Kinetics Analysis in Chemistry Workshop II
Translated by
ScribdTranslationsKinetics Analysis in Chemistry Workshop II
Translated by
ScribdTranslationsChemistry Workshop II
Professor: Dr. Alexander Mondragón Díaz
Unit III: Kinetics (Part B)
1. The cyclobutane decomposes into ethylene. Determine the order of reaction and the
constant speed based on the following pressures that were measured
cuando la reacción se llevó a cabo a 430°C en un recipiente a volumen constante.R
/= k = 1.19 x 10-4s-1
2. The following reaction was studied in the gas phase at 290°C, observing the change of the
pressure as a function of time, in a container at constant volume:
Determine the order of the reaction and the rate constant, based on the
following data:
where P is the total pressure. R /= first-order reaction, k = 1.08 x 10-3s-1
3. The reaction A -----» products is first order in A. Initially, [A] = 0.800 M
And after 54 minutes, [A] = 0.100 M.
(a) For what time is [A] = 0.025 M?
(b) What is the reaction rate when [A] = 0.025 M?
R /= a) 90 min, b) 9.6 x 10-4M/min
4. In the first-order reaction A ----- > products, [A] = 0.816 M initially and [A]
0.632 M transcurred 16.0 min.
What is the value of the rate constant k?
(b) What is the half-life of this reaction?
(c) How much time must pass for [A] = 0.235 M
(d) What will be the value of [A] after 2.5 hours?
R /= a) 0.0160 min-1, b) 43.3 min, c) 77.8 min, d) 0.074 M
5. What is the half-life of a compound if 75% of a sample of this compound
Does it decompose in 60 min? Assume a first-order kinetics. R /= 30 min
The thermal decomposition of phosphine (PH3in phosphorus (P4molecular hydrogen
It is a first-order reaction. The half-life of the reaction is 35.0 s at 680°C.
Calcule a) la constante de velocidad de primer orden para la reacción y b) el tiempo
required for 95% of phosphine to decompose. R /= a) 0.0198 s-1151 s
6. The rate constant for the second order reaction:
it is 0.80/M · s at 10°C. a) Starting with a concentration of 0.086 M, calculate
the concentration of NOBr after 22 s. b) Calculate the half-life when [NOBr]0
= 0.072 M and when [NOBr]0= 0.054 M. R /= a) 0.034 M, b) 17 s
7. The rate constant for the second order reaction
It is 0.54/M · s at 300°C. How much time will it take (in seconds) for the
NO concentration2decrease from 0.62 M to 0.28 M? R /= 3. 6 s
8. Given the same concentrations of reactants, the reaction
at 250°C is 1.50 x 103times faster than the same reaction at 150°C. Calculate the
activation energy for this reaction. Assume that the frequency factor is
constant.R /= Ea1.35 kJ/mol
9. Some reactions are described as parallel in the sense that the reactant
Simultaneously shapes different products with different speed constants.
An example is:
The activation energies are 45.3 kJ/mol for paak.1y 69.8 kJ/mol parax2. If the
Velocity constants equal to 320 K, what temperature will it be?1/k2= 2.00?