13-10-2025

2001CJA101001250023 JA

PHYSICS

SECTION-I(i)

1) A car travels 30 km at a uniform speed of 40km/h and the next 30 km at a uniform speed of 20
km/h. Find its average speed (in km/hr).

(A)

(B)

(C)

(D)

2) With what minimum acceleration should wedge "A" be moved so the block "B" remains at rest
with respect to "A". [All surface are smooth] :-

(A)

(B)

(C) g
(D) Not possible

3) At time t = 0 a particle starts moving along the x-axis. The net force acting on the particle is
proportional to t–1/2. Then its kinetic energy increases as :-

(A) t3/2
(B) t–3/2
(C) t
(D) t1/2

4) Mass 2m is kept on a smooth circular track of mass m which is kept on a smooth horizontal
surface. The circular track is given a horizontal velocity towards left and released. Find the

maximum height reached by 2m.

(A) R
(B) R/3
(C) R/4
(D) 2R/3

SECTION-I(ii)

1) A particle of mass m moves on the x-axis. It starts from rest at t = 0 from the point x = 0, and
come to rest at t = 1 at the point x = 1. No other information is available about it's motion at
intermediate time (0 < t < 1). If α denotes the acceleration of the particle then

(A) α cannot remain positive for all t in the interval 0 ≤ t ≤ 1

(B) α cannot exceed 2 at any point on its path
(C) α must be ≥ 4 for some points on its path
(D) None

2) Initially spring is compressed by 0.5 m and surface is smooth. Choose the correct option(s):-

(A) Initial potential energy in spring is 12.5 J.

(B) Kinetic energy of block A, when spring is at natural length for first time is 12.5 J.
(C) Work done by all forces on B is zero till spring attains it’s natural length for first time.
(D) None of these.

3) One end of a thread of length 'ℓ' is attached to an inclined plane of elevation of α. A point like
body of mass m = 1 kg is attached to the other end of the thread as shown in the figure. The body is
released without initial speed. Such that the thread is tight and horizontal. The coefficient of friction

between the slope and body is µ.

The tension in the thread, when the angle between the thread and the horizontal is ϕ is T = mg
(A)
(3 sin ϕ sin α – 2µϕ cos α)
(B) The tension in the string will be maximum when ϕ = 90°.

(C)
The tension in the string will be maximum when .
–1
(D) The maximum speed of the particle will be, when ϕ = cos (µ cot α)

SECTION-I(iii)
1) Particle is projected from point P perpendicular to OA plane and it strikes the OB plane

perpendicular at Q. (g = 10 m/s2)

List–I List–II

(P) Time of flight (in s) (1) 16.25

(Q) Maximum height from ground (in m) (2) 10

(R) Distance between P and Q points (in m) (3) 5√3

Speed of particle just before hitting at Q.

(S) (4) 2
(in m/s)

(5) 20
(A) P → 2;Q → 1;R → 5;S → 3
(B) P → 2;Q → 1;R → 5;S → 4
(C) P → 1;Q → 2;R → 4;S → 5
(D) P → 4;Q → 1;R → 5;S → 2

2) A sphere of mass 10 kg is placed in equilibrium in a V shaped groove plane made of two smooth

surfaces-1 and 2 as shown in figure. (g = 10 ms–2)

List-I List-II

(P) Normal reaction by Surface-1. (1) Zero

(Q) Normal reaction by surface-2. (2) 60 N

(R) Force on sphere by Earth. (3) 125/2 N

(S) Net force on sphere. (4) 100 N

(5) 120 N
(A) P → 1;Q → 2;R → 3;S → 4
(B) P → 2;Q → 4;R → 1;S → 3
(C) P → 3;Q → 3;R → 4;S → 1
(D) P → 4;Q → 3;R → 2;S → 1
3) Initially springs are in natural length. On applying a variable force F on block towards right ,
elongation in spring S1 is x1. If block moves slowly and floor is smooth then -

List-I List-II

(P) Work done by S2 on block (1)

(Q) Work done by S2 on S1 (2)

(R) Work done by F on block (3)

(S) Work done by S1 on wall (4) zero

(5)

(6)

(A) P → 3;Q → 1;R → 2;S → 6

(B) P → 2;Q → 3;R → 1;S → 4
(C) P → 4;Q → 6;R → 3;S → 5
(D) P → 5;Q → 3;R → 2;S → 6

SECTION-II

1) Position of a particle moving along x axis is given by x = t2 – 4t + 4 meter, the distance travelled
by particle from t = 0 to t = 3 sec is n meter. The value of n is.

2) A block of mass 4 kg is suspended through two light spring balances A and B. Find the reading of

spring balance A (in kg) :

3) A block of mass 2 kg is pushed normally against a rough vertically wall with a force of 40 N,
coefficient of static friction being 0.5. Another horizontal force of 15 N, is applied on the block in a
direction parallel to the wall. Acceleration (in m/s2) of the block is
4) A string with one end fixed on a rigid wall passing over a fixed frictionless pulley at a distance of 4
m from the wall has a point mass M = 2 kg attached to it at a distance of 3 m, from the wall. A mass
m = 0.5 kg attached at the free end is held at rest so that the string is horizontal between the wall
and the pulley, and vertical beyond the pulley. What will be the speed (in m/sec) with which the mass

M will hit the wall when mass m is released? (Take g = 10m/s2)

5) A small ring of mass m attached at an end of a light string, the other end of which is tied to a
small block B of mass 2 m. The ring is free to move on a fixed smooth horizontal rod as shown. The

velocity of the ring when the string becomes vertical is . (it is given that speed of ring is
double that of speed of block when string become vertical). Find the value of x

6) A bead kept at the bottom of a wedge moves towards right with a velocity 2v. If he wedge moves
towards left with a velocity v while accelerating towards right with an acceleration a as shown then
the magnitude of acceleration of the bead is x units. Find x if v = 3 and R = 9, a = 4 (all values are in
SI units)

CHEMISTRY

SECTION-I(i)

1) If 0.5 mol of BaCl2 is mixed with 0.1 mole of Na3PO4, the maximum number of mole of Ba3(PO4)2
that can be formed is:-

(A) 0.7
(B) 0.05
(C) 0.30
(D) 0.10
2) The ratio of minimum wavelengths of Lyman & Balmer series will be :-

(A) 1.25
(B) 0.25
(C) 5
(D) 10

3) Which is most acidic oxide ?

(A) Cl2O
(B) ClO2
(C) Cl2O6
(D) Cl2O7

4) If the magnetic moment of a dioxygen species is 1.73 B.M. it may be :

(A)
(B)
(C)
(D)

SECTION-I(ii)

1) For an ideal gas :

(A)

(B)

(C)

(D)

2) An open ended mercury manometer is used to measure the pressure exerted by a trapped gas as
shown in the figure. Initially manometer shows no difference in mercury level in both columns as

shown in diagram. After sparking 'A' dissociates according to

following reaction 2A(g) → 3B(g) + 2C(g) If pressure of Gas "A" decreases to 0.8 atm. Then (Assume
temperature to be constant and is 300 K)
(A) total pressure increased by 1.3 atm
(B) total pressure increased by 0.3 atm
(C) total pressure increased by 22.3 cm of Hg
(D) difference in mercury level is 228 mm.

3) The van der Waal's constants of a gas are

a = 0.751 dm6 atm mol–2 b = 0.0226 dm3 mol–1
Calculate the approximate critical constants.

3 –1
(A) VC = 0.678 dm mol
3 –1
(B) VC = 0.0678 dm mol
(C) PC = 54.5 atm
(D) TC = 120 K

SECTION-I(iii)

1)

List-I List-II

(P) attractive tendency dominates (1)

at the Boyle's temperature in the high pressure

(Q) (2) Z < 1
region

For a gas at very very low pressure and very very

(R) (3) Z > 1
high temperature

(S) At the critical point (4) Z = 1

(A) P → 4;Q → 1;R → 2;S → 3
(B) P → 2;Q → 3;R → 4;S → 1
(C) P → 2;Q → 4;R → 3;S → 1
(D) P → 1;Q → 3;R → 2;S → 4

2)

List-I List-II

(P) (1)

(Q) (2)
 (R) (3)

(S) (4)

(A) P → 4;Q → 3;R → 2;S → 1

(B) P → 4;Q → 2;R → 3;S → 1
(C) P → 1;Q → 3;R → 4;S → 2
(D) P → 3;Q → 2;R → 1;S → 4

3)

List-I List-II
(Thermodynamic Process/Condition) (Jumbled Options)

(P) Isothermal expansion of an ideal gas (1) w = 0

(Q) Adiabatic process (2) q +w

(R) Isochoric process (3) ΔU = 0

(S) Change in Internal energy (4) q = 0

(A) P → 1;Q → 3;R → 2;S → 4
(B) P → 1;Q → 4;R → 2;S → 3
(C) P → 2;Q → 1;R → 3;S → 4
(D) P → 3;Q → 4;R → 1;S → 2

SECTION-II

1) The As–Cl bond distance in AsCl3 is 2.20 Å. Estimate the SBCR (single bond covalent radius) in Å
of As. (Assume EN of both to be same and radius of Cl = 0.99 Å)

2) Calculate the difference (in eV) in first ionization energy of H and second ionization energy of He.

3) A diatomic molecule has a dipole moment of 1.2 D. If bond length is 1.0 Å, what percentage of an
electronic charge exists on each atom.

4) Water expands when it freezes. Determine magnitude of work in joules, done when a system
consisting of 1.0 L of liquid water freezes under a constant pressure of 1.0 bar and forms 1.1 L of
ice.
5) Assuming that the air is essentially a mixture of nitrogen and oxygen in mole ratio of 4 : 1.
Calculate the partial pressures of N2 in mm Hg on a day when the atmospheric pressure is 750 mm
of Hg. Neglect the pressure of other gases.

6) For one mole of a van der Waals gas when b = 0 and T = 300K, the PV vs. 1/V plot is shown
below. The value of the van der Waals constant 'a' (atm. liter2 mol–2) is -

MATHEMATICS

SECTION-I(i)

1) The number of integral values of m for which the quadratic expression.

(1 + 2m)x2 – 2(1 + 3m)x + 4(1 + m), x ∈ R, is always positive, is :

(A) 8
(B) 7
(C) 6
(D) 3

2) Let , then the maximum value of f(x) , is-

(A) 2
(B) 4
(C) 6
(D) 8
3) Value of expression is:-

(A) cos 2x
(B) cos2x
(C) 2cosx
(D) 1 + cosx

4)

Let λ1, λ2 ∈[0,π] are the solutions of the equation ,

then 8(sin2λ1 + sin2λ2) is equal to

(A) 2
(B) 4
(C) 6
(D) 8

SECTION-I(ii)

1) Let a1, a2, a3, .......be an arithmetic progression with a1 = 7 and common difference 8. Let T1, T2,
T3,....be such that T1 = 3 and Tn+1 – Tn = an for . Then, which of the following is/are TRUE?

(A)
(B)
(C)
(D)

2) The system of equations has -

(A) unique solution only for

unique solution for
(B)

(C) infinite number of solution for

(D) no solution for

3) Solution of the equation can be

(A)

(B)

(C)

(D)
 SECTION-I(iii)

1) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

Distance between the two lines and

(P) (1) 1
is

The variable line x + λy + λ – 5 = 0 (λ ∈ R) passes through

(Q) (2) 2
a fixed point. The x co-ordinate of fixed point is

The x-coordinates of the point of intersection of lines 3x +

(R) 4y = 9 and y = mx + 1 is an integer, if m is also an integer (3) 5
then sum of possible values of m is

The x-coordinate of incentre of triangle, whose

(S) (4) –3
vertices are and (2,0), is
(A) P → 2;Q → 3;R → 1;S → 4
(B) P → 2;Q → 3;R → 4;S → 1
(C) P → 3;Q → 2;R → 4;S → 1
(D) P → 1;Q → 2;R → 4;S → 3

2)

Matching Type

List-I List-II

(P) The least positive integer x, for which (1)

is positive, is equal to

If the quadratic equation 3x2 + 2(a2 + 1) x + (a2 – 3a

(Q) + 2) = 0 possess roots of opposite sign then a can (2) 1
be equal to

The roots of the equation

(R) (3) 6
can be
equal to

If the roots of the equation x4 – 8x3 + bx2 – cx + 16

(S) = 0 are all real and positive then 2(c – b) is equal (4) 16
to

(5) 10
(A) P → 1;Q → 3;R → 4;S → 2
(B) P → 4;Q → 2;R → 3;S → 5
(C) P → 5;Q → 2;R → 3;S → 4
(D) P → 2;Q → 1;R → 3;S → 4
3) Match the trigonometric expression to their range :

List-I List-II

(P) (1) [–1, 0]

(Q) (2)

(R) sin(2 cosx) (3) [–1, 1]

(S) (4) [–5, 5]

(5) [0, 1]
(A) P → 4;Q → 3;R → 2;S → 1
(B) P → 3;Q → 4;R → 1;S → 2
(C) P → 5;Q → 3;R → 3;S → 1
(D) P → 5;Q → 2;R → 3;S → 4

SECTION-II

1) Given and if , then X is equal to

2) If
then
|(a – b)3 + (b – c)3 + (c – a)3| is equal to

3) The interior angle bisector of angle A for the triangle ABC whose coordinates of the vertices
are A(–8, 5); B(–15, –19) and C(1, – 7) has the equation ax + 2y + c = 0. Then the value of a + c is

4) If the slope of one line of the pair of lines represented by ax2 + 10xy + y2 = 0 is four times the
slope of the other line, then a =

5)

Number of integral values of x which is satisfy the inequality log10(x2 – 16) ≤ log10(4x – 11) is

6) The number of terms common to the two A.P.'s 3, 7, 11, ...... 407 and 2, 9, 16, ......709 is
 ANSWER KEYS

PHYSICS

SECTION-I(i)

Q. 1 2 3 4
A. B A C B

SECTION-I(ii)

Q. 5 6 7
A. A,C A,B,C A,C,D

SECTION-I(iii)

Q. 8 9 10
A. D C B

SECTION-II

Q. 11 12 13 14 15 16
A. 5.00 4.00 2.50 5.87 8.00 9.00

CHEMISTRY

SECTION-I(i)

Q. 17 18 19 20
A. B B D A

SECTION-I(ii)

Q. 21 22 23
A. C,D B,D B,C,D

SECTION-I(iii)

Q. 24 25 26
A. B A D

SECTION-II

Q. 27 28 29 30 31 32
A. 1.21 40.80 25.00 10.00 600.00 1.5

MATHEMATICS
 SECTION-I(i)

Q. 33 34 35 36
A. B C C C

SECTION-I(ii)

Q. 37 38 39
A. A,C,D B,D A,B,C

SECTION-I(iii)

Q. 40 41 42
A. B D C

SECTION-II

Q. 43 44 45 46 47 48
A. 2.00 24.00 89.00 16.00 1.00 14.00
 SOLUTIONS

PHYSICS

1)

Explanation Question: We have to find average speed of moving car

Concept: This question is based on motion in 1D
Solution:

We known that,

So, let the time taken to cover first 30 km is t1

hours = hours
and let the time taken to cover next 30 km is t2

hours = hours

So, the total time = hours

Average speed = =

Average speed = km/hr.

Final Answer
The correct option is (2)

2)

Explanation Question: We have to find minimum acceleration of A so that it is at rest

Concept: This question is based on simple application of NLM

Solution: As block is at rest
so,

FBD of B wrt A. [B is at rest wrt A]

Final Answer option : (1)

3) F ∝ t–1/2
ma ∝ t–1/2
a ∝ t–1/2

v ∝ t1/2
∴ KE ∝ v2

4) Question Explanation:
The problem asks to find the maximum height reached by a mass 2m on a smooth circular
track of mass m. The track is initially given horizontal velocity of towards the left and
released.
Concept:
This question is based on conservation of momentum, conservation of energy.

Solution: Let v be the final speed of system.

By conserving momentum

......(1)
By W.E.T.

.....(2)
On solving we get

Final answer:
The correct option is (2).

5)

since it stops at x = 1
Hence acceleation should be –ve at some point.
Also acceleraiton can take any value.

6)
7)
using work-energy theorem :
wmag + wT + wN + wf = 4k

⇒ (mg sin α) (ℓ sin ϕ) + 0 + 0 – µmgcos α(ℓϕ) =

⇒ v2 = 2gℓsinα sin ϕ – 2µgℓϕcosα ....(1)
In radial direction,

T – (mg sin α)sin ϕ = ......(ii)

On solving equation (1) and equation (ii)
T = mg (3 sin ϕ sinα – 2 µϕ cos α)

To maximise T,

⇒ϕ=
Also,

To maximise
⇒&νβσπ ϕ = cos–1(µ cot α)

8)
at t = T ; vx = 0 ⇒ 10√3 - 5√3 T = 0

∴ T = 2 sec ⇒ OP = × 5 × (2)2 = 10

OQ = 10√3 × 2 - × 5√3 × 2 × 2 = 10√3

∴ PQ = 20 ⇒ at Q ⇒ v = vy = 5 × 2 = 10
Hmax = + 5 = 11.25 + 5 = 16.25

9)
N sin53° + N sin53° = 100

Newton

10)

11) x = t2 – 4t + 4
v = 2t – 4
v = 0 at t = 2 sec, particle turns back at
 t = 2 sec.
x0 = 4, x2 = 0, x3 = 1

12)

Tension is uniformly transmitted if the springs are massless.

13)

14) by conservation of energy

v cos 37 = ∴ v = 5.87 m/s

15)

from equation (i) & (ii)

16)

Answer

CHEMISTRY

17)

3BaCl2 + 2Na3PO4 → Ba3(PO4)2 + 6NaCl

i: 0.5 0.1 — —
r
–0.15 –0.1 0.05 0.033
:
f
0.35 0 0.05 0.033
:
 18)

19) High O.S → High E.N → High acidic strength

20) μ = 1.73 BM → 1 unpaired electron

21) For ideal gas internal energy is a function of temperature only.

22)

2A → 3B + 2C
i: 1 — —
r: –x +x

f: 1–x x
1 – x = 0.8 ⇒ x = 0.2 ⇒ PT = 1.3

23) VC = 3b = 0.0678

24)

Compressibility factor decreases due to attraction and in creases due to repulsion.

25)

According to Boyle's law PV = K

26)

ΔT = 0 ⇒ ΔU = 0
ΔU = q + W
adiabatic ⇒ q = 0
 isochoric ⇒ w = 0

27) rCl + rAs = 2.2

rAs = 2.2 – 0.99 = 1.21

28)
[Link] = 13.6, [Link] = 13.6 × 4
= 40.8

29) Theoretical μ = 1.6 × 10–19 × 10–10 cm

= 4.8 D

30) w = –PΔV
= –1 (1.1 – 1) = –0.1 L bar
|w| = 10 J

31)

32)

Slope of PV and is (–a)

a = 1.5

MATHEMATICS

33) Exprsssion is always positve it

2m + 1 > 0 ⇒ m > – & D < 0 ⇒ m2 – 6m – 3 < 0

.... (iii)
∴ Common interval is
3– <m<3+
∴ Intgral value of m {0,1,2,3,4,5,6}

34) C1 → C1 + C2 + C3
(2 + 4sin2x)
R2 → R2 – R1; R3 → R3 – R1

(2 + 4sin2x)
⇒ (2 + 4sin2x) (1)
(ƒ(x))max = 2 + 4 = 6

35)

= 2cosx

36)

Explaining the Question :- In this question, we have to find solution for given trigonometric
equation and then find value of given expression.

Concept:- Solving trigonometric equation.

Solution :- Given equation is

cosec + cosec

⇒
 [using 2sin A sin B = cos(A – b) – cos (A + B)]

⇒ cos x = cos 2x

⇒ cos x = 2 cos2 x – 1

⇒ 2cos2 x – cos x – 1 = 0

⇒ (2 cos x + 1) (cos x – 1) = 0

⇒ or cos x = 1

∵ x∈[0, π) ⇒ cos x = cos 0

⇒ ⇒ x=0

So l1 = & l2 = 0

=
Final Answer :- Option 3

37)

an = 8n – 1
Tn+1 – Tn = 8n –1
T2 – T1 = 8 × 1 –1
T3 – T2 = 8 × 2 –1
T4 – T3 = 8 × 3 – 1
.
.

Tn+1 – T1 = 4n(n+1) – n
Tn+1 = 4n2+3n+3
38)

for unique solution D ≠ 0 ⇒ α ≠ 8

for no solution D = 0, atleast one of Dx Dy Dz non-zero
⇒α=8

39) Question Explanation: Find the solutions of the equation sinθ+sin7θ=sin4θ.

Concept: Solving a trigonometric equation using sum-to-product identities.
sin θ + sin 7θ = sin 4θ
2 sin 4θ cos 3θ = sin 4θ

cos θ=

Final Answer:

40) (R)
m = –1, –2
sum = –3
(S) Triangle is equilateral

41)

(P)
 Ans. :
least positive Integer = 1
(P → 1)
(Q) 3x2 + 2(a2+1)x + (a2–3a+2) = 0

0 + 0 + a2 – 3a + 2 < 0
a (a–1) (a–2) < 0

a∈ (– ∞, 0) U (1, 2)

Ans. (p)

(R)

_(A)
for

x –1 ⇒x _(1)
also

x–1 ⇒x _(2)
Case-I : when 1 in equation (A)

x=5
x=5

No solution
Case-II : when

1=1
(x∈R)
solution : x∈ [5,10)
Case-III : When x

⇒ x = 10
from case- I, II & III
Ans x = 6, 10 (R,T)
40. Corrections
Ans. Key correction
(P) → (2), (Q) → (1), (R) → (3,5),(S) → (4)

(S) x4–8x3 + bx2 – cx + 16 = 0

α+β+γ+δ = 8
Σαβ = b
Σαβγ = c
αβγδ = 16
since α,β,γ,δ are positive

equality holds
∴α=δ=γ=δ=2
Σαβ = b = 6(4) = 24
Σαβγ = c = 4 (8) = 32
2(c-b) = 2(32–24) = 16

42) Do yourself

43) ∵

44)
(a – b)(b – c)(c – a) = ±8
|(a – b)3 + (b – c)3 + (c – a)3|
= |3(a – b)(b – c)(c – a)| = 24

45) Equation of AC is

3y – 15 = –4x – 32

Equation of AB y – 5 = (x + 8)

7y – 35 = 24x + 19
24x – 7y + 227 = 0

Internal angle bisector of angle A is

⇒ 20x + 15y + 85 = 24x + 7y – 227
44x + 8y + 312 = 0
⇒ 11x + 2y + 78 = 0
So a = 11
c = 78

46) m1 + m2 = –10

m1m2 =
given m1 = 4m2 ⇒ m2 = –2, m1 = –8,
a = 16

47)

x2 – 16 > 0
x ∊ (–∞, –4) ⋃ (4, ∞)
4x – 11 > 0

x>
x2 – 16 ≼ 4x – 11
⇒ (x + 1) (x – 5) ≼ 0
⇒ x ∊ [–1, 5]
Taking Intersection
x ∊ (4, 5]
∴ No. of integral value of x = 1

48) First A.P's sequence is 3, 7, 11, ....., 407

General term will be
Second A. P's sequence is 2, 9, 16, ....., 709
General term will be
The common terms will be
51, 79, ..., 28m + 51
Ans adding the 2 starting number count of the 2 A. P's i.e. 3 & 2
Number of common terms will be
12 + 2 = 14