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Infrared Spectroscopy Vibration Modes

The document provides a detailed list of vibrational frequencies and their corresponding functional groups, including intensity and mode of vibration. It covers various types of bonds such as O-H, N-H, C-H, and C=O, along with their associated stretching and bending characteristics. The frequencies range from 3700 cm⁻¹ to 400 cm⁻¹, indicating the types of molecular vibrations present in different chemical groups.

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7 views1 page

Infrared Spectroscopy Vibration Modes

The document provides a detailed list of vibrational frequencies and their corresponding functional groups, including intensity and mode of vibration. It covers various types of bonds such as O-H, N-H, C-H, and C=O, along with their associated stretching and bending characteristics. The frequencies range from 3700 cm⁻¹ to 400 cm⁻¹, indicating the types of molecular vibrations present in different chemical groups.

Uploaded by

putugttires
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as XLSX, PDF, TXT or read online on Scribd

Frequency

Functional
(cm⁻¹) Group
Vibration
/ Bond Mode
Intensity
3700–3600Free O-H (aStretching Sharp, Medium
3600–3200H-bonded O- Stretching Broad, Strong
3500–3300N-H (amineStretching Medium
3300 ≡C-H (termiStretching Strong
3100–3000 0 Stretching Medium
3000–2850C-H (alkaneStretching Strong
2850–2750Aldehyde CStretching Weak
2260–2220C≡N (nitrileStretching Medium
2260–2100C≡C (alkyneStretching Weak
1760–1690C=O (carbon Stretching Strong
1710–1680C=O (carbox Stretching Strong, Broad
1650–1600C=C (alkenStretching Variable
1600–1450C=C (aromat Stretching Medium
1550–1500N-O (nitro AsymmetricStrong
1470–1450C-H (alkaneBending Medium
1375 C-H (methySymmetric Medium
1300–1000C-O (alcohoStretching Strong
1250–1020C-N (amineStretching Medium
1150–1050C-F (alkyl f Stretching Strong
1000–650 0 Bending (oVariable
950–800 O-H (carboxBending Broad
720 (CH₂)ₙ (n ≥ Rocking Medium
690 C-Br (alkyl Stretching Strong
600–500 C-I (alkyl i Stretching Strong
500–400 C-Cl (alkyl Stretching Strong

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