole numbers (1)
● Write formula using these ratios (1)
Topic 1.34-1.35: Solution and Gas Calculations (Chemistry only)
Question Type: Calculate concentration
Mark Scheme:
● Concentration (mol/dm³) = moles ÷ volume (dm³) (1)
● Convert cm³ to dm³ by dividing by 1000 (1)
● Correct substitution (1)
● Correct answer with units (1)
Question Type: Calculate gas volume
Mark Scheme:
● 1 mole of gas = 24 dm³ at rtp (1)
● Volume = moles × 24 (dm³) (1)
● OR Volume = moles × 24000 (cm³) (1)
● Correct answer with units (1)
6. Ionic Bonding
Topic 1.37-1.38: Ion Formation
Question Type: Explain ion formation
Mark Scheme:
● Metals lose electrons to form positive ions / cations (1)
● Non-metals gain electrons to form negative ions / anions (1)
● To achieve full outer shell / stable electronic configuration (1)
● Group 1 metals form 1+ ions (1)
● Group 2 metals form 2+ ions (1)
● Group 7 non-metals form 1- ions (1)
● Group 6 non-metals form 2- ions (1)
Question Type: Know common ion charges
Mark Scheme:
● Memorize: Ag⁺, Cu²⁺, Fe²⁺, Fe³⁺, Pb²⁺, Zn²⁺ (1 each)
● Memorize: H⁺, OH⁻, NH₄⁺, CO₃²⁻, NO₃⁻, SO₄²⁻ (1 each)
Topic 1.39-1.40: Ionic Compounds
Question Type: Write formulae for ionic compounds
Mark Scheme:
● Balance charges to make compound neutral (1)
● Use brackets for compound ions when more than one present (1)
● Correct formula (1)
Question Type: Draw dot-and-cross diagrams
Mark Scheme:
● Show outer electrons only (1)
● Use dots for one atom, crosses for another (1)
● Show electron transfer with arrows (1)
● Show charges on ions formed (1)
● Show square brackets around ions (1)
Topic 1.41-1.43: Properties of Ionic Compounds
Question Type: Explain properties
Mark Scheme:
High melting/boiling points:
● Giant ionic lattice structure (1)
● Strong electrostatic forces of attraction (1)
● Between oppositely charged ions (1)
● Requires large amount of energy to overcome (1)
Electrical conductivity:
● Solid: does not conduct (1)
● Because ions cannot move / fixed in lattice (1)
● Molten/aqueous: does conduct (1)
● Because ions are free to move (1)
● And carry charge/current (1)
7. Covalent Bonding
Topic 1.44-1.46: Covalent Bond Formation
Question Type: Define covalent bonding
Mark Scheme:
● Sharing of a pair of electrons (1)
● Between two atoms (usually non-metals) (1)
● Electrostatic attraction between shared electrons and nuclei (1)
Question Type: Draw dot-and-cross diagrams
Mark Scheme:
● Show outer electrons only (1)
● Use dots for one atom, crosses for another (1)
● Show shared pairs in overlap region (1)
● Show non-bonding pairs if present (1)
Common molecules to know:
● H₂, O₂, N₂, Cl₂, HCl, H₂O, NH₃, CO₂, CH₄, C₂H₆, C₂H₄
Topic 1.47-1.48: Simple Molecular Structures
Question Type: Explain low melting/boiling points
Mark Scheme:
● Simple molecular structure (1)
● Weak intermolecular forces between molecules (1)
● Only small amount of energy needed to overcome these forces (1)
● Strong covalent bonds within molecules not broken (1)
Question Type: Explain trend in melting/boiling points
Mark Scheme:
● As Mr increases, melting/boiling point increases (1)
● Because intermolecular forces get stronger (1)
● With larger molecules (1)
● More energy needed to overcome forces (1)
Topic 1.49-1.50: Giant Covalent Structures
Question Type: Explain high melting/boiling points
Mark Scheme:
● Giant covalent structure / macromolecular (1)
● Many strong covalent bonds throughout structure (1)
● Requires large amount of energy to break bonds (1)
Question Type: Compare diamond, graphite, and C₆₀
Mark Scheme:
Diamond:
● Each carbon bonded to four other carbons (1)
● Tetrahedral arrangement (1)
● Very hard because all bonds must be broken (1)
● Does not conduct electricity - no free electrons (1)
Graphite:
● Each carbon bonded to three other carbons (1)
● Forms layers (1)
● Layers held by weak forces (1)
● Layers can slide - makes it soft/lubricant (1)
● Conducts electricity - one electron per carbon is delocalized (1)
C₆₀ Fullerene:
● 60 carbon atoms (1)
● Form spherical/cage structure (1)
● Soft - weak intermolecular forces between molecules (1)
Topic 1.51: Conductivity
Question Type: Explain non-conductivity
Mark Scheme:
● Covalent compounds do not conduct electricity (1)
● Because there are no charged particles (1)
● No ions present (1)
● No free/delocalized electrons (1)
8. Metallic Bonding (Chemistry only)
Topic 1.52-1.53: Structure and Bonding
Question Type: Draw metallic lattice diagram
Mark Scheme:
● Show regular arrangement of positive ions (1)
● Show sea of delocalized electrons (1)
● Label appropriately (1)
Question Type: Explain metallic bonding
Mark Scheme:
● Electrostatic attraction (1)
● Between positive metal ions (1)
● And delocalized electrons / sea of electrons (1)
Topic 1.54: Properties of Metals
Question Type: Explain electrical conductivity
Mark Scheme:
● Metals contain delocalized electrons (1)
● These electrons are free to move (1)
● Can carry charge/current through structure (1)
Question Type: Explain malleability
Mark Scheme:
● Metal ions can slide over each other (1)
● When force applied (1)
● Metallic bonding maintained (1)
● Because delocalized electrons move with ions (1)
● Therefore metal doesn't break / can be shaped (1)
9. Electrolysis (Chemistry only)
Topic 1.55-1.57: Conductivity and Ions
Question Type: Explain why ionic compounds conduct when molten/aqueous
Mark Scheme:
● Ionic compound contains ions (1)
● When solid, ions are fixed in lattice / cannot move (1)
● When molten/aqueous, ions are free to move (1)
● Can carry charge to electrodes (1)
● Cations = positive ions (1)
● Anions = negative ions (1)
Topic 1.58: Predicting Products
Question Type: Predict products at electrodes
Mark Scheme:
At cathode (negative electrode):
● Positive ions / cations attracted (1)
● Gain electrons / reduced (1)
● Metal or hydrogen produced (1)
● Reactive metals: hydrogen produced instead (1)
At anode (positive electrode):
● Negative ions / anions attracted (1)
● Lose electrons / oxidized (1)
● Non-metal produced (1)
● Oxygen produced if no halide present / from OH⁻ or SO₄²⁻ (1)
Common examples:
● Lead(II) bromide: Pb at cathode, Br₂ at anode
● NaCl(aq): H₂ at cathode, Cl₂ at anode
● Dilute H₂SO₄: H₂ at cathode, O₂ at anode
● CuSO₄(aq): Cu at cathode, O₂ at anode
Topic 1.59: Half Equations
Question Type: Write half equations
Mark Scheme:
● Show correct formula of ion (1)
● Show electrons on correct side (1)
● Balance equation (1)
● Include state symbols (1)
Examples:
● Reduction (gain electrons): Cu²⁺ + 2e⁻ → Cu
● Oxidation (lose electrons): 2Cl⁻ → Cl₂ + 2e⁻
Question Type: Identify oxidation/reduction
Mark Scheme:
● Oxidation: loss of electrons (1) / OIL (1)
● Reduction: gain of electrons (1) / RIG (1)
● Happens at anode (1) / happens at cathode (1)
10. Group 1 - Alkali Metals
Topic 2.1: Similarities in Reactions
Question Type: Describe reactions with water
Mark Scheme:
● All react vigorously with water (1)
● Produce hydrogen gas (1)
● Form metal hydroxide / alkali (1)
● General equation: 2M + 2H₂O → 2MOH + H₂ (1)
Observations:
● Metal floats on water (1)
● Fizzing / effervescence (1)
● Metal moves around surface (1)
● Solution becomes alkaline / pH increases (1)
● With lithium: gentle fizzing (1)
● With sodium: melts into ball / more vigorous (1)
● With potassium: lilac flame seen / very vigorous (1) / may ignite (1)
Topic 2.2: Trends in Reactivity
Question Type: Explain trend in reactivity
Mark Scheme:
● Reactivity increases down the group (1)
● Lithium < sodium < potassium (1)
● Reactions become more vigorous (1)
● Evidence: speed of reaction, amount of heat produced (1)
Reactions with air/oxygen:
● All form metal oxides (1)
● Tarnish when exposed to air (1)
● Must be stored in oil to prevent reaction (1)
● React more vigorously down the group (1)
Topic 2.3: Predicting Properties
Question Type: Predict properties of rubidium/caesium
Mark Scheme:
● More reactive than potassium (1)
● React very vigorously with water (1)
● Likely to explode/ignite in water (1)
● Form hydroxide and hydrogen (1)
● Lower melting/boiling point than potassium (1)
● Higher density than potassium (1)
Topic 2.4: Electronic Configuration Explanation (Chemistry only)
Question Type: Explain trend in terms of electrons
Mark Scheme:
● All Group 1 metals have 1 electron in outer shell (1)
● Down the group, more electron shells / larger atoms (1)
● Outer electron is further from nucleus (1)
● Weaker attraction between nucleus and outer electron (1)
● Shielding from inner electrons increases (1)
● Easier to lose outer electron (1)
● Therefore more reactive down the group (1)
11. Group 7 - Halogens
Topic 2.5: Physical Properties
Question Type: State colours and states
Mark Scheme:
● Fluorine: pale yellow gas (1)
● Chlorine: green/yellow gas (1)
● Bromine: red-brown liquid (1)
● Iodine: grey/black solid (1) / purple vapour (1)
Question Type: Describe trends
Mark Scheme:
● Melting/boiling points increase down the group (1)
● Change from gas → liquid → solid down the group (1)
● Colour darkens down the group (1)
● Become less volatile down the group (1)
Topic 2.6: Predicting Properties
Question Type: Predict properties of astatine
Mark Scheme:
● Solid at room temperature (1)
● Darker than iodine / black (1)
● Higher melting/boiling point than iodine (1)
● Less reactive than iodine (1)
● Forms At⁻ ions (1)
Topic 2.7: Displacement Reactions
Question Type: Describe displacement reactions
Mark Scheme:
● More reactive halogen displaces less reactive halogen (1)
● From its salt/compound (1)
● Chlorine displaces bromine and iodine (1)
● Bromine displaces iodine only (1)
● Iodine cannot displace chlorine or bromine (1)
Question Type: Observations in displacement
Mark Scheme:
● Cl₂ + KBr: solution turns orange/brown (bromine formed) (1)
● Cl₂ + KI: solution turns brown/black (iodine formed) (1)
● Br₂ + KI: solution turns brown/black (iodine formed) (1)
● Br₂ + KCl: no reaction / no colour change (1)
Topic 2.8: Electronic Configuration Explanation (Chemistry only)
Question Type: Explain reactivity trend
Mark Scheme:
● Reactivity decreases down the group (1)
● All Group 7 elements have 7 electrons in outer shell (1)
● Need to gain 1 electron to form stable ion (1)
● Down the group, more electron shells / atoms larger (1)
● Outer shell further from nucleus (1)
● Weaker attraction for incoming electron (1)
● Shielding from inner electrons increases (1)
● Therefore harder to gain electron (1)
● Less reactive down the group (1)
12. Gases in the Atmosphere
Topic 2.9: Composition of Air
Question Type: State percentage composition
Mark Scheme:
● Nitrogen: approximately 78% (1) / 4/5 (1)
● Oxygen: approximately 21% (1) / 1/5 (1)
● Argon: approximately 1% (1) / 0.9% (1)
● Carbon dioxide: approximately 0.04% (1)
● (Water vapour: variable amount)
Topic 2.10: Determining Oxygen Percentage
Question Type: Describe method using iron
Mark Scheme:
● Wet iron wool / filings placed in tube (1)
● Tube inverted over water (1)
● Iron rusts / reacts with oxygen (1)
● Water level rises (1)
● Rise equals volume of oxygen removed (1)
● Calculate: (volume risen ÷ original volume) × 100 (1)
● Should get approximately 20-21% (1)
Question Type: Describe method using phosphorus
Mark Scheme:
● Phosphorus burned in bell jar (1)
● Over water (1)
● Phosphorus reacts with oxygen only (1)
● Forms phosphorus oxide (white smoke) (1)
● Water level rises (1)
● Rise shows volume of oxygen (1)
● Approximately 1/5 of air volume (1)
Topic 2.11: Combustion in Oxygen
Question Type: Describe combustion of magnesium
Mark Scheme:
● Burns with bright white light / flame (1)
● Forms white powder / solid (1)
● Product is magnesium oxide (1)
● 2Mg + O₂ → 2MgO (1)
Question Type: Describe combustion of hydrogen
Mark Scheme:
● Burns with squeaky pop / blue flame (1)
● Forms water / colourless liquid (1)
● 2H₂ + O₂ → 2H₂O (1)
● Water can be tested with anhydrous copper sulfate (turns blue) (1)
Question Type: Describe combustion of sulfur
Mark Scheme:
● Burns with blue flame (1)
● Produces choking gas / acidic gas (1)
● Product is sulfur dioxide (1)
● S + O₂ → SO₂ (1)
Topic 2.12-2.13: Carbon Dioxide
Question Type: Thermal decomposition of carbonates
Mark Scheme:
● Metal carbonate → metal oxide + carbon dioxide (1)
● Example: CuCO₃ → CuO + CO₂ (1)
● Copper carbonate is green (1)
● Changes to black copper oxide when heated (1)
● Test for CO₂: turns limewater milky/cloudy (1)
Question Type: Greenhouse gases and climate change
Mark Scheme:
● CO₂ is a greenhouse gas (1)
● Traps heat in atmosphere / prevents heat escaping (1)
● Increasing levels in atmosphere (1)
● May contribute to climate change / global warming (1)
● Caused by burning fossil fuels (1) / deforestation (1)
13. Reactivity Series
Topic 2.15-2.17: Order of Reactivity
Question Type: State reactivity series
Mark Scheme: Most reactive:
● Potassium (1)
● Sodium (1)
● Lithium (1)
● Calcium (1)
● Magnesium (1)
● Aluminium (1)
● (Carbon) - for reference
● Zinc (1)
● Iron (1)
● (Hydrogen) - for reference
● Copper (1)
● Silver (1)
● Gold (1) Least reactive
Mnemonic: Please Stop Calling Me A Careless Zebra, Instead Try Learning How Copper
Saves Gold
Topic 2.15: Reactions with Water and Acid
Question Type: Reactions with water
Mark Scheme:
● K, Na, Li: react vigorously with cold water (1)
● Form metal hydroxide + hydrogen (1)
● Ca: reacts with cold water, less vigorously (1)
● Mg: reacts slowly with cold water, vigorously with steam (1)
● Zn, Fe: react with steam only (1), form metal oxide + hydrogen (1)
● Cu and below: no reaction with water or steam (1)
Question Type: Reactions with dilute acid
Mark Scheme:
● K, Na, Li, Ca: too dangerous / too reactive (1)
● Mg, Al, Zn, Fe: react to form salt + hydrogen (1)
● Reactivity decreases down the series (1)
● Cu, Ag, Au: no reaction with dilute acid (1)
● General equation: metal + acid → salt + hydrogen (1)
Topic 2.16: Displacement Reactions
Question Type: Metal + metal oxide displacement
Mark Scheme:
● More reactive metal displaces less reactive metal (1)
● From its oxide (1)
● Example: Fe₂O₃ + 3C → 2Fe + 3CO (carbon more reactive than iron) (1)
● Or: CuO + Mg → Cu + MgO (magnesium more reactive than copper) (1)
● Exothermic reaction / heat released (1)
Question Type: Metal + salt solution displacement
Mark Scheme:
● More reactive metal displaces less reactive metal (1)
● From its salt solution (1)
● Example: Mg + CuSO₄ → MgSO₄ + Cu (1)
● Observation: copper formed as brown solid (1)
● Blue solution becomes colourless/pale (1)
● If no reaction: metal is less reactive than metal in salt (1)
Topic 2.18-2.19: Rusting of Iron
Question Type: Conditions for rusting
Mark Scheme:
● Requires both oxygen and water (1)
● Air and water / moisture needed (1)
● Salt water speeds up rusting (1)
● Rusting is oxidation of iron (1)
● Forms hydrated iron(III) oxide (1)
Question Type: Prevention methods
Mark Scheme:
Barrier methods:
● Painting / coating (1)
● Oiling/greasing (1)
● Plastic coating (1)
● Prevents oxygen and water reaching iron (1)
Galvanising:
● Coating with zinc (1)
● Zinc is more reactive than iron (1)
● Zinc reacts instead of iron / acts as barrier (1)
Sacrificial protection:
● Attach blocks of more reactive metal (e.g. zinc, magnesium) (1)
● More reactive metal corrodes instead of iron (1)
● Protects iron by sacrificing itself (1)
● Used on ships, underground pipes (1)
Topic 2.20: Oxidation and Reduction
Question Type: Define terms
Mark Scheme:
In terms of oxygen:
● Oxidation: gain of oxygen (1)
● Reduction: loss of oxygen (1)
● Redox: reaction where oxidation and reduction occur simultaneously (1)
In terms of electrons:
● Oxidation: loss of electrons (1) OIL
● Reduction: gain of electrons (1) RIG
● Oxidising agent: substance that causes oxidation (1) / accepts electrons (1)
● Reducing agent: substance that causes reduction (1) / donates electrons (1)
Question Type: Identify oxidation/reduction in reactions
Mark Scheme: Example: 2Mg + O₂ → 2MgO
● Magnesium is oxidised (1) / gains oxygen (1)
● Oxygen is reduced (1)
● Oxygen is oxidising agent (1)
● Magnesium is reducing agent (1)
Example: ZnO + C → Zn + CO
● Zinc oxide is reduced (1) / loses oxygen (1)
● Carbon is oxidised (1) / gains oxygen (1)
14. Extraction and Uses of Metals (Chemistry only)
Topic 2.22: Metal Ores
Question Type: Define and explain ores
Mark Scheme:
● Ore: rock that contains enough metal to make extraction economical (1)
● Most metals found as compounds in ores (1)
● Unreactive metals (e.g. gold, silver) found as elements / uncombined (1)
● Extraction requires reduction (1)
Topic 2.23: Extraction Methods
Question Type: Relate extraction to reactivity
Mark Scheme:
● Metals more reactive than carbon: extracted by electrolysis (1)
● Example: aluminium (1)
● Metals less reactive than carbon: extracted by reduction with carbon (1)
● Example: iron (1)
● Carbon acts as reducing agent (1)
● Unreactive metals: found native/uncombined (1)
Question Type: Extraction of iron
Mark Scheme:
● Iron ore (e.g. haematite Fe₂O₃) (1)
● Heated with carbon/coke (1)
● In blast furnace (1)
● Carbon reduces iron oxide (1)
● Fe₂O₃ + 3C → 2Fe + 3CO (1)
● Or: Fe₂O₃ + 3CO → 2Fe + 3CO₂ (1)
● Iron oxide loses oxygen / is reduced (1)
● Carbon gains oxygen / is oxidised (1)
Question Type: Extraction of aluminium
Mark Scheme:
● Aluminium ore is bauxite (Al₂O₃) (1)
● Extracted by electrolysis (1)
● Ore dissolved in cryolite to lower melting point (1)
● At cathode: Al³⁺ + 3e⁻ → Al (1) / reduction (1)
● At anode: 2O²⁻ → O₂ + 4e⁻ (1) / oxidation (1)
● Expensive process / requires lots of electricity (1)
● Anode made of carbon / graphite (1)
● Anodes need replacing as they react with oxygen (1)
Topic 2.25: Uses of Metals
Question Type: Explain uses in terms of properties
Mark Scheme:
Aluminium:
● Low density / light (1) - used in aircraft, vehicles (1)
● Doesn't corrode / resistant to corrosion (1) - oxide layer protects (1)
● Good conductor of electricity (1) - used in power cables (1)
Copper:
● Excellent conductor of electricity (1) - used in electrical wiring (1)
● Good conductor of heat (1) - used in saucepans (1)
● Malleable / can be shaped (1)
● Unreactive with water (1) - used in water pipes (1)
Iron and steel:
● Strong (1)
● High tensile strength (1)
● Used in construction / buildings, bridges (1)
● Low-carbon/mild steel: soft, easily shaped (1) - car bodies (1)
● High-carbon steel: hard, strong (1) - cutting tools, blades (1)
● Stainless steel: resistant to corrosion (1) - cutlery, surgical instruments (1)
Topic 2.26-2.27: Alloys
Question Type: Define alloy
Mark Scheme:
● Mixture of a metal with one or more other elements (1)
● Usually other metals or carbon (1)
● Example: steel is iron + carbon (1)
● Example: brass is copper + zinc (1)
Question Type: Explain why alloys are harder
Mark Scheme:
● Pure metal has regular arrangement of identical atoms (1)
● Layers can slide over each other easily (1)
● In alloy, different sized atoms present (1)
● Disrupts regular arrangement / distorts layers (1)
● Layers cannot slide as easily (1)
● Therefore alloy is harder than pure metal (1)
15. Acids, Alkalis and Titrations
Topic 2.28: Indicators
Question Type: Colours of indicators
Mark Scheme:
Litmus:
● In acid: red (1)
● In alkali: blue (1)
● In neutral: purple (1)
Phenolphthalein:
● In acid: colourless (1)
● In alkali: pink / magenta (1)
Methyl orange:
● In acid: red / pink (1)
● In alkali: yellow (1)
Topic 2.29-2.30: pH Scale
Question Type: Describe pH scale
Mark Scheme:
● Scale from 0 to 14 (1)
● 0-3: strongly acidic (1)
● 4-6: weakly acidic (1)
● 7: neutral (1)
● 8-10: weakly alkaline (1)
● 11-14: strongly alkaline (1)
Question Type: Universal indicator
Mark Scheme:
● Shows approximate pH value (1)
● Different colours at different pH values (1)
● Red = strongly acidic (1)
● Orange/yellow = weakly acidic (1)
● Green = neutral (1)
● Blue = weakly alkaline (1)
● Purple = strongly alkaline (1)
Topic 2.31-2.32: Acids and Alkalis
Question Type: Define acids and alkalis
Mark Scheme:
● Acids in solution produce hydrogen ions (H⁺) (1)
● Alkalis in solution produce hydroxide ions (OH⁻) (1)
● Alkalis are soluble bases (1)
Question Type: Neutralisation
Mark Scheme:
● Acid + alkali → salt + water (1)
● H⁺ + OH⁻ → H₂O (ionic equation) (1)
● Exothermic reaction / heat released (1)
● pH moves towards 7 / neutral (1)
Topic 2.33: Titration Method (Chemistry only)
Question Type: Describe titration procedure
Mark Scheme:
Method:
● Use pipette to measure fixed volume of alkali (1)
● Into conical flask (1)
● Add few drops of indicator (1)
● Fill burette with acid (1)
● Record initial reading on burette (1)
● Add acid slowly / drop by drop near end point (1)
● Swirl flask constantly (1)
● Stop when indicator changes colour / end point reached (1)
● Record final reading (1)
● Calculate volume of acid used (final - initial) (1)
● Repeat to get concordant results (1)
● Calculate mean/average titre (ignore anomalies) (1)
Accuracy points:
● Read burette at eye level / avoid parallax error (1)
● Read to nearest 0.05 cm³ / 2 decimal places (1)
● White tile under flask to see colour change clearly (1)
● Wash conical flask between repeats (1)
16. Acids, Bases and Salt Preparations
Topic 2.34: Solubility Rules
Question Type: Predict solubility
Mark Scheme - SOLUBLE compounds:
● All sodium (Na⁺) compounds are soluble (1)
● All potassium (K⁺) compounds are soluble (1)
● All ammonium (NH₄⁺) compounds are soluble (1)
● All nitrates (NO₃⁻) are soluble (1)
● Most chlorides (Cl⁻) are soluble (1)
○ EXCEPT: silver chloride (AgCl) and lead(II) chloride (PbCl₂) are insoluble (1)
● Most sulfates (SO₄²⁻) are soluble (1)
○ EXCEPT: barium sulfate (BaSO₄), calcium sulfate (CaSO₄), lead(II) sulfate
(PbSO₄) are insoluble (1)
Mark Scheme - INSOLUBLE compounds:
● Most carbonates (CO₃²⁻) are insoluble (1)
○ EXCEPT: sodium, potassium, ammonium carbonates are soluble (1)
● Most hydroxides (OH⁻) are insoluble (1)
○ EXCEPT: sodium, potassium hydroxides are soluble (1)
○ Calcium hydroxide is slightly soluble (1)
Memory aid: "NAP" compounds (Sodium, Ammonium, Potassium) are generally soluble
Topic 2.35-2.36: Acids and Bases
Question Type: Define acids and bases
Mark Scheme:
● Acid: proton donor (1) / donates H⁺ ions (1)
● Base: proton acceptor (1) / accepts H⁺ ions (1)
● Proton transfer occurs in acid-base reactions (1)
● H⁺ ion transferred from acid to base (1)
Question Type: Give examples
Mark Scheme:
● HCl → H⁺ + Cl⁻ (acid donates proton) (1)
● NH₃ + H⁺ → NH₄⁺ (base accepts proton) (1)
Topic 2.37: Reactions of Acids
Question Type: Acid + Metal
Mark Scheme:
● Acid + metal → salt + hydrogen (1)
● Example: Mg + H₂SO₄ → MgSO₄ + H₂ (1)
● Example: Zn + 2HCl → ZnCl₂ + H₂ (1)
● Effervescence / fizzing observed (1)
● Test for hydrogen: squeaky pop with lighted splint (1)
● Only works with metals above hydrogen in reactivity series (1)
Question Type: Acid + Base (metal oxide/hydroxide)
Mark Scheme:
● Acid + base → salt + water (1)
● Acid + metal oxide → salt + water (1)
● Acid + metal hydroxide → salt + water (1)
Examples:
● CuO + H₂SO₄ → CuSO₄ + H₂O (1)
● NaOH + HCl → NaCl + H₂O (1)
● Fe₂O₃ + 6HNO₃ → 2Fe(NO₃)₃ + 3H₂O (1)
Question Type: Acid + Carbonate
Mark Scheme:
● Acid + carbonate → salt + water + carbon dioxide (1)
● Example: CaCO₃ + 2HCl → CaCl₂ + H₂O + CO₂ (1)
● Example: Na₂CO₃ + H₂SO₄ → Na₂SO₄ + H₂O + CO₂ (1)
● Effervescence / fizzing observed (1)
● Test for CO₂: turns limewater milky (1)
Question Type: Name salts formed
Mark Scheme:
● Hydrochloric acid produces chlorides (1)
● Sulfuric acid produces sulfates (1)
● Nitric acid produces nitrates (1)
● Salt name = metal + acid ending (1)
Topic 2.38: Bases and Alkalis
Question Type: Define bases and alkalis
Mark Scheme:
● Bases include: metal oxides, metal hydroxides, ammonia (1)
● Base: neutralises acids (1)
● Alkali: base that is soluble in water (1)
● Alkalis produce OH⁻ ions in solution (1)
● Examples of alkalis: NaOH, KOH, NH₃ solution (1)
Topic 2.39: Prepare Soluble Salt from Insoluble Base
Question Type: Describe method (e.g. copper sulfate from copper oxide)
Mark Scheme:
Method:
● Add excess insoluble base (e.g. CuO) to acid (e.g. H₂SO₄) (1)
● Warm the mixture / heat gently (1)
● Stir until no more reacts / acid neutralized (1)
● Filter to remove excess unreacted base (1)
● Heat/evaporate filtrate to concentrate solution (1)
● Leave to crystallize / cool slowly (1)
● Filter to collect crystals (1)
● Wash with cold distilled water (1)
● Dry crystals (in warm oven / between filter papers) (1)
Why excess base used:
● To ensure all acid is used up (1)
● Excess base can be filtered off as it's insoluble (1)
Equation example:
● CuO + H₂SO₄ → CuSO₄ + H₂O (1)
Topic 2.40: Prepare Soluble Salt from Acid + Alkali (Chemistry only)
Question Type: Describe titration method
Mark Scheme:
Method:
● Perform titration first (without indicator) to find volumes needed (1)
● OR: do titration, then repeat exact volumes without indicator (1)
● Measure fixed volume of alkali using pipette (1)
● Add to conical flask (1)
● Add acid from burette drop by drop (1)
● Use indicator (e.g. phenolphthalein) (1)
● Stop when indicator changes / neutralization reached (1)
● Note volume of acid used (1)
● Repeat using exact same volumes but without indicator (1)
● Evaporate solution to concentration point (1)
● Leave to crystallize (1)
● Filter and dry crystals (1)
Why repeat without indicator:
● To get pure salt (1)
● Indicator would contaminate the salt (1)
Topic 2.41: Prepare Insoluble Salt (Chemistry only)
Question Type: Describe precipitation method
Mark Scheme:
Method (e.g. lead sulfate from lead nitrate + sodium sulfate):
● Mix two soluble salt solutions (1)
● That contain the ions needed for the insoluble salt (1)
● Precipitate forms immediately (1)
● Filter to collect precipitate (1)
● Wash with distilled water (1)
● Dry the precipitate (1)
Example:
● Pb(NO₃)₂(aq) + Na₂SO₄(aq) → PbSO₄(s) + 2NaNO₃(aq) (1)
● Or ionic: Pb²⁺(aq) + SO₄²⁻(aq) → PbSO₄(s) (1)
Choosing reactants:
● Choose two soluble compounds (1)
● That contain the required ions (1)
● Check against solubility rules (1)
17. Chemical Tests
Topic 2.44: Gas Tests
Question Type: Test for hydrogen
Mark Scheme:
● Use lighted splint / burning splint (1)
● Hydrogen burns with squeaky pop (1)
● Or: makes popping sound (1)
Question Type: Test for oxygen
Mark Scheme:
● Use glowing splint (1)
● Splint relights / bursts into flames (1)
Question Type: Test for carbon dioxide
Mark Scheme:
● Bubble through limewater / calcium hydroxide solution (1)
● Limewater turns milky / cloudy / white precipitate forms (1)
● Equation: Ca(OH)₂ + CO₂ → CaCO₃ + H₂O (1)
Question Type: Test for ammonia
Mark Scheme:
● Use damp red litmus paper (1)
● Paper turns blue (1)
● Or: has pungent/sharp smell (1)
● Only alkaline gas commonly tested (1)
Question Type: Test for chlorine
Mark Scheme:
● Use damp litmus paper (1)
● Paper bleached / turns white (1)
● Or: has sharp/choking smell (1)
Topic 2.45-2.46: Flame Tests
Question Type: Describe flame test procedure
Mark Scheme:
● Clean nichrome wire / platinum wire (1)
● By dipping in concentrated HCl (1)
● Heat in blue Bunsen flame until no colour seen (1)
● Dip wire in sample / compound (1)
● Hold in blue flame (1)
● Observe colour produced (1)
Question Type: State flame test colours
Mark Scheme:
● Lithium (Li⁺): red / crimson (1)
● Sodium (Na⁺): yellow / golden (1)
● Potassium (K⁺): lilac / pale purple (1)
● Calcium (Ca²⁺): orange-red (1)
● Copper (Cu²⁺): blue-green (1)
Memory aid: LiNa K CalCu = Red Yellow Lilac Orange-red Blue-green
Topic 2.47: Cation Tests with NaOH
Question Type: Test for ammonium ions (NH₄⁺)
Mark Scheme:
● Add sodium hydroxide solution (1)
● Warm/heat the mixture (1)
● Ammonia gas produced / released (1)
● Test with damp red litmus (turns blue) (1)
● Or: pungent smell detected (1)
● Equation: NH₄⁺ + OH⁻ → NH₃ + H₂O (1)
Question Type: Test for metal cations
Mark Scheme:
Copper (Cu²⁺):
● Add sodium hydroxide solution (1)
● Blue precipitate forms (1)
● Precipitate is copper(II) hydroxide (1)
● Precipitate insoluble in excess NaOH (1)
● Cu²⁺ + 2OH⁻ → Cu(OH)₂ (1)
Iron(II) (Fe²⁺):
● Add sodium hydroxide solution (1)
● Green precipitate forms (1)
● Precipitate is iron(II) hydroxide (1)
● May turn brown on standing (oxidation in air) (1)
● Fe²⁺ + 2OH⁻ → Fe(OH)₂ (1)
Iron(III) (Fe³⁺):
● Add sodium hydroxide solution (1)
● Brown precipitate forms / rust-colored (1)
● Precipitate is iron(III) hydroxide (1)
● Fe³⁺ + 3OH⁻ → Fe(OH)₃ (1)
Topic 2.48: Anion Tests
Question Type: Test for halide ions (Cl⁻, Br⁻, I⁻)
Mark Scheme:
Method:
● Add dilute nitric acid (1)
● Then add silver nitrate solution (1)
● Observe precipitate formed (1)
Results:
● Chloride (Cl⁻): white precipitate (silver chloride) (1)
● Bromide (Br⁻): cream precipitate (silver bromide) (1)
● Iodide (I⁻): yellow precipitate (silver iodide) (1)
Why add nitric acid:
● To remove carbonate ions (1)
● Which would also form white precipitate (1)
Equations:
● Ag⁺ + Cl⁻ → AgCl (1)
● Ag⁺ + Br⁻ → AgBr (1)
● Ag⁺ + I⁻ → AgI (1)
Question Type: Test for sulfate ions (SO₄²⁻)
Mark Scheme:
● Add dilute hydrochloric acid / or nitric acid (1)
● Then add barium chloride solution (1)
● White precipitate forms (1)
● Precipitate is barium sulfate (1)
● Ba²⁺ + SO₄²⁻ → BaSO₄ (1)
Why add acid:
● To remove carbonate/sulfite ions (1)
● Which would also give white precipitate with Ba²⁺ (1)
Question Type: Test for carbonate ions (CO₃²⁻)
Mark Scheme:
● Add dilute acid (e.g. HCl or H₂SO₄) (1)
● Effervescence / fizzing / gas produced (1)
● Bubble gas through limewater (1)
● Limewater turns milky/cloudy (1)
● Confirms gas is carbon dioxide (1)
● Equation: CO₃²⁻ + 2H⁺ → CO₂ + H₂O (1)
Topic 2.49-2.50: Tests for Water
Question Type: Test for presence of water
Mark Scheme:
● Use anhydrous copper(II) sulfate (1)
● White/grey powder (1)
● Turns blue in presence of water (1)
● Forms hydrated copper(II) sulfate (1)
● CuSO₄ + 5H₂O → CuSO₄·5H₂O (1)
Alternative:
● Use anhydrous cobalt chloride (1)
● Blue paper (1)
● Turns pink in presence of water (1)
Question Type: Test for pure water
Mark Scheme:
● Measure boiling point (1)
● Pure water boils at exactly 100°C (at standard pressure) (1)
● Or measure melting/freezing point (1)
● Pure water freezes at exactly 0°C (1)
● Impure water has range of melting/boiling points (1)
● Or: boiling point is higher / melting point is lower than pure (1)
To identify an unknown compound systematically:
1. Flame test → identify metal cation (if coloured)
2. Add NaOH solution → identify metal cation (by precipitate colour)
3. Add dilute acid → test for carbonate (effervescence)
4. Add silver nitrate + HNO₃ → test for halides (precipitate colour)
5. Add barium chloride + HCl → test for sulfate (white precipitate)
18. Energetics (Physical Chemistry)
Topic 3.1: Types of Reactions
Question Type: Define exothermic and endothermic
Mark Scheme:
● Exothermic reaction: releases/gives out heat energy (1)
● To the surroundings (1)
● Temperature of surroundings increases (1)
● Endothermic reaction: takes in/absorbs heat energy (1)
● From the surroundings (1)
● Temperature of surroundings decreases (1)
Question Type: Give examples
Mark Scheme:
● Exothermic examples:
○ Combustion (1)
○ Neutralisation (1)
○ Displacement reactions (1)
○ Respiration (1)
○ Oxidation reactions (1)
● Endothermic examples:
○ Thermal decomposition (1)
○ Photosynthesis (1)
○ Dissolving some salts (e.g. ammonium nitrate) (1)
Topic 3.2-3.4: Calorimetry
Question Type: Describe calorimetry experiment
Mark Scheme:
● Method:
○ Measure mass of substance/solution (1)
○ Measure initial temperature (1)
○ Carry out reaction in insulated container/polystyrene cup (1)
○ Stir mixture (1)
○ Measure maximum/minimum temperature reached (1)
○ Calculate temperature change (ΔT = final - initial) (1)
Question Type: Calculate heat energy change
Mark Scheme:
● Use equation: Q = mcΔT (1)
● Q = heat energy change in joules (J) (1)
● m = mass in grams (g) (1)
● c = specific heat capacity (4.2 J/g°C for water) (1)
● ΔT = temperature change in °C (1)
● Correct substitution (1)
● Correct answer with units (J or kJ) (1)
Question Type: Calculate molar enthalpy change (ΔH)
Mark Scheme:
● Calculate heat energy change Q first using Q = mcΔT (1)
● Calculate moles of limiting reactant (1)
● ΔH = Q ÷ moles (1)
● Include correct sign (negative for exothermic, positive for endothermic) (1)
● Correct units (kJ/mol) (1)
Topic 3.5-3.7: Energy Level Diagrams and Bond Energies (Chemistry
only)
Question Type: Draw energy level diagram
Mark Scheme:
● Exothermic:
○ Products at lower energy level than reactants (1)
○ Arrow pointing downwards (1)
○ ΔH shown as negative/pointing down (1)
○ Activation energy shown from reactants to peak (1)
● Endothermic:
○ Products at higher energy level than reactants (1)
○ Arrow pointing upwards (1)
○ ΔH shown as positive/pointing up (1)
○ Activation energy shown from reactants to peak (1)
Question Type: Explain bond breaking and making Mark Scheme:
● Bond breaking is endothermic (1)
● Requires/absorbs energy (1)
● Bond making is exothermic (1)
● Releases energy (1)
Question Type: Calculate enthalpy change from bond energies
Mark Scheme:
● Energy in = sum of all bonds broken (1)
● Energy out = sum of all bonds formed (1)
● ΔH = energy in - energy out (1)
● OR: ΔH = bonds broken - bonds formed (1)
● If result is negative, reaction is exothermic (1)
● If result is positive, reaction is endothermic (1)
● Correct answer with units (kJ/mol) (1)
19. Rates of Reaction
Topic 3.9-3.10: Factors Affecting Rate
Question Type: Describe methods to measure rate
Mark Scheme:
● Methods:
○ Measure volume of gas produced using gas syringe (1)
○ At regular time intervals (1)
○ Measure mass loss using balance (1)
○ Measure time for solution to become cloudy (1)
○ Measure time for colour change (1)
Question Type: Factors that affect rate
Mark Scheme:
● Increasing temperature increases rate (1)
● Increasing concentration of solution increases rate (1)
● Increasing pressure of gas increases rate (1)
● Increasing surface area of solid increases rate (1)
● Using a catalyst increases rate (1)
Topic 3.11: Collision Theory
Question Type: Explain effect of temperature
Mark Scheme:
● Higher temperature gives particles more energy (1)
● Particles move faster (1)
● More frequent collisions (1)
● More collisions have energy ≥ activation energy (1)
● Therefore rate increases (1)
Question Type: Explain effect of concentration
Mark Scheme:
● Higher concentration means more particles (1)
● In same volume (1)
● Particles closer together (1)
● More frequent collisions (1)
● Therefore rate increases (1)
Question Type: Explain effect of surface area
Mark Scheme:
● Smaller pieces/powder have larger surface area (1)
● More particles exposed to react (1)
● More frequent collisions (1)
● Therefore rate increases (1)
Question Type: Explain effect of pressure (gases)
Mark Scheme:
● Higher pressure means same number of gas particles (1)
● In smaller volume (1)
● Particles closer together (1)
● More frequent collisions (1)
● Therefore rate increases (1)
Topic 3.12-3.14: Catalysts
Question Type: Define and explain catalysts
Mark Scheme:
● Catalyst: increases rate of reaction (1)
● Without being used up/chemically unchanged at end (1)
● Only small amount needed (1)
● Works by providing alternative pathway (1)
● With lower activation energy (1)
● More particles have energy ≥ activation energy (1)
● Therefore more successful collisions (1)
Question Type: Draw reaction profile diagram (Chemistry only)
Mark Scheme:
● x-axis labeled "progress of reaction" (1)
● y-axis labeled "energy" (1)
● Reactants and products labeled (1)
● Activation energy shown from reactants to peak (1)
● ΔH shown between reactants and products (1)
● Catalyzed pathway shown with lower peak (1)
● Lower activation energy labeled (1)
20. Reversible Reactions and Equilibria (Chemistry only)
Topic 3.17-3.18: Reversible Reactions
Question Type: Define reversible reaction
Mark Scheme:
● Reaction that can go in both directions (1)
● Forward and backward/reverse reaction occur (1)
● Shown by ⇌ symbol (1)
Question Type: Give examples
Mark Scheme:
● Hydrated copper sulfate ⇌ anhydrous copper sulfate + water (1)
● CuSO₄·5H₂O ⇌ CuSO₄ + 5H₂O (1)
● Blue crystals ⇌ white powder (when heated) (1)
● White powder + water → blue crystals (when water added) (1)
● Ammonium chloride ⇌ ammonia + hydrogen chloride (1)
● NH₄Cl ⇌ NH₃ + HCl (1)
Topic 3.19-3.20: Dynamic Equilibrium
Question Type: Define dynamic equilibrium Mark Scheme:
● Occurs in sealed/closed container (1)
● Forward and reverse reactions occur at same rate (1)
● Concentrations of reactants and products remain constant (1)
● Reactions haven't stopped / still occurring (1)
● Macroscopic properties unchanged (1)
Topic 3.21: Effect of Catalyst on Equilibrium
Question Type: Explain catalyst effect
Mark Scheme:
● Catalyst increases rate of forward reaction (1)
● Catalyst increases rate of reverse reaction equally (1)
● Position of equilibrium unchanged (1)
● Equilibrium reached faster (1)
● But same amount of products formed (1)
Topic 3.22: Le Chatelier's Principle
Question Type: Effect of temperature change
Mark Scheme:
● Increase in temperature:
○ Shifts equilibrium in endothermic direction (1)
○ To absorb the extra heat (1)
● Decrease in temperature:
○ Shifts equilibrium in exothermic direction (1)
○ To release heat (1)
Question Type: Effect of pressure change
Mark Scheme:
● Increase in pressure:
○ Shifts equilibrium to side with fewer moles of gas (1)
○ To reduce pressure (1)
● Decrease in pressure:
○ Shifts equilibrium to side with more moles of gas (1)
○ To increase pressure (1)
● No effect if equal moles of gas on both sides (1)
Question Type: Apply to Haber Process (N₂ + 3H₂ ⇌ 2NH₃, ΔH = -92 kJ/mol)
Mark Scheme:
● Forward reaction is exothermic (1)
● High pressure favors forward reaction (1)
● Because 4 moles gas → 2 moles gas (1)
● Low temperature favors forward reaction (1)
● Because forward reaction is exothermic (1)
● But low temperature gives slow rate (1)
● Compromise temperature used (about 450°C) (1)
● Catalyst (iron) used to increase rate (1)
21. Organic Chemistry - Introduction
Topic 4.1-4.3: Basic Concepts
Question Type: Define key terms
Mark Scheme:
● Hydrocarbon: compound containing hydrogen and carbon only (1)
● Homologous series: family of compounds (1) with same functional group (1) and same
general formula (1) / similar chemical properties (1)
● Functional group: atom or group of atoms (1) that determines chemical properties (1)
● Isomers: compounds with same molecular formula (1) but different structural formulae
(1)
Question Type: Types of formulae
Mark Scheme:
● Empirical formula: simplest whole number ratio of atoms (1)
● Molecular formula: actual number of atoms of each element (1)
● General formula: algebraic formula for homologous series (1) e.g. C H₂ ₊₂ (1)
● Structural formula: shows arrangement of atoms (1) e.g. CH₃CH₂CH₃ (1)
● Displayed formula: shows all bonds between atoms (1)
Topic 4.6: Types of Reactions
Mark Scheme:
● Substitution: one atom/group replaced by another (1)
● Addition: two molecules join to form one (1) / atoms added across double bond (1)
● Combustion: reaction with oxygen (1) / burning (1)
22. Crude Oil
Topic 4.7-4.10: Fractional Distillation
Question Type: Describe crude oil
Mark Scheme:
● Mixture of hydrocarbons (1)
● Mainly alkanes (1)
● Different chain lengths (1)
● Formed from ancient dead organisms (1)
● Over millions of years (1)
● Under high temperature and pressure (1)
Question Type: Describe fractional distillation process
Mark Scheme:
● Crude oil heated to vaporize (1)
● Vapors pass into fractionating column (1)
● Column has temperature gradient (1)
● Hotter at bottom, cooler at top (1)
● Hydrocarbons condense at different heights (1)
● According to their boiling points (1)
● Collected as fractions (1)
Question Type: Name fractions and uses
Mark Scheme:
● Refinery gases: used for bottled gas / camping gas / heating (1)
● Gasoline/petrol: used as fuel for cars (1)
● Kerosene: used as fuel for aircraft / jet fuel (1)
● Diesel: used as fuel for cars, lorries, trains (1)
● Fuel oil: used as fuel for ships, power stations (1)
● Bitumen: used for road surfacing / roofing (1)
Question Type: Trends in fractions
Mark Scheme:
● As chain length increases going down column:
○ Boiling point increases (1)
○ Viscosity increases / becomes thicker (1)
○ Color darkens (1)
○ Flammability decreases / harder to ignite (1)
○ Volatility decreases / evaporates less easily (1)
Topic 4.11-4.16: Combustion and Pollution
Question Type: Complete combustion
Mark Scheme:
● Requires plentiful/excess oxygen (1)
● Hydrocarbon + oxygen → carbon dioxide + water (1)
● Example: CH₄ + 2O₂ → CO₂ + 2H₂O (1)
● Exothermic reaction / releases energy (1)
Question Type: Incomplete combustion Mark Scheme:
● Occurs when oxygen supply is limited (1)
● Hydrocarbon + oxygen → carbon monoxide + water (1)
● Or: → carbon (soot) + water (1)
● Example: 2CH₄ + 3O₂ → 2CO + 4H₂O (1)
Question Type: Explain danger of carbon monoxide
Mark Scheme:
● Carbon monoxide is toxic/poisonous (1)
● Colorless and odorless (1)
● Binds to hemoglobin in blood (1)
● Prevents oxygen being transported (1)
● Can cause death (1)
Question Type: Nitrogen oxides formation
Mark Scheme:
● High temperatures in car engines (1)
● Nitrogen and oxygen from air react (1)
● N₂ + O₂ → 2NO (1)
● Nitrogen oxides contribute to acid rain (1)
● Cause photochemical smog (1)
● Respiratory problems (1)
Question Type: Sulfur dioxide pollution
Mark Scheme:
● Sulfur impurities in hydrocarbon fuels (1)
● Sulfur burns during combustion (1)
● S + O₂ → SO₂ (1)
● Sulfur dioxide dissolves in rain water (1)
● Forms sulfuric acid / acid rain (1)
● H₂O + SO₂ → H₂SO₃ (1)
● Damages buildings, trees, aquatic life (1)
Topic 4.17-4.18: Cracking
Question Type: Describe cracking
Mark Scheme:
● Breaking down long-chain hydrocarbons (1)
● Into shorter-chain alkanes and alkenes (1)
● Thermal decomposition reaction (1)
● Catalyst: silica or alumina (1)
● Temperature: 600-700°C (1)
Question Type: Explain why cracking is needed
Mark Scheme:
● High demand for short-chain hydrocarbons (1)
● Low demand for long-chain hydrocarbons (1)
● Converts excess long chains into useful products (1)
● Produces alkenes for polymers (1)
● Produces short-chain alkanes for petrol (1)
Question Type: Write cracking equation
Mark Scheme:
● Example: C₁₀H₂₂ → C₈H₁₈ + C₂H₄ (1)
● Long-chain alkane → shorter alkane + alkene (1)
● Products must balance with reactant (1)
23. Alkanes
Topic 4.19-4.21: Properties and Structure
Question Type: Define alkanes
Mark Scheme:
● General formula: C H₂ ₊₂ (1)
● Saturated hydrocarbons (1)
● Contain only single C-C bonds (1)
● No double bonds (1)
Question Type: Draw and name alkanes
Mark Scheme:
● Methane: CH₄ (1)
● Ethane: C₂H₆ or CH₃CH₃ (1)
● Propane: C₃H₈ or CH₃CH₂CH₃ (1)
● Butane: C₄H₁₀ or CH₃CH₂CH₂CH₃ (1)
● Pentane: C₅H₁₂ or CH₃CH₂CH₂CH₂CH₃ (1)
● Correct displayed formula showing all bonds (1)
Topic 4.22: Reactions of Alkanes
Question Type: Substitution with halogens
Mark Scheme:
● Alkane + halogen → haloalkane + hydrogen halide (1)
● Requires ultraviolet light / UV radiation / sunlight (1)
● Example: CH₄ + Cl₂ → CH₃Cl + HCl (1)
● Hydrogen atom replaced by halogen atom (1)
● Substitution reaction (1)
24. Alkenes
Topic 4.23-4.26: Properties and Structure
Question Type: Define alkenes
Mark Scheme:
● Contain C=C double bond (1)
● Functional group: >C=C< (1)
● General formula: C H₂ (1)
● Unsaturated hydrocarbons (1)
● Contain at least one double bond (1)
Question Type: Draw and name alkenes
Mark Scheme:
● Ethene: C₂H₄ or CH₂=CH₂ (1)
● Propene: C₃H₆ or CH₃CH=CH₂ (1)
● Butene: C₄H₈ or CH₃CH₂CH=CH₂ (1)
● Correct displayed formula showing double bond (1)
Topic 4.27-4.28: Reactions of Alkenes
Question Type: Addition with bromine
Mark Scheme:
● Alkene + bromine → dibromoalkane (1)
● Example: C₂H₄ + Br₂ → C₂H₄Br₂ (1)
● Double bond broken (1)
● Bromine atoms added across double bond (1)
● Addition reaction (1)
Question Type: Test for alkenes
Mark Scheme:
● Add bromine water (1)
● Alkene: orange/brown bromine water decolorizes (1)
● Turns colorless (1)
● Alkane: no color change (1)
● Remains orange/brown (1)
25. Alcohols (Chemistry only)
Topic 4.29-4.30: Structure
Question Type: Define and draw alcohols
Mark Scheme:
● Functional group: -OH (1)
● Hydroxyl group (1)
● Methanol: CH₃OH (1)
● Ethanol: C₂H₅OH or CH₃CH₂OH (1)
● Propanol: C₃H₇OH or CH₃CH₂CH₂OH (1)
● Butanol: C₄H₉OH or CH₃CH₂CH₂CH₂OH (1)
Topic 4.31: Oxidation of Ethanol
Question Type: Methods of oxidation
Mark Scheme:
● Complete combustion:
○ Burn in oxygen/air (1)
○ C₂H₅OH + 3O₂ → 2CO₂ + 3H₂O (1)
○ Produces carbon dioxide and water (1)
● Microbial oxidation:
○ React with oxygen in air (1)
○ Microbes/bacteria present (1)
○ Forms ethanoic acid (1)
○ C₂H₅OH + O₂ → CH₃COOH + H₂O (1)
● Chemical oxidation:
○ Heat with potassium dichromate(VI) (1)
○ In dilute sulfuric acid (1)
○ Forms ethanoic acid (1)
○ Orange solution turns green (1)
Topic 4.32-4.33: Manufacture of Ethanol
Question Type: Hydration of ethene
Mark Scheme:
● Ethene reacted with steam (1)
● Catalyst: phosphoric acid (1)
● Temperature: about 300°C (1)
● Pressure: about 60-70 atm (1)
● C₂H₄ + H₂O → C₂H₅OH (1)
● Advantages: continuous process, fast, pure product (1)
● Disadvantages: uses non-renewable ethene, high energy cost (1)
Question Type: Fermentation
Mark Scheme:
● Glucose converted to ethanol (1)
● C₆H₁₂O₆ → 2C₂H₅OH + 2CO₂ (1)
● Uses yeast / enzymes in yeast (1)
● Temperature: about 30°C (optimum) (1)
● Absence of air / anaerobic conditions (1)
● Takes several days / batch process (1)
● Advantages: uses renewable resources, low temperature (1)
● Disadvantages: slow, dilute product needs purification (1)
Question Type: Explain fermentation conditions
Mark Scheme:
● Absence of air needed:
○ Prevents oxidation to ethanoic acid (1)
○ Yeast respires anaerobically (1)
● Optimum temperature needed:
○ Too low: enzymes work slowly (1)
○ Too high: enzymes denature (1)
○ About 30°C gives fastest rate (1)
26. Carboxylic Acids (Chemistry only)
Topic 4.34-4.35: Structure
Question Type: Functional group
Mark Scheme:
● Functional group: -COOH (1)
● Carboxyl group (1)
● Contains C=O and -OH (1)
Question Type: Draw and name carboxylic acids
Mark Scheme:
● Methanoic acid: HCOOH (1)
● Ethanoic acid: CH₃COOH (1)
● Propanoic acid: CH₃CH₂COOH or C₂H₅COOH (1)
● Butanoic acid: CH₃CH₂CH₂COOH or C₃H₇COOH (1)
Topic 4.36-4.37: Reactions
Question Type: Reactions of carboxylic acids
Mark Scheme:
● Acid + metal → salt + hydrogen (1)
○ Example: 2CH₃COOH + Mg → (CH₃COO)₂Mg + H₂ (1)
● Acid + carbonate → salt + water + carbon dioxide (1)
○ Example: 2CH₃COOH + CaCO₃ → (CH₃COO)₂Ca + H₂O + CO₂ (1)
● Weak acids (1)
● Partially ionize in solution (1)
Question Type: Vinegar
Mark Scheme:
● Vinegar contains ethanoic acid (1)
● Aqueous solution of ethanoic acid (1)
● About 4-8% ethanoic acid (1)
27. Esters (Chemistry only)
Topic 4.38-4.42: Structure and Formation
Question Type: Functional group
Mark Scheme:
● Functional group: -COO- (1)
● Ester link (1)
Question Type: Formation of esters
Mark Scheme:
● Alcohol + carboxylic acid → ester + water (1)
● Acid catalyst needed (e.g. concentrated H₂SO₄) (1)
● Heat mixture (1)
● Esterification reaction / condensation reaction (1)
● Example: CH₃COOH + C₂H₅OH → CH₃COOC₂H₅ + H₂O (1)
● Ethanoic acid + ethanol → ethyl ethanoate + water (1)
Question Type: Name and draw esters
Mark Scheme:
● Name: [alcohol part] [acid part]-oate (1)
● Example: ethyl ethanoate from ethanol and ethanoic acid (1)
● Structure: CH₃COOC₂H₅ or CH₃-COO-CH₂-CH₃ (1)
Question Type: Properties and uses
Mark Scheme:
● Volatile / evaporate easily (1)
● Distinctive/pleasant smells (1)
● Used as food flavorings (1)
● Used in perfumes (1)
● Sweet/fruity smells (1)
28. Synthetic Polymers
Topic 4.44-4.47: Addition Polymers
Question Type: Define addition polymer
Mark Scheme:
● Formed by joining many small molecules (1)
● Small molecules called monomers (1)
● Monomers contain C=C double bond (1)
● Double bond opens up to form polymer (1)
● No other products formed (1)
Question Type: Draw repeat unit
Mark Scheme:
● Brackets around repeat unit (1)
● Extension bonds/continuation bonds shown (1)
● Subscript n outside brackets (1)
● Example: poly(ethene) from ethene:
○ Monomer: CH₂=CH₂ (1)
○ Repeat unit: -[CH₂-CH₂]- (1)
● Example: poly(propene) from propene:
○ Monomer: CH₂=CHCH₃ (1)
○ Repeat unit: -[CH₂-CH(CH₃)]- (1)
Question Type: Problems with disposal
Mark Scheme:
● Non-biodegradable (1)
● Chemically inert / unreactive (1)
● Persist in environment / landfill (1)
● Take hundreds of years to break down (1)
● Burning produces toxic gases (1)
● E.g. hydrogen chloride from PVC (1)
● E.g. carbon monoxide from incomplete combustion (1)
Topic 4.48-4.50: Condensation Polymers (Chemistry only)
Question Type: Formation of polyesters
Mark Scheme:
● Formed from dicarboxylic acid + diol (1)
Question Type: Formation of polyesters
Mark Scheme:
● Formed from dicarboxylic acid + diol (1)
● Each monomer has two functional groups (1)
● Small molecule (water) eliminated (1)
● Ester links formed (1)
● Example: ethanedioic acid + ethanediol → polyester + water (1)
Question Type: Draw polyester structure
Mark Scheme:
● Show repeat unit in brackets (1)
● Show ester link -COO- (1)
● Extension bonds shown (1)
● Subscript n (1)
Question Type: Biodegradable polymers Mark Scheme:
● Some polyesters are biodegradable (1)
● Called biopolyesters (1)
● Can be broken down by microorganisms (1)
● More environmentally friendly (1)
● Reduce landfill problems (1)
Practical Skills Mark Schemes
General Practical Assessment Criteria
Accuracy and precision (2-3 marks):
● Measurements to appropriate significant figures (1)
● Repeat readings taken (1)
● Anomalous results identified and excluded (1)
Safety (1-2 marks):
● Appropriate safety precautions mentioned (1)
● Risk assessment considerations (1)
Method description (4-6 marks):
● Clear, logical sequence (1-2)
● Sufficient detail for reproducibility (1-2)
● Correct equipment identified (1-2)
Results presentation (2-3 marks):
● Table with headings and units (1)
● Graph with labeled axes (1)
● Appropriate scale chosen (1)
Analysis and conclusion (2-4 marks):
● Results analyzed correctly (1-2)
● Conclusion linked to results (1)
● Evaluation of reliability (1)
Common Mark Scheme Terminology
Command words you must understand:
● State: Give a simple answer, no explanation needed
● Describe: Give characteristics or main features
● Explain: Give reasons why or how
● Compare: Give similarities and differences
● Suggest: Use knowledge to propose answer to unfamiliar situation
● Calculate: Work out numerical answer, show working
● Deduce: Draw conclusion from information provided
Marking points:
● (1) = 1 mark
● [2] = total marks for question
● Any two from: = choose any 2 correct points for 2 marks
● ECF = error carried forward (credit for correct method even if earlier error)
Exam Technique Tips
For full marks, ensure:
1. Use correct scientific terminology consistently
2. Show all working in calculations
3. Include units where appropriate
4. Balance equations before using them
5. Check significant figures match data given
6. Link explanations to particle behavior when appropriate
7. Use comparative language (more/less, higher/lower, stronger/weaker)
8. Answer the command word - if it says "explain" you must give reasons