Solutions (PYQs)

Q. 1 Excess of NaOH(aq) was added to 100 ml of FeCl3(aq) resulting in 2.14 g of Fe(OH)3. The
molarity of FeCl3(aq) is :
(Given molar mass of Fe=56 g mol−1 and molar mass of Cl=35.5 g mol−1)

Option 1:
0.2 M

Option 2:
0.3 M

Option 3:
0.6 M

Option 4:
1.8 M

Correct Answer:
0.2 M

Solution:
Given,

molar mass of Fe=56 g mol−1 and molar mass of Cl=35.5 g mol−1

The chemical equation for the reaction is as follows:

3NaOH(aq) + FeCl3(aq) —> 3NaCl(aq) + F(OH)3(aq)

Therefore, the mole ratio of FeCl3 and Fe(OH)3 is 1 : 1

Now moles of Fe(OH)3 is given by:

Moles = Given mass / Molar mass

Molar mass of Fe(OH)3 = 56 + 48 +3 = 107 grams / moles

2.14 g / (107g / mole) = 0.02 moles.

Therefore, the moles for FeCl3 are also 0.02 moles

Now, Molarity = moles per volume(L)

The molarity of FeCl3 is thus : (0.02 / 100) x 1000

Therefore, the molarity of FeCl3 = 0.2M

Hence, the answer is an option (1).

 Q. 2 The freezing point of benzene decreases by 0.450C when 0.2 g of acetic acid is added to 20 g
of benzene. If acetic acid associates to form a dimer in benzene, the percentage association
of acetic acid in benzene will be :

(Kf for benzene = 5.12 K kg mol−1)

Option 1:
74.6%

Option 2:
94.6%

Option 3:
64.6%

Option 4:
80.4%

Correct Answer:
94.6%

Solution:
Given,

Kf for benzene = 5.12 K kg mol−1

In benzene,

t=0 1 -

t=t 1-

where ß is the degree of association.

Given:

w = 0.2g W = 20 g T = 0.45 K

As we know,

Therefore, observed M = 113.78 (acetic acid)

The molecular weight of acetic acid = 60

The van't hoff factor is given as,

% degree of association = 94.5 %

Hence, the answer is an option (2).

Q. 3 Two 5 molal solutions are prepared by dissolving a non-electrolyte non-volatile solute

separately in the solvents X and Y. The molecular weights of the solvents are MX and MY ,
respectively where
. The relative lowering of vapour pressure of the solution in X is “m” times that
of the solution in Y. Given that the number of moles of solute is very small in comparison to
that of solvent, the value of “m” is :

Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:
As we learnt in

Expression of relative lowering of vapour pressure -

wherein,

Hence, the answer is an option (2).

Q. 4 The mass of a non-volatile, non-electrolyte solute (molar mass=50 g ) needed to be

dissolved in 114 g octane to reduce its vapour pressure to 75%, is :

Option 1:
37.5 g

Option 2:
75 g

Option 3:
150 g

Option 4:
12.5 g

Correct Answer:
12.5 g

Solution:
As we learnt in

Expression of relative lowering of vapour pressure -

(100-75)/100 = (W2*114)/(50*114)

w2 = 12.5

Hence, the answer is an option (4).

Q. 5 18 g glucose (C6H12O6) is added to 178.2 g water. The vapor pressure of water (in torr) for
this aqueous solution is :

Option 1:
7.6

Option 2:
76.0

Option 3:
752.4

Option 4:
759.0

Correct Answer:
752.4

Solution:
Moles of Glucose

Moles of Water

Mole fraction of Glucose

From Raoult's law,

ps = 752.4 tour

Hence, the answer is the option (3).

Q. 6 For 1 molal aqueous solution of the following compounds, which one will show the highest
freezing point ?

Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:
The complex which will provide the minimum number of ions will show the highest freezing point.

So the complex will be

Hence, the answer is an option (1).

Q. 7 The solubility of N2 in water at 300 K and 500 torr partial pressure is 0.01 g L−1. The solubility
(in g L−1) at 750 torr partial pressure is :

Option 1:
0.0075

Option 2:
0.015
 Option 3:
0.02

Option 4:
0.005

Correct Answer:
0.015
Solution:

Hence, the answer is an option (2).

Q. 8 At room temperature, a dilute solution of urea is prepared by dissolving 0.60g of urea in 360
g of water. If the vapour pressure of pure water at this temperature is 35 mmHg, lowering of
vapour pressure(in mmHg) will be:

(molar mass of urea = 60g/mol)

Correct Answer:
0.017

Solution:
Molecular weight of urea = 60 g / mol

Now, we know that :

Relative lowering of vapour pressure is equal to the molar mass of the solute.

Hence, the answer is (0.0174 mmHg).

Q. 9 of a non-volatile non-electrolyte solute is dissolved in of two different solvents

and whose ebullioscopic constants are in the ratio of . The ratio of the elevation in
their boiling points, is:
 Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:

given
----------------(1)
----------------(2)
On dividing equation(1) by (2), we get:

Hence, the answer is the option (3).

Q. 10 Molal depression constant for a solvent is . The depression in the freezing

point (in K) of the solvent for solution of K2SO4 is :

( Assume complete dissociation of the electrolyte )

Correct Answer:
0.36

Solution:
We know the Mathematical Expression of Depression in Freezing point -

The solute undergoes complete dissociation

 1 0 0

0 2 1

So,

Hence, the answer is (0.36K).

Q. 11 gas is bubbled through water during a soft drink manufacturing process at

exerts a partial pressure of bar then would
dissolve in of water. The value of is__________. (Nearest integer)

(Henry's law constant for at 298 K is bar )

Correct Answer:
25

Solution:

Thus, the mole fraction of dissolved

Hence, the answer is (25).

 Q. 12 A solution is prepared by dissolving 0.6 g of urea (molar mass = 60g ) and 1.8 g of
glucose (molar mass = 180 g ) in 100 mL of water at . The osmotic pressure of
the solution is (in atm):

(R = 0.08206 L atm

(Response should be up to only two decimal digits like 78.76 or 0.78).

Correct Answer:
4.92

Solution:
Osmotic Pressure -

Osmotic Pressure ( ) is excess pressure developed on the solution side due to osmosis.

no. of moles of Urea

Given Water = 100ml

no. of moles of glucose =

Total moles =

Osmotic pressure =

Hence, the answer is the option (1).

Q. 13 Two open beakers one containing a solvent and the other containing a mixture of that
solvent with non volatile solute are together sealed in a container. Over time:

Option 1:
the volume of the solution and the solvent does not change

Option 2:
the volume of the solution increases and the volume of the solvent decreases
 Option 3:
the volume of the solution decreases and the volume of the solvent increases

Option 4:
the volume of the solution does not change and the volume of the solvent decreases.

Correct Answer:
the volume of the solution increases and the volume of the solvent decreases
Solution:
There will be a lowering in vapor pressure in the solution due to which the transfer of solvent molecules
will take place from the beaker containing pure solvent to that containing the solution.

Hence, the answer is the option(2).

Q. 14 At 35oC, the vapour pressure of CS2 is 512mm Hg and that of acetone is 344mm Hg. A
solution of CS2 in acetone has a total vapour pressure of 600mm Hg. The false statement
among the following is:

Option 1:
Heat must be absorbed in order to produce the solution at 35o C

Option 2:
a mixture of 100 mL CS2 and 100 mL acetone has a volume <200 mL

Option 3:
CS2 and acetone are less attracted to each other than to themselves

Option 4:
Raoult's law is not obeyed by this system

Correct Answer:
a mixture of 100 mL CS2 and 100 mL acetone has a volume <200 mL

Solution:
We have:

Pobserved = 600Hg

We know:

Pcalc = PoAxA + PoBxB

= 512x + 344 - 344x
= 168x + 344
= 512 ( if x =1 for maximum value)

Thus, Pcalc < Pobserved

Thus, the process deviated from Raoult's law, showing a positive deviation from Raoult's law.

, i.e., heat absorbed.

This means the solution will show +ve deviation Hence

Vs > VA + VB

200 < 100 + 100

Hence, the answer is the option(2).

Q. 15 Of the following four aqueous solutions,total number of those solutions whose freezing
point is lower than that of is __________ (Integer answer)

Correct Answer:
4

Solution:

So, the greater the value of i, the greater will be the depression in the freezing point, and the lower the
value of the freezing point.

Thus, all given compounds have a greater value of van't Hoff factor than

Hence, the answer is (4).

Q. 16 An aqueous KCl solution of density has a molality of .

The molarity of the solution in is _______.(Nearest integer)

[Molar mass of KCl = 74.5]

Correct Answer:
3

Solution:
Given,
Let, 1kg of solvent be taken.

And,

Hence, the answer is (3).

Q. 17 of glucose (Molar mass ) is mixed with of water. The freezing point of

solution is ______________ . (Nearest integer)

[Given : ; Density of water ; Freezing point of water

]

Correct Answer:
271

Solution:
Weight of Glucose

Moles of glucose

And the volume of water

Weight of water

Molality of Glucose

Now,

Freezing point

Hence, the answer is (271).

 Q. 18 The molarity of the solution prepared by dissolving of Oxalic Acid
in of water in is . The value of is__________. (Nearest integer)

Correct Answer:
20

Solution:
Given,

and,

Hence, the answer is (20).

Q. 19 A 6.50 molal solution of has a density of 1.89 g cm -3. The molarity of the
solution is _____ mol dm -3. (Round off to the Nearest Integer).

[Atomic masses : ]

Correct Answer:
9

Solution:
6.5 molal KOH = 1000g solvent has 6.5 moles KOH

so wt of solute = 6.5 × 56 = 364 g

wt of solution = 1000 + 364 = 1364

Hence, the answer is (9).

Q. 20 aqueous solution of sucrose can be cooled up to before

freezing. The amount of ice (in g) that will be separated out is ___________(Nearest integer)

[Given: ]

Correct Answer:
518

Solution:
The amount of ice separated at can be calculated by finding out the molality of the solution at
.

Now, the Initial solution contained 0.75 moles of sucrose in 1kg solvent.

Mass of Sucrose per kg of solvent

Mass of Sucrose in 1 kg Solution

mass of water

And, moles of Sucrose

Finally,

molality

The mass of ice separated

Hence, the answer is (518).

Q. 21 Which one of the following aqueous solutions will exhibit the largest freezing point
depression?
 Option 1:
glycine

Option 2:
hydrazine

Option 3:

Option 4:
glucose

Correct Answer:

Solution:
The greater the van't hoff factor, the greater is the depression at the freezing point.

Since has the greatest Van't Hoff factor, i = 3. It will have the greatest depression at the freezing
point.

Hence, the answer is the option (3).

Q. 22 The vapour pressures of A and B at are respectively. If

A and B are mixed such that the mole fraction of A in the mixture is , then the mole
fraction of B in the vapour phase is . The value of is________
(Nearest integer)

Correct Answer:
1

Solution:
Given,

Hence, the answer is the option (1).

 Q. 23 solution of ion was the minimum concentration of
required to precipitate a negative sol in one h.

The moles of ion present in the 100 ml sample is . The value of is

____(Nearest integer)

Correct Answer:
5

Solution:
The coagulating value is the millimoles of an electrolyte that must be added to 1 litre of a colloidal
solution for complete coagulation in 2 hours.

Given, 100 ml of 0.0018 % w/v of was taken.

This means 100 ml solution contains 0.0018 g of Chloride ions.

Hence, the answer is the option (1).

Q. 24 Which one of the following aqueous solutions has lowest freezing point?

Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:
As we have learnt,
For equimolar solutions, the freezing point decreases as the van't Hoff factor increases.

Since, forms the greatest number of ions in solution, it has the greatest van't Hoff factor and
as a result, has the lowest freezing point.

Hence, the answer is the option (1).

Q. 25 The density of solution is . The molality of this solution is _______ .

(Round off to the Nearest Integer)
[Use : Atomic masses :
Density of ]

Correct Answer:
5

Solution:
Given,

Let 1 litre of solution be taken

Assuming 1 litre of solution containing 1 litre of water.

Hence, the answer is the option (1).

Q. 26 An open beaker of water in equilibrium with water vapour is in a sealed container. When few
grams of glucose are added to the beaker of water, the rate at which water molecules:

Option 1:
leaves the vapour increases

Option 2:
leaves the solution increases
 Option 3:
leaves the solution decreases

Option 4:
leaves the vapour decreases

Correct Answer:
leaves the vapour increases
Solution:
With the addition of solute in solvent, surface area for vapourisation decreases causes a lowering in
vapour pressure.

To maintain the equilibrium vapour increases while vapour pressure decreases.

Hence the answer is the option(1).

Q. 27 Freezing point of a 4% aqueous solution of X is equal to freezing point of 12% aqueous

solution of Y. If molecular weight of X is A, then molecular weight of Y (in terms of A) is :

Correct Answer:
3

Solution:
As we have learned in the mole concept

98 and 88 are the weight of solvent (100-4 = 96 ) and (100-12 = 88)

Hence, the answer is the option (3).

Q. 28 is 40% ionised in aqueous solution.

The value of its Van't Hoff factor (i) is :

(Response should be upto only one decimal digit like 78.7 or 3.5).
 Correct Answer:
1.8

Solution:
Van't Hoff factor for dissociation -

Where

n is the no. of dissociated particles

degree of dissociation

Now,

Hence, the answer is the option (1).

Q. 29 Liquids A and B form an ideal solution in the entire composition range . At 350 K , the vapor
pressures of pure A and pure B are , respectively . The
composition of the vapor in equilibrium with a solution containing 40 mol percent of A at this
temperature is :

Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:
We know that
Hence, the answer is the option (2).

Q. 30 Which one of the following statement regarding Henry's law is not correct?

Option 1:
Higher the value of at a given pressure , higher is the solubility of the gas in the liquids.

Option 2:
Different gases have different (Henry's law constant) value at the same temperature

Option 3:
The mole fraction of the gas in the solution in vapour phase is proportional to the partial pressure of
the gas

Option 4:
The value of increases with the increase in temperature and is dependant on the nature of
the gas

Correct Answer:
Higher the value of at a given pressure , higher is the solubility of the gas in the liquids.

Solution:
Henry's Law -

It decides the solubility of gases in liquids.

= mole fraction of gas in a liquid.

= Partial pressure of the gas over the liquid surface.

-as we know that, (liquid solution)

The more the value of KH the less will be the solubility.

The solubility is lesser at a higher temperature so the value of KH increases with the temperature

Hence, the answer is the option (1).

 Q. 31 Elevation in the boiling point for 1 molal solution of glucose is 2K. The depression in the
freezing point for 2 molal solution of glucose in the same solvent is 2K. The relation between
Kb and Kf is:

Option 1:
Kb = Kf

Option 2:
Kb =1.5 Kf

Option 3:
Kb =0.5 Kf

Option 4:
Kb =2 Kf

Correct Answer:
Kb =2 Kf

Solution:

Hence, the answer is the option (4).

Q. 32 100 mL of solution contains 3.45 g of sodium. The molarity of the solution is ______
(Nearest integer)

[Atomic Masses - ]

Correct Answer:
50

Solution:
Given,
Mass of Na = 3.45 g

100 ml contains 0.05 moles

1 lit contains 0.5 moles

Thus, Molarity

Hence, the answer is (50).

Q. 33 Sodium oxide reacts with water to produce sodium hydroxide. of sodium oxide is
dissolved in of water. Neglecting the change in volume, the concentration of the
resulting solution is __________ (Nearest integer)

Correct Answer:
13

Solution:
The reaction is

Moles of

Moles of obtained in

Hence, the answer is (13).

Q. 34 of an organic acid is separately dissolved in of benzene

and of acetone The acid is
known to dimerize in benzene but remain as a monomer in acetone. The boiling point of the
solution in acetone increases by . The increase in boiling point of solution in benzene
in . The value of is_________. (Nearest integer)
 Correct Answer:
13

Solution:
Let the molality of organic acid present in its sample in both Acetone and Benzene be .

Now the acid dimerises in Benzene but remains unchanged in acetone

and

Now, in Acetone, the elevation in Boiling point is

Next, for Benzene

Hence, the answer is (x=13).

Q. 35 If of copper sulphate is dissolved in delonised water to make of

[Link] concentration of the copper sulphate solution is . The
value of is__________.

Correct Answer:
64

Solution:
Hence, the answer is (64).

Q. 36 How much amount of NaCl (in grams) should be added to 600g of water to decrease the
freezing point of water to ?

(Assume that the freezing point depression constant for water = 2K kg mol-1)

Correct Answer:
1.76

Solution:

Hence, the answer is (w = 1.76g).

Q. 37 The solubility product of at 298 K is . The concentration of

hydroxide ions in a saturated solution of will be :

Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:

s 3s
Hence, the answer is the option (3).

Q. 38 10.30 mg is dissolved into a liter of sea water of density 1.03 g/mL. The concentration of
in ppm is:

Option 1:
10

Option 2:
20

Option 3:
25

Option 4:
40

Correct Answer:
10

Solution:

= 10.

Hence, the answer is the option (1).

Q. 39 1 molal aqueous solution of an electrolyte is 60% ionised. The boiling point of the
solution at 1 atm is _____ K. (Rounded off to the nearest integer)
 Correct Answer:
375

Solution:

Now, we know

And

Hence, the answer is ( ).

Q. 40 The weighed out to make 50mL of an aqueous solution containing 70mg per
mL is _____g.

[Given: Atomic weight in g mol-1 - Na:23, N:14, O:16]

Correct Answer:
13

Solution:
Hence, the answer is ( ).

Q. 41 When 12.2 g of benzoic acid is dissolved in 100g of water , the freezing frequency point of
solution was found to be . The number of
benzoic acid molecules associated (assuming 100% association) is _______.

Correct Answer:
2

Solution:

Hence, the answer is (n=2).

Q. 42 The osmotic pressure of a dilute solution of an ionic compound in water is four times
that of a solution of in water. Assuming complete dissociation of the given
ionic compounds in water, the concentration of in solution is :

Option 1:

Option 2:

Option 3:
 Option 4:

Correct Answer:

Solution:
Osmotic Pressure - Osmotic Pressure ( ) is excess pressure developed on the solution side due to
osmosis.

Vant Hoff factor (i) -

In the case of electrolytes, the observed colligative property is different from the theoretical colligative
property. The ratio is defined by the Vant Haff factor

- wherein

Given,

Hence, the answer is the option (2).

Q. 43 Liquid and liquid form an ideal solution. The vapour pressures of pure liquids
and are and , respectively, at the same temperature. Then correct
statement is :

Option 1:

Option 2:
 Option 3:

Option 4:

Correct Answer:

Solution:
The vapour pressures of pure liq. & are of Hg and of Hg respectively,

( more volatile)

Hence, the answer is the option (4).

Q. 44 At 363K, the vapour pressure of A is 21 kPa and that B is 18kPa. One mole of A and 2moles of
B are mixed. Assuming that this solution is ideal, the vapour pressure of the mixture is
__________ kPa (round off to the integer)

Correct Answer:
19

Solution:

An Ideal solution is prepared by mixing 1 mol A and 2 mol B.

According to Raoult's low

Hence, the answer is (19kPa).

Q. 45 If of an aqueous solution containing of a protein A is isotonic with one litre

of another aqueous solution containing of a protein , AT , the ratio of the
molecular masses of and is ______ (to the nearest integer).

Correct Answer:
177

Solution:
Let the molar mass of protein A = x g/mol
Let the molar mass of protein B = y g/mol

Now,

= 177

Hence, the answer is (177).

Q. 46 The elevation of boiling point of 0.1 m aq solution is two times that of 0.05
aq. solution. The value of x _____

(Assume 100% ionization of complex and , coordination number of Cr is 6 and that

all of molecules are present inside the coordination sphere.)

Correct Answer:
5

Solution:
Thus, i = 3

Therefore, the complex is dissociated into 3 ions.

Hence, the complex is

Thus, the value is 5.

Hence, the answer is (5).

Q. 47 2 molal solution of a weak acid HA has a freezing point of 3.885oC. The degree of dissociation
of this acid is _________

(Round off to the Nearest Integer).

[Given : Molal depression constant of water Freezing point of pure

water = 0o C]

Correct Answer:
50

Solution:
Given,

2 molal solution of a weak acid HA has a freezing point of 3.885ºC.

m=2

Molal depression constant of water (Kf) = 1.85 K kg mol-1

The freezing point of pure water Ti = 0ºC

van't Hoff factor i is related to the degree of dissociation \alpha as, if n = number of ions,

Here n = 2 (H+and A-)

So,

We know the formula of depression at the freezing point.

i = 1.05

Now,

Hence, the answer is (50).

Q. 48 The vapour pressure of aqueous solution of glucose is_______ .

[ Given :The density of , aqueous solutions of glucose is and vapour
pressure of pure water is .]
(Molar mass of glucose is )

Correct Answer:
23

Solution:

weight of solute
Volume of solution
wt. of solution
wt. of solvent

Hence, the answer is (23).

 Q. 49 In the depression of freezing point experiment

A. Vapour pressure of the solution is less than that of pure solvent

B. Vapour pressure of the solution is more than that of pure solvent
C. Only solute molecules solidify at the freezing point
D. Only solvent molecules solidify at the freezing point

Choose the most appropriate answer from the options given below:

Option 1:
A and C only

Option 2:
A only

Option 3:
A and D only

Option 4:
B and C only

Correct Answer:
A and D only

Solution:
On adding non-volatile solute to pure solvent, depression in the freezing point and lowering in vapour
pressure occurs.

Hence, the answer is the option (3).

Q. 50 of was dissolved in deionized water to prepare a stock solution this

solution would be required to prepare of solution?
Given: Molar Mass of and is 23,16 and respectively

Correct Answer:
180

Solution:
Molarity of stock solution
Hence, the answer is (180).

Q. 51 solution is isotonic with glucose solution. Percentage dissociation

of is________

(Nearest integer)

Correct Answer:
75

Solution:
For isotonic solution

Hence, the answer is (75).

Q. 52 The number of units, which are used to express concentration of solutions from the
following is______ Mass percent, Mole, Mole fraction, Molarity, ppm, Molality

Correct Answer:
5

Solution:
Conc. Express in mass percentage
Hence, the answer is (5).

Q. 53 The total pressure observed by mixing two liquids A and B is 350 mmHg when their mole
fractions are 0.7 and 0.3 respectively. The total pressure become 410 mmHg if the mole
fractions are changed to 0.2 and 0.8 respectively for A and B. The vapour pressure of pure A
is________ mm Hg. (Nearest integer) Consider the liquids and solutions behave ideally.

Correct Answer:
314

Solution:

Hence, the answer is (314).

Q. 54 A solution of sugar is obtained by mixing 200g of its 25% solution and 500g of its
40% solution (both by mass).
The mass percentage of the resulting sugar solution is_______(Nearest integer)

Correct Answer:
36

Solution:
Solution (I)

Solution (II)

Hence, the answer is (36).

 Q. 55 If the boiling points of two solvents X and Y (having same molecular weights) are in the ratio
2 : 1 and their
enthalpy of vaporizations are in the ratio 1 : 2, then the boiling point elevation constant of X
is m times the
boiling point elevation constant of Y. The value of m is________(nearest integer)

Correct Answer:
8

Solution:

Hence, the answer is the option (1).

Q. 56 If the degree of dissociation of aqueous solution of weak monobasic acid is determined to be

0.3, then the observed freezing point will be_____________ % higher than the
expected/theoretical freezing point. (Nearest integer)

Correct Answer:
30

Solution:
For mono-basic acid

Hence, the answer is the option (1).

 Q. 57 The number of correct statement/s involving equilibria in physical from the following
is__________
(1) Equilibrium is possible only in a closed system at a given temperature.
(2) Both the opposing processes occur at the same rate.
(3) When equilibrium is attained at a given temperature, the value of all its parameters
(4) For dissolution of solids in liquids, the solubility is constant at a given temperature.

Correct Answer:
3

Solution:
(A) is correct

(B) for equilibrium

(C) at equilibrium, the value of parameters becomes constant at a given temperature and does not equal.

(D) for a given solid solute and a liquid solvent solubility depends upon temperature only

Hence, the answer is the option (1).

Q. 58 A solution is prepared by adding 2 g of "X" to 1 mole of water. Mass percent of "X" in the
solution is

Option 1:
5%

Option 2:
20%

Option 3:
2%

Option 4:
10%

Correct Answer:
10%

Solution:
Hence, the answer is the option (4).

Q. 59 1.2 mL of acetic acid is dissolved in water to make 2.0 L of solution. The depression in the
freezing point observed for this strength of acid is . The percentage of dissociation
of the acid is __________.(Nearest integer)

[ Given: Density of acetic acid is

The molar mass of acetic acid is

Correct Answer:
5

Solution:

Now,

Hence, the answer is (5).

 Q. 60 What weight of glucose must be dissolved in 100 g of water to lower the vapour pressure by
0.20 mmHg?
(Assume dilute solution is being formed)
Given : Vapour pressure of pure water is 54.2 mmHg at room temperature. Molar mass of
glucose is 180gmol-1.

Option 1:
2.59g

Option 2:
3.59g

Option 3:
3.69g

Option 4:
4.69g

Correct Answer:
3.69g

Solution:

Hence, the answer is the option (3).

Q. 61 The depression in freezing point observed for a formic acid solution of concentration
is . Density of formic acid is . The Van't Hoff factor of
the formic acid solution is nearly :
(Given for water )

Option 1:
0.8

Option 2:
1.1
 Option 3:
1.9

Option 4:
2.4

Correct Answer:
1.9

Solution:
We know,

given,

Now, the concentration of formic acid means is

present in 1 liter

So, Mass

So, 0.525 g of is present in 1 liter of water

then

Put all value in (1)

Hence, the answer is the option (3).

Q. 62 The pressure of a moist gas at is . The volume of the container is doubled at the
same temperature. The new pressure of the moist gas is_______ . (Nearest
integer)
(Given : The vapour pressure of water at .)

Correct Answer:
22
Solution:

Given, the vapor pressure of water = 0.4 atm.

If the volume of the container is doubled at the same temperature.

The vapor pressure of water will be the same but the pressure of the gas will change.

The new pressure of the moist gas will be

(New)

Hence, the answer is (22).

Q. 63 Solution of of non-electrolyte (A) prepared by dissolving it in of water exerts

the same osmotic pressure as that of 0.05M glucose solution at the same temperature. The
empirical formula of A is . The molecular mass of A is____________ g. (Nearest integer)

Correct Answer:
240

Solution:

Hence, the answer is (240 gm).

 Q. 64 An aqueous solution of volume contains of protein. The osmotic pressure
of the solution at is 1.29 mbar. The molar mass of the protein is__________ .

Correct Answer:
40535

Solution:

Hence, the answer is (40535 gm/mol).

Q. 65
For the given reaction, if the initial pressure is and the pressure at time is
at a constant temperature and constant volume . The fraction of
decomposed under these conditions is . The value of is________________. (nearest
integer)

Correct Answer:
3

Solution:

Fraction of A decomposed

So,
Hence, the answer is (3).

Q. 66 Chlorophyll extracted from the crushed green leaves was dissolved in water to make a
solution of of concentration The number of atoms of in this solution is
atoms. The value of is ______________. (Nearest Integer)

Correct Answer:
24

Solution:
Concentration of mg is 48 ppm that means

48 mg of mg in 1000 ml or 1 L of solution hence 2 L of solution will contain 96 mg of mg

Value of x = 24

Hence, the answer is (24).

Q. 67 When of nitric acid is heated in a beaker, its volume is reduced to half and
of nitric acid is evaporated. The molarity of the remaining nitric acid solution is
(Nearest Integer)

Correct Answer:
54

Solution:
Initially, Solution is 0.5 m 800 ml

On heating

Volume is reduced to 400 ml and 11.5 g of is evaporated.

[Link]

Answer = 54

Hence, the answer is (54).

Q. 68 80 mole percent of is dissociated in aqueous solution. The vapour pressure of 1.0

molal aqueous solution of at is . (Nearest integer)
Given: Vapour pressure of water at is .

Correct Answer:
48

Solution:

Hence, the answer is (48).

Q. 69 Sea water contains 29.25% NaCl and 19% by weight of solution. The normal boiling
point of the seawater is _____°C. (Nearest integer)
Assume 100% ionization for both NaCl and
Given: Kb( ) = 0.52 K kg mol–1
The molar mass of NaCl is 58.5 and 95 g mol–1 respectively.

Correct Answer:
116

Solution:
Amount of solvent = 100 – (29.25 + 19) = 51.75g
Hence, the answer is ( ).

Q. 70 The size of a raw mango shrinks to a much smaller size when kept in a concentrated salt
solution which one of the following process can explain this?

Option 1:
Reverse osmosis

Option 2:
Diffusion

Option 3:
Osmosis

Option 4:
Dialysis

Correct Answer:
Osmosis

Solution:
The size of the mango shrinks when it is kept in a concentrated salt solution. This is due to osmosis in
which the water molecules move out from the mango into the salt solution causing the mango to shrink.

Hence, the answer is the option (3).

Q. 71 1 L aqueous solution of contains 0.02 m mol .50% of this solution is diluted

with deionized water to give 1 L solution (A). In solution (A), 0.01 m mol of are
added. Total m mols of in the final solution is ________

Correct Answer:
20

Solution:
0.5 lit solution (A) initially contains 0.01 mmole. The solution is then diluted and a further 0.01 mmole is
added.
Hence, the answer is (20).

Q. 72 A commercially sold conc. by mass. If the density of this commercial acid

is the molarity of this solution is :
(Atomic mass : )

Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:
Given,

Concentration of by mass.

Let us assume the total volume of Solution

From density, the total mass of Solution

Hence, the answer is the option (3).

 Q. 73 A percent solution of potassium chloride was found to freeze at . The
percentage dissociation of potassium chloride is__________. (Nearest integer)

(Molal depression constant for water is and molar mass of

)

Correct Answer:
98

Solution:
Given , soln is

Assuming of solution, the mass of is

Given,

Depression of freezing point is .

Molar mass of

Let us now calculate the molality of the solution

Now, for the dissociation of ,

The van't Hoff factor(i) is given as

Thus, the % dissociation of KCl is 98%

Hence, the answer is (98).

 Q. 74 The osmotic pressure exerted by a solution prepared by dissolving of protein of molar
mass in of water at is __________Pa.[integer value]

Correct Answer:
415

Solution:

Hence, the answer is (415).

Q. 75 Given below are two statements : one is labelled as Assertion (A) and the other is labelled
as Reason (R).

Assertion (A) : At [atomic masses of

respectively], is . The solution is cooled to
. The molality of the solution will remain unchanged.

Reason (R): The molality of a solution does not change with temperature as mass remains
unaffected with temperature.
In the light of the above statements, choose the correct answer from the options given
below.

Option 1:
Both (A) and (R) are true and (R) is the correct explanation of (A).

Option 2:
Both (A) and (R) are true but (R) is not the correct explanation of (A).

Option 3:
(A) is true but (R) is false.

Option 4:
(A) is false but (R) is true.
 Correct Answer:
Both (A) and (R) are true and (R) is the correct explanation of (A).
Solution:
The temperature does not change the mass of the solute or the solvent and hence, the molality of the
solution remains the same.

Hence both Assertion and Reason are true and the Reason correctly explains the Assertion.

Hence, the answer is the option (1).

Q. 76 of a non-volatile non-electrolyte solute is dissolved in of two different solvents A

and B whose ebullioscopic constants are in the ratio of . The elevation in boiling points
of are in the ratio . The value of is_________. (Nearest Integer)

Correct Answer:
8

Solution:
Given

We know,

Hence, the answer is (8).

Q. 77 2.5 g of protein containing only glycine is dissolved in water to make 500 mL of

solution. The osmotic pressure of this solution at 300 K is found to be bar. The
total number of glycine units present in the protein is__________.

Correct Answer:
330

Solution:
Given,

Osmotic pressure -

We have-

Hence, the answer is (330).

Q. 78 A solution containing of a solute dissolved in of water boils

at . The molar mass of the solute is _________ .[nearest integer]

Correct Answer:
45

Solution:
Given,

Now, using the expression for Molality, we have

Hence, the answer is (45).

Q. 79 The vapour pressures of two volatile liquids A and B at

, respectively. If the liquid mixture contains 0.3 mole fraction of A, then the mole fraction of
liquid B in the vapour phase is . The value of x is ________.

Correct Answer:
14

Solution:
From Raoult's Law

Thus,

Now, the mole fraction of B in the vapor phase is given as

Hence, the answer is (14).

Q. 80 Solute A associates in water. When 0.7 g of solute A is dissolved in 42.0 g of water,it

depresses the freezing point by . The percentage association of solute A in water is:

[Given: Molar mass of . Molal depression constant of water is

Option 1:
50%
 Option 2:
60%

Option 3:
70%

Option 4:
80%

Correct Answer:
80%
Solution:
Solute A associated with water.

So,

The can't Hoff factor can be calculated as

Now given,

We know,

Putting the value of i in , we have

Hence, the answer is the option (4).

 Q. 81 When a certain amount of solid is dissolved in of water at to make a dilute
solution, the vapour pressure of the solution is reduced to one-half of that of pure water.
The vapour pressure of pure water is . The number of moles of solute
added is__________. (Nearest Integer)

Correct Answer:
3

Solution:
We know the formulas

due to dilute solution

then

So,

Ans = 3

Hence, the answer is (3).

Q. 82 If O2 gas is bubbled through water at 303 K the number of millimoles of O2 gas that dissolve
in 1 liter of water is __________. (Nearest Integer)

(Given: Henry's Law constant for O2 at 303 K is 46.821 k-bar and partial pressure of = O2
0.920 bar & Assume solubility of O2 in water is too small, nearly negligible).

Correct Answer:
1

Solution:
 [ due to solubility of in water is too small]

Hence, the answer is (1).

Q. 83 Elevation in boiling point for 1.5 molal solution of glucose in water is 4 K. The depression in
freezing point for 4.5 molal solution of glucose in water is 4 K. The ratio of molal elevation
constant to molal depression constant is __________.

Correct Answer:
3

Solution:

Hence, the answer is (3).

Q. 84 The oxygen dissolved in water exerts a partial pressure of 20 kPa in the vapour above water.
The molar solubility of oxygen in water is ___________ . (Round off to the
Nearest Integer)

[Given: Henry's law constant

Density of water with dissolved oxygen ]

Correct Answer:
25
Solution:
The effect of pressure on the solubility of the gas in the liquid is given by Henry's law, which states that
the solubility of a gas in a liquid is directly proportional to the pressure of the gas over the
solution at a definite temperature.

The solubility is taken as the mass of the gas dissolved per unit volume of the liquid. Thus, if m is the
mass of the gas dissolved per unit volume of the solvent and P is the pressure of the gas in equilibrium
with the solution, then

where K is the proportionality constant.

So,

Hence, the answer is (25).

Q. 85 The density of solution of . Molality of the solution is

(Nearest integer).
Given: Molar mass of and is 23 and respectively.

Correct Answer:
364

Solution:

Hence, the answer is (364).

Q. 86 of acetic acid is dissociated when its is added to of water. The depression

in freezing point of such water is __________
Atomic mass of and are 12,1 and 16 a.m.u. respectively.
[Given : Molal depression constant and density of water are and
respectively.
 Correct Answer:
372

Solution:

Hence, the answer is (372).

Q. 87 Lead storage battery contains by weight solution of . The van't Hoff factor is
2.67 at this concentration. The temperature in Kelvin at which the solution in the battery will
freeze is __ (Nearest integer). Given

Correct Answer:
243

Solution:

Hence, the answer is (243).

Q. 88 The molality of a solution of di-bromine solution in (carbon tetrachloride)

is
_____________ . (Nearest integer)
 Correct Answer:
139

Solution:

mass of solute
mass of solvent

Hence, the answer is (139).

Q. 89 A solution containing of a non-volatile solute in of water boils at . The

molecular mass of the solute is___________ (Nearest integer)
Given, water boils at , for water

Correct Answer:
100

Solution:

Hence, the answer is (100).

Q. 90 A 100mL solution was made by adding 1.43g of . The normality of the

solution is 0.1N. The value of x is___________.

(The atomic mass of Na is 23 g/mol)

Correct Answer:
10

Solution:
Molar mass(M) of Na2CO3.xH2O
M = 23 × 2 + 12 + 48 + 18x
M = 46 + 12 + 48 + 18x
M = (106 + 18x)

As nfactor in dissolution will be determined from net cationic or anionic charge; which is 2 so.
[Link]. = = (53 + 9x)

As volume = 100 ml = 0.1 Litre

53 + 9x = 143
9x = 90
x = 10.00

Hence, the answer is (10).

Q. 91 Solution of two components containing n1 moles of 1st component and n2 moles of 2nd
component is prepared, M1 and M2 are molecular weight of component 1 and 2
respectively. If d is the density of the solution in g mL-1, C2 is the molarity and x2 is the mole
fraction of 2nd component, C2 can be expressed as:

Option 1:

Option 2:

Option 3:

Option 4:
 Correct Answer:

Solution:

Hence, the answer is the option (3).

Q. 92 At ,a solution containing of solute in of solution exerts an osmotic

pressure of . The molar mass of the solute is (Nearest integer)
(Given : )

Correct Answer:
62250

Solution:

Hence, the answer is (62250).

 Q. 93 What is the mass ratio of ethylene glycol required
for making 0.25 molal aqueous solution and 0.25 molal aqueous solution?

Option 1:
1: 1

Option 2:
2: 1

Option 3:
1: 2

Option 4:
3: 1

Correct Answer:
2: 1

Solution:
Case I

Case II

equation (1) equation (2)

Hence, the answer is the option (2).

Q. 94 of acetic acid was contaminated with ascorbic acid to lower down

its freezing point by . The value of is___________.(Nearest integer)
[Given
molar mass of ascorbic acid ]
 Correct Answer:
15

Solution:
Given , 150 g of
10.2 g of ascorbic acod having 0.058 moles.

.
M. mass of ascorbic acid = 176 g/mol.

Hence, the answer is .

Q. 95 of solute A was dissolved in of ethanol and the freezing point of the

solution was found to be . The molar mass of solute is ___ [Given: The
freezing point of ethanol is
The density of ethanol is
The freezing point depression constant of ethanol is ]

Correct Answer:
80

Solution:

Hence, the answer is (80 g/mol).

 Q. 96 When of a substance is dissolved in , it raises the boiling point by
. The molar mass of the substance is ________ . (Nearest integer).

[Given ]

Correct Answer:
250

Solution:
As we have learned,

Thus, molarity

This means, 1 kg of solvent contains 0.12 moles

100 g of solvent contains 0.012 moles

Hence, the answer is (250).

Q. 97 Consider the following pairs of solution which will be isotonic at the same temperature. The
number of pairs of solutions is/are______________

Correct Answer:
4

Solution:
Hence, the answer is (4).

Q. 98 1.46 g of a biopolymer dissolved in a 100mL water at 300 K exerted an osmotic pressure of

The molar mass of the biopolymer is_____ . (Round off to the Nearest Integer) .
[Use : ]

Correct Answer:
15

Solution:
As we have learnt,

Now,

Putting these values in the formula, we have

Hence, the answer is the option (1).

Q. 99 The freezing point of a diluted milk sample is found to be , while it should have
been for pure milk. How much water has been added to pure milk to make the
diluted sample ?
 Option 1:
2 cups of water to 3 cups of pure milk.

Option 2:
3 cups of water to 2 cups of pure milk.

Option 3:
1 cup of water to 3 cups of pure milk.

Option 4:
1 cup of water to 2 cups of pure milk.

Correct Answer:
3 cups of water to 2 cups of pure milk.

Solution:
The freezing point of milk

The freezing point of milk (diluted)

Hence, the answer is the option (2).

Q. A solution containing 62 g ethylene glycol in 250 g water is cooled to . If for

100
water is 1.86 K kg , the amount of water (in g ) separated as ice is:

Correct Answer:
64

Solution:
To solve this question, we need to calculate the molality of the solution for which the value depression in
freezing point is 10oC.

Then based on the molality, we will be able to calculate the mass of the solvent which is present in the
solution.

This will enable us to calculate the weight of the solvent which has separated as ice.
62 g ethylene glycol in 250 g water is cooled to ice, the amount of water (in g ) separated as ice is-

Hence, the answer is (64gm).

Q. Boiling point of a aqueous solution of a non-volatile solute is equal to the boiling point
101 of aqueous solution of a non-volatile solute . The relation between molecular weights
of is

Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:
We know that

will be the same for and due to the solvent being the same (water aqueous) and the boiling point of an aqueous
solution of both and are equal.

will be due to the solvent being the same or and.

Hence,

Now, 2% aqueous solution of a non-volatile solute means in 100 ml or 100 g water 2 g of is present and 8% aqueous
solution means in 100 ml or 100 g of water 8 g of is present.

So,
Hence, the answer is the option (2).

Q. Two solutions and are prepared by dissolving of non-volatile solutes and

102 respectively in of water. The ratio of depression in freezing points for and is found
to be The ratio of molar masses of and is

Option 1:

Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:
We know,

, if the solvent is the same

Hence, the answer is the option (2).

 Q. A gaseous mixture of two substances under a total pressure of is in
103 equilibrium with an ideal liquid solution. The mole fraction of substance is in the
vapour phase and in the liquid phase. The vapour pressure of pure liquid is_______
atm. (Nearest integer)

Correct Answer:
2

Solution:
Given,
Hence

= Vapour pressure in the liquid phase for substances A and B respectively

= Vapour pressure in gaseous / vapor phase for elements A and B respectively

We know that -

Hence, the answer is (2).

Q. A set of solutions is prepared using 180 g of water as a solvent and 10 g of different non-
104 volatile solutes A,B and C. The relative lowring of vapour pressure in the presence of these
solutes are in the order [Given, molar mass of A=100 g mol -1; B=200 g mol -1; C=10,000 g mol
-1]

Option 1:

Option 2:

Option 3:

Option 4:
 Correct Answer:

Solution:
Here vapour pressure of water is lowered.

We know this formula,

Partial Vapour pressure of water Pwater = PoXwater

Lowering Vapour pressure of water = Po – Pwater

The relative lowering of vapour pressure

Now,

From above,

Hence, the answer is the option (3).

Q. A 300 K, the vapour pressure of a solution containing 1 mole of n-hexane and 3 moles of n-
105 heptane is 550 mm of Hg. At the same temperature, if one more mole of n-heptane is added
to this solution, the vapour pressure of the solution increases by 10mm of Hg. What is the
vapour pressure in mm Hg of n-heptane in its pure state __________?

Option 1:
600

Option 2:
-

Option 3:
-
 Option 4:
-

Correct Answer:
600
Solution:
At 300 K, the vapour pressure of a solution containing 1 mole of n-hexane and 3 moles of n-heptane is
550 mm of Hg.

We know,

1) 1 mole of n-hexane and 3 moles of n-heptane is 550 mm of Hg.

So,

........(i)

2) At the same temperature, if one more mole of n-heptane is added to this solution, the vapour pressure
of the solution increases by 10 mm of Hg.

So,

........(ii)

From (i) and (ii),

The vapour pressure in mm Hg of n-heptane in its pure state is 600 mm Hg.

Ans =600

Hence, the answer is the option (1).

Q. The mole fraction of glucose in an aqueous binary solution is 0.1. The mass
106
percentage of water in it to the nearest integer is-

Option 1:
47

Option 2:
-

Option 3:
-
 Option 4:
-

Correct Answer:
47
Solution:
Mole fraction of glucose, in

Now, let's assume we have 10 moles of solution.

Thus, moles of

Ans, moles of

Now, the mass of water = number of moles x molar mass

Thus, the mass of water

Mass of

Now, the mass per cent of water is given as:

Thus, the correct answer is 47.

Hence, the answer is the option (1).

Q. The elevation in boiling point for molal solution of non-volatile solute is The
107 depression in freezing point for molal solution of in the same solvent is The ratio
of and is . The value of is [nearest integer]

Option 1:
1

Option 2:
-

Option 3:
-

Option 4:
-
 Correct Answer:
1
Solution:
We know,

Now,

And

So, the ratio of and

So,

Hence, the answer is the option (1).

Q. Henry's constant (in K bar) for tour gases in water at 298 K is given below:
108

50 2 0.5
(density of water = 103 kg/m3 at 298 K) This table implies that

Option 1:
has the highest solubility in water at a given pressure

Option 2:
Solubility of at 308 K is lower than at 298 K

Option 3:
The pressure of a 55.5 molal solution of s 1 bar

Option 4:
The pressure of a 55.5 molal solution of is 250 bar
 Correct Answer:
The pressure of a 55.5 molal solution of is 250 bar
Solution:

So, has the greatest solubility as it has the least value of Henry's constant.

(2) On increasing temperature solubility of gases decreases, solubility is greater at 298K than 308K
although that is not implied by the table.

(3) Now,

We know this formula.

The Correct Statement: The pressure of a 55.5 molal solution is 250 bar

Hence, the answer is the option (4).

Q. If the concentration of glucose in blood is , the molarity of glucose

109
in blood is ____ . (Nearest integer)

[Given : Atomic mass of ]

Correct Answer:
4

Solution:
Given,

Concentration of Glucose

Thus, a 1-litre glucose solution contains 0.72 g

Hence, the answer is the option (1).

 Q. The osmotic pressure of blood is bar at . To inject glucose into a patient
110 intravenously, it has to be isotonic with blood. The concentration of glucose solution is
__________.
(Molar mass of glucose , ) (Nearest integer)

Correct Answer:
54

Solution:
Let the concentration of Glucose be

The concentration of Glucose in

Hence, the answer is (54).

Q. Solid Lead nitrate is dissolved in 1 liter of water. The solution was found to boil at .
111 When 0.2 mol of is added to the resulting solution, it was observed that the solution
froze at −0.8 0C. The solubility product of formed is_____ at 298 K. (Nearest
integer)

(Given: and Assume molality to be equal to

molarity in all cases.)

Correct Answer:
13

Solution:
Let a mole be added

In final solution
Hence, the answer is (13).

Q. Millimoles of calcium hydroxide are required to produce 100 mL of the aqueous solution of
112 is .The value of x is_______(Nearest integer).
Assume complete dissociation.

Correct Answer:
5

Solution:

Hence, the answer is (5).

Q. The number of pairs of the solutions having the same value of the osmotic pressure from
113 the following is (Assume ionization)

Correct Answer:
4

Solution:
We know,
So,

(a)

Osmotic pressure will be the same.

(b)

Osmotic pressure will be the same.

(c)

Osmotic pressure will not be the same.

(d)

Osmotic pressure will be the same.

(e)

Osmotic pressure will be the same.

Hence, the answer is (4).

Q. A company dissolves an 'x' amount of 298 K in 1 liter of water to prepare soda water.
114 ____________ . (nearest integer)

(Given: partial pressure of , at 298 K = 0.835 bar.

Henry's law constant for 298K = 1.67 kbar.

The atomic masses of H, C, and O are 1, 12, and 16 g respectively.

Correct Answer:
1221

Solution:
We have to find the amount of dissolved, in 1 liter of

Given,

Henry's law constant,

Using Henry's Law, we have

Let the mass of dissolved be . So we can write

Now, assuming a very dilute solution, we can approximate as

Then,

Hence, the answer is (1221).

Q. A solution of two miscible liquids showing negative deviation from Raoult’s law will have ?
115

Option 1:
decreased vapour pressure, increased boiling point

Option 2:
increased vapour pressure, decreased boiling point

Option 3:
decreased vapour pressure, decreased boiling point

Option 4:
increased vapour pressure, increased boiling point

Correct Answer:
decreased vapour pressure, increased boiling point

Solution:
A solution of two miscible liquids showing negative deviation from Raoult’s law then vapor pressure will
decrease increasing its boiling point.

Hence, the answer is the option (1).

 Q. A solution of H SO is 31.4%H SO by mass and has a density of 1.25 g/mL. The
116
2 4 2 4

molarity of the H SO solution is_________ M (nearest integer).

2 4

[Given molar mass of H 2

SO 4 = 98 g mol
−1
]

Correct Answer:
4

Solution:
W 10
M = % × d ×
W M solute

10 .
= 31.4 × 1.25 ×
98

= 4M

Hence, the answer is (4).

Q. Molality of 0.8MH 2 SO 4 solution (density 1.06 g cm −3

) is__________ ×10 −3
.
m
117

Correct Answer:
815

Solution:
1000M
m =
1000 d − MM solute

1000 × 0.8 −3 −3
= = 814.9 × 10 = 815 × 10
(1000 × 1.06) − (0.8 × 98)

Hence, the answer is (815).

Q. The quantity which changes with temperature is:

118

Option 1:
Molarity

Option 2:
Mass percentage

Option 3:
Molality
 Option 4:
Mole fraction

Correct Answer:
Molarity
Solution:
Molarity depends on temperature while other terms are mass dependent and temperature independent.

Hence, the answer is the option (1).

Q. The osmotic pressure of a dilute solution is 7 × 10 5

Pa at 273 K. Osmotic pressure of the
119 same solution at 283 K is________×10 Nm .
4 −2

Correct Answer:
73

Solution:
π = CRT

π1 T1
=
π2 T2

5
7 × 10 × 283
⇒ π2 =
273

4 4
= 72.5 × 10 ≈ 73 × 10

Hence, the answer is (73).

Q. Among the colloids cheese (C), milk (M) and smoke (S), the correct combination of the
120 dispersed phase and dispersion medium, respectively is :

Option 1:
C: liquid in solid; M: liquid in solid; S: solid in gas

Option 2:
C: liquid in solid; M: liquid in liquid; S: solid in gas

Option 3:
C: solid in liquid; M: Liquid in Liquid; S: gas in solid

Option 4:
C: solid in liquid; M: solid in liquid; S: solid in gas
 Correct Answer:
C: liquid in solid; M: liquid in liquid; S: solid in gas
Solution:
Cheese ⟶ liquid in solid

Milk → liquid in the liquid

Smoke → Solid in gas

Hence, the answer is the option (2).

Q. The osmotic pressure of solutions of PVC in cyclohexanone at 300 K are plotted on the
121 graph. The molar mass of PVC is ____ gmol (Nearest integer)
−1

(Given : R = 0.083 L atm K −1

mol
−1
)

Correct Answer:
41500

Solution:
W/M
′
π = M RT = ( )RT
V

W 1 RT
⇒ π = ( )( )RT = C ( )
V M M

π RT
⇒ = ≠ f (c)
C M

If we assume graph between π

C
and C

Assuming π vs C graph

RT 0.083 × 300 −4
Slope = = = 6 × 10
M M
0.083 × 300 830 × 300
∴ M = =
−4
6 × 10 6

= 41, 500

Hence, the answer is (41,500).

 Q. The expression ΔH = −ve is true for given solution :
122
mix

Option 1:
Benzene + toluene

Option 2:
Water + alcohol

Option 3:
water + nitric acid

Option 4:
n - hexane + n - heptane

Correct Answer:
water + nitric acid

Solution:
As we learn

Condition for negative deviation -

When A - A interactions and B - B interactions are weaker than A - B interactions.

e.g. Acetone + Chloroform

- wherein

ΔH mix < 0

ΔV mix < 0

(V f < V A + V B )

ΔH − Change in enthalpy

ΔV − Change in volume

Water + nitric acid, forms a negative deviation solution, for which,

ΔH mix
= −ve, ΔV mix
= −ve, ΔS mix
= +ve and ΔG = −ve
mix

Hence, the answer is the option (3).

Q. The force of attraction among molecules should be neglected at

123

Option 1:
High temperature, high pressure
 Option 2:
low temperature, high pressure

Option 3:
low temperature, low pressure

Option 4:
none of these

Correct Answer:
low temperature, high pressure
Solution:
As we learn

The behavior of real gas -

Attraction forces exist between molecules at low temperatures.

Attraction among molecules should not be neglected at high pressure and low temperature.

Hence, the answer is the option (2).

Q. 12 g of acetic acid is dissolved in Benzene to obtain 2 lit solution at 300 K . The osmotic
124 pressure of the solution is found to be 1.64 atm . If acetic acid dimerises in Benzene, then
the extent of association of acetic acid is

atm − lit
( Use R = 0.082 )
mol − K

Option 1:
1

Option 2:
1

Option 3:
2

Option 4:
3

Correct Answer:
2

Solution:
As we learnt,

π = iCRT

⇒ 1.64 = i(0.1) × (0.082) × (300)

2
⇒ i =
3

Let the degree of association of acetic acid (CH 3 COOH) in benzene is α ,then

∴ Total moles = 1 − α + α

2
= 1 −
α

2
or i = 1 −
α

Now put the value of i ,

α 2
∴ 1 − =
2 3

2
⇒ α =
3

Hence, the answer is the option (3).

Q. In a solvent 50% of an acid HA dimerizes and the rest dissociates. The van't Hoff factor of the
125 acid is ........ x 10–2. (Round off to nearest integer)

Correct Answer:
125

Solution:
The dissociation and association processes are given as

Given,

Thus, the Vant Hoff factor

Hence, the answer is (125).

Q. 83 g of ethylene glycol dissolved in 625 g of water. The freezing point of the solution is
126 ________K. (Nearest integer)

[Use: Molal Freezing point depression constant of water = 1.86 K kg mol-1,

Freezing point of water = 273 K,

Atomic masses : C : 12.0u, O : 16.0u, H : 1.0u

Correct Answer:
269

Solution:
The structure of Ethylene Glycol is given below:

Molar mass of Ethylene Glycol = 62 g

∴ Moles of Ethylene Glycol =
83

62

83 × 1000
∴ molality = = 2.14
62 × 625

Now,

ΔT f = K f × m

= 1.86 × 2.14

= 3.98K

≅ 4K

∴ Freezing point = (273 − 4)K = 269 K

Hence, the answer is (269).

Q. 224 mL of SO at 298 K and 1 atm is passed through 100 mL of 0.1 m NaOH solution. The
127
2( g)

non-volatile solute produced is dissolved in 36 g of water. The lowering of vapour pressure

of solution (assuming the solution is dilute) (P o

H2 O
= 24 mm of Hg) is x × 10 −2
mm of Hg,
the value of x is . (Integer answer)

Option 1:
18
 Option 2:
12

Option 3:
17

Option 4:
10

Correct Answer:
18
Solution:

The balanced equation is

SO 2 + 2NaOH ⟶ Na 2 SO 3 + H 2 O

moles of NaOH = molarity × volume (in litre)

= 0.1 × 0.1

= 0.01 moles

Here, NaOH is limiting the Reagent

2 mole NaOH ⟶ 1 mole Na SO 2 3

0.01 mole NaOH ⟶ × 0.01 mole 1

2
2
Na 2 SO 3

Moles of Na 2
SO 3 ⟶ 0.005 mole
+ 2−
Na 2 SO 3 ⟶ 2Na + SO
3

Moles of H O =
2
36

18
= 2 moles
According to RLVP -
∘
P − PA
A
= iX B
∘
P
A
∘
P − PA in A
A
= (iin A ≃ 0)
∘
P in A + n B
A

nB < nA

{n A + n B ≃ n A }

0
P − PA nB
A
= i ×
∘
P nA
A

2H − P A 0.005
= 3 ×
2H 2

⇒ 2H − P A = 0.18

Lowering in pressure = 0.18 mm of Hg lowering in pressure = 18 × 10 −12

mm of Hg
x = 18
Hence, the answer is the option (1).

Q. An artificial cell is made by encapsulating 0.2M glucose solution within a semipermeable

128 membrane. The osmotic pressure developed when the artificial cell is placed within a 0.05 M
solution of NaCl at 300 K is__________×10 bar. (Nearest Integer)
−1

[Given : R = 0.083 Lbarmol K ]

−1 −1

Assume complete dissociation of NaCl

Correct Answer:
25

Solution:

+ −
NaCl ⟶ Na + Cl

0.05M 0.05M 0.05M

Total C 1 = 0.05 + 0.05 = 0.1M(NaCl)

C 2 = 0.2M( glucose )

π = (C 2 − C 1 )RT

= (0.2 − 0.1) × 0.083 × 300

= 2.49 bar

−1
= 24.9 × 10 bar

Hence, the answer is (25).

Q. A solution is prepared by mixing 8.5 g of CH2Cl2 and 11.95 g of CHCl3. If vapour pressure of
129 CH2Cl2 and CHCl3 at 298 K are 415 and 200 mmHg respectively, the mole fraction of CHCl3 in
vapour form is : (Molar mass of Cl=35.5 g mol−1)

Option 1:
0.162

Option 2:
0.675

Option 3:
0.325
 Option 4:
0.486

Correct Answer:
0.325
Solution:
P0 = Vapor pressure = 200 mm of Hg

Mass of solute (CH 2 Cl 2 ) = 8.5 g

Mass of solvent (CHCl 3) = 11.95 g

Mole fraction in solution phase can be calculated as:

(8.5/85)
X CH 2 Cl 2 = = 0.5
(8.5/85) + (11.95/119.5)

(11.95/119.5)
X CH Cl 3 = = 0.5
(8.5/85) + (11.95/119.5)

Mole fraction in vapor phase is given by the formula:

o
P . X CHCl 3
Y CHCl 3 = o
o P .X CH Cl
P . X CHCl 3 + P 2 2 =

200 × 0.5

200 × 0.5 + 415 × 0.5

= 0.325

Hence, the answer is the option (3).

Q. 0.05MCuSO 4 when treated with 0.01MK Cr O gives green colour solution of

2 2 7
130 Cu 2 Cr 2 O 7 . The [SPM : Semi Permeable Membrane]

K 2 Cr 2 O 7 CuSO 4

Side X SPM Side Y

Due to Osmosis :

Option 1:
Green colour formation observed on side Y.
 Option 2:
Green colour formation observed on side X.

Option 3:
Molarity of K 2
Cr 2 O 7 solution is lowered.

Option 4:
Molarity of CuSO solution is lowered.
4

Correct Answer:
Molarity of CuSO solution is lowered.
4

Solution:
Only solvent Molecules are allowed to pass through the SPM.

Hence, the answer is the option (4).

Q. 2.7Kg of each of water and acetic acid are mixed, The freezing point of the solution will be
131 −x C. Consider the acetic acid does not dimerise in water, nor dissociates in water x =
∘

___________ (nearest integer)

[Given : Molar mass of water = 18 g mol , acetic acid = 60 g mol

−1 −1
]
Kf −1
H 2 O : 1.86 K kg mol

Kf acetic acid : 3.90 K kg mol −1

freezing point : H 2O = 273 K , acetic acid = 290 K]

Correct Answer:
31

Solution:
As moles of water > moles of CH 3
COOH water is solvent.
∘
T − (T F ) = KF × M
F S

2700/60
0 − (T F ) = 1.86 ×
S 2700/1000

∘
( TF ) = −31 C.
S

Hence, the answer is (31).

 Q. Considering acetic acid dissociates in water, its dissociation constant is 6.25 × 10 . If 5 mL
−5

132 of acetic acid is dissolved in 1 litre water, the solution will freeze at −x × 10 C, provided
−2 ∘

pure water freezes at 0 C. ∘

x=___________.(Nearest integer)

Given : (K ) f
= 1.86 K kg mol
water
. −1

density of acetic acid is 1.2 g mol −1

molar mass of water = 18 g mol . −1

molar mass of acetic acid = 60 g mol . −1

density of water = 1 g cm −3

Acetic acid dissociates as

Θ ⊕
CH 3 COOH ⇌ CH 3 COO + H

Correct Answer:
19

Solution:
Mass of CH 3 COOH = V × d

= 5ml × 1.2 g/ml

= 6gm

6
n CH = = 0.1 mol
3 COOH
60

0.1
m CH 3 COOH ≈ M CH 3 COOH = = 0.1M
1
− +
CH 3 COOH ⇌ CH 3 COO + H

C − Cα Cα Cα
2
Cα
Ka =
1 − α
2
1 − α ≈ 1 ⇒ K a = Cα

−5
Ka 6.25 × 10
√ −3
α = √ = = 25 × 10
C 0.1

V.f . (i) = 1 + α(n − 1) = 1 + α(2 − 1) = 1 + α

−3
= 1 + 25 × 10 = 1.025

ΔT f = iK t m

= (1.025)(1.86)(0.1)

= 0.19

−2
= 19 × 10

Hence, the answer is (19).

Q. During the detection of acidic radical present in a salt, a student gets a pale yellow
133 precipitate soluble with difficulty in NH OH solution when sodium carbonate extract was
4

first acidified with dil. HNO and then AgNO solution was added. This indicates presence
3 3

of:
 Option 1:
−
Br

Option 2:
2−
CO
3

Option 3:
−
I

Option 4:
−
Cl

Correct Answer:
−
Br

Solution:
Ag
+
+ I
−
→ AgI Yellow ppt.
Ag
+
+ Cl
−
→ AgCl White ppt
Ag
+
+ Br
−
→ AgBr Pale yellow ppt

Hence, the answer is the option (1).

Q. Consider the dissociation of the weak acid HX as given below

134 HX(aq) ⇌ H
+
(aq) + X
−
(aq), Ka = 1.2 × 10
−5

[K a : dissociation constant ]

The osmotic pressure of 0.03M aqueous solution of HX at 300 K is________ ×10

−2

bar (nearest integer).

[Given : R = 0.083 LbarMol −1

K
−1
]

Correct Answer:
76

Solution:
+ − −5
HX ⇌ H + X K a = 1.2 × 10

0.03M

0.03 − x x x

2
−5
x
K a = 1.2 × 10 =
0.03 − x

0.03 − x ≈ 0.03 ( K a is very small )

2
x −5
= 1.2 × 10
0.03
−4
x = 6 × 10
 Final solution : 0.03 − x + x + x

4
= 0.03 + x = 0.03 + 6 × 10

4
Π = (0.03 + (6 × 10 )) × 0.083 × 300

−2 −2
= 76.19 × 10 ≈ 76 × 10

Hence, the answer is (76).

Q. A maxima or minima obtained in the temperature composition curve of a mixture of two

135 liquids indicates:

Option 1:
an azeotropic mixture

Option 2:
an eutectic formation

Option 3:
that the liquids are immiscible with one another

Option 4:
that the liquids are partially miscible at the maximum or minimum

Correct Answer:
an azeotropic mixture

Solution:
Negative deviation from Raoult's Law behaviour -
When the pressure exerted by vapours of the mixture is less than that in the case of ideal behaviour.

0 0
PT < P xA + P xB
A B

An azeotropic mixture boil at a particular temperature without changing its composition.

Hence, the answer is the option (1).

 Q. AB 2 is 10% dissociated in water to A and B . The boiling point of a 10.0 molal aqueous
2+ −

136 solution of AB is − − − − − − −− C . (Round off to the Nearest Integer).

o
2

[Given : Molal elevation constant of water K = 0.5 K kg mol − 1

b boiling point pure water

= 100 C ]
∘

Correct Answer:
106

Solution:
2+ −
AB 2 → A + 2 B

t = 0

t = t a − aα aα 2aα

n T = a − aα + aα + 2aα

= a(1 + 2α)

so i = 1 + 2α

Now ΔT b = i × m × K b

Δ T b = (1 + 2α) × m × K b

∵ α = 0.1 m = 10 K b = 0.5

Δ T b = 1.2 × 10 × 0.5

= 6

So boiling point = 106

Hence, the answer is (106).

Q.
137

Choose the correct answer from the options given below :

 Option 1:
A-I, B-III, C-II, D-IV

Option 2:
A-III, B-I, C-IV, D-II

Option 3:
A-III, B-I, C-II, D-IV

Option 4:
A-III, B-II, C-I, D-IV

Correct Answer:
A-III, B-I, C-II, D-IV

Solution:
(A) van't Hoff factor, i

(B) kf = Cryoscopic constant

(C) Solutions with the same osmotic pressure are known as isotonic solutions.

(D) Solutions with the same composition of vapor over them are called Azeotrope.‘

Hence, the answer is the option (3).

Q. Match List I and List II

138

Choose the correct answer from the options given below :

Option 1:
A-I, B-III, C-IV, D-II

Option 2:
A-III, B-I, C-IV, D-II
 Option 3:
A-III, B-I, C-II, D-IV

Option 4:
A-I, B-III, C-II, D-IV

Correct Answer:
A-III, B-I, C-IV, D-II
Solution:
(i) Electro osmosis: When movement of colloidal particles is prevented by some suitable means (porous
diaphragm or semi permeable membranes), it is observed that the D.M. begins to move in an electric
field. This phenomenon is termed electrosmosis.

(ii) Solvent molecules pass through semi-permeable membrane towards solvent side is termed as reverse
osmosis.

(iii) When an electric potential is applied across two platinum electrodes dipping in a colloidal solution, the
colloidal particles move towards move towards one or the other electrode. The movement of colloidal
particles under an applied electric potential is called electrophoresis.

(iv) Solvent molecules pass through semipermeable membrane towards the solution side is termed as
osmosis.

Hence, the answer is the option (2).

Q. A beaker contains a solution of the substance ‘A’. Precipitation of substance ‘A’ takes place
139 when a small amount of ‘A’ is added to the solution. The solution is _________.

Option 1:
saturated

Option 2:
supersaturated

Option 3:
unsaturated

Option 4:
concentrated

Correct Answer:
supersaturated

Solution:
Adding a small amount of solute to an already saturated solution will make the solution supersaturated
and will lead to the precipitation of the solute.

Hence, the answer is the option (2).

 Q. The density of ' x ' M solution (' x ' molar) of NaOH is 1.12 g mL . while in molality, the
−1

140 concentration of the solution is 3 m ( 3 molal). Then x is (Given : Molar mass of NaOH is
40 g/mol )

Option 1:
3.5

Option 2:
3.0

Option 3:
3.8

Option 4:
2.8

Correct Answer:
3.0

Solution:
1000 × M
Molality =
1000 × d − M × (Mw) solute

1000 × x
3 =
1000 × 1.12 − (x × 40)

x = 3

Hence, the answer is the option (2).

Q. For the solution of the gases, w,x,y and z in water at 298 K, the henry's law constants (KH) are
141 0.5,2,35 and 40 kbar, respectively. The correct plot for the given data is

Option 1:
 Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:
P gas = K H × mole f raction of gas

= K H × X gas = K H (1 − X H ) = KH − KH XH
2O 2O

P gas = KH − KH XH
2O

y = mx + c

m = −K H = slope is negative

Hence, the answer is the option (1).

Q. Molarity (M) of an aqueous solution containing xg of anhyd. CuSO in 500 mL solution at

142
4

32 C is 2 × 10 M. Its molality will be _________ m (nearest integer).

∘ −1 −3
×10

[Given density of the solution = 1.25 g/mL.]

Correct Answer:
81

Solution:
M soln n
=v sol 1 × d sol n

=500 × 1.25 = 625 g

Mass of solute (x) = 0.2 × 0.5 × 159.5

= 15.95

n solute = 0.1,

Mass of solvent = Mass of solution − Mass of solute

= 625 − 15.95

= 609.05

0.1
m =
609.05

1000

−3
m = 0.164 = 164 × 10

Hence, the answer is (81).

Q. Molality of an aqueous solution of urea is 4.44 m.

143 Mole fraction of urea in solution is x × 10 . −3

Value of x is (integer answer)

 Correct Answer:
74

Solution:
Molality of urea is 4.44 m, that means 4.44 moles of urea present in 1000gm of water

4.44
∴ X urea =
4.44 +
1000

18
.
= 0.0740

OR
−3
74 × 10

X = 74

Hence, the answer is (74).

Q. Molality (m) of 3M aqueous solution of NaCl is: (Given : Density of solution

144 = 1.25 g mL , Molar mass in gol : Na − 23, Cl − 35.5)
−1 −1

Option 1:
2.90 m

Option 2:
2.79 m

Option 3:
1.90 m

Option 4:
3.85 m

Correct Answer:
2.79 m

Solution:
3 moles are present in 1 litre solution
molality = 3×1000
= 2.79 m
1.25×1000−[3×58.5]

Hence, the answer is the option (2).

Q. Select the correct statement out of the following regarding a binary solution
145

Option 1:
Component which is present in excess is solute
 Option 2:
Component which is present in excess is solvent

Option 3:
In a solution , the physical state of the solute is retained .

Option 4:
In a solution , the physical state of the solvent is not retained .

Correct Answer:
Component which is present in excess is solvent
Solution:
In a solution , the species which is present in the same state as the solution is the solvent . In case both
species are in the same physical state , then the species present in excess is the solvent .

Hence, the answer is the option (2).

Q. The graph of vapour pressure and temperature for three different liquids X, Y, and Z is
146 shown below:

The following inferences are made:

(A) X has higher intermolecular interactions compared to Y.

(B) X has lower intermolecular interactions compared to Y

(C) Z has lower intermolecular interactions compared to Y

The correct inference(s) is /are :

Option 1:
(C)

Option 2:
(A)

Option 3:
(B)
 Option 4:
(A) and (C)

Correct Answer:
(B)
Solution:
Vaporizing starting means boiling started.

Given in the graph, at zero vapour pressure the boiling starting point.

So, the Order of B.P. is Z > Y > X

If the boiling point is low it will easily vaporize due to weak intermolecular force of attraction.

Order of Intermolecular Interaction: Z > Y > X.

the intermolecular force of attraction increases, the boiling point increases then vapour pressure
decreases.

So, X has lower intermolecular interactions compared to Y and Z

Hence, the answer is the option (3).

Q. 4.5 g of compound (MW = 90) was used to make 250 mL of its aqueous solution. The
147
molarity of the solution in M is x × 10 . The value of x is
−1
(Rounded to nearest
integer)

Option 1:
2

Option 2:
1

Option 3:
3

Option 4:
4

Correct Answer:
2

Solution:
Weight
Moles of A =
M.w

4.5 1
= = = 0.05
90 20
Volume (Lit) == 250

1000
= 0.250 lit

Weight
Moles of A =
M.w

4.5 1
= = = 0.05
90 20

Volume (Lit) == 250

1000
= 0.250 lit

Mole 0.05
Molarity (M ) = = = 0.2
( Lit)volume 0.250

mol
−1
= 2 × 10
Lit

x = 2

Hence, the answer is the option (1).

Q. The solubility of H S when expressed in terms of molality is 0.2 m at a pressure of 1 atm of

2
148 H S. The value of Henry's Constant for the dissolution of H S in water is
2 2

Option 1:
27.78 atm

Option 2:
277.8 atm

Option 3:
36 atm

Option 4:
360 atm

Correct Answer:
277.8 atm

Solution:
Molality = 0.2
0.2×18 −3
∴ Molef raction (X B ) = = 3.6 × 10
1000

P 1
∴ KH = = −3
= 277.8 atm
XB 3.6×10

Hence, the answer is the option (2).

 Q. Solubility of N at 298 K and partial pressure equal to 0.8 atm was found to be roughly
149
2

7 × 10 mollit
−4
. Assuming the density of water to be unaffected due to dissolution of N
−1
2

. Find the Henry's Constant for N . 2

Option 1:
2
3.2 × 10 atm

Option 2:
3
7.8 × 10 atm

Option 3:
4
6.4 × 10 atm

Option 4:
5
9.6 × 10 atm

Correct Answer:
4
6.4 × 10 atm

Solution:
Answer : (3)

Molarity of N 2 = 7 × 10
−4
∴ Moles of H 2O in 1 lit = 1000

18

−4
7×10 ×18 −5
∴ X N2 = = 1.26 × 10
1000

P 0.8 4
∴ KH = = −5
= 6.4 × 10 atm
XN 1.26×10
2

Hence, the answer is the option (3).

Q. Assertion (A): Elevation in boiling point is a colligative property.

150
Reason (R): Elevation in boiling point is directly proportional to molarity.

Option 1:
Both Assertion (A) and Reason (R) are correct statements, and
Reason (R) is the correct explanation of the Assertion (A).

Option 2:
Both Assertion (A) and Reason (R) are correct statements, but
Reason (R) is not the correct explanation of the Assertion (A).

Option 3:
Assertion (A) is correct, but Reason (R) is wrong statement.
 Option 4:
Assertion (A) is wrong, but Reason (R) is correct statement.

Correct Answer:
Assertion (A) is correct, but Reason (R) is wrong statement.
Solution:
Assertion (A): Elevation in boiling point is a colligative property.

Reason (R): Elevation in boiling point is directly proportional to morality, not molarity.

Assertion (A) is correct, but Reason (R) is wrong statement.

Hence, the answer is the option (3).

Q. 25 mL of an aqueous solution of KCl was found to require 20 mL of 1MAgNO solution

151
3

when titrated using K CrO as an indicator. What is the depression in freezing point of
2 4

KClsolutions of the given concentration? (Nearest integer).

(Given : K = 2.0 K kg mol )

f
−1

Assume 1) 100% ionization and

2) density of the aqueous solution as 1 g mL −1

Correct Answer:
3

Solution:

At equivalence point,

Mmole of KCl = mmole of AgNO 3 = 20 mmole

Volume of solution = 25ml

Mass of solution = 25gm

Mass of solvent = 25 − mass of solute

−3
= 25 − [20 × 10 × 74.5]

= 23.51gm

mole of KCl
Molality of KCl =
mass of solvent in kg

−3
20 × 10
= = 0.85
−3
23.51 × 10

i of KCl = 2(100% ionisation )

ΔT f = i × K f × m

= 2 × 2 × 0.85

= 3.4

≃ 3

Hence, the answer is (3).

 Q.
152

Correct Answer:
1

Solution:
ΔT f = i × K f × m

= (1) × 5.12 ×

Tf

Q.
153
(solution)

Option 1:
52

Option 2:
65

Option 3:
26

Option 4:
13

Correct Answer:
26

Solution:
Given,
C6 H6

C H freeze is ______
6 6

5.12 C/m.)
∘

10/58

200

= T K(

= 1.086 C
× 1000

solvent )

= 5.5 − 4.414

∘
∘
− ΔT f

≈ 1.09 C = 1 (nearest integer)

Hence, the answer is (1).

ΔT f =
5.12×50

58
= 4.414

boiling point by 0.3 0C. The molar mass of ‘X’ is [Kb=0.52K kg mol-1]

‘X’ dimerises in water to the extent of 80%.

2.5g of ‘X’ in 100g of water increases the boiling point by 0.3 0C.
⎥
freezes at 5.5 C. The temperature at which a solution of 10 g of C H in 200 g of
∘

⎦
4 10

C. (The molal freezing point depression constant of C H is

∘
6 6

Solute ‘X’ dimerises in water to the extent of 80%. 2.5g of ‘X’ in 100g of water increases the
Kb=0.52K kg mol-1

1
i = 1 + α( − 1)
n

1
i = 1 + 0.8 ( − 1)
2

i = 1 − 0.4 = 0.6

According to elevation in boiling point equation, we have

W 100
ΔT b = K b × × × i
m W

2.5 1000
0.3 = 0.52 × × × 0.6
m 100

therefore molar mass will be =

0.52 × 2.5 × 10 × 0.6

0.3

= 26

Hence, the answer is the option (3).

Q. When 9.45g of ClCH2COOH is added to 500mL of water, its freezing point drops by 0.5 C.
∘

154 The dissociation constant of ClCH2COOH is x × 10 . The value of x is _____(Rounded off to

−3

the nearest integer)

−1
[K f (H = 1.86Kkgmol ]
2 O)

Correct Answer:
35

Solution:
Hence, the answer is (35).

Q. When ' x ' ×10 mL methanol (molar mass = 32 g; density = 0.792 g/cm ) is added to
−2 3

155 100 mL water (density = 1 g/cm ), the following diagram is obtained.

3

x = ……......... . (nearest integer)

[Given: Molal freezing point depression constant of water at 273.15 K is 1.86 K kg mol
2 −1

]
 Correct Answer:
543

Solution:
ΔT f = 273.15 − 270.65 = 2.5 K

n
ΔT f = K f m ⇒ 2.5 = 1.86 ×
0.1

⇒ n = 0.1344 moles

⇒ w = 0.1344 × 32 = 4.3 g

4.3 −2
Volume = = 5.43ml = 543 × 10 ml
0.792

Hence, the answer is (5.43).

Q. The vapour pressures of pure liquids A and B are 400 and 600 mmHg , respectively at 298 K
156 . On mixing the two liquids, the sum of their initial volumes is equal to the volume of the final
mixture. The mole fraction of liquids B is 0.5 in the mixture. The vapour pressure of the final
solution, the mole fractions of components A and B in vapour phase, respectively are :

Option 1:
450mmHg, 0.5, 0.5

Option 2:
450mmHg, 0.4, 0.6

Option 3:
500mmHg, 0.4, 0.6

Option 4:
500mmHg, 0.5, 0.5

Correct Answer:
500mmHg, 0.4, 0.6

Solution:

Raoult's Law -

The partial pressure of any volatile constituents of a solution at a given temperature is equal to the
product of vapour pressure of pure constituent and its mole fraction in the solution.
0
PA = P xA
A

0
PB = PB xB
- wherein

P
0
A
and P 0
B
are vapour pressures of pure liquids.

PA and P are vapour pressures of A and B respectively.

B

o o
P A = 400mmHg P B = 600mmHg

X B = 0.5 X A = 0.5
o o
→ Ps = XA P + XB P = 0.5 × 400 + 0.5 × 600 = 500mmHg
A B
o o
PA = xA P = Y A P s ( f or vapour phase )
A

mole fraction of A in vapour phase

o
PA xA P
A 0.5×400
YA = = = = 0.4
PS Ps 500

Y B = 1 − 0.4 = 0.6

P s = 500mmHg Y A = 0.4 Y B = 0.6

Hence , the answer is the option (3).

 Q. For the compounds:
157 (A) H C − CH − O − CH − CH − CH
3 2 2 2 3

(B) H C − CH − CH − CH − CH
3 2 2 2 3

(C)

(D)

The increasing order of boiling point is : Choose the correct answer from the options given
below :

Option 1:
(A) < (B) < (C) < (D)

Option 2:
(B) < (A) < (C) < (D)

Option 3:
( D ) < (C) < (A) < (B)

Option 4:
(B) < (A) < (D) < (C)

Correct Answer:
(B) < (A) < (C) < (D)

Solution:
Compounds having same number of carbon atoms follow the boiling point order as:
(Boiling point ) > ( Boiling point )
Hydrogen bonding >high polanity

( Boiling point ) low polarity > ( Boiling point ) non polar

Hence, the answer is the option (2)

 Q. The vapour pressure vs. temperature curve for a solution solvent system is shown below:
158

The boiling point of the solvent is ________ ∘

C ?

Correct Answer:
82

Solution:
We know that the temperature at which the vapour pressure of a liquid becomes 1 atm . is called the
boiling point of the liquid.
we can clearly see that Graph I is for pure solvent whereas Graph II is for the solution. Hence the boiling
point of solvent and solution are 82 C and 83 C respectively.
∘ ∘

Boiling point of solvent is 82 ∘

C .

Hence , the answer is (82).

Q. A concentrated solution of lead nitrate in water can be stored in

159

Option 1:
an iron vessel

Option 2:
a copper vessel

Option 3:
a zinc vessel

Option 4:
a magnesium vessel
 Correct Answer:
a copper vessel
Solution:
Since Mg, Fe, Zn are more reactive than PbSO so it can displace Pb from their salt. So ' Cu is the only
4
′

metal which is less reactive than PbSO . 4

Hence, the answer is the option (2).

Q. Mass of Urea (NH CONH ) required to be dissolved in 1000 g of water in order to reduce
160
2 2

the vapour pressure of water by 25% is _____ g. (Nearest integer)

Given : Molar mass of N, C, O and H are 14, 12, 16 and 1 g mol −1

respectively.

Correct Answer:
1111

Solution:

25 moles of urea
=
1000
75 ( )
18

1 1000
× = moles of urea
3 18
1 1000
Mass of urea = × × 60
3 18

= 1111.11gm

Hence the answer is (1111).

Q. If a compound AB dissociates to the extent of 75% in an aqueous solution, the molality of

161 the solution which shows a 2.5 K rise in the boiling point of the solution is molal.
(Rounded-off to the nearest integer)
−1
[K b = 0.52K kg mol ]
 Correct Answer:
3

Solution:
+ −
AB → A + B

1 − α α α

α = 3/4

N = 2

i = [1 + (2 − 1)α]

2.5 = [1 + (2 − 1)3/4] × 0.52 × m

2.5 10
m = = = 2.747
0.52 × 7/4 3.64

m = 2.747 ≃ 3 mol/kg

Hence, the answer is (3)

Q. A mixture of 100 m mol of Ca(OH) and 2 g of sodium sulphate was dissolved in water and
2
162 the volume was made up to 100 mL . The mass of calcium sulphate formed and the
concentration of OH in resulting solution, respectively, are : (Molar mass of
−

Ca(OH) , Na SO and CaSO are 74, 143 and 136 g mol , respectively; K of
−1
2 2 4 4 sp

Ca(OH) is 5.5 × 10 . −6
2

Option 1:
−1
1.9 g, 0.28 mol L

Option 2:
−1
13.6 g, 0.28molL

Option 3:
−1
1.9 g, 0.14molL

Option 4:
−1
13.6 g, 0.14molL

Correct Answer:
−1
1.9 g, 0.28 mol L

Solution:
Given,

Mol of Na2SO4 = 2/142 = 14 m mol

Ca(OH) 2 + Na 2 SO 4 ⟶CaSO 4 + 2NaOH

mmol 100 14
Mass of CaSO 4
=
14×136

1000
= 1.9gm

Molarity of OH −
=
28

100
= 0.28 mol/L

Hence, the answer is the option (1).

Q. At 300 K the vapour pressures of two pure liquids. A and B are 100 and 500 mm Hg..
163 respectively. If in a mixture of A and B, the vapour pressure is 300 mm Hg, the mole fractions
of A in the liquid and in the vapour phase, respectively, are:

Option 1:
1/2 and 1/10

Option 2:
1/4 and 1/6

Option 3:
1/4 and 1/10

Option 4:
1/2 and 1/6

Correct Answer:
1/2 and 1/6

Solution:
0 0
P T = P A × A + P B (1 − X A )

0 0 0
300 = P × A + P − P X
A B B

0 0 0
300 = X A (P − P ) + P
A B B

300 = X A (−400) + 500

X A = 0.5
 PA = PT YA

YA = mole fraction in gaseous phase

1
PA = × 100
2

= 50

50 1
YA = =
300 6

Hence, the answer is the option (4).

Q. A solute A dimerizes in water. The boiling point of a 2 molal solution of A is 100.52 o

C . The
164 percentage associated of A is ______ (Rounded off to the nearest integer)

[ Use: K for water = 0.52KKgmol

b
−1

Boiling point of water = 100 o

C ]

Correct Answer:
100

Solution:

So,
Initial moles
i =
Final moles

1 − α + 1 − α + α
i =
1 + 1
α
i = 1 −
2

Now,
 0
ΔT b = T b − T
b

Δ T b = 100.52 − 100
∘
Δ T b = 0.52 C

∵ Δ Tb = i Kb × m

α
0.52 = (1 − ) × 0.52 × 2
2

So, α = 1

So, percentage association = 100%.

Ans = 100

Hence, the answer is (100).

Q. Molecules of benzoic acid (C H COOH) dimerize in benzene. 'w' g of the acid dissolved in
6 5
165 30 g of benzene shows a depression in freezing point equal to 2 K . If the percentage
association of the acid to form dimer in the solution is 80 , then w (in g ) is :
(Given that K = 5 K kg mol , Molar mass of benzoic acid = 122 g mol )
f
−1 −1

Correct Answer:
2.4

Solution:
Molecules of benzoic acid C6H5COOH dimerize in benzene.

So, the reaction will be :-

C6 H6

−
2 (C 6 H 5 − COOH) → (C 6 H 5 COOH)
2
30g

′
w g of the acid dissolved in 30 g of benzene shows a depression in the freezing point equal to 2 K .
So,

ΔT = 2K

Weight of solvent = 30 g = 30/1000 kg

−1
K f = 5 kg mol

weight of acid (Solute or benzoic acid) = w

mole of solute = w/122
w × 1000
molality (m) =
122 × 30
Now, the degree of association and van't hoff factor

nA → An n

Initial Moles: 1 mol

At equilibrium 1 − α

Total moles = 1 − α + α/n

i = 1 − α + α/n

i − 1
α =
1
− 1
n

Here, If the percentage association of the acid to form dimer in the solution is 80

means α = 80% = 0.8 and n = 2 (Dimer)

0.8
i = 1 − 0.8 + = 0.6
2

We know the formula

Δ f T = iK f m

After putting the values

w × 1000
2 = 0.6 × 5 ×
122 × 30

w = 2.44g

Hence, the answer is the option (1).

Q. The osmotic pressure of a solution of NaCl is 0.10 atm, and that of a glucose solution is 0.20
166 atm. The osmotic pressure of a solution formed by mixing 1L of the sodium chloride solution
with 2L of the glucose solution is x × 10 atm. x is _________ (nearest integer)
−3

Correct Answer:
167

Solution:
We know this formula.
πf vf = π1 v1 + π2 v2

π1 v1 + π2 v2
πf =
vf

0.1 × 1 + 0.2 × 2
πf =
3

0.5 500 −3
πf = = × 10
3 3

x = 167

------------------------------------------

Alternate Solution

Osmotic pressure = π = i × C × RT
For NaCli = 2 so

π NaCl = i × C NaCl × RT C NaCl = conc. of NaCl

0.1 = 2 × C NaCl × RT

0.05
C NaCl = C glucose = conc. of glucose
RT

For glucose i = 1 so

π Glucose = i × C glucose × RT

0.2 = 1 × C glucose × RT

0.2
C glucose =
RT

η NaCl = No . of moles NaCl

η NaCl in 1 L = C × V
NaCl = Litre
0.05

RT

η glucose = No. of moles glucose

η glucose in 2 L = C × V
glucose Litre
=
0.4

RT

Concentration = mole/volume

V Total = 1 + 2 = 3 L

0.05
so f inal conc. NaCl =
3RT

0.4
Final conc. glucose =
3RT

π Total = π NaCl + π glucose

= [i × C NaCl + C glucose ] × RT

2 × 0.05 0.4
= ( + ) × RT
3RT 3RT

0.5
= atm
3

= 0.1666 atm

−3
= 166.6 × 10 atm

−3
⇒ 167.00 × 10 atm

x = 167

Hence, the answer is (167).

 Q. The vapour pressure of pure benzene and methyl benzene at 27 C is given as 80Torr and ∘

167 24Torr, respectively. The mole fraction of methyl benzene in vapour phase, in equilibrium

with an equimolar mixture of those two liquids (ideal solution) at the same temperature is
________ ×10 (nearest integer)
−2

Correct Answer:
23

Solution:
P methylbenzene
X methylbenzene = 0.5Y methylbenzene =
P total

0.5×24
Y methylbenzene =
0.5×80+0.5×24

12 −2
= = 0.23 = 23 × 10
40+12

Hence , the answer is (23).

Q. A solution containing 10 g of an electrolyte AB in 100 g of water boils at 100.52

2
∘
C . The
168 degree of ionization of the electrolyte (α) is _______ ×10 . (nearest integer)
−1

[Given : Molar mass of AB = 200 g mol ⋅ K (molal boiling point elevation const. of
2
−1
b

water) = 0.52 K kg mol , boiling point of water = 100 C; AB ionises as

−1 ∘
2

2+ −
AB 2 → A + 2 B ]

Correct Answer:
5

Solution:
+2 ⊖
AB 2 → A + 2 B

i = 1 + (3 − 1)α

i = 1 + 2α

ΔT b = k b im

10

200
0.52 = 0.52(1 + 2α) 100

1000

10
1 = (1 + 2α)
20

2 = 1 + 2α

α = 0.5

Ans. α = 5 × 10 −1

Hence, the answer is (5).

 Q. Liquid A and B form an ideal solution. The vapour pressure of pure liquids A and B are 350
169 and 750 mm Hg respectively at the same temperature. If x and x are the mole fraction of
A B

A and B in solution while y A

and y are the mole fraction of A and B in vapour phase then
B

Option 1:
xA yA
<
xB yB

Option 2:
xA yA
=
xB yB

Option 3:
xA yA
>
xB yB

Option 4:
(x A − y A ) < (x B − y B )

Correct Answer:
xA yA
>
xB yB

Solution:
0 0
P = 350 mmHg P = 750 mmHg
A B

350x A 350x B
yA = yB =
PT PT

yA 350x A
=
yB 750x B
yA xA
⇒ <
yB xB

Hence, the correct answer is option (3).

Q. Which of the following graph correctly represents the plots of K at 1 bar gases in water
170
H

versus temperature ?

Option 1:
 Option 2:

Option 3:

Option 4:

Correct Answer:

Solution:
As temperature increases, solubility first decreases and then increases.

Hence K first increase than decrease, also at moderate temperature K value of He > N
H H 2
> CH 4 .
Hence, the correct answer is option (4).

Q. A solution is made by mixing one mole of volatile liquid A with 3 moles of volatile liquid B.
171 The vapour pressure of pure A is 200 mm Hg and that of the solution is 500 mm Hg. The
vapour pressure of pure B and the least volatile component of the solution, respectively, are
:

Option 1:
1400 mm Hg, A

Option 2:
1400 mm Hg, B

Option 3:
600 mm Hg, B

Option 4:
600 mm Hg, A

Correct Answer:
600 mm Hg, A

Solution:
Given

PS = 500

PA
∘
= 200
o o
PS = PA ⋅ XA + PB ⋅ XB

1 o
3
500 = 200 × + P ⋅
B
4 4
o
P B = 600 mmHg
As P o

A
< P
0
B
⇒ A is least volatile.

Hence, the correct answer is option (4).

Q. Given below are two statements :

172 Statement (I) : NaCl is added to the ice at 0 ∘
C , present in the ice cream box to prevent the
melting of ice cream.

Statement (II): On addition of NaCl to ice at 0 C, there is a depression in freezing point.

∘

In the light of the above statements, choose the correct answer from the options given
below :

Option 1:
Statement I is false but Statement II is true

Option 2:
Both Statement I and Statement II are true

Option 3:
Both Statement I and Statement II are false

Option 4:
Statement I is true but Statement II is false

Correct Answer:
Both Statement I and Statement II are true

Solution:
Statement 1

NaCl addition to ice causes preventing the melting of ice. On adding NaCl to ice, freezing point lowers.
This creates a colder mixture, preventing the ice cream from melting.

Melting point of ice is 0 C. When only ice is used to make ice cream, at 0 C ice starts melting by
∘ ∘

absorbing the energy from its environment in the form of heat. Addition of salt to ice while making the
cream lowers the freezing point of the ice, allowing it to reach a colder temperature and thus the ice
cream mixture freezes properly, So, the salt causes ice to melt at a lower temperature than pure ice.

Statement II:

Decrease in freezing point while addition of NaCl to ice at 0 ∘

C is due to the colligative property
depression in freezing point.

Both statements are correct

Hence, the correct answer is option (2).

 Q. If A Bis 30% ionised in an aqueous solution, then the value of van't Hoff factor (i) is __
173
2

×10 . −1

Correct Answer:
16

Solution:
2+ −
AB 2 ⇌ A + 2 B

1 0 0

1 − α α 2α

i = 1 + 2α

= 1 + 2 × (0.3)

= 1.6

−1
= 16 × 10

Hence, the answer is (16).

Q. 1.24 g of AX (molar mass 124 g mol ) is dissolved in 1 kg of water to form a solution

2
−1

174 with boiling point of 100.0156 C, while 25.4 g of AY (molar mass 250 g mol ) in 2 kg of
∘ −1
2

water constitutes a solution with a boiling point of 100.0260 C. ∘

−1
K b (H 2 O) = 0.52 K kg mol

Which of the following is correct?

Option 1:
AX and AY (both) are completely unionised.
2 2

Option 2:
AX and AY (both) are fully ionised.
2 2

Option 3:
AX is completely unionised while AY is fully ionised.
2 2

Option 4:
AX is fully ionised while AY is completely unionised.
2 2

Correct Answer:
AX is fully ionised while AY is completely unionised.
2 2

Solution:
For AX 2 : −ΔT b = K b × m × i

0.01
0.0156 = 0.52 × × i AX 2
1

⇒ i AX = 3 ⇒ complete ionisation
2

For AY 2 : −ΔT b = K b × m × i

0.026 = 0.52 × 0.0508 × i AY

2

⇒ i AY 2 ≃ 1 ∴ complete unionisation

Hence, the correct answer is option (4).

Q. ' x ' g of NaCl is added to water in a beaker with a lid. The temperature of the system is
175 raised from 1 C to 25 C. Which out of the following plots, is best suited for the change in
∘ ∘

the molarity (M) of the solution with respect to temperature ?

[Consider the solubility of NaCl remains unchanged over the temperature range]

Option 1:

Option 2:

Option 3:

Option 4:
 Correct Answer:

Solution:

The molarity first increases as temperature rises to 4 C, but then decreases as it continues to 25 C. The
∘ ∘

graphical representation of this relationship would exhibit an initial increase in molarity, followed by a
decrease, correlating with changes in the volume of water due to temperature variations.

Hence, the correct answer is option (2).

Q. Given below are two statements :

176
Statement (I) : Molal depression constant K is given by , where symbols have their
M 1 RT f

f
ΔS f us

usual meaning.
Statement (II) : K for benzene is less than the K for water.
f f

In the light of the above statements, choose the most appropriate answer from the options
given below :

Option 1:
Statement I is incorrect but Statement II is correct

Option 2:
Both Statement I and Statement II are incorrect

Option 3:
Both Statement I and Statement II are correct

Option 4:
Statement I is correct but Statement II is incorrect

Correct Answer:
Statement I is correct but Statement II is incorrect

Solution:
Statement-I
2

Molar depression constant k

M i RT
f
f =
ΔH f ius

M 1 RT f
kf =
ΔH f is
[ ]
Tf

M 1 RT f
kf =
Δ S f us

Hence statement-I is correct

but k for benzene = 5.12
∘
C
f
molal

k for water = 1.86 Hence statement- II is incorrect

∘
C
f
molal

Hence, the correct answer is option (4).

Q. At the sea level, the dry air mass percentage composition is given as nitrogen gas : 70.0,
177 oxygen gas : 27.0 and argon gas : 3.0. If total pressure is 1.15 atm , then calculate the ratio of
followings respectively :
(i) partial pressure of nitrogen gas to partial pressure of oxygen gas
(ii) partial pressure of oxygen gas to partial pressure of argon gas
(Given : Molar mass of N, O and Ar are 14, 16, and 40 g mol respectively)
1

Option 1:
4.26, 19.3

Option 2:
2.59, 11.85

Option 3:
5.46, 17.8

Option 4:
2.96, 11.2

Correct Answer:
2.96, 11.2

Solution:
PN x N ⋅P T nN

Po 2
2
=
2

x O ⋅P T
=
nO
2
{using Dalton's law of partial pressure}
2 2

70/28
= = 2.96
27/32

PO nO 27/32
i 3
= = = 11.25
P Ar n Ar 3/40

Hence, the correct answer is option (4).

 Q. The observed and normal masses of compound MX are 65.6 and 164 respectively. The
178
2

percent degree of ionisation of MX is ________ %. (Nearest integer)

2

Correct Answer:
75

Solution:
+2 −
MX 2 → M + 2X

normal molar mass

i =
observed molar mass

164
i =
65.6

164
1 + (3 − 1)α =
65.6

98.4
2α =
65.6

α = 0.75

percent dissociation = 75%

Ans. 75

Hence, the answer is (75).

Q. 2 moles each of ethylene glycol and glucose are dissolved in 500 g of water. The boiling point
179 of the resulting solution is
(Given : Ebullioscopic constant of water = 0.52 K kg mol )−1

Option 1:
379.2 K

Option 2:
377.3 K

Option 3:
375.3 K

Option 4:
277.3 K

Correct Answer:
377.3 K

Solution:
ΔT b = i 1 m 1 k b + i 2 m 2 k b

Each solute has 2 moles dissolved in 500 grams of water ( 0.5 kg ):

 2 moles −1
m1 = = 4 mol kg
0.5 kg

2 moles −1
m2 = = 4 mol kg
0.5 kg

Substitute into the Formula:

ΔT b = 1 ⋅ 4 ⋅ 0.52 + 1 ⋅ 4 ⋅ 0.52 = 4.16

The normal boiling point of water is 373.16 K .

Add the boiling point elevation to the normal boiling point:

T b ( solution ) = 373.16 + 4.16 = 377.3 K

Thus, the boiling point of the resulting solution is 377.3 K .

Hence, the correct answer is option (2).

Q. When a non-volatile solute is added to the solvent, the vapour pressure of the solvent
180 decreases by 10 mm of Hg . The mole fraction of the solute in the solution is 0.2 . What
would be the mole fraction of the solvent if decrease in vapour pressure is 20 mm of Hg ?

Option 1:
0.6

Option 2:
0.4

Option 3:
0.2

Option 4:
0.8

Correct Answer:
0.6

Solution:
∘
∵ P − P ∝ X solute

and ∵ 10 ∝ 0.2

∴ 20 ∝ 0.4

∴ X solvent = 1 − X solute

= 1 − 0.4

= 0.6

Hence, the correct answer is option (1).

 Q. The molarity of a 70% (mass / mass) aqueous solution of a monobasic acid (X) is _______
181 M (Nearest integer)
[Given : Density of aqueous solution of (X) is 1.25 g mL−1

Molar mass of the acid is 70 g mol ]

−1

Correct Answer:
12.5

Solution:
Moles of solute = 70

70
= 1

Assuming 100 gm solution contains 70 gm solute.

Volume of solution = 100
= 80 mL
1.25

1
M = × 1000 = 12.5
80
−1
M = 125 × 10

Hence, the answer is 12.5.

Q. When 1 g each of compounds AB and AB are dissolved in 15 g of water separately, they

2
182 increased the boiling point of water by 2.7 K and 1.5 K respectively. The atomic mass of A (in
amu) is _______ ×10 (Nearest integer)
−1

(Given : Molal boiling point elevation constant is 0.5 K kg mol )

−1

Correct Answer:
24.8

Solution:
For AB

ΔT b = 2.7

−1
K b = 0.5 K kg mol

ΔT b
m = = 5.4 m
Kb

For AB 2

ΔT b = 1.5 K

1.5
m = = 5.4 m
0.5

Moles of AB = 0.081 mol

Moles of AB 2
= 0.045 mol

Molar mass of AB = 12.35 g/mol

Molar mass of AB = 22.22 g/mol
2

Let atomic mass of A = a, B = b

a + b = 12.35

a + 2b = 22.22

On solving a = 2.48
−1
= 24.8 × 10

Hence, the answer is 24.8.

Q. The percentage dissociation of a salt (MX 3

) solution at given temperature (van't Hoff factor
183 i = 2) is__________% (Nearest integer)

Correct Answer:
33%

Solution:
+3 −
MX 3 → M + 3X

i = 1 + (n − 1)α

i = 1 + (4 − 1)α = 2

1
α = = 33.33% ≈ 33%
3

Hence, the answer is 33%.

Q. 20 mL of sodium iodide solution gave 4.74 g silver iodide when treated with excess of silver
184 nitrate solution. The molarity of the sodium iodide solution is ________ M. (Nearest Integer
value)
(Given : Na = 23, I = 127, Ag = 108, N = 14, O = 16 g mol ) −1

Correct Answer:
1

Solution:
Let molarity of Nal solution be ×M
NaI + AgNO 3 → AgI + NaNO 3

This is a 1:1 molar reaction — 1 mole of NaI gives 1 mole of AgI.

Moles of AgI = 4.74
≈ 0.02017 mol
235

So, moles of Nal = moles of Agl = 0. 02017 mol

Step 3: Use molarity formula

moles 0.02017
Molarity = = ≈ 1.0085M
volume in L 0.020

Hence, the answer is 1.

Q. HA(aq) ⇌ H
+
(aq) + A
−
(aq)
185
The freezing point depression of a 0.1 m aqueous solution of a monobasic weak acid HA is
0.20 C. The dissociation constant for the acid is
∘

Given :
K (H O) = 1.8 K kg mol
f 2 , molality ≡ molarity
−1

Option 1:
−3
1.38 × 10

Option 2:
−2
1.1 × 10

Option 3:
−3
1.90 × 10

Option 4:
−1
1.89 × 10

Correct Answer:
−3
1.38 × 10

Solution:
ΔT f = iK f m

ΔT f
i =
Kf ⋅ m

0.20
i = = 1.11
1.8 × 0.1

i = 1.11

i − 1
α = ( f or HA, n = 2)
n − 1

1.11 − 1
α = = 0.11
1
2 2
cα 0.1 × (0.11)
−3
Ka = = = 1.38 × 10
1 − α 1 − 0.11
Hence, the correct answer is option (1).

Q. Arrange the following solutions in order of their increasing boiling points.

186 (i) 10 MNaCl
−4

(ii) 10 M U rea
−4

(iii) 10 MNaCl
−3

(iv) 10 MNaCl
−2

Option 1:
(ii)<(i)<(iii)<(iv)

Option 2:
(ii)<(i)≅(iii)<(iv)

Option 3:
(i)<(ii)<(iii),(iv)

Option 4:
(iv)<(iii)<(i)<(ii)

Correct Answer:
(ii)<(i)<(iii)<(iv)

Solution:
.
ΔT b = iK b , m. ∝ i. C

where C = concentration

Let's find effective particle concentration, i ⋅ m, for each:

1.
−4
(i) 10 MNaCl
+ −
NaCl → Na + Cl ⇒ i = 2

−4 −4
i ⋅ m = 2 ⋅ 10 = 2 × 10

2.
(ii) 10 −4
M Urea

Urea is a non-electrolyte → does not dissociate

i = 1

−4 −4
i ⋅ m = 1 ⋅ 10 = 1 × 10

3.
−3
(iii) 10 MNaCl

i = 2

−3 −3
i ⋅ m = 2 ⋅ 10 = 2 × 10

4.
 −2
(iv) 10 MNaCl

i = 2

−2 −2
i ⋅ m = 2 ⋅ 10 = 2 × 10

Option i.C.
(i) 2 × 10
−
4

(ii) 1 × 10
−
4

(iii) 2 × 10
−
3

(iv) 2 × 10
−
2

B.P. order :
(ii) < (i) < (iii) < (iv)

Hence, the correct answer is option (1).

Q. Consider the given plots of vapour pressure (VP) vs temperature (T/K) Which amongst the
187 following options is correct graphical representation showing ΔTf, depression in the freezing
point of solvent in a solution ?

Option 1:

Option 2:
 Option 3:

Option 4:

Correct Answer:

Solution:
On adding non-volatile solute in a solvent, the freezing point of solution decreases.
0
Tf < T
f

F.P. of solution < F.P. of pure solvent

Also V.P. of solution decreases on adding nonvolatile solute in a solvent.

Hence, the correct answer is option (3)

 Q. What is the freezing point depression constant of a solvent, 50 g of which contain 1 g non
188 volatile solute (molar mass 256 g mol ) and the decrease in freezing point is 0.40 K ?
−1

Option 1:
−1
5.12 K kg mol

Option 2:
−1
4.43 K kg mol

Option 3:
−1
1.86 K kg mol

Option 4:
−1
3.72 K kg mol

Correct Answer:
−1
5.12 K kg mol

Solution:
Freezing point depression:

ΔT f = K f ⋅ m

Given:
The decrease in freezing point ΔT is 0.40 K . f

The mass of the solute is 1 g and its molar mass is 256 g/mol.
The mass of the solvent is 50 g (or 0.050 kg ).
Moles of solute = =
1 g

256 g/mol
mol
1

256

1
mol
256 1
m = = mol/kg
0.050 kg 256×0.050

Now, substitute into the formula to find K : f

1
0.4 = K f ⋅
256×0.050

Solving for K : f

K f = 0.4 ⋅ 256 × 0.050 = 5.12 K kg/mol

Thus, the freezing point depression constant of the solvent is 5.12 K kg/mol.

Hence, the correct answer is option (1).

 Q. XY is the membrane / partition between two chambers 1 and 2 containing sugar solutions
189 of concentration c and c (c > c )molL . For the reverse osmosis to take place identify
−1
1 2 1 2

the correct condition

(Here p and p are pressures applied on chamber 1 and 2)
1 2

(A) Membrane/Partition ; Cellophane, p > π

1

(B) Membrane/Partition ; Porous. p > π

2

(C) Membrane/Partition ; Parchment paper, p 1

> π

(D) Membrane/Partition : Cellophane, p > π

2

Choose the correct answer from the option given below :

Option 1:
B and D only

Option 2:
A and D only

Option 3:
A and C only

Option 4:
C only

Correct Answer:
A and C only

Solution:

Normal osmosis occurs from (2) to (1)

For reverse osmosis from (1) to (2)
Pressure : P > π
1

∴ Answer [A & C] only

Hence, the correct answer is option (3).

 Q. Match List-I with List-II
190

List - I List - II

(A) Solution of chloroform and (I) Minimum boiling

acetone azeotrope

(B) Solution of ethanol and water (II) Dimerizes

(C) Solution of benzene and (III) Maximum boiling

toluene azeotrope

(D) Solution of acetic acid in (IV) ΔV mix = 0

benzene
Choose the correct answer from the options given below :

Option 1:
(A)-(III), (B)-(I), (C)-(IV), (D)-(II)

Option 2:
(A)-(II), (B)-(IV), (C)-(I), (D)-(III)

Option 3:
(A)-(III), (B)-(IV), (C)-(I), (D)-(II)

Option 4:
(A)-(II), (B)-(I), (C)-(IV), (D)-(III)

Correct Answer:
(A)-(III), (B)-(I), (C)-(IV), (D)-(II)

Solution:
Acetone + chloroform shows negative deviation and forms maximum boiling point azeotrope. Ethanol
and water show positive deviation and form minimum boiling point azeotrope.

Benzene + toluene ⇒ Ideal solution

Hence, ΔV mix
= 0

Acetic acid will dimerise in benzene.

Hence, the correct answer is option (1).

Q. Which of the following binary mixture does not show the behaviour of minimum boiling
191 azeotropes ?

Option 1:
H 2 O + CH 3 COC 2 H 5
 Option 2:
C 6 H 5 OH + C 6 H 5 NH 2

Option 3:
CS 2 + CH 3 COCH 3

Option 4:
CH 3 OH + CHCl 3

Correct Answer:
C 6 H 5 OH + C 6 H 5 NH 2

Solution:
The solution showing positive deviation from Raoult's law will form a minimum boiling azeotrope. Phenol
+ Aniline shows negative deviation, so they will not form a minimum boiling azeotrope.

A binary mixture of C H OH and C H NH exhibits negative deviation from Raoult's law. This means
6 5 6 5 2

that the vapor pressure of the solution is lower than the vapor pressures of the pure components,
C H OH and C H NH . Consequently, the boiling point of the solution is higher than the boiling
6 5 6 5 2

points of the pure substances. Therefore, this mixture forms a maximum boiling azeotrope.

Hence, the correct answer is option (2).

Q. Consider a binary solution of two volatile liquid components 1 and 2x and y are the mole
1 1
192 fractions of component 1 in liquid and vapour phase, respectively. The slope and intercept of
the linear plot of vs are given respectively as :
1

x1
1

y1

Option 1:
0 0 0
P P −P
1 2 1

0
, 0
P P
2 2

Option 2:
0 0 0
P P −P
2 1 2
0 , 0
P P
1 2

Option 3:
0 0 0
P P −P
1 1 2

0
, 0
P P
2 2

Option 4:
0 0 0
P P −P
2 2 1

0
, 0
P P
1 2

Correct Answer:
0 0 0
P P −P
1 2 1
0 , 0
P P
2 2
Solution:
∵ For the liquid solution of two liquids ' 1 ' and ' 2 '

where P1 and P2 are the vapor pressure of liquids 1 and 2, and P1o and P2o are the pure component
vapor pressure of component liquids 1, and 2, respectively at the given temperature.
∘
P1 = PT y1 = P1 x1
∘
PT P
1
∴ =
x1 y1
∘ ∘ ∘ ∘
P + x 1 (P − P ) P
2 1 2 1
∴ =
x1 y1

∘ ∘
P2 ∘ ∘
P1
∴ + (P 1 − P 2 ) =
x1 y1
∘ ∘ ∘
1 P 1 P − P
1 2 1
∴ = ( )( ) + ( )
∘ ∘
x1 P y1 P
2 2
∘
P1
∴ Slope = ( )
∘
P
2
∘ ∘
P2 − P1
∴ Intercept = ( )
∘
P
2

Hence, the correct answer is option (1).

Q. CrCl 3 ⋅ xNH 3 can exist as a complex. 0.1 molal aqueous solution of this complex shows a
193 depression in freezing point of 0.558 C. Assuming 100% ionisation of this complex and
∘

coordination number of Cr is 6 , the complex will be (Given K = 1.86 K kg mol ) f

−1

Option 1:
[Cr(NH 3 ) ]Cl 3
6

Option 2:
[Cr(NH 3 ) Cl 2 ]Cl
4

Option 3:
[Cr(NH 3 ) Cl]Cl 2
5

Option 4:
[Cr(NH 3 ) Cl 3 ]
3

Correct Answer:
[Cr(NH 3 ) Cl]Cl 2
5

Solution:
Given : ΔT f = 0.558 C
∘
 K × kg
k f = 1.86
mol

0.1 m aq. sol.

⇒ΔT f = i × k f × m

⇒0.558 = i × 1.86 × 0.1

⇒i = 3

The van 't Hoff factor i = 3 indicates that the complex ionizes into three particles in solution. Given the
coordination number of Cr is 6 , we analyze the possible complexes:

[Cr(NH 3 ) Cl]Cl 2
5

[Cr(NH 3 ) 4 Cl 2 ]Cl

[Cr(NH 3 ) ]Cl 3
6

[Cr(NH 3 ) Cl 3 ]
3

The complex that gives three ions upon dissociation could be [Cr(NH 3
) Cl]Cl 2
5
. This is because the
complex will dissociate as:
2+ −
[Cr(NH 3 ) Cl] + 2Cl
5

This results in three ions total, matching the van 't Hoff factor i = 3.
Therefore, the complex is [Cr(NH ) Cl]Cl .
3 5 2

Hence, the correct answer is option (3).

Q. Assume a living cell with 0.9%(ω/ω) of glucose solution (aqueous). This cell is immersed in
194 another solution having equal mole fraction of glucose and water.
(Consider the data upto first decimal place only)
The cell will :

Option 1:
(1) shrink since soluton is 0.5%(ω/ω)

Option 2:
shrink since solution is 0.45%(ω/ω) as a result of association of glucose molecules (due to hydrogen
bonding)

Option 3:
swell up since solution is 1%(ω/ω)

Option 4:
Show no change in volume since solution is 0.9%(ω/ω)

Correct Answer:
Show no change in volume since solution is 0.9%(ω/ω)
Solution:
Living cell has 0.9 g glucose in 100 g solution.
Which is dipped in a solution with X =
H2 O
1

2
.

Molecular mass of Glucose = 180

Molecular mass of water = 18

Weight of solution = × 180 + × 18 = 99 g.
1

2
1

So, the solution has 90 g glucose in 99 g solution or %w/w = 90.9%

Concentrated solution =Cell will shrink.