24-11-2025

4602CJA101032250011 JM

PART-1 : PHYSICS

SECTION-I

1) The power emitted per unit area of a black body is R watt/m2. At what wavelength will the power
radiated by the black body be maximum? If the Stefan's constant is σ and Wien's constant is b, then
:-

(A)
λ=

(B)
λ=

(C)
λ=
λ=
(D)

2) Four rods of same material with different radii r and length ℓ are used to connect two reservoirs
of heat at different temperatures. Which one will conduct most heat ?

(A) r = 4cm, ℓ = 1m
(B) r = 4cm, ℓ = 4m
(C) r = 1cm, ℓ = 1m
(D) r = 2 cm, ℓ = 2 m

3) A given mass m of a solid is supplied with heat continuously at a constant rate and the graph
shown in the figure is plotted. If Lf and Lv are latent heat of fusion and latent heat of vaporization
and Sℓ and Ss are specific heats of liquid and solid respectively, then :-

(A)
(B)
(C)
(D)
4) Two light wires of the same material (Young's modulus Y) and same length L but different radii R
and 2R, as shown in the figure, are joined end to end and supported from a fixed support. A weight

W is suspended from the combination. The elastic potential energy in the system is :-

(A)

(B)

(C)

(D)

5) The graph shown is the extension of wire of length 1m suspended from the top of a roof at one
end and with a load W connected to the other end. If the cross sectional area of the wire is 1 mm2,

then the Young's modulus of the material of the wire :-

(A) 2 × 1011 Nm–1

(B) 2 × 1010 Nm–2

(C)
× 1011 Nm–2
(D) None of these

6) In the circuit given in figure, 1 and 2 are ammeters. Just after key K is pressed to complete the

circuit, the reading will be :-

(A) zero in both (1) and (2)

(B) maximum in both (1) and (2)
(C) zero in (1) and maximum in (2)
(D) maximum in (1) and zero in (2)

7) In the figure shown let i1 be current from battery just after the switch is closed and i2 be current

at steady state. Find i1/i2 :-

(A) 1
(B) 0.8
(C) 1.25
(D) None

8) A current 'I' flows through a thin wire as shown in the figure. If there exists an external magnetic

field B in the same plane of the wire, the torque acting on the coil is :-

(A)

(B)

(C)

(D) 0

9) In the figure, there is a conducting wire having current i and which has a shape of half ellipse

is kept in a uniform magnetic field B as shown. If the mass of wire is m, the

acceleration of wire will be :-

(A)
(B)

(C)

(D)

10) Consider the figure below, initially distance between plates of capacitor is ‘d’ and ‘A’ is area of
plates. In this state spring (non condcuting) is at its natural length. Now, charges +Q & –Q are
given to plates and system is allowed to reach mechanical equillibrium. Find potential difference

between plates in this state of equillibrium :-

(A)

(B)

(C)

(D)

11) The circuit shown below shows a steady state with S open. When S is closed :-

(A) No charge passes through S.

(B) A steady current of 30 A flows through S.
(C) 90µC of charge flows from B to A
(D) 120 µC of charge flows from A to B

12) The V versus x plot for six identical metal plates of cross-sectional area A is as shown. The
equivalent capacitance between 2 and 5 is (Adjacent plates are placed at a separation d) :-
(A)

(B)

(C)

(D)

13) Which of the following options is incorrect regarding the below diagram ?

(A) I1 = 8 Amp.
(B) I2 = 4 Amp.
(C) I1 = 0
(D) I3 = 8 Amp.

14) Two light bulbs shown in the circuit have ratings A (24 V, 24 W) and B (24 V and 36W) as shown.

When the switch is closed :-

(A) the intensity of light bulb A increases

(B) the intensity of light bulb A decreases
(C) the intensity of light bulb B remain unchange
(D) the intensity of light bulb B decreases

15) Two smooth rings A and B are connected by a string. A another string connect. Ring A and block,
if strings are tight then at given moment :-

(A) vB = 15 m/s
(B) vB = 24 m/s
(C) vB = 20 m/s
(D) vB = 12 m/s

16) As shown in figure, the coefficient of friction for blocks A, B and C

are respectively. The minimum value of 'F' so as to shift block C, is :-

(A)
(B)
(C)
(D)

17) Potential energy as a function of r is given by , where r is the interatomic distance,

A and B are positive constants. The equilibrium distance between the two atoms will be :-

(A)

(B)

(C)

(D)

18) A force acts on a body and produces a displacement . The work

done will be :-

(A) 10 J
(B) 20 J
(C) 30 J
(D) 40 J
19) A plane surface is inclined making an angle θ with the horizontal. From the bottom of this
inclined plane, a bullet is fired with velocity v. The maximum possible range of the bullet on the
inclined plane is :-

(A)

(B)

(C)

(D)

20) As shown in figure, a body is projected with velocity u1 from the point O. At the same time
another body is projected vertically upwards with the velocity u2 from the point B. The value of u1/u2

so that both the bodies collide is :-

(A)

(B)

(C)
(D)

SECTION-II

1) How long does a 10 kw water heater take to raise the temperature of 100 L of water from 21°C to
31ºC (in min) :-

2) A long cylindrical vessel having a linear coefficient of expansion α is filled with a liquid upto a
certain level. On heating, it is found that the height of liquid in the cylinder remains the same. The
coefficient of volume expansion of liquid is given by β × 10–γ. Fill γ + β in OMR sheet. (β & γ are
smallest possible integers) [Given : α = 5 × 10–7/°C]

3) Two particles perform SHM of same frequency and about same mean position. Their amplitude is

same A, and time period T. At t = 0, their separation is maximum and is A. Their separation at t =

is . Find n.
4) A spring (spring constant k) having one end attached to rigid wall & other end attached to a block
of mass m kept on a smooth surface as shown in figure. Initially spring is in its natural length at x =

0, now spring is compressed to x = –a and released. (Coefficient of restitution (e) = ). If velocity of

block just after first collision is . Find the value of n.

5) The height at which the acceleration due to gravity decreases by 36% of its value on the surface
of the earth is R/x, then the value of x is : (Assume radius of the earth is R)

PART-2 : CHEMISTRY

SECTION-I

1) n, ℓ and m values of an electron in 3py orbital are :-

(A) n = 3 ; ℓ = 1 and m = +1
(B) n = 3 ; ℓ = 1 and m = –1
(C) Both (A) and (B) are correct
(D) None of these

2) What is the ratio of the De-Broglie wave lengths for electrons accelerated through 200 volts
and 50 volts :-

(A) 1 : 2
(B) 2 : 1
(C) 3 : 10
(D) 10 : 3

3) If wavelength of first lyman line for H-atom is 'x' then determine wavelength of limiting line of
Balmer series :-

(A)

(B) 3x

(C)

(D)

4) 1 mole of CO2 dissociate in 1 Liter container as follows :-

⇌ CO(g) +
The equilibrium constant KP is given by :-
(when α <<1) (P ⇒ Total pressure at equilibrium)

(A)

(B)

(C)

(D)

5) Two solid compounds X and Y dissociates at a certain temperature as follows

X(s) A(g) + 2B(g); = 9 × 10–3 atm3
Y(s) 2B(g) + C(g); = 4.5 × 10–3 atm3
The total pressure of gases over a mixture of X and Y is :-

(A) 4.5 atm

(B) 0.45 atm
(C) 0.6 atm
(D) None of these

6) In the reaction xA → yB,

Then, x : y is :-

(A) 5 : 3
(B) 2 : 1
(C) 5 : 2
(D) 3 : 1

0
7) What is the molarity of H2SO4 solution which is 98% by weight and the density of solution at 35 C
is 1.84 gm/cm3 :-

(A) 4.18 M
(B) 8.14 M
(C) 18.4 M
(D) 18 M

8) The normality of ‘20V’ H2O2 is :-

(A) 1.79
(B) 3.57
(C) 60.86
(D) 6.086
9) What is the molar solubility of :-
Ag2CO3 (Ksp = 4 × 10–13) in 0.1 M Na2CO3 solution?

(A) 10–6
(B) 10–7
(C) 2 × 10–6
(D) 2 × 10–7

10) The degree of hydrolysis of salt of weak acid and weak base in its 0.1M solution is found to be
50%. If the molarity of the solution is 0.5M, then the percentage degree of hydrolysis of the salt
should be :-

(A) 100%
(B) 50%
(C) 25%
(D) None of these

11) M (OH)x has a Ksp of 4 × 10–9 and its solubility is 10–3 M. The value of x is :-

(A) 4
(B) 1
(C) 3
(D) 2

12) One molal solution of a carboxylic acid in benzene shows the elevation of boiling point of 1.518
K. The degree of association for dimerization of the acid in benzene is (Kb for benzene = 2.53 K kg
mol–1) :-

(A) 60%
(B) 70%
(C) 75%
(D) 80%

13) The elimination of HX from an alkyl halide forms an alkene. The order of the elimination reaction
is :-

(A) 3º halide > 2º halides > 1º halides

(B) 1º halide > 2º halides >3º halides
(C) 1º halide = 2º halides > 3º halides
(D) 2º halide > 1º halides > 3º halides

14) Give correct order of reactivity towards electrophilic aromatic substitution :-

(A) 4 > 3 > 2 > 1
(B) 1 > 2 > 3 > 4
(C) 2 > 3 > 1 > 4
(D) 1 > 4 > 3 > 2

15) Increasing order of reactivity of the following compounds for SN1 substitution is :-

(A) (B) < (C) < (D) < (A)

(B) (A) < (B) < (D) < (C)
(C) (B) < (A) < (D) < (C
(D) (B) < (C) < (A) < (D)

16) Find out the reaction in which obtained product give positive isocyanide test :-

(A)

(B)

(C)

(D)

17) The decreasing order of basic characters of the following is :-

(A) III > I > IV > II
(B) II > I > IV > II
(C) IV > III > II > I
(D) I > II > III > IV

18) The given osazone can be obtained by :-

(A) D–glucose
(B) D–mannose
(C) D–Idose
(D) Both (A) & (B)

19) At (pH = 2) glycine exists as :-

(A)

(B)
(C) H2N—CH2—COOH
Θ
(D) H2N—CH2—COO

20) (A) (B)

Structure of (A) is :-

(A)

(B)
(C)

(D)

SECTION-II

1) Following figure shows a graph in log10K vs where K is rate constant and T is temperature. The

straight line BC has slope, tanθ = and an intercept of 5 on Y–axis. Thus Ea, the energy of

activation is (in calories) :-

2) For a 1st order reaction, find ratio of t75% to t50%, where t75% is time for 75% completion of reaction :-

3) Calculate the weight of non-volatile solute having molecular weight 40, which should be dissolved
in 57 gm octane (C8H18) to reduce its vapour pressure to 80% :-

4) 6 × 10–3 mole of K2Cr2O7 reacts completely with 9 × 10–3 mole of Xn+ to give and Cr3+. The
value of n is :-

5) One mole of P2H4 loses ten moles of electrons to form a new compound Y. Assuming that all the
phosphorous appears in the new compound, what is the oxidation state of phosphorous in Y ?

PART-3 : MATHEMATICS

SECTION-I

1) Let P(4, –4) and Q(9, 6) be two points on the parabola, y2= 4x and let X be any point on the arc
POQ of this parabola, where O is the vertex of this parabola, such that the area of ΔPXQ is maximum.
Then this maximum area (in sq. units) is

(A)
(B)

(C)

(D)

2) If the length of a transverse common tangent to two circle is 7 and that of a direct common
tangent is 11, then the product of the radii of the two circle

(A) 12
(B) 14
(C) 16
(D) 18

3) If a variable line, 3x + 4y – λ = 0 is such that the two circles x2 + y2 – 2x – 2y + 1 = 0 and x2 + y2 –

18x–2y + 78 = 0 are on its opposite sides, then the set of all values of λ is the interval

(A) [12, 21]

(B) (2, 17)
(C) (23, 31)
(D) [13, 23]

4) One of the members of the family

x(a + 2b) + y(2a – b) + a + 2b = 0 a, b ∈ R
which cuts off equal non-zero intercepts on co-ordinate axes is

(A) x – y + 1 = 0
(B) x – 2y + 1 = 0
(C) x + y + 1 = 0
(D) 2x + y + 2 = 0

5) General solution of the differential equation

is
(Where c is the constant of integration)

(A) y = f(x) + ce–x

(B) y = –f(x) + cexf(x)
(C) y = f(x) – cex
(D) y = f(x) – ce–x

6) The solution of differential equation is

(A)

(B)

(C)

(D)

7) The area (in sq. units) of the region

{(x, y) ∈ R2|4x2 ≤ y ≤ 8x + 12) is

(A)

(B)

(C)

(D)

8) The value of is

(A)

(B) ℓn 2
(C) π ℓn 2

(D)

9)

(A)

(B)

(C)

(D)

10) If curve and intersect orthogonally then the value of a is

(A)
(B)

(C) 2
(D) 3

11) Let .
If f(x) is differentiable in [0,2], then value of p is

(A)

(B)

(C)

(D)

12) Let .

The value of so that the function is continuous at is

(A)

(B)

(C)

(D)

13) Range of is

(A)
(B)
(C) {0}
(D)

14) Let ,

then value of is equal to (n ∈ I)

(A) 100
(B) 110
(C) 120
(D) 210

15)

If the quadratic equation x2 + bx + c = 0 and

x2 + cx + b = 0 (b c) have a common root.
Then equation formed by their uncommon roots is

(A) x2 + x + bc = 0
(B) x2 + x + 1 = 0
(C) x2 + 6cx + 1 = 0
(D) None of these

16) Given the relation R = {(2, 3), (3, 4)} on the set {2, 3, 4}.
The minimum number of ordered pairs to be added to R so that R is reflexive and symmetric

(A) 4
(B) 5
(C) 7
(D) 6

17)

The sum of series , is

(A)

(B)

(C)

(D)

18)

Let , then value of expression

is equal to

(A)

(B)

(C)

(D)
19) In ΔABC if , then angle A is

(A) 15°
(B) 30°
(C) 45°
(D) 60°

20) The point (0,3) is nearest to the curve x2 = 2y at

(A)

(B) (0,0)
(C) (2,2)
(D) None of these

SECTION-II

1) Length of semi latus rectum of the parabola whose focal chord is PSQ (where S is focus) such that
PS = 1 and QS = 3 is

2) A line L having positive slope passing through the point (1,1) intersects the curves 2x2 – y2 + 2x –
4y + 2 = 0 at points A and B. If the lines joining origin and the points A and B are such that the co-
ordinate axes are the angle bisector between them then the equation of line L is given by ax + by +
1 = 0, then value of (3a – b) is

3) If , then 'k' is equal to

4) If
then (a + b + c) is

5) is equals to
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D A C C B D B A D A C B C B C C C A B A

SECTION-II

Q. 21 22 23 24 25
A. 7.00 7.00 2.00 3.00 4.00

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C A B A B A C B A B D D A B B A A D B C

SECTION-II

Q. 46 47 48 49 50
A. 2.00 2.00 5.00 1.00 3.00

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A D A C B A D C B B A D D D A B B B D C

SECTION-II

Q. 71 72 73 74 75
A. 1.50 5.00 4.00 1.00 1.00
 SOLUTIONS

PART-1 : PHYSICS

1) (for black body e = 1)

R = σT4

λmT = b

2) H =

3) For latent heats,

Q = mL ⇒ Q , L
For specific heat,

slope =

4) Tension in both the rods is same = W

P.E. =

∴ Total P.E. =

5)
6) Initially capacitor behaves shorted while inductor behaves open switch.

7) i1 = 1A
For i2
Req = 8Ω

8)

9)

Clearly F = BIℓ = BI × (2b)

∴a=

10)
Let ‘x’ be equilibrium extension, F = kx

V = E(d – x)

11) Charge initially

Charge finally

for this charge arrangement to happen, 90C charge has to flow upwards.
12)

Ceq. = =C=

13)
Req = 2Ω
[All 3 resistances are in parallel]

So total current = = 12 Amp.

14) Potential difference across bulb A decreases on closing the switch

⇒ intensity decreases
Potential difference across bulb B increases on closing the switch
⇒ intensity increases

15) vA cos37° = 12
vA = 15 m/s
and vA cos 37° = vB cos 53°
⇒ vB = 20 m/s

16)

17)

18)
19)

As we know range on an incline is given be.

To maximize we have to find and equate to zero,

Putting this α in expression of R

20) For collision relative vertical initial velocity should be same.

u1 sinθ = u2

21) ΔQ = msDT = 100 × 4200 × 10 = 42 × 105

P × t = Q.
10 × 103 × t = 42 × 105
t = 420 sec
= 7 min

22) Since level of liquid in the cylinder remains same thus height remain same

γliq = 2a = 2 × 5 × 10–7 = 10 × 10–7 = 10–6

γ+β=7

23)
Phase differene = 60°

in , each turns by 30°,

 ∴ 1 particles is at mean position and other at

24)

Speed just before collision

Speed just after collision

25) g' =

= , = , h = R/4

PART-2 : CHEMISTRY

26) 3py
n = 3, ℓ = 1 m = –1 or +1

27) V1 = 200

V2 = 50
If we are concern about e– then mass and charge (e) are same

so

⇒ = = = =1:2

28)
Unknown = 3x

29) ⇌ +
t=0 1 mole 0 0

t = teq (1– α) α

∵ 1 >> α ⇒ (1–α)

KC =

30) Let x is partial pressure of A and y is partial pressure of C when both equilibrium
simultaneously established in a vessel

⇒ x = 0.1 atm;
∴ y = 0.05 atm
Total pressure of gases = PA + PB + PC
= 3(x + y)
= 0.45 atm.

31) log3 + log rA = log rB + log5

log (3 × rA) = log (5 × rB)

3rA = 5rB;
x : y = 5 : 3.

32) M = = =18.4 M

33)
34) Ag2CO3(s) 2Ag+ +
(2s) (s)
Na2CO3 → = 0.1
Ksp =
4 × 10–13 = (2s)2 × (s + 0.1)
↓
Neglected
s = 10–6

35) Degree of hydrolysis of salt of weak acid and weak base is independent from
concentration.

36) M(OH)x
AB2 then x = 2

37)

ΔTb = 1. kb . m
1.518 = 1 × 2.53 × 1
i = 0.6

∵i=1+a

0.6 = 1 + α
α = 0.8 = 80%

38)

Alkyl halide generally show E1 & E2 elimination reaction & reactivity order of E1 & E2 is 3o >
2o > 1o alkyl halide

39)

Reactivity of electrophilic aromatic substitution α +H effect.

1>2>3>4

40)

Reactivity order depends on stability of carbocation (intermediate) formed after heterolysis of

C – Cl bond.
41)

42)

43)

D-Glucose and D-Mannose are C–2 Epimers.

44)

In acidic medium, glycine exists as positively charged ion.

45) In Hoffman degradation one carbon decrease

46) Slope =
⇒ Ea = R = 2 calorie

47) For 1st order reaction

48)
Msolute = 40, W = 57 gm, Msolvent = 114
 ∵
∴ w = 5g

49) K2Cr2O7 + Xn+ —→ X5 + + Cr3+

6 × 10–3 × 6 = (5 – n) × 9 × 10–3 ⇒ n = 1

50)
in compound Y;
2x + 4 = +10
2x = +6 ⇒ [x = +3]

PART-3 : MATHEMATICS

51) y2 = 4x
2yy' = 4

Area =

52) Ans. (4)

...(1)

...(2)
(1) – (2)
4r1r2 = 121 – 49 Þ r1r2 = 18

53)
Centre of circles are opposite side of line
(3 + 4 – l) (27 + 4 – l) < 0
(λ – 7) (λ – 31) < 0
λ ∈ (7, 31)
distance from S1

⇒ λ∈(–∞, 2] ∪[(12,∞]
distance from S2

⇒ λ∈ (–∞, 21] ∪[41, ∞)

so λ∈ [12, 21]

54) a(x + 2y +1) + b(2x – y + 2) = 0

x + 2y + 1 + (2x – y + 2) = 0
L1 + λL2 = 0
∴ Family of lines passes through the point of intersection of L1 = 0 & L2 = 0

solving these, we get (–1, 0)

Now, equation of the line passing through (–1, 0) and cutting off equal non-zero intercepts on
co-ordinate axes (m = –1) is
y – 0 = –1(x + 1)
x+y+1=0

55)

If

y = –ƒ(x) + cexƒ(x)

56) 2x3 dy + 5y4 dy =6x2 y dx

5y4 dy = 6x2y dx – 2x3 dx

5y2dy = 2 d
57) 4x2 – y ≤ 0 and 8x – y + 12 ≥ 0
On solving y = 4x2
and y = 8x + 12
We get A (–1, 4) & B(3, 36)
Required area = area of the shaded region

58)
⇒ x = tan θ

⇒ I = π ln 2

59) = =

now put

60)

Two curves intersect orthogonally if

..... (i)
Now eliminating y from the given equations we have

..... (ii)
Eliminating x2 from (i) and (ii) we get

61) Continuous at x = 1
 ∴ p + q = –2 +
Differentiable at x = 1

62)

63) Domain is singletan set x =1

⇒ Range is

64) ...............(1)

................(2)
by (1) and (2)

65) x2 + bx + c = 0 ... (1)

x2 + cx + b = 0 ... (2)
(1) – (2) given x = 1 or 1 + c = –b
So uncommon roots are c and b.
require equation is x2 – (b – c) x + bc = x2 + x + bc = 0

66) R = {(2, 2), (3, 3), (2, 3), (3, 2), (3, 4), (4, 3), (4, 4)}

67)
sum
∴n→∞

68)

Expression

69) ⇒ b2 + c2 – a2 = bc

A = 60°

70)

71)

Harmonic mean of PS and OS is semi-latus rectum of parabola.

∴ length of semi latusrectum .

72) y – 1 = m(x – 1) ⇒ .....(1)

Homogenise the curve with (1)
Coeff. of xy = 0

⇒
–2(m – 1) – 4m(m – 1) – 4m = 0
–2m + 2 – 4m2 + 4m – 4m = 0
2m2 + m – 1 = 0
2m2 + 2m – m – 1 = 0
⇒ (2m – 1)(m + 1) = 0

L: ⇒ 2y – 2 = x – 1
x – 2y + 1 = 0
∴ a = 1 & b = –2
Hence 3a – b = 5

73)

74) I =

∴I=

75) Put x = 2 + h

f(0+) = = =1
Put x = 2 – h

f(0–) = = = 1.
∴ f(2) = 1 as f(x) is continuous at x = 2.