17-11-2025

1001CJA101016250032 JA

PART-1 : PHYSICS

SECTION-I (i)

1) A tank full of water has a small hole at the bottom. If one-fourth of the tank is emptied in t1

seconds and the remaining three-fourths of the tank is emptied in t2 seconds. Then the ratio is

(A)
(B)

(C)

(D)

2) Two identical soap bubbles, each of radius x, coalesce to form a bubble of radius y. If P be the
atmospheric pressure, and assuming that the process is isothermal, what is the surface tension of
soap solution? (No air comes from outside).

(A)

(B)

(C)

(D)

3) Two different adiabatic paths for the same gas intersect two isothermal curves as shown in P-V

diagram. The relation between the ratio and the ratio is:
(A)

(B)

(C)

(D)

4) A uniform thin rod of length 2ℓ and mass m can rotate in a horizontal plane about a vertical

hinged axis through its centre. The rod is at rest when a small bullet of mass travelling in the
rotation plane is fired into one end of the rod. As shown in the figure, the bullet's path makes angle θ
= 60° with the rod. If the bullet lodges in the rod and the angular velocity of the rod is ω
immediately after the collision, what is the bullet's speed just before impact?

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) A set of n-identical cubical blocks lies at rest along a line on a smooth horizontal surface. The
separation between any two adjacent blocks is L. The block at one end is given a speed V towards
the next one at time t = 0. All collisions are completely inelastic, then :-

The last block starts moving at t = n (n – 1)

(A)

The last block starts moving at t = (n – 1)

(B)

(C) The centre of mass of the system will have a final speed V/n
(D) The centre of mass of the system will have a final speed V

2) The wires A and B shown in the figure are made of the same material, and have radii rA and
rB respectively. The block between them has a mass m. When the force F is mg/3, one of the wires

breaks–

(A) A will break before B if rA = rB

(B) A will break before B if rA < 2rB
(C) Either A or B may break if rA = 2rB
(D) The lengths of A and B must be known to predict which wire will break

3) Potential energy function along x-axis in a certain free field is given as

For the given free field,

(A) the points of equilibrium are x = 1, x = 2 and x = 3

(B) the point x = 2 is a point of unstable equilibrium
(C) the points x = 1 and x = 3 are points of stable equilibrium
(D) there exists no point of neutral equilibrium

4) In a situation, a board is moving with a velocity v with respect to earth, while a man A and man B
are running with a velocity 2v with respect to earth and both men are running from the opposite
ends of the board at the same time, as shown. Length of the board is L. If they meet after time T,

then

(A) Value of T is L/4 v

(B) Value of T is L/2 v
(C) Displacement of man B with respect to board in time T is 3L/4
(D) Displacement of man A with respect to board in time T is L/4

SECTION-II

1) A golfer standing on the ground hits a ball with a velocity of 52 m/s at an angle θ above the
horizontal if . Find the time in s for which the ball is at least 15 m about the ground (g =
10 m/s2)

2) A block of mass 10 kg is placed on rough inclined plane as shown in figure. Then friction force on
block is 20k. Find k. (Friction coefficient between the block and inclined surface = 0.8 ) [Take g = 10

m/s2]

3) A small sphere is given vertical velocity of magnitude u = 5 m/s and it swings in a vertical plane

about the end of a massless string. The angle with the vertical at which string will
break, knowing that it can with stand a maximum tension equal to twice the weight of the sphere.

Find value of P [Take g = 10 m/s2 ].

4) A spherical block body at absolute temperature T is surrounded by a thin spherical and concentric
shell of radius R, black on both sides. Surrounding temperature is constant T0. Find the ratio of rate
of energy loss by black body before and after it is surrounded by spherical shell, consider the space
between shell and black body is evacuated with no conduction loss (given R = 2m, r = 1m)

5) A cylinder fitted with piston as shown in figure. The cylinder is filled with water and is taken to a
place where there is no gravity. Mass of the piston is 50 kg. The system is accelerated with
acceleration 0.5 m/sec2 in positive x–direction. Find the force exerted by fluid on the surface AB of
the cylinder in decanewton. Take area of cross–section of cylinder to be 0.01 m2 neglect atmospheric

pressure (1 decanewton =10 N)

6) A disc of mass 4kg and radius 6 metre is free to rotate in horizontal plane about a vertical fixed
axis passing through its centre. There is a smooth groove along the diameter of the disc and two
small balls of mass 2kg each are placed in it on either side of the centre of the disc as shown in
figure. The disc is given initial angular velocity ω0 = 12 rad/sec released. Find the angular speed of
disc (in radian/sec) when the balls reach the ends to disc.

7) In the given equation ; t is time and v velocity . If dimensional formula of y is Mx

y z
L T then value of x + 2y + z is equal to

8) Initially spring is relaxed when m1 is released from rest. Calculate for what minimum value of m1

the block of mass m will just leave the contact with surface ? Give answer in terms of .

PART-2 : CHEMISTRY

SECTION-I (i)

1) The diffusion coefficient of an ideal gas is proportional to its mean free path and mean speed. The
absolute temperature of an ideal gas is increased 4 times and its pressure is increased 2 times. As a
result, the diffusion coefficient of this gas increases x times. The value of x is

(A)

(B) 2
(C) 4
(D) 8

2) The correct stability order of following carbocations will be-

(a) (b)
(c) (d)

(A) a > c > d > b

(B) a > d > c > b
(C) b > c > d > a
(D) d > c > a > b

3) Which of the following molecules contains the least basic nitrogen atom ?

(A)

(B)

(C)

(D)

4) With in each pair of elements of F & C, N & P, and Li & Na, respectively, the elements that
release more energy upon an electron gain are -

(A) F, N and Na
(B) C,P and Li
(C) F, P and Li
(D) C, N and Na

SECTION-I (ii)

1) The dissociation of phosgene, which occurs according to the reaction COCl2 (g) ⇌ CO(g) + Cl2(g)
is an endothermic process .Which of the following will increase the degree of dissociation of COCl2?

(A) Adding Cl2 to the system

(B) Adding helium to the system at constant pressure
(C) Decreasing the temperature of the system
(D) Reducing the total pressure

2) In which of following options both species are aromatic ?

(A)
&

(B)

&

(C)

&

(D)

&

3) Which of the following statement is CORRECT -

(A) XeF6 having perfect octahedral structure

(B) XeF2 & XeF4 are non polar
(C) XeF2 & XeF4 are planar
(D) PH5 does not exist

4) Identify the correct statement :-

(A) The electron gain enthalpy (ΔHeg) for an isolated gaseous anion is always positive
(B) Electronegativity of Sulphur is greater than phosphorous
(C) The number of electrons having ℓ = 2 in La(Z = 57) is equal to 21
(D) IE2 (Mg) < IE2(Aℓ)

SECTION-II

1) For a gas phase reaction at equilibrium, N2(g) + 3H2(g) ⇌ 2NH3(g), the partial pressure of N2(g)
and H2(g) are 0.8 and 0.4 atm respectively. The total pressure of the entire system is 2.8 atm. What
will be KP (in atm–2).

2) A 10 gm sample of NaCN is dissolved in 50 ml of 0.3 M mild alkaline solution of KMnO4 and

heated strongly to convert all CN– to OCN–. The left solution is then acidified with H2SO4 which
require 500 ml of 0.05 M FeSO4. The percentage purity of NaCN in sample is ?
3) A naturally occuring uranium ore contain D2 and CH4 in 1: 8 mole ratio. If it is desired to enrich
the D2 to 80% of the sample (by moles) making use of relative rates of effusion of D2 and CH4
isotopes. How many minimum effusion steps are required.

4) The distance between the two radial nodes is d Å for the given orbital of H-atom whose wave
function is given as

Ψ=

0
where a and z are constants and ,find value of 'd' ?

5) How many given molecules are chiral and show geometrical isomerism?

(a) (b)

(c) Cl–CH=C=CH-Cl (d)

(e) (f)

(g) (h)

6) How many of the following statements are correct regarding separation techniques?
(a) Crystallisation is based on solubility of compounds.
(b) Column and thin layer chromatographic techniques are based on the principle of differential
adsorption.

(c) Rf =
(d) Distillation under reduced pressure is used to separate for such liquids which decompose at or
below their boiling points.
(e) Lassaigne's test is used to detect oxygen and carbon in the organic sample.
(f) The sodium fusion extract is acidified with HNO3 before testing the halogen to remove the
impurity of cyanide or sulphide of sodium.

7) Consider melamine molecule

If (A) Number of sp hybrid orbitals are x
(B) Number of lone pairs in a molecule are y
(C) Number of 2pπ-2pπ bonds are z
Calculate the value of x + y + z

8) How many of the following has hydrogen bonding

(a) NH3 (b) CH4 (c) H2O

(d) HI (e) HF (f) HCOOH
(g) B(OH)3 (h) CH3COOH
(i) HCO3– ion

PART-3 : MATHEMATICS

SECTION-I (i)

1) Let A = {(x,y) : y = mx + 1}
B = {(x,y) : x2 + 4y2 = 1}
C = {(α,β) : (α,β) ∈ A and (α,β) ∈ B and α > 0}. If set C is singleton set then sum of all possible
values of m is

(A) 0

(B)

(C)

(D) none of these

2) If area of quadrilateral formed by tangents drawn at ends of latus rectum of hyperbola

is equal to square of distance between centre and one focus of hyperbola, then e3 is (e is
eccentricity of hyperbola)

(A)
(B) 2
(C) 3
(D) 8

3) Consider permutation of the all the letters of the word "MAKRANA" then which of the following
statement is INCORRECT ?

(A) Total number of permutation is 840

(B) Total numbers of permutation which contains KARAN is 6
(C) Total number of permutation in which all A's lies some where between R and N is 96
(D) Total number of permutation in which all A's are consecutive are 120

4) The coefficient of x18 in the expansion of (1 + x)20 + x(1 + x)19 + x2(1 + x)18 + ... + x18(1 + x)2 is
(A) 1352
(B) 1330
(C) 1872
(D) 1430

SECTION-I (ii)

1) Let tangents PA & PB are drawn from variable point P on the parabola y2 = 4x to the circle x2 + y2
+ 10x – 4y + 25 = 0, then locus of circumcentre of ΔPAB

(A) is a parabola

(B)
is satisfied by point
(C) never cuts y-axis
(D) intersect x-axis.

2) The sum of first n terms (n > 2) of an A.P. is 77 and common difference is 2. If the first term is an
integer, then-

(A) number of possible values of n is 4.

(B) number of possible values of n is 3.
(C) first term of given A.P. can be 5.
(D) first term of given A.P. can be –3.

3) A circle of radius 4 cm is inscribed in a triangle ABC, which touches the side BC at D. If BD = 6

cm, DC = 8 cm, then

(A) the triangle is necessarily acute angled

(B)

(C) perimeter of the triangle is 42 cm

(D) area of the triangle is 84 cm2

4) If 'N' denotes number of ways in which 15 identical coins can be distributed among A, B, C, D
such that Mr. 'A' must get atleast '2' coins and Mr. D must get atleast '4' coins, then

(A) Number of divisors of '2N' are '16'

(B) Number of divisors of '2N' are '18'
(C) Number of even divisors of '2N' are '12'
(D) Number of divisors of '2N' which are divisible by 2 but not divisible by 5 are '6'

SECTION-II

1) All the letters of the word 'HUDHUD' are written in all possible orders and these words are
written out as in a dictionary. If the rank of the word 'DUHDUH' is 'N', then sum of digits of 'N' is
2) Let a,b,c ∈ R such that |a – b| = 1, |b – c| = 1, |c – a| = 2 and abc = 60,

if , (where a, b, c ≠ 0), then the value of 20S is equal to

3) Number of solutions of the equation in x ∈ [0, 2π] is equal to

4) If a, 2b, c are distinct numbers in A.P. and line ax + by + c = 0 always passes through a fixed
point (p, q), then value of |p + 2q| is

5) A circle S = 0 passes through points of intersection of circles x2 + y2 – 2x + 4y – 1 = 0 and x2 + y2

+ 4x – 2y – 5 = 0 and cuts the circle x2 + y2 = 4 orthogonally. Then length of tangent from origin on
circle S = 0 is

6) Number of 7 digit numbers in which first four digits are in ascending order and last four digits are
in descending order and middle digit is a perfect square, is N, then unit's digit of N is

7) If N is number of pairs of two divisors of 75600 such that product of these divisors is 60480, then

the value of is

8) If N denotes total number of permutations (taken all at a time) of the letters of the word 'LALAJI'

such that no two alike letters are together then the value of is
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. D C C A

SECTION-I (ii)

Q. 5 6 7 8
A. A,C A,B,C A,B,C,D A,C,D

SECTION-II

Q. 9 10 11 12 13 14 15 16
A. 2.00 3.00 4.00 1.25 5.00 4.00 0.00 2.00

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 17 18 19 20
A. C A B C

SECTION-I (ii)

Q. 21 22 23 24
A. B,D B,D B,C,D A,B,C,D

SECTION-II

Q. 25 26 27 28 29 30 31 32
A. 50.00 7.35 5.00 1.58 or 1.59 4.00 4.00 9.00 7.00

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 33 34 35 36
A. C B C B

SECTION-I (ii)

Q. 37 38 39 40
A. A,B,D B,C,D A,B,C,D A,C,D
 SECTION-II

Q. 41 42 43 44 45 46 47 48
A. 5.00 1.00 4.00 7.00 2.00 8.00 2.00 6.00
 SOLUTIONS

PART-1 : PHYSICS

1) Question Explanation:
We need to compare the time of emptying the initial one fourth of tank and remaining part of
tank.

Concept:
This question is based on Bernoulli's equation.

Solution:

t1 = =

t2 =

Final Answer:
The correct option is (4).

2) Question Explanation:
It is asked to find the surface tension of soap solution.

Concept:
This question is based on surface tension.

Solution:
Radius of combined bubble = y
no. of moles constant

Initially pressure

Final pressure ( T surface tension)

as temp. same

Final Answer:
The correct option is (3)

3) For adiabatic process

TVγ–1 = constant

4) Apply angular momentum conservation.

L1 = L2

5)

mv = nv′ m ⇒ v′ =

time for first collision is t1 =

2nd collisions t2 = = 2t1

so t = t1 + 2t1 + 3t1 + at1 ...........(n–1) t1.
t = t1 [1 + 2 + 3] .......................(n–1)]

= =

so t = n (n – 1)

6)

Explaining the Question :-

Two wire A + B are made of the same material and have radii rA and rB. The block between
them as a mass m. When the force F is mg/3, then we need to compare the breaking conditions
for different radii.
Concept:- This question is based on Stress, strain, breaking force.
Solution :-
When force F = mg/3 is applied at the lower end then

stress in wire B = and

Stress in wire
(i) If rA = rB = r (let), then

Stress in wire B = and

stress in wire A =
i.e. stress in wire A > stress in wire B
So, the wire A will break before B.
(ii) If rB = r1 (let), then rA = 2r

Stress in wire B = and stress in wire A =

i.e. stress in wire A = stress in wire B. It means either A or B may break.
(iii) If rA < 2rB then stress in wire A will be more than B.
i.e. A will break before B.
Final Answer :- (1), (2) & (3)

7) Explanation Question: We are given a potential energy as a function of position we have

to comment the type of equilibrium.
Concept: Conmment the type of equilibrium
Solution:
For equilibrium points,

∴ Final answer = option 1,2,3 and 4

8)
At the plane VAB = 4V

9)

10) As angle of inclined less than angle of repose

so block will not move.

Hence friction force f = mg sin θ.

11)

T = mg

P=4

12)

Rate of energy loss by block body E1 = σ4πr2 (T4 – T04)

When block body is enclosed by spherical shell, let temp of shell is T1
E2 = σ4πr2 (T4 – T14)
Also σ4πr2 (T4 – T14) = σ4πR2 (T14 – T04)
 = 1.25

13)

Force due to piston = 50 × 0.5 = 25 N

There due to fluid = (ρah) A=A (1000 × 5 × 0.5) = 2500 Pa × 0.01 m2 = 25 N
There on the surface AB = 50N = 5 decanewton

14) Since τnet external = 0

is conserved
∴ Li = Lf

∴ ωf = = 4 rad/s

15) = dimensionless; ;

Value of x + 2y + z ⇒ 0 + 2 –2 ⇒ 0

16)
PART-2 : CHEMISTRY

17)

D ∝ λ × vavg

Vavg ∝

so D ∝

⇒ so D2 = 4D1

18) Correct stability order is a > c > d > b

(a) (Stable through + M effect of oxygen)

(b) (Unstable due to –I of C = O group)

(c) (Stable through resonance with phenyl group)

(d) (Stable through hyperconjugation, α–H = 4)

19) In option B the lone pair on the nitrogen atom between two C = O groups is delocalised
into the both adjacent C = O. This delocalisation significantly reduces the availability of the
lone pair, making this nitrogen the least basic among all the options.

20)

The correct answer is option (C)

21) Apply Le–chatalier's principle.

22) (B) &

(D) &

23)

The correct answer is option (B),(C),(D)

24)

The correct answer is option (A),(B),(C),(D)

25) N2(g) + 3H2(g) ⇌ 2NH3(g)

at eqm 0.8 atm 0.4 atm (2.8 – 0.8 – 0.4)
= 1.6 atm

KP = = 50 atm–2

26) For II titration

Equivalents of FeSO4 = Equivalents of KMnO4 (in acidic medium)

0.05 × ×1=

Used
Total millimoles of KMnO4 initially taken = 15,
so millimoles of KMnO4 used in I titration = 15 – 5 = 10
For I titration
Equivalents of NaCN = Equivalents of KMnO4 (in basic medium)
nNaCN × 2 = 10 × 10–3 × 3
nNaCN = 15 × 10–3
 % NaCN = = 7.35

27)

n=5

28) σ2 – 4σ + 3 = 0 , σ = 3 , 1
n–ℓ–1=2
ℓ=0
n=3

, (Z = 1)

r= ,

r – r1 =
⇒ 3 × a0 = 3 × 0.529Å
⇒ 1.587 Å = d

29) Molecules b, e, f and g are chiral and show geometrical isomerism.

Molecules a, c and d are chiral and donot show geometrical isomerism, while molecules (h) is
achiral but shows geometrical isomerism

30) Statement a, b, d and f are correct.

Statement c and e are wrong.

31) x = 0 , y = 6 , z = 3

32) NH3, H2O, HF, HCOOH, B(OH)3, CH3COOH, HCO3– ion

PART-3 : MATHEMATICS

33) y = mx + 1 is tangent to ellipse

x2 + 4y2 = 1 in Ist quadrant ∴ m < 0
∴ 1 = m2 +

or
(reject)

34) ends of L.R

35) (A)
(B) ⇒
(C)
(D)

36) Coefficient of x18 in

⇒ (1 + x)21 – (1 + x)2 x19
coefficient of x18 is 21C18

37) Middle point is

2h = (k – 1)2 – 5
2h + 4 = k2 – 2k

(B) Put k = 1 ⇒
(C) When x = 0, y2 – 2y – 4 = 0
D>0
(D) When y = 0, x = –2

38) Given

∵ a ∈ I ⇒ n must be divisor 77
⇒ possible values of n = 7,11,77
∴ (n,a) = (7,5), (11,–3), (77,–75)
39) We have and

Now

∴
⇒ 2s = 3a = 42
(since a = BD + DC = 14 cm)
∴ perimeter = 42 cm

Also, area = r.s = 4 × 21 = 84 cm2 and r = (s – a) ⇒ .

Since , , each is less than 1.

∴ each is less than .

40) A + B + C + D = 15
A ≥ 2, B ≥ 0, C ≥ 0, D ≥ 4
Number of solutions = 12C3 = 220
N = 220
'2N' = 2351111

41) D D ...........

D H ...........

D U D .......
DUHDHU = 1
DUHDUH = 1

42) S =

or

∴ 20S = 1

43)

∴ y = 27, y = 1
Hence
sin2x + 2cos2x = 3,
sin2x + cos2x = 2 [Not possible] OR
sin2x + 2cos2x = 0
2(sinx + cosx)cosx = 0
cosx = 0 tanx = –1

44)

45) Equation of required circle

x2 + y2 – 2x + 4y – 1 + λ(x2 + y2 + 4x – 2y – 5) = 0
Apply condition of orthogonality with
x2 + y2 = 4

⇒ 1 + 5λ = –4 – 4λ

⇒ 9λ = –5 ⇒
length of tangent from origin

46) _ _ _ 4 _ _ _ 3C3.4C3 = 4
_ _ _ 9 _ _ _ 8C3.9C3 = 4704
⇒ N = 4708

47) N = 75600 = 24335271

Let divisors is and
Product of divisors is 60480 = 26335171
∴ a1 + a2 = 6 ⇒ 3 ways
b1 + b2 = 3 ⇒ 4 ways
c1 + c2 = 1 ⇒ 2 ways
d1 + d2 = 1 ⇒ 2 ways

48)
= 180 – 120 + 24 = 84