29-10-2025

7101CJA101001250020 JM

PHYSICS

SECTION-I

1) If the work done in blowing a bubble of volume V is W, then the work done in blowing the bubble
of volume 2V from the same soap solution will be :-

(A) W/2
(B)
(C)
(D)

2) The work done in increasing the size of a rectangular soap film with dimensions 8 cm × 3.75 cm
to 10 cm × 6 cm is 2 × 10–4 J. The surface tension of the film in N/m is:

(A) 1.65 × 10–2

(B) 3.3 × 10–2
(C) 6.6 × 10–2
(D) 8.25 × 10–2

3) In a viscometer, two coaxial cylinders of length L are used. The radius of inner solid cylinder is R
and outer cylinder is 1.2R. The gap between the two cylinders is completely filled by a viscous oil.
The outer cylinder is kept stationary and the inner cylinder is being rotated with f revolutions per
second. Using external constant torque τ. Find the coefficient of viscosity of the oil:

(A)

(B)

(C)

(D)

4) A structural steel rod has a radius of 10 mm and length of 1.0 m. A 100 kN force stretches it along
its length. Young's modulus of structural steel is . The percentage strain is about
(A) 0.16 %
(B) 0.32 %
(C) 0.08 %
(D) 0.24 %

5) A frame made of metallic wire enclosing a surface area A is covered with a soap film. If the area
of the frame of metallic wire is reduced by 50%, the energy of the soap film will be changed by:

(A) 100%
(B) 75%
(C) 50%
(D) 25%

6) If 'M' is the mass of water that rises in a capillary tube of radius 'r', then mass of water which will
rise in a capillary tube of radius '2r' is :

(A) 4M
(B) M
(C) 2M

(D)

7) Pressure inside to soap bubbles are 1.01 and 1.02 atmosphere, respectively. The ratio of their
volumes is:

(A) 8 : 1
(B) 0.8 : 1
(C) 2 : 1
(D) 4 : 1

8) Two spherical soap bubbles of radii r1 and r2 in vacuum combine under isothermal conditions. The
resulting bubble has a radius equal to:

(A)

(B)

(C)

(D)

9) A small ball of mass M and density ρo is dropped in a viscous liquid of density ρ1. After some time,
the ball falls with a constant velocity. What is the viscous force on the ball ?

(A)

(B)
(C)

(D)

10) A flat plate of area 10 cm2 is separated from a large plate by a layer of glycerine 1 mm thick. If
the coefficient of viscosity of glycerine is 20 poise, the force required to keep the plate moving with
a velocity of 1 cm/sec is :-

(A) 80 dyne
(B) 200 dyne
(C) 800 dyne
(D) 2000 dyne

11) If the terminal speed of a sphere of gold (density = 19.5 kg/m3) is 0.2 m/s in a viscous liquid
(density = 1.5 kg/m3), find the terminal speed of a sphere of silver (density = 10.5 kg/m3) of the same
size in the same liquid :-

(A) 0.133 m/s

(B) 0.1 m/s
(C) 0.2 m/s
(D) 0.4 m/s

12) A 2 m long light metal rod AB is suspended from the ceiling horizontally by means of two vertical
wires of equal length, tied to its ends. One wire is of brass and has cross-section of 0.3 × 10–4 m2 and
the other is of steel with 0.1 × 10–4 m2 cross-section. In order to have equal stresses in the two wires,
a weight is hung from the rod. The position of the weight along the rod from end A should be :

(A) 66.6 cm
(B) 133 cm
(C) 50 cm
(D) 155.6 cm

13) Two wires of same length and radius are joined end to end and loaded. The Young's modulii of
the materials of the two wires are . The combination behaves as a single wire then its
Young's modulus is:

(A)
(B)

(C)

(D)

14) The only elastic modulus that applies to fluids is :

(A) Young’s modulus

(B) Shear modulus
(C) Modulus of rigidity
(D) Bulk Modulus

15) A cube of aluminium of sides 0.1 m is subjected to a shearing force of 100 N. The top face of the
cube is displaced through 0.02 cm with respect to the bottom face. The shearing strain would be :

(A) 0.02
(B) 0.1
(C) 0.005
(D) 0.002

16) A ball of radius r and density ρ falls freely under gravity through a distance h before entering
water. Velocity of ball does not change even on entering water. If viscosity of water is η, the value of

h is given by

(A)

(B)

(C)

(D)

17) A metal block of mass m is suspended from a rigid support through a metal wire of diameter 14
mm. The tensile stress developed in the wire under equilibrium state is Nm-2. The value of
mass m is ______ kg.
(Take, g = 9.8 ms-2 and

(A) 5kg
(B) 11 kg
(C) 22 kg
(D) 12 kg

18) An air bubble of volume 1cm3 rises from the bottom of a lake 40m deep to the surface at a
temperature of 12oC. The atmospheric pressure is Pa, the density of water is 1000 kg/m3 and
g = 10 m/s2. There is no difference of the temperature of water at the depth of 40m and on the
surface. The volume of air bubble when it reaches the surface will be

(A) 5 cm3
(B) 2 cm3
(C) 4 cm3
(D) 3 cm3

19) The force required to stretch a wire of cross-section 1 cm2 to double its length will be (Given
Young's modulus of the wire = )

(A)
(B)
(C)
(D)

20) Water rises in a capillary upto a height h. If now this this capillary is tilted by an angle of 45o,
then the length of the water column in the capillary becomes:-

(A) 2h

(B)

(C)

(D)

SECTION-II

1) A particle performing linear SHM with time period T is at x = moving towards positive

extreme. The time after which it will first come to rest is . Find N.

2) A cubical block (of side 2m) of mass 20 kg slides on inclined plane lubricated with the cell of
viscosity η = 10-1 poise with constant velocity of 10 m/s. Find out the thickness of layer of liquid in
mm. (g = 10 m/s2)

3) A particle performs SHM such that at t = 0, x = 0. The time taken by it to go from x = A/2 to A is

t1 and the time taken to go from x = 0 to A/2 is t2. Find the value of .

4) A square plate of 1m side moves parallel to a second plate with velocity 4 m/s. A thin layer of
water exist between plates. If the viscous force is 2 N and the coefficient of viscosity is 0.01 poise
then find the distance between the plates in mm.

5) A drop of liquid of radius R = 10–2 m having surface tension divides itself into
K identical drops. In this process the total change in the surface energy ΔU = 10–3 J. If K = 10α
then the value of α is (approximately)
[Hint: log (1030301) = 6.01]

CHEMISTRY

SECTION-I

1) A system has internal energy equal to E1, 450 J of heat is taken out of it and 600 J of work is done
on it. The final energy of the system will be -

(A) (E1 + 150)

(B) (E1 + 1050)
(C) (E1 – 150)
(D) None of these

2)

The following two reactions are known :

Fe2O3(s) + 3CO(g) → 2Fe(s) + 3CO2(g) ;
ΔH = –26.8 kJ
FeO(s) + CO(g) → Fe(s) + CO2(g) ;
ΔH = –16.5 kJ
Then enthalpy of following reaction is ?
Fe2O3(s) + CO(g) → 2FeO(s) + CO2(g)

(A) –43.3 kJ
(B) –10.3 kJ
(C) + 6.2 kJ
(D) + 10.3 kJ

3)

For the reaction

Ag2O(s) → 2Ag(s) + ½ O2(g), which one of the following is true :

(A) ΔH = ΔE
(B) ΔH = ½ ΔE
(C) ΔH < ΔE
(D) ΔH > ΔE

4) For isothermal expansion of an ideal gas into vacuum, among the following how many are zero
ΔU, ΔH, ΔT, q, pext , ΔSsystem , ΔSuniverse

(A) 7
(B) 4
(C) 5
(D) 6

5) The gas expands adiabatically such that:- T ∝ .

The value of γ, i.e. (Cp/Cv) of the gas will be:

(A) 1.30
(B) 1.50
(C) 1.70
(D) 2

6) Consider the reversible isothermal expansion of an ideal gas in a closed system at two different
temperatures T1 and T2 (T1 < T2). The correct graphical depiction of the dependence of work done
(w) on the final volume (V) is:

(A)

(B)
(C)

(D)

7) An ideal gas is taken around the cycle ABCA as shown in P-V diagram. The net work done by the

gas during the cycle is equal to :

(A) –6P1V1
(B) 6P1V1
(C) 5P1V1
(D) –5P1V1

8) At 27 °C latent heat of fusion of a compound is 2930 J/mol. Entropy change is -

(A) 9.77 J/mol –K

(B) 10.77 J/mol –K
(C) 9.07 J/mol –K
(D) 0.977 J/mol –K

9) One mole of an ideal gas is expanded isothermally and reversibly to half its initial pressure. ΔS for
the process in JK–1mol–1 is : [ln 2 = .693 and R = 8.314 J/mol.K]

(A) 10.76
(B) 6.76
(C) 8.03
(D) 5.76

10) The reversible expansion of an ideal gas under adiabatic and isothermal conditions is shown in
the figure. Which of the following statement is incorrect ?
(A)
(B)
(C)
(D)

11) Which of the following reaction has positive entropy change ?

(A) N2(g) + 3H2(g) → 2NH3(g)

(B) H2O(s) → H2O(l)
(C) Cgraphite → Cdiamond
(D) CO2(g) + H2O(l) → H2CO3(aq)

12) Consider two moles of an ideal monoatomic gas initially at 27°C and 1 atm pressure, undergoing
the following reversible cycle:

a Isothermal compression to 2 atm

b Isobaric temperature increases to 127°C

c Return to the initial by a different path. Calculate ΔS for each stage.

(A) +11.52 J/K, –11.96 J/K, +0.44 J/K
(B) –11.52 J/K, +11.96 J/K, –0.44 J/K
(C) –16.23 J/K, +15.64 J/K, –1.02 J/K
(D) +16.23 J/K, –15.64 J/K, +1.02 J/K

13) What can be concluded about the values of ΔH and ΔS from this graph?

(A) ΔH > 0, ΔS > 0

(B) ΔH > 0, ΔS < 0
(C) ΔH < 0, ΔS > 0
(D) ΔH < 0, ΔS < 0

14) Two blocks of the same metal having same mass and at temperature T1 and T2, respectively are
brought in contact with each other and allowed to attain thermal equilibrium at constant pressure.
The change in entropy, for this process is:

(A)

(B)

(C)

(D)

15)

Using the data provided, calculate the multiple bond energy (kJ mol–1) of a bond in C2H2. That
energy is (Take the bond energy of a C–H bond as 350 kJ mol–1)
;
;
;

(A) 1165
(B) 837
(C) 865
(D) 815

16) Two moles of an ideal gas is expanded irreversibly and isothermally at 37oC until its volume is

doubled and 3.41 kJ heat is absorbed from surrounding. (system + surrounding) is :

(A) -0.52 J/K

(B) 0.52 J/K
(C) 22.52 J/K
(D) 0

17) Determine enthalpy of formation for H2O2(l), using listed enthalpies of reaction :
N2H4(l) +2H2O2(l) → N2(g) + 4H2O(l) ;
ΔrH1° = –818 kJ/mol
N2H4(l) + O2(g) → N2(g) + 2H2O(l) ;
ΔrH2° = –622 kJ/mol

H2(g) + O2(g) → H2O(l) ;

ΔrH3° = –285 kJ/mol

(A) –383 kJ/mol

(B) –187 kJ/mol
(C) –498 kJ/mol
(D) None of these

18)

Consider the reaction at 300 K

C6H6(ℓ) + , kJ
What is ΔU for the combustion of 1.5 mole of benzene at 27ºC ?

(A) –326.25 kJ
(B) –4900.25 kJ
(C) –4906.5 kJ
(D) –3274.75 kJ

19) One gram sample of NH4NO3 is decomposed in a bomb calorimeter. The temperature of the
calorimeter increase by 6.12 K. The heat capacity of the system is 1.23 kJ/g/K. What is the molar
heat of decomposition for NH4NO3

(A) 7.53 kJ/mol

(B) 398.1 kJ/mol
(C) 16.1 kJ/mol
(D) 602 kJ/mol

20) How many of the following are correctly matched ?

(I) ;

(II)
(III)
(IV)

(A) 1
(B) 2
(C) 3
(D) 4

SECTION-II

1) The integral enthalpies of solution of anhydrous CuSO4(s) and hydrated CuSO4 . 5H2O(s) are –70
kJ and 10 kJ per mol respectively. Determine the magnitude of enthalpy of hydration (kJ) of 0.1 mole
anhydrous CuSO4(s)
2) If 1.0 kcal of heat is added to 1.2 L of O2 in a cylinder at constant pressure of 1 atm, the volume
increases to 1.5 L. Calculate ΔU (internal energy) of the process in kJ. (Nearest Integer)

3) Find magnitude of difference in standard Gibb's energy of formation of H2O(g) & H2O(l) at 300K in
kJ/mol if Vapour pressure of H2O at 300 K is 30 torr. [Use : 1 bar = 75 cm Hg]
[Give your answer as nearest integer]

4) In a cyclic process ABCA consist of three processes. if qAB = –20J; qBC = –40J; qCA = –30J & WAB =
80J; WBc = 40Jthen find work done by system in process CA. (only magnitude)
Fill your answer as sum of digits (excluding decimal places) till you get the single digit answer

5) How many changes at constant pressure is work done by the surrounding on system ?

Initial state Final state

(i) H2O (g) ——→ H2O(l)
(ii) H2O (s) ——→ H2O(g)
(iii) H2O (l) ——→ H2O(s)
(iv) 3H2 (g) + N2(g) ——→ 2NH3(g)
(v) CaCO3 (s) ——→ CaO (s) + CO2(g)
(vi) 2O3 (g) ——→ 3O2(g)
(vii) N2O4 (g) ——→ 2NO2(g)
(viii) A(g) + B(g) ——→ C(g)
(ix) 2C6H6(l) + 15O2 (g) ——→ 12CO2 (g) + 6H2O(l)
(x) CH4(g) + 2Cl2(g) ——→ CCl4(l) + 2H2(g)

MATHS

SECTION-I

1) The equation of the line cutting of an intercept –3 from the y-axis and inclined at an angle tan–1
to the x-axis is -

(A) 5y – 3x + 15 = 0
(B) 5y – 3x = 15
(C) 3y – 5x + 15 = 0
(D) none of these

2) If ax + y - 16 = 0 and x + ay - 6 = 0 represent two adjacent sides of a rhombus whose diagonals

intersect at (3, 5) then sum of possible value of a is :

(A) 4
(B) 2
(C) -2

(D)

3) The equations of the lines on which the perpendiculars from the origin make 30° angle with x-axis

and which form a triangle of area with axes, are

(A)
(B)
(C)
(D) None of these

4) Two mutually perpendicular straight lines through the origin from an isosceles triangle with the
line
2x + y = 5 . Then the area of the triangle is -

(A) 5
(B) 3

(C)

(D) 1

5) (sinθ, cosθ) and (3, 2) lies on the same side of the line x + y = 1, then θ lies between

(A) (0, π/2)

(B) (0, π)
(C) (π/4, π/2)
(D) (0, π/4)

6) If the lines and are concurrent, then a, b, c are in

(A) A. P.
(B) G. P.
(C) H. P.
(D) None of these

7) For all real values of a and b lines (2a + b)x + (a + 3b)y + (b – 3a) = 0 and mx + 2y + 6 = 0 are
concurrent, then m is equal to :-

(A) –2
(B) –3
(C) –4
(D) –5

8) Find the equation of the bisector of the obtuse angle between the lines x – 2y + 4 = 0and 4x –3y +
2 = 0.
(A)
(B)
(C)
(D) None of these

9) Let and be three points. Then the equation of the bisector of

the angle PQR is

(A)

(B)

(C)

(D)

10) If the sum of slopes of the pair of lines represented by is equal to

the product of the slopes, then the value of h is

(A) –6
(B) –2
(C) –4
(D) 4

11) will represent a pair of straight lines, when λ =

(A) 2
(B) 4
(C) 6
(D) 8

12) The lines joining the origin to the points of intersection of the line 3x – 2y = 1 and the curve
, are

(A) Parallel to each other

(B) Perpendicular to each other
(C) Inclined at 45º to each other
(D) None of these

13) Distance between the lines represented by the equation is

(A) 5/2
(B) 5/4
(C) 5
(D) 0

14) A triangle formed by 3 lines denoted by the equation will always be

(A) acute angled

(B) obutse angled
(C) right angled
(D) none of these

15) Let A be the set of all points (α ,β) such that the area of triangle formed by the points (5, 6), (3,
2) and (α ,β) is 12 square units. Then the least possible length of a line segment joining the origin to
a point in A, is :

(A)

(B)

(C)

(D)

16) If the orthocentre of the triangle, whose vertices are (1, 2), (2, 3) and (3, 1) is (α, β), then the
quadratic equation whose roots are α + 4β and 4α + β, is

(A) x2 – 19x + 90 = 0
(B) x2 – 18x + 80 = 0
(C) x2 – 22x + 120 = 0
(D) x2 – 20x + 99 = 0

17) In an isosceles triangle ABC, the vertex A is (6, 1) and the equation of the base BC is 2x + y = 4.
Let the point B lie on the line x + 3y = 7. If (α, β) is the centroid , then is equal to :

(A) 39
(B) 41
(C) 51
(D) 63

18) If the point lies on the curve traced by the mid-points of the line segments of the lines

x cos θ + y sin θ = 7, θ between the co-ordinates axes, then α is equal to

(A) 7
(B) –7
(C)
(D)

19) A straight line through a fixed point (2, 3) intersects the coordinate axes at distinct points P and
Q. If O is the origin and the rectangle OPRQ is completed, then the locus of R is :

(A) 2x + 3y = xy
(B) 3x + 2y = xy
(C) 3x + 2y = 6xy
(D) 3x + 2y = 6

20) Slope of a line passing through P(2, 3) and intersecting the line, x + y = 7 at a distance of 4 units
from P, is

(A)

(B)

(C)

(D)

SECTION-II

1)

The line through the points (h, 3) and (4, 1) intersects the line 7x – 9y – 19 = 0 at right angle, then

the value of is

2) The vertex A of ΔABC is (3, –2) and the equations to two of its medians are 5x + 3y = 11 and 4x +
3y = 8. If the equation of side BC is ax + by = 7, then (a + b) is equal to

3) Number of straight lines passing through the fixed point (3, 2) & cutting positive integral
intercepts on coordinate axes is

4) If the triangle is formed by the lines given by 3x – 2y + 6 = 0, x + y = 8 and x – 2y – 2 = 0, then

how many circles can be drawn touching all the three sides of the triangle formed.

5) The line 3x + 2y = 24 meets the y-axis at A & the x-axis at B. The perpendicular bisector of AB
meets the line through (0,–1) parallel to x-axis at C. If the area of triangle (ABC) is ab where a & b
are digits of number, find a – b
 ANSWER KEYS

PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. D B C A C C A C A D B C B D D C B A C D

SECTION-II

Q. 21 22 23 24 25
A. 6 4 2 2 6

CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. A C D C B B D A D B B B A C D B B B D B

SECTION-II

Q. 46 47 48 49 50
A. 8 4 8 3 5

MATHS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A D B A A A A A C B D B A D C D C A B C

SECTION-II

Q. 71 72 73 74 75
A. 1 5 4 4 8
 SOLUTIONS

PHYSICS

1)

Work done to from a soap bubble

W = 8πR2T [As V ∝ R2 ∴ R ∝ V1/3]
2/3
∴ W∝V

= (2)2/3 ⇒ W2 = (4)1/3 W

2) Change in surface energy = 2 × 10–4 J

ΔA = 10 × 6 – 8 × 3.75 = 30 cm2
= 30 × 10–4 m2
Work done W = T × 2 × (Change in area)
Now, Change in surface energy = Work done
2 × 10–4 = T × 2 × 30 × 10–4
∴ T = 3.3 × 10–2 N/m

3)

4) r = 10 mm = 10 × 10-3 = 10-2 m.
= 1m
F = 100 kN = 100 × 103 = 105N

y = 2 × 10''

strain =

strain = = 0.159 × 10-2

5) Let initial surface area = A

then final surface area =

% change =

= = –50%

6) Height of liquid rise in capillary tube h =

⇒ h∝
when radius becomes double height become half

∴ h' =
Now, M = πr2h × ρ
and M' = π (2r)2 (h/2) × ρ = 2M
Option (3)

7)

Ans. (d)

8)

No. of moles is conserved

n1 + n2 = n3
P1V1 + P2V2 = P3V3

9)
For constant velocity Fnet = 0
Fvis + ρ0vg = ρvg
Fvis = (ρ – ρ0) vg

10)

= 2000 dyne

11)

12)
so Fbrass = 3 Fsteel
so Fbrass x = Fsteel (2 – x)
⇒ x = 0.5 m

13)

14) due to shear stress, its escape will change.

Due to longitudinal stress, its size will also change.
15)

Shear strain
= 0.002

16)

17)
⇒ m = 11kg

18) Ans. 5cm3

19)

20)

21) Let the particle is at P position particle first comes to rest when it reaches right extreme

position then by phasor diagram angle moved by particle is

Time taken

hence
 22)

⇒
⇒

23) Question Explanation: Finding the ratio of times taken for a particle to travel specific
distances in SHM.
Concept: Time in SHM.
Solution: The time taken for a particle to travel a certain distance from the mean position is a
specific fraction of the total time period. We can use the SHM equation for displacement to
find this ratio.
Calculation:

Final Answer: The ratio is 2.

24)

25)

K= 1030301

CHEMISTRY

26)

Solution/Explanation:
Internal energy heat and work are given and final energy is asked.
Given Data:
Heat (q) = – 450 J
Work (w) = 600 J
Concept:
ΔE = q + w
E2 – E1 = q + w
E2 = q + w + E 1
Calculation:
E2 = – 450 + 600 + E1
E2 = E1 + 150
Final Answer :- E2 = E1 + 150

27) Question Explanation

Find the enthalpy change (ΔH) for the reaction:

using the given reactions and Hess's Law.

Concept
Hess's Law: ΔH of a reaction = Sum of ΔH of steps leading to it.
Explanation

Final Answer (3)

28)

Question Explanation
The given reaction is the decomposition of silver oxide:

We are asked to compare the enthalpy change for this

reaction.

Concept

, where Δn = change in moles of gas, R = gas constant, T = temperature.

Solution:
In the reaction:
Ag2O (s) → 2Ag(s) + 1/2 O2(g)
Change in gaseous moles:
Δn = 0.5 – 0 = + 0.5
Since gas is produced (Δn > 0).
ΔH = ΔE + positive value ⇒ ΔH > ΔE

Hence,
Correct option: (4) ΔH > ΔE

29) ΔSsys > 0

ΔSsur > 0
ΔSuni > 0

30) T ∝
TV1/2 = constant
For adiabatic process, TV1/2 = TVγ – 1 = constant

∴γ–1=

31) For reversible isothermal expansion,

w = –nRTln

⇒ |w| = –nRTln
|w| = nRT(lnV2 – lnV1)
|w| = nRT ln V2 – nRT V1
y = mx + c
So, slope of curve 2 is more than curve 1 and intercept of curve 2 is more negative than curve
1.

32) Work done by the gas in the cyclic process = Area bounded (ABCA) = 5P1V1

33) Explanation:
Find (ΔS)f

Given Data:
ΔHfusion = 2930 J/mol, T = 27°C

Concept:
T = 273 + 27 = 300 K

Find Answer: 9.77 J/mol-K

Hence, option (1) is correct.
34) ΔS = 2.303 nR log

35)

Adiabatic expansion

36) Ssolid < Sliquid

ΔS = +ve

37) (a) For isothermal process, = –11.52 J/K

(b) For isobaric process, = +11.96

J/K
(c) For a cyclic process,
= –{(–11.52) + 11.96} = –0.44 J/K

38) Conceptual

39)

Both boxes are identical,

So Cp will be same

40)
41)

42) (b) For

H2(g) + O2(g) → H2O2(l)

ΔfH°(H2O2, l) =

43)

ΔH = ΔU + ΔngRT

–3271 = ΔU +
ΔU = –3267.25 KJ/mol
for 1 mole of bezene
ΔU for 1.5 mol of benzene
= – 3267.25 × 1.5
= – 4900.25 KJ

44) S = 1.23 kJ/gm/K

C = MS = 80 × 1.23 kJ/mole K.
ΔE = nC ΔT
= 1 × 80 × 1.23 × 6.12
⇒ 602 kJ/mole

45)

(I) Bond enthalpy is defined in gaseous state.

(II) It is combustion of 2 mole.

46) Δhyd H = Δsol H (CuSO4 (S)) – Δsol H(CuSO4⋅5H2O(S))

 47)
= 4.15

48)

H2O(l) ⇌ H2O(g)
ΔrG° =
= – RTlnK

= –RTln = –2.303 ×
= +8 kJ (nearest integer)

49) ∆U = 0
Wtotal = – qtotal
80 + 40 + WCA = –(–20 – 40 – 30)
WCA = – 30 J

50) (i), (iv), (viii), (ix), (x)

At constant pressure, w = –PΔV (work on system w = +ve, ΔV = –ve)

MATHS

51)

m= , c = –3

y = x–3
5y = 3x–15
52)

53)

α = 30º
ncos30º + ysin30º = p
x + y = 2p

+ =1

Δ=

⇒
p2 = 25
p = ±5

54)

= P2

=
=5

55) Explaining the Question :- We are given a line and two points. We need to find the range
of q so that both the points lie on same side of given line.
Concept:-Point and lineTwo points (x, y) and (x2, y2) lie on the same side of the line ax + by +
c + 0 if and only if (ax1 + by1 + c) (ax2 + by2 + c) > 0
Solution :-

For point A and B lie on the same side of Line

L:x+y–1=0
(3 + 2 – 1) (sin q + cos q – 1) > 0
Let P =

⇒
Final Answer :- Option 1

56)
–a–2(b–c) + (4b–3c) = 0
–a–c+2b = 0
2b = a+c
a, b, c are in A.P

57)

a(2x+y–3)+b(x+3y+1) = 0

x = 2 , y = –1
is anualy of line pases through (2,–1)
⇒ mx+2y+6 = 0
m(2)+2(–1)+6 = 0
2m = –4
m = –2

58) Explaining the Question :- We need to find the obtuse angle bisector between given
lines.

Concept:- Based on angle bisector.

Solution :- Let L1 : x – 2y + 4 = 0 Here c1 = 4 > 0

 L2 : 4x – 3y + 2 = 0 Here c2 = 2 > 0The constant terms are already
positive.
a1a2 + b1b2 = 1 ×4 + (–2) × (–3) = 10 > 0
So +ve sign in the bisector formula will give the equation of the obtuse angle bisector.

⇒
⇒

Final Answer :- Option (1)

59) Explaining the Question :- We need to find the equation of the line that bisects the angle
formed at vertex Q by the line segment QP and QR
Concept:-Angle bisector
* Let L1 : y = m1x and L2 : m2x then the angle bisector of L1 and L2 are given by the
formulla.

Solution :-

Equation of line QP

....(1)

equation of line QR y – 0 = ....(2)

* Angle bisector equations are given by

+ve –ve
Final Answer :- Option 3

60) Explanation Question: We are given a pair of straight lines passing through origin and it
is given the sum and product of slope are equal then we need to find the value of 'h'
Concept: This question is based on pair of straight lines passing
Through origin :
ax2 + 2hxy + by2 = 0

sum of slopes m1 + m2 =

product of slopes m1m2 =

Solution: Let the given pair of straight lines 4x2 + 2hxy – 7y2 = 0

Given, m1 + m2 = m1m2

-2h = 4
h = –2
Final Answer: (2)

61)

a = 2, b = 3, c = λ

g = 4, f= , h =
abc + 2fgh-af2-bg2-ch2 = 0

2(3)λ + 2(7) (4) - 2(7)2

-3(4)2-λ =0
24λ + 784-392-192-49λ = 0
–25λ + 200 = 0
λ=8

62)

3x – 2y = 1
3x2 + 5xy–3y2 + 2x(3x–2y)+3y(3x–2y) = 0
⇒ ax2 + 10xy – 9y2 = 0
coff of x2 + coff of y2 = 0
⇒ times are Lr to each other
63)
x2+2 xy + 3y2
= (x+ y)2
⇒ x2 + 2 xy + 3y2–3x–3 y–4
= (x+ y+c1) (x+ y+c2)
⇒ c1 + c2 = –3, c1c2 = –4

Distance =

64) All lines passes through origin

Hence No Δ will be formed.

65)

4α – 2β – 8 = ±24
positive sign
4α – 2β – 8 = 24
4α – 2β = 32
2α – β = 16
Take point (α , 2α–b)
Distance of point from origin

10α–64 = 0
10α = 64

Point

β= – 16
=

=
Distance from

= negative sign
4α – 2β – 8 = 24
4α – 2β – 8 + 24 = 0
4α – 2β + 16 = 0
2α – β + 8 = 0
Distance of point from origin

10α + 32 = 0

β = (2α + 8)

Point
Minimum Distance

from origin =

66)
MBH × MAC = –1

β–3 = 3α–4
β = 2α–1 ....... (1)
MAH × MBC = –1
2β–4 = α–1
2β–α–3 = 0 ....... (2)
solve (1) and (2)

α= β=
α + 4β = 11
β + 4α = 9
x2 – 20x + 99 = 0

67)

Point B(1, 2)
Now let C be (h, 4–2h)
(As C lies on 2x + y = 4)
is isosceles with base BC

or h = 1

Thus

Centroid

68)
x - intercept

y - intercept

Locus of mid

⇒ ⇒

69)

Explaining the Question :-

In this question we have given a straight line passing through fixed point (2, 3) and intersects
coordinate axes at P and Q and a rectangle form using OPRQ then find the locus of R.
Concept:-
(i) Locus problem
(ii) Equation of line
Solution :-

Equation of PQ

passes through (2, 3)

So
So locus

Final Answer :- Option 2

70)

Let slope of line is tanθ

Parametric coordinates of point on the line which is 4 unit distance from (2,3) is (4cosθ+2,
4sinθ+3) which lies on x+y = 7
4cosθ+2, 4sinθ+3 = 7

sinθ + cosθ =

sinθ = =
2
3tan θ + 8tanθ + 3 = 0

71)

Slope of line through (h,3) and (4,1)

is

slope of 7x – 9y – 19 = 0 is

14 = 36 – 9h

9h = 22 ∴

72)
Point F lies on median CF

∴
and point E lies on median BE

∴ B = (1,2) and C = (5,–4)

∴ equation of BC is 3x+ 2y = 7

73) ⇒ =1–

⇒ b=
a = 4, b = 8 & a = 2 but b = –4
a = 5, b = 5 a = 1 but b = –1
a = 6, b = 4 a = 0 but b = 0 a = 9, b = 3

74)

Ans. (4)

75)
Coordinates of points A & B
At A : x = 0
2y = 24
y = 12 ⇒ A(0, 12)
At B : y = 0
3x = 24
x = 8 ⇒ B(8, 0)
Middle point of AB : (4, 6)

Slope of line AB = , So slope of line ⊥rl to AB =

Equation of ⊥rl bisector of Ab ⇒ :

(y – 6) = …(1)

Equation of line parallel to x-axis and passing through (0, –1) is

y = –1 intersection of line y = –1 and perpendicular bisector of AB:
Put y = –1 in equation …(1)

–1 – 6 =
x=

Point C ≡

So, Ar ΔABC =

=
= 3 × 29 + 4 = 91
∵ ab ≡ 91
∴ a–b=9–1=8