Binding Energy and Nuclear Stability
Binding Energy and Nuclear Stability
(2-1)Binding Energy
1
When the lack of mass is converted into energy according to Einstein's
equation, binding energy is produced, which can be represented by the
following equation:
But in most tables, the mass of the atom is given instead of the mass of
the nucleus, so equation (3-2) can be written as follows:
Note from equation (2-4) replacing the mass of the proton with the mass
of the hydrogen atom because it contains an electron, in order to delete
the electron masses in the atomic masses of the elements (see Appendix -
II-).
The binding energy per nucleon can be defined as the ratio between the
nuclear binding energy and the mass number of the nucleus, ie:
B.E
...(2-5)
A
as:
so the:
B.E 16.54MeV
B.E [ ZM H NM N M ( A, Z )]C 2
3
because the two oxygen nuclei have self-bonding energy, which
represents the bonding energy (16) nucleons for each nucleus.
To calculate the emission energy of a helium nucleus (alpha
particle) from some nuclei, especially the heavy and radioactive ones for
238
these particles, we take the uranium nucleus ( 92U146 ) as it is composed
4 234
of a helium nucleus ( 2 He2 ) and a thorium nucleus ( 90Th144 ), its
bonding energy will be:
The negative value of the binnding energy means that the uranium
nucleus decomposes into a helium nucleus and a thorium nucleus, and
this is a certain fact, since uranium nuclei have radioactivity in which
these nuclei radiate, and this energy can be called the emission energy of
4
But if the reverse process is performed, i.e. the fusion of the
nucleus (A-1,Z) and the neutron (n) to form the nucleus (A,Z), an energy
will be released exactly equal to ( ), which is called the fusion energy.
p [m p M( A 1, Z 1) M ( A, Z )] C 2 ... (2-8)
the number of protons is greater than the number of neutrons, the nuclei
graph is drawn between the values of (N) as the y-axis and (Z) as the x-
axis, it will produce a straight line that passes through the origin, as
shown in Figure (2-1), where we notice from the figure that the stable
nuclei are concentrated around this line (as for the unstable nuclei) In the
direction of decay ( ) they will concentrate below this line and the
the line ( ). Figure (2-1) shows that the stability line in the light nuclei
5
increasing the number of neutrons to overcome the repulsive Coulomb
energy of the protons.
Second: The odd and even formula for the numbers of protons and
neutrons have an important role in the stability of the nucleus, and Table
(2-1) shows this.
Table(2.1): The stability of the nucleus as a function of the odd and even
formulas for the numbers of protons and neutrons.
7
Figure(2-2): Binding energy per nucleon as a function of mass number.
8
The nuclear force has a short range within ( 10 15 m ) and vanishes
(up to zero) at a distance ( 10 10 m ) i.e. within the size of the atom and does
not follow the inverse square law. one as one particle. This force tries to
make the nucleus spherical and make the nucleons in the form of pairs.
The nuclear force is saturated, meaning that each nucleon inside
the nucleus can deal (interact) with force with a limited number of
nucleons surrounding it. From Figure (2-2), we note that the rate of
nuclear bonding energy for each nucleon is approximately equal, and this
means that the nuclear force is saturated.
The nuclear force does not depend on the charge and type of the
nucleon, meaning that the nuclear forces that bind two protons(P-P) or
two neutrons (n-n) or a neutron and a proton (P-n ) are equal.
In 1935, the scientist Hideki Yakawa hypothesized the first
important theory to explain the nuclear force to explain how the nucleus
is held together through an effort that combines the components of atomic
nuclei of protons and neutrons. This attractive potential explains the lack
of dissociation of the nucleus under the influence of the repulsion of the
positively charged protons.
The nuclear force between nucleons occurs as a result of the
exchange of particles between them, which are called pi mesons. These
particles have a very short lifespan so that they cannot be detected when
conducting practical experiments, so they were theoretically imposed as
imaginary particles as well as being heavy particles (their mass is greater
than the mass of the electron by 270 times It was referred to by the
scientist Yukawa (Yakawa) in the year 5193 AD, and it was
experimentally proven in the year 1937 AD, and he was awarded the
Nobel Prize in 1949 AD.
To express the Yukawa voltage V(r), it can be represented by the
following equation:
9
( ) ...(2-9)
We notice from Figure (2-4) that the potential between two protons
contains a repulsive Coulomb potential, which represents the positive part
of the figure. As for the potential between a proton-neutron and a
neutron-proton and a neutron-neutron, there is no positive potential
because the neutron is neutral.
11
There are three types of pions: a zero-pion ( ) produced when a
proton turns into a proton or a neutron into a neutron, a positive-pion
( ) when a proton turns into a neutron, and a negative ion ( ) when A
neutron is converted into a proton according to the following equations:
ℏ ℏ
ℏ
...(2-10)
Whereas:
11
We note from equation (2-10) that the value of the distance
traveled by the pion is within the diameter of the nucleus, and this proves
that the nuclear force is within the ionic (short-range) range.
Table(2-2): The four forces, their strength, their range, and the
interchangeable particles
الجسيواخ الوتثادلح
) تايىىPion (
12
(2-5) Nuclear Models
The liquid drop model is the first model that appeared to explain the
structure of the nucleus. It resembles the state of atoms in a solid and
molecules in a liquid. In the solid state, the atoms vibrate around fixed
points in a crystalline arrangement, while the molecules in liquids move
almost freely while maintaining a constant distance between them, The
nuclei of atoms resemble a liquid drop in their behavior, so this model was
called the liquid-drop model, meaning that the components of the nucleus
move randomly within the [Link] Weizsäcker in 1935 and continued
to make adjustments to the constants of the equation for subsequent years.
The basic assumptions of the nucleus as a drop of liquid are that it
be homogeneous in charge and not retractable, and that the nuclear force
does not depend on the charge and that it is a saturated force, so nucleons
interact only with their neighbors. This model is considered one of the
most comprehensive, applied models and a special explanation of the
phenomenon of nuclear fission (the fission of the drop when exposed to
any disturbance into two equal masses) and the calculation of the mass of
the nucleus and the estimation of the radius, but it failed to explain the
extrapolation of nuclei that have magic numbers of protons and neutrons.
This model relied on the following energies to calculate the total
bonding energy, which are as follows:
EV 5 AU av A
Surface Energy: There are some nuclei on the surface of the nucleus
and they are surrounded by less than 10 nuclei, for example. The number
of surface nuclei in the nucleus depends on its surface area. If the surface
area of a nucleus, its mass number (A) is:
ES as A2 / 3
will reduce the binding energy of the nucleus by ( ) this
energy plays an important role in the case of light nuclei because there is
a large percentage from the surface nuclei. Since the spherical surface
constitutes the smallest area surrounding a specific volume, and in the
absence of an external force, the nucleus will take a spherical shape.
14
Coulomb's Energy: This energy plays an important role in the
binding energy and stands out in the case of medium and heavy nuclei. If
we have a nucleus with atomic number (Z), then this energy is equal to
the work needed to collect (Z) protons within a volume equal to the
volume of the nucleus. Therefore, the Coulomb energy is directly
proportional to [Z(Z-1)/2] which represents the pairs of protons in the
nucleus and inversely with the radius of the nucleus (R = R 0 A1/3), and the
amount of this energy is:
( ) ( )
The total binding energy (Eb) of a nucleus is equal to the sum of the
three energies: volume energy, surface energy, and colomb energy. It is
equal to:
Z ( Z 1)
Eb av A as A2 / 3 ac ...(2-11)
A1 / 3
Eb a Z ( Z 1)
av 1s/ 3 ac ...(2-12)
A A A4 / 3
Figure (2-6) shows the change of the three terms in this equation.
15
Figure(2-6): Binding energy per nucleon as a function of mass number
(volume, surface, and coulomb energies).
Asymmetry Energy: It was noted that the ratio between the number
of protons and neutrons in the stable light nuclei is (1), meaning that (N =
Z) and it was found that this fact changes in the heavier nuclei (N ≠ Z),
where their stability is relatively less due to the difference between the
numbers of protons and neutrons as shown in the figure (2-7) meaning
that:
N Z ( A Z ) Z A 2Z
This energy will reduce the total binding energy and equal to:
( )
The coupling energy depends on a factor called the coupling factor (δ),
which can be represented by the following formula:
EP P aP A1/ 2
Whereas:
Z ( Z 1) ( A 2Z )
2
B.E aV A a S A 2/3
aC 1/ 3
aa EP ...(2-13)
A A
Z ( Z 1) ( A 2Z ) 2
M ( Z , A) Zm p Nmn (aV A a S A2 / 3 aC 1/ 3
aa EP ) / c 2
A A
...(2-14)
17
,
Figure (2-9): shows the energies on which the total binding energy
depends and shown in equation (2-14).
18
(2-5-2) Shell Model
19
There are other observations that indicate the importance of the
numbers 2, 8, 20, 28, 50, 82 and 126 in the nuclear structure, so these
numbers are called the magic number, and from these observations is the
nuclear quadruple moment, which represents the distance distribution The
nuclear charge is about the spherical distribution, the spherical nucleus
does not have a quadruple moment, while the oval-shaped nucleus has a
positive moment and the pear-shaped nucleus has a negative moment.
21
Figure(2-10):The sequence of energy levels according to the shell
model
21
The shell model can explain several nuclear phenomena in addition to
magic numbers:
The nuclei are (even Z , even N): The levels of these nuclei are filled
with even numbers of protons and neutrons in the secondary levels, and
they are more stable and the total angular momentum is zero, as the
perpendicular and orbital momentum of these nuclei erase each other, and
there are about 160 even-even stable nuclei.
The nuclei are (odd Z , odd N): The levels of these nuclei are filled with
odd numbers of protons and neutrons in the secondary levels and are less
stable, and the total angular momentum (the sum of the spin and orbital
momentum of these nuclei) is equal to an integer, and there are only four
The nuclei are even-odd or the nuclei are even-odd: The levels of these
nuclei contain a single particle, either a proton or a neutron in the
secondary levels, and the total angular momentum (the sum of the spin
and orbital momentum of these nuclei) is equal to half of the integers.
Theory of Shell Model
The one-particle shell model is based on two main assumptions:
1- Every nucleus moves freely and fluently in the force field, which is
expressed as potential.
2- Applying the Pauli Selection Principle, meaning that the energy
levels or shells are filled with respect to the Selection Principle.
According to quantum mechanics, we will show a general model that
includes the existence of shells or nuclear levels using the nucleus voltage
V(r) in the form of the square well potential and the harmonic oscillator
potential on the basis that the nuclei are spherical, as shown in Figure
(2-11).
22
Figure(2-11): Harmonic oscillator voltage and well voltage.
23
In the case (2P), it splits into two secondary levels due to the interaction
of spinning with the orbital to give the state (2P1/2) and the state (2P3/2)
and these levels are filled with (2J+1) nuclei, i.e.:-
2 P1 / 2 (2 1 / 2) 1 1 1 2
2 P3 / 2 (2 3 / 2) 1 3 1 4
The angular momentum (nuclear spin) and nuclear symmetry for any
nucleus in the ground state can be estimated according to the following
two assumptions:
Based on these two assumptions, we can arrive at the following two basic
rules:
First rule: The total angular momentum* for any nucleus in the ground
state whose number of nucleons (even - even) is equal to zero and
therefore the symmetry will be positive.
J n 0 , J P 0
Second rule:
a- The nucleus in which ( odd Z , even N ) is and the ground state for
spinning the nucleus depends on spinning the last proton.
24
b- The nucleus in which (even Z, odd N) is spinning and the ground
state for spinning the nucleus depends on spinning the last neutron.
c- The nucleus in which (odd Z, odd N) is calculated by calculating
the ground state in relation to spinning the nucleus from the last
dissolution into a neutron and two helium nuclei ( 24 He2 ), then find the
total bonding energy of a beryllium nucleus.
9
4 Be5 01n 224He2
58 MeV
25
Example(2)
Sol:
3
1 H 2 11p 01n 01n
p (13H 2 ) [m p 2m( 01n ) M (13H 2 )]c 2
7.97 MeV
3
2 He1 11p 12H1
5MeV
We note from the above results that the energy to separate a proton
Is the beryllium nucleus ( 48 Be4 ) stable for alpha particle decay? Explain
this.
26
Sol:
8
4 Be4 24 He2 24He2
16.097 MeV
What is the minimum energy that can be expended for a fluorine nucleus
19
9 F10 ) to split into a proton, a nucleus ( 37 Li4 ) and a nucleus ( 151B6 )?.
19
9 F10 11p 37Li4 11
5 B6
cleavage is ( 31.02668MeV ).
Example(5)
Prove that the nuclear force does not depend on the charge by taking the
27
( 1.008665–3.016049) 931.5
= 8.5 MeV
( ) ( ( ))
( 1.007825 )
= 7.72 MeV
There is a difference in the bonding energy between the two nuclei
resulting from the repulsion force between the two protons of the helium
nucleus, so we will calculate the Coulomb energy as follows:
( )]
= ( )]
( )]
=
( )
( )
28
kg
( )
Example(7)
Calculate the coupling energy using the liquid drop model for the
following nuclei:
Sol:
As for the carbon-12 nucleus, it has the number of protons (6) and the
number of neutrons (6), meaning that it is an even-even nucleus, so the
pairing energy is:
( )
As for the nitrogen-13 nucleus, it has the number of protons (7) and the
number of neutrons (6), meaning that it is an odd-even nucleus, so the
pairing energy is:
As for the nitrogen-14 nucleus, it has the number of protons (7) and the
number of neutrons (7), meaning that it is an odd-odd nucleus, so the
pairing energy is:
( )
Example(8)
Sol:
29
The volumetric energy is calculated from the following equation:
Why is the surface energy less than the volumetric energy? Leave the
answer to the student.
Example(9)
Find the nuclear spin and symmetry of the ground state of the calcium
nucleus, which contains (Z=20) protons and (N=23) neutrons,
according to the shell model?
Sol:
The levels can be filled with protons and neutrons according to the shell
model, as follows:
First: Filling the first level (S-state) (ℓ = 0), the total angular momentum
is calculated from the sum of the spin of the proton (S=1/2) and the
orbital angular momentum (ℓ = 0), i.e. (j=ℓ+s), j=1 /2)), so the number of
protons will be (2j+1=2(1/2)+1=2), and the plane will be filled with two
protons. It will be the same for neutrons.
Second: Filling the second plane (state-p) (ℓ = 1 ), calculating the total
angular momentum from the sum of the spin of the proton (S=1/2) and
the orbital angular momentum (ℓ = 1) i.e. j= ℓ ±s) j=1 /2, 3/2)), and here
we will have two levels, the first will be filled with two protons
2j+1=2(1/2)+1=2)), and the second will be filled with four protons
2j+1=2(3/2) +1=4)). It will be the same for neutrons. And so for the rest
of the levels, where the distribution continues until reaching the level (f).
31
The ground state is calculated from the last single proton or neutron in the
last plane.
The figure below shows the distribution of protons and neutrons for a
calcium-43 nucleus. From the figure, we notice that the ground state of
the nucleus is (1 ), meaning that the nuclear spin is equal to (7/2),
and the symmetry will be:
، ( ) ( ) ( )
So, the ground state of the calcium-43 nucleus is: (( ) .
Example(10)
Find the nuclear spin and symmetry according to the shell model for the
following nuclei:
Note: The nuclear spin of the even numbers of nucleons is equal to zero
according to the shell model.
31
Sol:
( ) ( )
( ) ( )
( ) ( )
( ) ( )
( )
( ) ( )
( )
( )
32
( ) ( )
( )
( )
( ) ( )
( )
( )
( ) ( )
( )
33
و ( )
( ) ( ) ( )
8. Oxygen-16
In this case, the nuclear spin and symmetry will be calculated from the
last neutron and these neutrons will be filled as follows:
( ) ( ) ( ) ( )
The last neutron will be in the plane (1d 5/2), so the nuclear spin is equal
to (5/2), and the symmetry is calculated as follows:
d – state
So the symmetry
( ) ( )
34
10. Nitrogen -14
Since the number of neutrons and the number of protons is odd, so for
protons it will be.
( ) ( )
As for the neutrons:
( ) ( ) ( )
( ) ( ) ( )
So the nuclear spin would be JP-Jn and JP+ Jn So the nuclear spin would
be:
The symmetry will be the product of the symmetry of the last proton and
the last neutron as follows:
( )( )
( )
So, the ground state of the nucleus is:
35
Chapter two questions and problems
Q1/ Define binding energy and what is the relationship between it and
the stability of the nucleus?
Q2/ What is the difference between the energy of emitting a neutron and
the energy of emitting a proton from a nucleus, which is greater and
why?
Q3/ What is the idea of the liquid drop model of the nucleus?
Q6/ Calculate the total binding energy for the following nuclei ( 168O8 ),(
4
2 He2 ) and ( 126C6 ).
Q7/ Find the proton separation energy and the neutron separation energy
of the two nuclei ( 24 He2 ) and ( 12 H 1 ), and what can you conclude from the
results that you will get?
Q8/ Calculate the binding energy for each nucleon and compare the
6
results for the following nuclei 208 62
82 Pb126 , 28 Ni34 , 3
Li3 .
24
Q9/ Which is more stable, the magnesium nucleus ( 12 Mg12 ) or the
27
aluminum nucleus ( 13 Al14 )?.
Q11/ How much energy is needed to split the lithium nucleus ( 36 Li3 ) into
three equal nuclei?
36
Q12/ Calculate the energy of separating a proton and a neutron from a
nucleus ( 23 He1 ), and is there a difference between them and why?
20
Q15/ Calculate the mass of the nucleus ( 10 Ne10 ) according to the liquid
drop model.
Q16/ Distribute the nucleons according to the shell model for the
36 35 32
following nuclei ( 18 Ar18 ), ( 17 Cl18 ) and ( 16 S16 ).
Q17/ Calculate the difference in the total binding energy of the iron
nucleus ( ) when it is calculated using the liquid drop model and
calculated by decreasing mass.
37