HALLIBURTON
·~
MATERIAL SAFETY DATA SHEET
Product Trade Name: BAROID®
Revision Date: 16-Jan-2014
11. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product Trade Name: BAROID®
Synonyms: None
Chemical Family: Mineral
Application: Weight Additive
Manufacturer/Supplier Baroid Fluid Services
Product Service Line of Halliburton
P.O. Box 1675
Houston, TX 77251
Telephone: (281) 871-4000
Emergency Telephone: (281) 575-5000
Prepared By Chemical Compliance
Telephone: 1-580-251-4335
e-mail: fdunexchem@[Link]
12. COMPOSITION/INFORMATION ON INGREDIENTS
Substances CAS Number PERCENT (w/w) ACGIH TLV-TWA OSHA PEL-TWA
Barium sulfate 7727-43-7 60- 100% TWA: 10 mgfm3 15 mg/M3
Crystalline silica, quartz 14808-60-7 1 -5% TWA: 0.025 mg/m 3 10 mg/m3
%Si02 + 2
- may be enforced by some states, agencies, or other author1t1es.
More restr1ct1ve exposure hm1ts
..
13. HAZARDS IDENTIFICATION
Hazard Overview CAUTION! -ACUTE HEALTH HAZARD
May cause eye, skin, and respiratory irritation. May be harmful if swallowed.
DANGER! - CHRONIC HEALTH HAZARD
Breathing crystalline silica can cause lung disease, including silicosis and lung
cancer. Crystalline silica has also been associated with scleroderma and kidney
disease.
This product contains quartz, cristobalite, and/or tridymite which may become
airborne without a visible cloud. Avoid breathing dust. Avoid creating dusty
conditions. Use only with adequate ventilation to keep exposures below
recommended exposure limits. Wear a NIOSH certified, European Standard EN
149, or equivalent respirator when using this product. Review the Material Safety
Data Sheet (MSDS) for this product, which has been provided to your employer.
~- FIRST AID MEASURES
BAROID®
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Storage Information Do not reuse empty container. Store in a cool, dry location. Use good
housekeeping in storage and work areas to prevent accumulation of dust. Close
container when not in use.
Is. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls Use approved industrial ventilation and local exhaust as required to maintain
exposures below applicable exposure limits.
Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures,
the selection and proper use of personal protective equipment should be
determined by an industrial hygienist or other qualified professional based on the
specific application of this product.
Respiratory Protection Wear a NIOSH certified, European Standard EN 149 (FFP2/FFP3), or equivalent
respirator when using this product.
Hand Protection Normal work gloves.
Skin Protection Wear clothing appropriate for the work environment. Dusty clothing should be
laundered before reuse. Use precautionary measures to avoid creating dust when
removing or laundering clothing.
Eye Protection Wear safety glasses or goggles to protect against exposure.
Other Precautions None known.
~- PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Solid
Color: Pink to tan to gray
Odor: Odorless
pH: Not Determined
Specific Gravity @ 20 C (Water=1 ): 4.23
Density@ 20 C (lbs./gallon): Not Determined
Bulk Density @ 20 C (lbs/ft3): 135
Boiling Point/Range (F): Not Determined
Boiling Point/Range (C): Not Determined
Freezing Point/Range (F): Not Determined
Freezing Point/Range (C): Not Determined
Vapor Pressure @ 20 C (mmHg): Not Determined
Vapor Density (Air-1): Not Determined
Percent Volatiles: Not Determined
Evaporation Rate (Butyl Acetate=1 ): Not Determined
Solubility in Water (g/100ml): Insoluble
Solubility in Solvents (g/100ml): Not Determined
VOCs (lbs./gallon): Not Determined
Viscosity, Dynamic@ 20 C (centipoise): Not Determined
Viscosity, Kinematic@ 20 C (centistokes): Not Determined
Partition Coefficient/n-Octanoi/Water: Not Determined
Molecular Weight (g/mole): 233.4
110. STABILITY AND REACTIVITY
~ Stability Data: Stable
Hazardous Polymerization: Will Not Occur
BAROID®
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Barium sulfate 7727-43-7 > 307,000 mg/kg > 2,000 mg/kg 0.4 mg/L
> 2000mg/kg (similar substance-
barium dichloride)
Crystalline silica, quartz 14808-60-7 500 mg/kg ( Rat ) No data available No data available
l12. ECOLOGICAL INFORMATION
Ecotoxicological Information
Ecotoxicity Product
Acute Fish Toxicity: TLM96: 7500 ppm (Oncorhynchus mykiss)
Acute Crustaceans Toxicity: Not determined
Acute Algae Toxicity: Not determined
Ecotoxicity Substance
~ubstances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to Daphnia Magna (Water
Microoraanisms Flea>
Barium sulfate 7727-43-7 EC50(72h): (growth rate) TLM96: 7500 ppm TLM96: > 1,000,000 ppm
EC50(3h): (respiration
> 1.92 mg/L (Oncorhynchus mykiss) rate) >1000 mg/L (Mysidopsis bahia)
(Pseudokirchnerella LC50(96h): > 97.5 mg/L (activated sludge) LC50(48h) 14500 ug/L
subcapitata) (Danio rerio) (Daphnia Magna)
Crystalline silica, 14808-60-7 No information available No information available No information available No information available
quartz
12.2 Persistence and degradability
The methods for determining biodegradability are not applicable to inorganic substances.
12.3 Bioaccumulative potential
No information available
12.4 Mobility in soil
No information available
12.5 Results of PBT and vPvB assessment
No information available.
12.6 Other adverse effects
l13. DISPOSAL CONSIDERATIONS
Disposal Method Bury in a licensed landfill according to federal, state, and local regulations.
Contaminated Packaging Follow all applicable national or local regulations.
l14. TRANSPORT INFORMATION
Land Transportation
DOT
Not restricted
Canadian TOG
Not restricted
~ ADR
Not restricted
BAROID®
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Additional Information For additional information on the use of this product, contact your local Halliburton
representative.
For questions about the Safety Data Sheet for this or other Halliburton products,
contact Chemical Compliance at 1-580-251-4335.
Disclaimer Statement This information is furnished without warranty, expressed or implied, as to
accuracy or completeness. The information is obtained from various sources
including the manufacturer and other third party sources. The information may not
be valid under all conditions nor if this material is used in combination with other
materials or in any process. Final determination of suitability of any material is the
sole responsibility of the user.
***END OF MSDS***
BAROID®
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