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Conservation of Mass & Dalton's Theory

The document discusses the Law of Conservation of Mass, which states that the total mass of reactants equals the total mass of products in a closed system during a chemical reaction. It also explains the Law of Constant Proportion, indicating that a chemical compound always contains the same elements in a fixed mass ratio. Additionally, Dalton's atomic theory is outlined, including its postulates and drawbacks regarding the indivisibility of atoms and variations in atomic mass among elements.

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0% found this document useful (0 votes)
5 views3 pages

Conservation of Mass & Dalton's Theory

The document discusses the Law of Conservation of Mass, which states that the total mass of reactants equals the total mass of products in a closed system during a chemical reaction. It also explains the Law of Constant Proportion, indicating that a chemical compound always contains the same elements in a fixed mass ratio. Additionally, Dalton's atomic theory is outlined, including its postulates and drawbacks regarding the indivisibility of atoms and variations in atomic mass among elements.

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jakharmayank987
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© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd

LAW OF CONSERVATION OF MASS

BaCL2+CuSO4 gives BaSO4+CuCL2


The total mass of the closed system, including the
reactants, is measured before the reaction. After
the reaction has completed and the products have
formed, the total mass of the closed system is
measured again

The Law of Conservation of Mass is proved by


demonstrating that the total mass of the
reactants,{BaCl2 and CuSO4 in a closed system is
equal to the total mass of the products,
BaSO4}and CuCl2after the reaction has occurred.
LAW OF CONSTANT PROPORTION
According to this law, a chemical compound
always contains the same elements combine
together in a fixed ratio by mass. This implies that
any pure sample of a compound, no matter the
source, will always consist of the same elements
that are present in the same ratio by mass.
For example, pure water obtained from different
sources such as a river, a well, a spring, the sea,
etc., always contains hydrogen and oxygen
together in the ratio of 1:8 by mass.

Dalton's atomic theory


Postulates
(1) All the matter is made up of very small particles called
atoms.
(2) Atoms can neither be created nor be destroyed.
(3) All the atoms of a given element are identical in every
respect, having same physical and chemical properties.
(4) Atoms of different elements differ in every respect i.e. mass,
size and chemical properties.
(5) During chemical combination, atoms of different elements
combine in small whole numbers to form compounds.

Drawbacks
(1) Dalton said that atoms are indivisible but they can be
further divided into electron, proton and neutron

2. Dalton said that atoms of a given element have


exactly same masses. It is however now known
that atoms of same element can have different
masses (isotopes).
3. Dalton said that atom of different elements have
different masses. It is however now known that
atoms of different elements can have same
masses (isobars).

Common questions

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Dalton's postulate that all atoms of a given element are identical has impacted the periodic classification by simplifying the categorization of elements based solely on their atomic mass. This postulate, however, does not account for isotopes—atoms of the same element with different masses due to differing neutron numbers. This oversight led to challenges in the early classification of elements, as isotopes could disrupt the orderly arrangement based on mass. Modern periodic tables resolve this by organizing elements by atomic number rather than atomic mass .

The Law of Constant Proportion can be experimentally verified by analyzing water from different sources, such as rivers, wells, or seas, and measuring the mass of hydrogen and oxygen in each sample. Regardless of the water's origin, the mass ratio of hydrogen to oxygen should always be 1:8, validating that these elements combine in a fixed ratio by mass to form the compound consistently .

A closed system is essential for validating the Law of Conservation of Mass because it ensures no mass is lost to or gained from the surroundings during a chemical reaction. By measuring the total mass of reactants and products in a closed system, like in the reaction between BaCl2 and CuSO4, it can be demonstrated that the mass before the reaction is equal to the mass afterwards, confirming the law .

The Law of Constant Proportion states that a chemical compound will always have the same proportion of elements by mass. Using water as an example, regardless of its source, whether from a river or the sea, water is always composed of hydrogen and oxygen in a fixed ratio of 1:8 by mass. This law implies that for any pure sample of water, the mass ratio of hydrogen to oxygen remains constant .

Dalton's Atomic Theory postulated several key assumptions: matter is composed of tiny indivisible particles called atoms; atoms cannot be created or destroyed; all atoms of a given element are identical in mass and properties; and atoms combine in whole-number ratios to form compounds. However, this theory has limitations. Modern science has discovered that atoms are divisible into subatomic particles such as electrons, protons, and neutrons. It is also known that atoms of the same element can have different masses, as in the case of isotopes, and atoms of different elements can have the same mass, known as isobars .

Dalton's Atomic Theory posited that all atoms of a given element were identical in mass, and atoms of different elements had different masses. The discovery of isotopes, which are atoms of the same element with differing masses due to varying numbers of neutrons, contradicts the idea of identical mass. Similarly, isobars, which are atoms of different elements with the same mass, challenge Dalton's notion that atoms of different elements have different masses .

The Law of Conservation of Mass is applied to the reaction between BaCl2 and CuSO4 by ensuring that the total mass of the reactants before the reaction is equal to the total mass of the products after the reaction. This is verified in a closed system where no mass is lost or gained. For the given reaction, BaCl2 and CuSO4 react to form BaSO4 and CuCl2, and the masses of these compounds are measured before and after the reaction to demonstrate that mass is conserved in accordance with the law .

The Law of Conservation of Mass is evidenced by experiments in which the total mass of a closed system is measured both before and after a chemical reaction. In the reaction between BaCl2 and CuSO4, the mass of the reactants and the products, BaSO4 and CuCl2, remain unchanged, demonstrating that no mass was lost or gained during the reaction, thus supporting the law .

Dalton’s Atomic Theory contributes to the understanding of chemical reactions by establishing the foundational concept that matter is composed of indivisible atoms and that these atoms combine in fixed whole-number ratios to form compounds. Despite its limitations, such as the misunderstanding of atom divisibility and mass variations among isotopes, the theory provides a basis for the modern atomic model and explains how atoms interact to form various compounds .

The Law of Conservation of Mass holds true under conditions where the system is closed, meaning no mass can escape or enter the reaction environment. This is demonstrated by conducting reactions, such as between BaCl2 and CuSO4, in a sealed container where the total mass of reactants and products is measured before and after the reaction, showing no change and thereby supporting the law .

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