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Physics and Chemistry Exam Questions

The document contains a series of physics, chemistry, and mathematics problems, each with multiple-choice answers. It includes questions on topics such as electromagnetism, chemical reactions, and matrix algebra. The problems are structured to test knowledge in these subjects, with specific numerical values and scenarios provided.

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0% found this document useful (0 votes)
30 views38 pages

Physics and Chemistry Exam Questions

The document contains a series of physics, chemistry, and mathematics problems, each with multiple-choice answers. It includes questions on topics such as electromagnetism, chemical reactions, and matrix algebra. The problems are structured to test knowledge in these subjects, with specific numerical values and scenarios provided.

Uploaded by

prakashraj91280
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

02-11-2025

0999DJM262103250007 JM

PART-1 : PHYSICS

SECTION-I

1) Two identical coaxial circular loops carry a current i each circulating in the same direction. If the
loops approach each other

(A) the current in each will decrease


(B) the current in each will increase
(C) the current in each will remain the same
(D) the current in one will increase and in other will decrease

2) A uniform but time varying magnetic field


B = Kt – C; , where K and C are constants and t is time, is applied perpendicular to the
plane of the circular loop of radius 'a' and resistance R. Find the total charge that will flow through a
cross–section of loop.

(A)

(B)

(C)

(D)

3) A small square loop of wire of side ℓ is placed inside a large square loop of wire of side L (>> ℓ).
The loops are coplanar and their centres coincide. The mutual inductance of the system is :

(A)

(B)

(C)

(D)
4) The network shown in the figure is a part of a complete circuit. If at a certain instant the current i
is 5A and is decreasing at the rate of 103 A/s then VB – VA is :-

(A) 5 V
(B) 10 V
(C) 15 V
(D) 20 V

5) The current 'i' in an inductance coil varies with time 't' according to following graph

which of the following plots shows the variation of voltage in the coil :

(A)

(B)

(C)

(D)

6) One conducting U-tube can slide inside another as shown in figure, maintaining electrical
contacts between the tubes. The magnetic field B is perpendicular to the plane of the figure. If each
tube moves towards the other at a constant speed v, then the e.m.f induced in the circuit in terms of

B, ℓ and v, where ℓ is the width of each tube, will be :

(A) Bℓv
(B) –Bℓv
(C) zero
(D) 2Bℓv

7) Two coaxial solenoids are made by winding thin insulated wire over a pipe of cross-sectional
area A = 10 cm2 and length = 20 cm. If one of the solenoids has 300 turns and the other 400 turns,
their mutual inductance is :

(A) 2.4π × 10–5 H


(B) 4.8π × 10–4 H
(C) 4.8π × 10–5 H
(D) 2.4π × 10–4 H

8) In the given figure if the magnetic field, which is perpendicular to the plane of the paper in the

inward direction increases, then-

(A) Plate B of the capacitor will become positively charged.


(B) Plate A of the capacitor will become positively charged.
(C) The capacitor will not be charged.
(D) Both plates will be charged alternately.

9) A metallic rod completes its circuit as shown in the figure. The circuit is normal to a magnetic
field of B = 0.15 tesla. If the resistance of the rod is 3Ω the force required to move the rod with a

constant velocity of 2 m/sec is-

(A) 3.75 × 10–3 N


(B) 3.75 × 10–2 N
(C) 3.75 × 102 N
(D) 3.75 × 10–4 N

10) A coil of resistance 40 Ω is connected to a galvanometer of 160 Ω resistance. The coil has radius
6 mm and turns 100. This coil is placed between the poles of a magnet such that magnetic field is
perpendicular to coil. If coil is dragged out then the charge through the galvanometer is 32 μC. The
magnetic field is :
(A) 6.55 T
(B) 5.66 T
(C) 0.655 T
(D) 0.566 T

11) A thin rod of mass m and length ℓ is oscillating about horizontal axis through its one end. Its
maximum angular speed is ω. Its centre of mass will rise upto maximum height :-

(A)

(B)

(C)

(D)

12) A string is wrapped arround a cylinder of mass M and radius R as shown. The string is pulled
vertically up to prevent the centre of mass from falling as cylinder unwinds the string. The tension in

string is :-

(A) 2 Mg

(B)

(C) Mg
(D) 3 Mg

13) A rod of length L has one end on horizontal floor. It fall while rotating about contact point
without slipping initially it is inclined at α from horizontal its angular speed when it is at horizontal
floor is :-

(A)

(B)

(C)

(D)

14) A uniform pole of length L and mass M is pivoted on the ground with a frictionless hinge. The
pole makes an angle θ with the horizontal. The moment of inertia of the flag pole about one end is
(1/3)ML2. If it starts falling from this position shown in the accompanying figure, the linear

acceleration of the free end of the pole would be :

(A) (2/3) gcosθ


(B) (2/3) g
(C) g
(D) (3/2) gcosθ

15) A thin wire of length L and uniform linear mass density ρ is bent into a circular loop with centre

at O as shown. The moment of inertia of the loop about the axis XX’ is :–

(A) ρL3/8π2
(B) ρL3/16π2
(C) 5ρL3/16π2
(D) 3ρL3/8π2

16) A rod of mass M and length L is placed in a horizontal plane with one end hinged about the

vertical axis. A horizontal force of F = is applied at a distance from the hinged end. The

angular acceleration of the rod will be :-

(A)

(B)

(C)

(D)
17) A rigid body is rotating about a vertical axis at n rotations per minute. If the axis slowly becomes
horizontal in t seconds and the body keeps on rotating at n rotations per minute then the torque
acting on the body will be, if the moment of inertia of the body about axis of rotation is I :-

(A) zero

(B)

(C)

(D)

18) A solid sphere rolls without slipping on a rough horizontal surface with centre of mass having
constant speed v0. If mass of the sphere is m and its radius is R, then what is the angular momentum
of the sphere about the point of contact

(A)

(B)

(C)

(D)

19) Force of 10 N is applied tangentially on a disc of mass 2 kg and radius 1m, which is free to rotate
on its geometric axis then angular velocity of disc after 2 seconds is :-

(A) 10 rad/sec
(B) 20 rad/sec
(C) 5 rad/sec
(D) 40 rad/sec

20) A thin and circular disc of mass M and radius R is rotating in a horizontal plane about an axis
passing through its centre and perpendicular to its plane with an angular velocity ω. If another disc
of same dimensions but of mass M/4 is placed gently on the first co-axially, then the new angular
velocity of the system is:-

(A)
ω

(B)
ω

(C)
ω

(D)
ω

SECTION-II
1) Two concentric circular coils, C1 and C2, are placed in the XY plane. C1 has 500 turns, and a radius
of 1 cm. C2 has 200 turns and radius of 20 cm. C2 carries a time dependent current I(t) = (5t2 – 2t +

3) A where t is in s. The emf induced in C1 (in mV), at the instant t = 1s is . The value of x is ____.

2) A coil of inductance 5H is joined to a cell of emf 6V through a resistance 10Ω at time t = 0. The

emf (In volt) across the coil at time t = ℓn s is :-

3) A ring of resistance 10 Ω, radius 10 cm and 100 turns is rotated at a rate 100 revolutions per
second about its diameter is perpendicular to a uniform magnetic field of induction 10 mT. The
amplitude of the current (In Amp.) in the loop will be nearly (Take : π2 = 10)

4)

A mass M is supported by a massless string wound round a uniform cylinder of mass M and radius R.

on releasing the mass from rest, it will fall with acceleration . Find n.

5) Four disc each of mass m and radius R are placed as shown in figure then what will be the
moment of inertia of the system about an axis passing through centre of diagonally opposite disc and

in the same plane as shown in figure is NmR2. Then N is :-

PART-2 : CHEMISTRY

SECTION-I

1) A cell is constituted as follows Pt | H2 (1 atm) | HA1| | HA2 | H2 (1 atm)| Pt The pH of two acid
solutions HA1 and HA2 are 5 and 3 [Link] emf of the cell is :-

(A) 0.059 V
(B) 0.0295 V
(C) 0.118 V
(D) – 0.118 V
2) A solution is one molar in each of NaCl, CdCl2, ZnCl2 and PbCl2. To this, tin metal is added. Which
of the following is true? Given :

(A) Sn can reduce Na+ to Na


(B) Sn can reduce Zn+2 to Zn
(C) Sn can reduce Cd2+ to Cd
(D) Sn can reduce Pb2+ to Pb

3) Deduce from the following E° values of half cells, what combination of two half cells would result
in a cell with the largest potential :

(A) (i) and (iii)


(B) (i) and (iv)
(C) (ii) and (iv)
(D) (iii) and (iv)

4)

The ratio in the buffer present in blood (pH = 7.4) is approximately :-


(pKa = 6.1 for H2CO3)

(A) 20
(B) 16
(C) 24
(D) 10

5) M (OH)x has a Ksp of 4 × 10–9 and its solubility is 10–3 M. The value of x is :-

(A) 4
(B) 1
(C) 3
(D) 2

6) Zirconium phosphate [Zr3(PO4)4] dissociates into three zirconium cations of charge +4 and four
phosphate anions of charge –3. If molar solubility of zirconium phosphate is denoted by S and its
solubility product by Ksp then which of the following relationship between S and Ksp is correct ?

1/7
(A) S = {Ksp/144}
1/7
(B) S = {Ksp/(6912) }
1/7
(C) S = (Ksp/6912)
7
(D) S = {Ksp/6912}

7) The acid ionisation of hydrated zinc ions is


Zn(H2O)62+(aq) + H2O(ℓ) ⇌ (O)5OH+(aq) +H3O+(aq)
and Ka is 1.25 × 10–10. The pH of 0.8 M aqueous solution of ZnCl2 is [log 2 = 0.3]

(A) 4.0
(B) 4.7
(C) 5.0
(D) 5.3

8) Which is correct for any H like species :-

(A) (E2 – E1) > (E3 – E2) > (E4 – E3)


(B) (E2 – E1) < (E3 – E2) < (E4 – E3)
(C) (E2 – E1) = (E3 – E2) = (E4 – E3)
(D) (E2 – E1) = 1/4 (E3 – E2)=1/9 (E4 – E3)

9) Three energy levels P, Q, R of a certain atom are such that EP < EQ < ER. If λ1, λ2 and λ3 are the
wave length of radiation corresponding to transition R → Q ; Q → P and R → P respectively. The
correct relationship between λ1, λ2 and λ3 is :

(A) λ1 + λ2 = λ3

(B)

(C) λ3 =

(D)

10) Number of possible spectral lines which may be emitted in bracket series in H atom, if electrons
present in 9th excited level returns to ground level, are

(A) 21
(B) 6
(C) 45
(D) 5

11) Most basic compound is :

(A)

(B)
(C)

(D)

12) Most basic compound is :

(A)

(B)

(C)

(D)

13) Which of following is feasible reaction

(A)
+ NaOH →
(B) CH3 – C ≡ CH + NaOH →

(C)

+ NaHCO3 →
(D) HC ≡ CH + NaNH2 →

14) Identify correct acidic strength order ?


(A)

(B)

(C)

(D)

15) Which will undergo deprotonation most readily in basic medium?

(A) a only
(B) c only
(C) Both a and c
(D) b only

16) Total number of resonating structure of product obtained in following reaction.

(A) 2
(B) 3
(C) 4
(D) 5

17) Which of the following set is INCORRECT regarding basic strength.

(A)

Ph—NH—Ph < Ph—NH2 <


(B)

(C)

(D)

18)
The least basic N-atom is :

(A) P
(B) Q
(C) R
(D) S

19) Given below are two statements, one is labelled as Assertion A and the other is labelled as
Reason R.
Assertion A : Order of acidic nature of the following compounds is A > B > C.

Reason R : Fluoro is a stronger electron withdrawing group than Chloro group.


In the light of the above statements, choose the correct answer from the options given below:

(A) A is false but R is true.


(B) Both A and R are correct and R is the correct explanation of A.
(C) Both A and R are correct but R is NOT the correct explanation of A.
(D) A is true but R is false.

20) Product A will be :-

(A)

(B)

(C)

(D) None of these

SECTION-II

1) A 250 mℓ sample of a 0.2 M Cr3+ is electrolysis with a current of 96.5 amp; if the remaining
concentration of Cr3+ ion is 0.1 M, the duration of electrolysis is : (Atomic wt. of Cr = 52) Assume
volume of solution remains constant during electrolysis :-

2) Ionic conductance at infinite dilution of Al3+ and SO42– ions are 189 ohm–1cm2eq–1 and
160 ohm–1cm2eq–1 respectively. Limiting conductance of Al2 (SO4)3 in ohm–1 cm2 eq–1 will be :-

3) How many of the following are soluble in [Link]?

(a) (b)
(c) (d)

(e) (f)

(g) (h)

4) Out of following in how many cases Ist is more basic than IInd.

(i)

(ii)

(iii)

(iv)

(v)

(vi)

(vii)

5) Number of compounds from the following which will not dissolve in cold NaHCO3 and NaOH
solutions but will dissolve in hot NaOH solution is _____ .

, ,
,

PART-3 : MATHEMATICS

SECTION-I

1)

If A = , then value of Tr is equal to


(here adj(X) denotes adjoint of matrix X and Tr(X) denotes trace of matrix X)

(A) 2
(B) 1

(C)

(D)

2)

Let A be a 3 × 3 matrix. If every column vector X satisfies XTAX = 0 and a12 = 2008, a13 = 1010, a23 =
–2012. Then the value of a21 + a31 + a32 is (where XT represents transpose of matrix X)

(A) –6
(B) 1006
(C) –1006
(D) 0

3) , then a + b is equal to

(A) –5050
(B) –5040
(C) 5040
(D) 5000

4) Let ,

where and I3 be the identity matrix of order 3. If the determinant of the matrix

is then the value of is equal to ________

(A) 18
(B) 36
(C) 9
(D) 27

5) Let A be matrix of order 3 × 3 such that

|A| = 1, let B = 2A–1, C = then the value |AB2C3| is

(A) 8
(B) 4
(C) 64
(D) 16

6) Given the matrix and satisfies pA3 = qA2 + rA + sI (where (p,q,r,s) are constants &

I is a unit matrix of order 3 × 3), then the value of is

(A) 3
(B) 2.5
(C) 2
(D) 0.50

7) Let A,B and C are matrices then


Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

If |A| = 2, then |2A–1|=?


(P) (1) 0
(where order of A is 3)

(Q) If |A| = , then |[Link](2A)| (2) 1


= (where order A is 3)
If (A + B)2 = A2 + B2 and
(R) |A| = 2, (3) 3
then |B| = (where order A is 3)

|A2×2| = 2, |B3×3| = 3 and


|C4×4| = 4,
(S) (4) 4
then is equal to

(5) 5

(6) 7
(A) P → 4;Q → 2;R → 1;S → 3
(B) P → 2;Q → 4;R → 3;S → 1
(C) P → 1;Q → 3;R → 5;S → 6
(D) P → 5;Q → 3;R → 4;S → 2

8) Let and I be the identity matrix of order 3. If Q = [qij] is a matrix such that p50 – Q

= I, then equals

(A) 52
(B) 103
(C) 201
(D) 205

9) If the vertex of a parabola is at origin and directrix be x + 5 = 0 then its latus rectum is :-

(A) 20
(B) 5
(C) 25
(D) None of these

10) The length of the chord of the parabola x2 = 4y having equation is :

(A)
(B)
(C)
(D)

11) The point A on the parabola y2 = 4ax for which |AC – BC| is maximum, whose B(0, a) and C(–a, 0)
is :-

(A) (a, 2a)


(B) (4a, 4a)
(C) (a, –2a)
(D) None of these

12) The equation of a circle touching the parabola y = x2 at the point (1, 1) and passing through the
point (2, 2) is :-

(A) x2 + y2 – 6x + 4 = 0
(B) x2 + y2 – 6y + 4 = 0
(C) x2 + y2 + 6x + 4 = 0
(D) x2 + y2 + 6y + 4 = 0

13) If the area of the auxiliary circle of the ellipse is twice the area of the
ellipse, then the eccentricity of the ellipse is :-

(A)

(B)

(C)

(D)

14) Let a, b and λ be positive real numbers. Suppose P is an end point of the latus rectum of the

parabola y2 = 4λx, and suppose the ellipse passes through the point P. If the tangents to
the parabola and the ellipse at the point P are perpendicular to each other, then the eccentricity of
the ellipse is :-

(A)

(B)

(C)

(D)

15) If the normal at one end of the latus rectum of an ellipse passes through one end of
the minor axis then :

(A) e4 – e2 + 1 = 0
(B) e2 – e – 1 = 0
(C) e2 + e + 1 = 0
(D) e4 + e2 – 1 = 0
16)

Let S = 0 be an ellipse whose vertices are the extremities of minor axis of the ellipse

E: .

If S = 0 passes through the foci of E, then its eccentricity is (considering the eccentricity of E as e)

(A)

(B)

(C)

(D)

17) Locus of mid points of all chords of hyperbola 3x2 – 2y2 + 6x – 4y = 0 having slope 2 is :-

(A) 3x + 4y = – 1
(B) 3x – 4y = – 1
(C) 3x – 4y = 1
(D) 3x + 4y = 1

18) Eccentricity of hyperbola whose asymptotes are x + 2y = 3 and 2x – y = 1 is

(A)
(B) 2

(C)

(D)

19) If the eccentricity of the hyperbola x2 – y2 sec2θ = 4 is times the eccentricity of the ellipse
x2sec2θ + y2 = 16, then the value of θ equals to :-

(A) π/6
(B) 3π/4
(C) π/3
(D) π/2

20) If PQ is a double ordinate of hyperbola such that OPQ is an equilateral triangle, O


being the centre of the hyperbola. Then the eccentricity e of the hyperbola satisfies

(A)
(B)
(C)
(D)

SECTION-II

1) Let , if matrix A is represented as the sum of symmetric matrix P and skew


symmetric matrix Q and det(P) = 0, then sum of all real values of x is equal to

2) There are two possible values of A (say A1 & A2) in the solution of matrix equation

then find –27(A1 + A2)

3) Let A(4,–4) and B(9,6) be points on the parabola, y2 = 4x. Let C be chosen on the arc AOB of the
parabola, where O is the origin, such that the area of ΔACB is maximum. Then, the four times of area
(in sq. units) of ΔACB, is :-

4) A hyperbola is such that its length of latus rectum equal to 6 and the length of its conjugate axis is

equal to one third of its distance between foci, if its eccentricity is (where a and b are prime)
then value of ab is -

5) If the equations of directrices of the hyperbola 9x2–16y2–18x + 32y – 151 = 0 are x = a and x = b,
then value of a + b is -
ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A A D C B D D A A D C C A D D B C B B C

SECTION-II

Q. 21 22 23 24 25
A. 5 3 2 2 5

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C D C A D C C A B B D B D C A D C A C A

SECTION-II

Q. 46 47 48 49 50
A. 75 349 3 4 3

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B C A B A D A B A C A A B A D A C A B D

SECTION-II

Q. 71 72 73 74 75
A. 3 9 125 6 2
SOLUTIONS

PART-1 : PHYSICS

1)

According to lenz's law when coils approaches, flux increase so induce current will be opposite
to existing current to decrease flux so current in both coli decrease

2) t = 0, B = – C

B= ∴ ΔB = C
2
∴ Δϕ = AΔB = πa C

q=

3) ϕ = Mi
BAcos0° = Mi

4)

= 5 × 10–3 × 103 = 5V
VA – 5 × 1 + 15 + 5 = VB
VB – VA = 15V

5)

solpe of i – t graph

6) Relative velocity = v + v = 2v
∴ emf = Bℓ (2v) = 2Bℓv

7) M =

=
= 2.4 π × 10–4 H

8) t B then induced emf try to oppose

9)

Induced current,
Required force, F = Fm = BIℓsinθ
= 0.15 × 0.05 × 0.5 × sin 90° = 3.75 × 10–3 N

10) q = |Δϕ| = A|B2–B1|

= A|O – B| =

= = 0.566 T

11)

The Correct Answer is (C)

12) T.R = I . α

T.R =
2T = Ma ...(1)
T – Mg = 0 ...(2)
T = Mg and a = 2g

α=
13)

Mg sin α = I ω2

Mg sin α = ω2

∴ω=

14) Taking torque about contact point with ground


τ = Iα

mg ×

so linear acceleration of face end of the pole,


a = αL

a=

a=

15) The moment of inertia of a thin loop about its diameter is ..(1)

here linear mass density,

Also we have, 2πR = L ⇒


so by (1)

Now using parallel axis theorem,

16) τ = Iα = dF (Where d is distance of F from hinged end)


17)

18) L = Lcm + mvR = Icmω + mv0R

19) For Disc τ = R × F = Iα Here


α = 10 r/s2
then ω = ω0 + αt
= 0 + 10 × 2

= 20

20) According to conservation of angular momentum


I1ω1 = I2ω2

⇒ MR2ω = ω2

∴ ω2 = ω

21)

= 8 × 10–4 = 0.8 mV
0
22) ε = L , i = i (1–e–t/τ)

23)

E=

I = E/R = 2A

24)

According to law of conservation of energy.

or

Also

25)

I = sum of MOI of all the disc


= 5MR2 = ηMR2
Hence η = 5

PART-2 : CHEMISTRY

26) H2 → 2H+ 10–5 M


2H+ → H2
10–3 M
2H+ → 2H+
10–3M 10–5M

E = E0 = 0.118 volt

27)

Element having more negative value of S.R.P can reduce less negative value of S.R.P.
28)
0
{E = S.R.P}

29) pH = pKa + log

or 7.4 = 6.1 + log

or = 20

30) M(OH)x
AB2 then x = 2

31) Zr3(PO4)4 → 3Zr+3 + 4 PO4–3


3s 4s
Ksp = (3s)3 (4s)4

s=

32) [H+] or [H3O+]

= =10–5
∴ pH = 5

33)

E = –13.6 × eV

34)
EP < EQ < ER
ER→P = ER→Q + EQ→P

35)

9th excited state


n = 10
number of lines in bracket series
= n2 – 4

36) lone pair of nitrogen is not involved in resonance with the


ring .

37) conjugate acid of '2'

38) A.S. : Acid1 > Acid2

39)

Solution/Explanation:

A. Question: The question identify correct acidic strength order.

B. Given Data:

Options are:

1 2

3 4

C. Concept:

Acidity: Ability of a compound to donate a proton (H+). Stronger acids (Ka) donate protons
more readily. And more stable conjugated base.

Factors affecting acidity:

A. Electron-withdrawing groups: -I and -M effect Increase acidity by stabilizing the


conjugate base (the anion formed after deprotonation).

A. Electron-donating groups: +I and +M effect Decrease acidity by destabilizing the


conjugate base.

B. Resonance Effects: Resonance can stabilize the conjugate base and increase acidity.

C. Extra stability of conjugated base by intramolecular Hydrogen bonding.


D. Explanation:

1 2

Solution Solution

So given order is wrong. So given order is wrong.

3 4

Solution Solution

So given order is correct. So given order is wrong.

E. Final Answer: 3

F. Question Level: Easy

40) Most easily deprotonation

41)

42)

Explanation Question: Asking about he wrong order of basic strength.


Concept: This question is based on electronic effects on basicity
Solution:
Basic strength (Kb) ∝ lone pair donation power and proton (H+) acceptor tendency.


Except option (3) all other are correct.
Correct Kb order for option (3) amines is
Final Answer : (3)

43)

Becouse of lone pair of Nitrogen is canjugation with carbonyl group

44) Acidic strength α – I effect

α effect
F, Cl exerts –I effect, Methyl exerts +I effect, C is least acidic.
Among A and B; since inductive effect is distance dependent, Extent of –I effect is higher in A
followed by B even though F is stronger electron withdrawing group than Cl. Thus, A is more
acidic than B.

45)

More acidic H are replace first by

46)

Initial equivalent of Cr+3 = M × V × V.F.

⇒ 0.2 × ×3
⇒ 0.15

Final equivalent of Cr+3 = 0.1 × ×3


⇒ 0.075
Left equivalent of Cr+3 = 0.15 – 0.075
⇒ 0.075

w=

0.075 =
t = 75 sec.

47)
–1 2 –1
= 189 + 160 = 349 ohm cm eq
= 349 ohm–1 cm2eq–1

48)

Compounds which are more acidic than H2O are soluble (reacts) in NaOH

49) (i), (iii), (v) and (vi) are correct.

Compound pka of its conjugate ⇒ 5.21

Compound pka of its conjugate ⇒ 4.62

Compound pka of its conjugate ⇒ 9.11


(vii) % of s–character.

50) Compound 2, 3, 7

PART-3 : MATHEMATICS

51)

(AadjA)A= |A|IA = 2A

∴ [(AadjA)A]–1A = (2A)–1A =

52)

Let ,
a11x1 + a22x2 + a33x32 + (a12 + a21)x1x2 + (a13 + a31)x1x3 + (a23 + a32)x2x3 = 0.
2 2

Its true for every x1, x2, x3 then a11 = a22 = a33 = 0, a12 + a21 = 0, a13 + a31 = 0, a23 + a32 = 0.
∴ A is skew symmetric matrix
a21 = –2008
a31 = –2010
a32 = 2012
53)

=
a + b = –5050

54)

Let

Now

55) |AB2C3| = |A| |B|2 |C|3

|A| = 1, |B| = |2A–1| =

∴ |C| = |adj A|

∴ |A| |B|2 |C|3 = (1) (64) =8

56) |A – λI| = 0
⇒ ⇒ λ3 = λ2 + 1
3 2
⇒A =A +I
∴ p =1, q = 1, r = 0, s = 1.

57) (P) If |A| = 2, then

(Q) |A| = then |adj (adj(2A)|

(R) If (A + B)2 = A2 + B2
then AB + BA = 0
or AB = –BA
or |AB| = |–BA|
or 2|A| |B| = 0
or |B| = 0
(S) |A2 × 2| = 2 |B3 × 3| = 3 and |C4 × 4| = 4

58)
P=1+B
P50 = (I + B)50

59) Here a = 5 hence 4a = 20

60) x2 = 4y

Solving together we get

x1 + x2 = 2; x1x2 = = –16
Similarly,

2y2 + 32 – 16y = 4y

2y2 – 20y + 32 = 0

ℓAB =

=
61) |AC – BC| is maximum if area of ΔABC = 0

= 0 ⇒ x1 – y1 + a = 0 ....(1)
2
Δ(x1y1) lies on y = 4ax
= 4ax1 ....(2)
from (1) & (2) x = a, y = 2a

62)
Eq. of tangent to parabola y = x2 at P(1, 1) is
2x – y – 1 = 0
Eq. of circle is
(x – 1)2 + (y – 1)2 + λ(2x – y –1) = 0 ....(i)
Circle passes through Q(2, 2)
∴ (2 – 1)2 + (2 – 1)2 + λ(4 – 2 – 1) = 0
⇒ λ = –2 Put λ = –2 in (i)
x2 + y2 – 6x + 4 = 0

63)

Given ellipse is = 1 whose area is π ab.


The auxiliary circle to the given ellipse is x2 + y2 = a2 whose area is πa2.
Given that,

Now , eccentricity of ellipse

64)

y2 = 4λx, P(λ, 2λ)


Slope of the tangent to the parabola at point P

Slope of the tangent to the ellipse at P


As tangents are perpendicular y' = –1

65)

= –e

Slope of normal =
eq. of normal

It passes through (0, –b),

–b – = (0 – ae)

⇒ =+a


66) and a2e2 = b2(1 – e12)

67) T = S1


= 3h2 – 2k2 + 6h – 4k


⇒ 3h – 4k = 1
⇒ 3x – 4y = 1

68) Eccentricity of rectangular hyperbola =


69)

eH =
eE =
Also eH =

⇒ cos2 θ = 1/2 ⇒

⇒ θ=

70) Let P be end points of double ordinates and O(0,0), is the centre of the hyperbola. Now

Since OQ = OP = PQ,

∴ 4b2tan2θ = a2sec2θ + b2tan2θ

⇒ ⇒

⇒ ⇒

⇒ , (∵ sin2θ < 1)

71)
P Q
So det(P) = 0
or (x – 4)(x2 + 1)(x + 1) = 0
or x = 4 or –1
sum of x = 3
72)
⇒ A2 + 5A – 10 = 28A2 + 14A – 280

27A2 + 9A – 270 = 0 ⇒ A1 + A2 = – , – 27(A1 + A2) = 9.

73)

Area = 5|t2 – t – 6| =

is maximum if

74) Here

75) Here equations of directrices are x = and

x=– ⇒a+b=

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