08-09-2024

9610YJA801445240002 JA

PART 1 : PHYSICS

SACTION-A

1) In the circuit shown if resistance of ammeter is 100Ω, reading of ammeter will be

(A) 0.2 A
(B) 0.05 A
(C) 0.1 A
(D) zero

2) When a 2Ω resistance is connected to a cell then 2A current flow in it and when 9Ω resistance is
connected to cell then 0.5 A current flow in it. Internal resistance of cell is -

(A) 1Ω
(B) 2Ω

(C)

(D)

3) Potential of certain points in circuit are maintained as marked. What is reading of voltmeter(If
ammeter reads zero)?

(A) 10V
(B) 25V
(C) 5V
(D) 20V
4) In the figure, capacitor is completely charged and switch is closed at t = 0. The time after which

the current from the capacitor becomes 1/4th of its maximum value will be :-

(A) 2 RC ln2

(B)

(C) RC ln2

(D)

5) Two parallel plate capacitors of capacitance C0 and 2C0 are connected in parallel and charged to a
potential difference V0. The battery is disconnected and the region between the capacitor plates of
capacitance C0 is completely filled with a dielectric of dielectric constant K. The potential difference
across the capacitors, now becomes :

(A)

(B)

(C)

(D)

6) An isolated parallel-plates capacitor has circular plates of radius 4.0 cm. Its gap is filled with a
partially conducting material of dielectric constant K and conductivity 5.0 × 10–4 Ω–1 m–1. When the
capacitor is charged to a surface charge density of 15 µC/m2, the initial current between the plates is
1.0 A. Determine the value of dielectric constant K (approximately).

(A) K = 1.32
(B) K = 4.26
(C) K = 8.74
(D) K = 2.1

7) On a rotating horizontal disk put a block, On it from above put an identical block connected by a
thread to axis of a disk. At what angular speed of rotation of a disk the bottom block will slip out?
When it lies alone, it starts to slide at angular speed ω0. Factors of friction between all surfaces are
identical.

(A)

(B)

(C)

(D)

8) Two moving particles P and Q are 10 m apart at any instant. Velocity of P is 8 m/s at 30° , from
line joining the P and Q and velocity of Q is 6m/s at 30°.Calculate the angular velocity of P w.r.t. Q

(A) 0.7 rad/s

(B) 0.9 rad/s
(C) 1 rad/s
(D) 1.2 rad/s

9) A particle is projected with velocity m/s at 45° with horizontal. After 1 s, find radius of
curvature of the trajectory at that point. (Take g = 10 m/s2)

(A) 25 m
(B)
(C)
(D)

10) In arrangement shown the block A of mass 15 kg is supported in equilibrium by the block B.

Mass of the block B is closest to :-

(A) 2 kg
(B) 3 kg
(C) 4 kg
(D) 5 kg

11) A painter of mass M stands on a platform of mass m and pulls himself up by ropes which hang
over pulley as shown. He pulls each rope with force F and moves upward with a uniform
acceleration a. Find a, neglecting the fact that no one could do this for long time

(A)

(B)

(C)

(D)

12) Three point masses m, 2m and m, connected with ideal spring (of spring constant k) and ideal
string as shown in the figure, are placed on a smooth horizontal surface

At t = 0, three constant forces F, 2F and 3F start acting on the point masses m, 2m and m
respectively, as shown in figure. Find the maximum extension in the spring

(A)

(B)

(C)

(D)

13) A particle of mass 5 kg is moving on rough fixed inclined plane with constant velocity of 5 m/s as
shown in the figure. Find the friction force acting on a body by plane.
(A) 25 N
(B) 20 N
(C) 30 N
(D) None of these

14) The block is initially at rest. Find the minimum force F required to move the block towards right

:-

(A) 30 N
(B) 50 N
(C) 37.5 N
(D) 40 N

15) A block of mass 2 kg is kept on a rough horizontal floor and pulled with a force F. If the
coefficient of friction is 0.5. then the minimum force required to move the block is :-

(A) 10 N

(B)

(C)

(D) 20 N

16)

Resistances R1 and R2, each , are connected in series. The potential difference between points A
and B is 120 V. Find the reading of voltmeter connected between points C and D if its resistance
.

(A) 40
(B) 20
(C) 48
(D) 52

17) If trolley accelerates horizontally with acceleration a then bob is displaced backward from its

initial vertical position. The angular deflection of the bob in equilibrium is :-

(A)
θ = cos–1
θ = sin–1
(B)

(C)
θ = cot–1
θ = tan–1
(D)

18) A long, straight wire of radius a carries a current distributed uniformly over its cross-section.

The ratio of the magnetic fields due to the wire at distance and 2a, respectively from the axis of
the wire is :

(A)

(B)

(C)

(D) 2

19) In the circuit shown here, what is the value of the unknown resistor R so that the total resistance

of the circuit between points 'P' and 'Q' is also equal to R :–

(A) 3 Ω
(B) Ω
(C) Ω
(D) 10 Ω

20) The value of equivalent capacitance of the combination shown in figure between the points P and
Q is :–

(A) 3 C
(B) 2 C
(C) C

(D)

SECTION-B

1) The figure shown below shows a circuit for which the resistance of each branch is 4Ω. Determine

the electrical resistance (in ohms) between points A and B.

2) A parallel plate capacitor having its lower end fixed and upper end is attached with spring having
spring constant K. Upper plate is in equilibrium before switch is closed. After switch is closed, the
condition on the potential of battery so that the system can acquire new equilibrium position is

. Then p + q + r is ? [p & q are smallest possible integers and V is potential

difference across the battery]

3) Nine identical capacitors, each of capacitance C = 15μF are connected as shown in Figure. The
equivalent capacitance between terminals 1 and 4 is (10 + n) μF. Find the value of n.
4) Consider two rings with radius r = 1.5 m as depicted in the figure: the ring-1 is at rest, and the
ring-2 rotates around the point O (which is one of the intersection points of the two rings) with a
constant angular speed ω = 2 rad/s. Find maximum speed (in m/s) of the other intersection point of

the two rings.

5) A small object placed on a rotating horizontal turn table just slips when it is placed at a distance
of 4 cm from the axis of rotation. If the angular velocity of the turn table is doubled, the object slips
when its distance from the axis of rotation is R cm. Find R (in cm)

6) A ring rotates about x–axis as shown in figure. The plane of rotation is y–z. At a certain instant the

acceleration of the particle P on the ring is . Find the ratio of tangential acceleration

to angular velocity .

7) In the arrangement shown in figure, a sphere of mass 1 kg kept at rest with the help of two
inclined plane. Plane OA makes fixed angle from horizontal (53°) and plane OB can make a variable
angle θ from the horizontal. Value of normal contact force (N) applied by plane OB on sphere
depends on angle θ. At some value of θ, value of N will be minimum. Find that minimum value of N
in newton.
8) Two blocks of masses 1 kg and 2 kg connected to each other through a light spring as shown. If
we push the block of 1 kg with a force 14 N, which cause acceleration 4 m/s2 in block of 1 kg, then

the acceleration (in m/s2) of block of 2 kg is :-

9) A block of mass 10 kg is pulled along horizontal surface by a rod of mass 2 kg. If coefficient of
friction between block and ground is 0.5 & force 15N is applied to the free end of the rod, then

tension at the mid point of the rope is x. Find the value of x/3.

10) Find acceleration of block B (in m/s2) if all surfaces are smooth.

PART 2 : CHEMISTRY

SECTION-A

1) A mixture containing 0.05 mole of K2Cr2O7 and 0.02 mole of KMnO4 was treated with excess of KI
in acidic medium. The liberated iodine required 1.0 L of Na2S2O3 solution in mild acidic medium for
titration. Concentration of Na2S2O3 solution was :

(A) 0.40 mol L–1

(B) 0.20 mol L–1
(C) 0.25 mol L–1
(D) 0.30 mol L–1

2) CN– is oxidised by NO3– in presence of acid :

a CN– + b NO3– + c H+ —→ (a + b) NO + a CO2 + H2O

What are the values of a, b, c in that order :

(A) 3,7,7
(B) 3,10,7
(C) 3,10,10
(D) 3,7,10

3) N2 + 3H2 ⟶ 2NH3, molecular weight of NH3 and N2 are X1 and X2 and their equivalent weight are
Y1 and Y2 respectively, then (Y1 – Y2) is :

(A) (2X1− X2)/6

(B) (X1 – X2)
(C) (3X1 – X2)
(D) (X1 – 3X2)

4) MnO4– is good oxidising agent in different medium changing to -

Changes in oxidation number respectively are -

(A) 1, 3, 4, 5
(B) 5, 4, 3, 2
(C) 5, 1, 3, 4
(D) 2, 6, 4, 3

5) If power of a bulb is 80 watt and wavelength of emitted radiation is 5000 Å, find number of
photons emitted per second :-

(A) 2 × 1010
(B) 2 × 1030
(C) 12 × 1010
(D) None of these

6) The shortest wavelength of hydrogen atom in Lyman series is λ. The longest wavelength in
Balmer series of He+ is

(A)
(B)

(C)

(D)

7) Which of the following statement is correct ?

If the mass number of two different nuclei are in the ratio 1 : 3, then according to Rutherford
(A)
formula, their diameters are in the ratio 1 : 27 respectively.
Rutherford's experiment, which established the nuclear model of the atom used a beam of He
(B)
atoms, which impinged on a metal foil and got scattered.
Isotopes have different number of protons, different number of electrons and different number
(C)
of nucleons.
The potential energy of a system consisting of two opposite charges decreases to a greater
(D)
negative value as the separation between two charges decreases upto a optimum distance.

8) The threshold wavelength for ejection of electrons from a metal is 330 nm. The work function for
the photoelectric emission from the metal is (h = 6.6 × 10-34 J-s)

(A) 1.2 × 10-18 J

(B) 6.0 × 10-19 J
(C) 1.2 × 10-20 J
(D) 6.0 × 10-12 J

9) For FCC arrangement, arrangement of sphere on given should plane will be :

(A)

(B)

(C)

(D)

10) An element crystallizes into a structure which may be described by a cubic type of unit cell
having one atom on each corner of the cube and two atoms on one of its body diagonals. If the
volume of this unit cell is 24 × 1024 cm3 and density of element is 7.2 g cm–3, calculate the number of
atoms present in 200 g of element

(A) 1.1513 × 1024

(B) 3.472 × 1024
(C) 10.416 × 1024
(D) None

11) What is the percent by mass of titanium in rutile, a mineral that contain titanium and oxygen, if
structure can be described as a closet packed array of oxide ions, with titanium in one half of the
octahedral holes. What is the oxidation number of titanium ?

(A) 30%, +4
(B) 60%, +2
(C) 60%, +4
(D) 30%, +2

12) What type of crystal defect is indicated in the diagram below ?

Na+ Cl– Na+ Cl– Na+ Cl–
Cl– ‫׵‬ Cl– Na+ ‫׵‬ Na+
+ – – +
Na Cl ‫׵‬ Cl Na Cl–
Cl– Na+ Cl– Na+ ‫׵‬ Na+

(A) Frenkel defect

(B) Schottky defect
(C) Interstitial defect
(D) Frenkel and Schottky defects

13) The volume of a colloidal particle, VC as compared to the volume of a solute particle in a true
solution VS, could be :-

(A)

(B)

(C)

(D)

14) For micelle formation, which of the following statements are correct?
(A) Micelle formation is an exothermic process.
(B) Micelle formation is an endothermic process.
(C) The entropy change is positive.
(D) The entropy change is negative.
(A) A and D only
(B) A and C only
(C) B and C only
(D) B and D only

15) Which of the following is true in respect of adsorption ?

(A) ΔH > 0 ΔS < 0 ΔG < 0

(B) ΔH < 0 ΔS < 0 ΔG < 0
(C) ΔH > 0 ΔS > 0 ΔG > 0
(D) ΔH > 0 ΔS > 0 ΔG < 0

16) Select the graph that correctly describes the adsorption isotherms at two temperatures T1 and T2
(T1 > T2) for a gas :
(x – mass of the gas adsorbed ; m – mass of adsorbent ; P – pressure)

(A)

(B)

(C)

(D)

17) For gaseous elementary reaction ; 2A(g) + B(g) → P(g) Initially A and B are present in
stoichiometric mole ratio and total pressure decrease from 120 torr to 80 torr in 5 minutes, than
average rate of reaction is .

(A) 8 torr /min.

(B) 6 torr /min.
(C) 2 torr /min.
(D) 4 torr /min.

18) If first order reactions are operating in series

(starting with only A)

Then ratio of is given by :-

(A)

(B)

(C)

(D) None

19) aA + bB → Product, dx/dt = k [A]a [B]b . If concentration of A is doubled, rate becomes four times.
If concentration of B is made four times, rate is doubled. What is relation between rate of
disappearance of A and that of B ?

(A) – {d [A] / dt} = – {d [B] / dt}

(B) – {d [A] / dt} = – {4 d [B] / dt}
(C) – {4 d [A] / dt} = – {d [B]/ dt}
(D) None of these

20) Which of the reaction represented in these diagram will show greatest percentage increase in
rate for same increase in temperature, Given : (Eaf) = 40 kJ/mole for reaction (I) (Eaf) = 28

kJ/mole for reaction (II)

(A) Reaction – (I) forward

(B) Reaction – (I) backward
(C) Reaction – (II) forward
(D) Reaction – (II) backward

SECTION-B

1) Consider two reactions at 27ºC

(I). A → B ; ( I order kinetics)
(II). X → Y; ( Zero order kinetics)
If both A & X each having initial concentration 0.1M & same initial half life period. If ratio of rate

constants for I & II reactions. is 'X' find value of ? [ln2 = 0.7]

2) If for a first order reaction, t90% = X.t1/2, t99% = Y.t1/2 and t99.9% = Z.t1/2, then calculate value
of . [log2 = 0.3]

3)

When 0.36 gm of Iron pyrite (FeS2) was heated strongly in air following reaction takes place
FeS2(s) + O2(g) → Fe2O3(s) + SO2(g)
The SO2(g) produced was titirated with acidified K2Cr2O7 solution. Calculate the volume in ml of 1M
K2Cr2O7 solution used in the redox titration.[Fe – 56, S – 32)

4) Balance the following equation and choose the quantity which is the sum of the coefficients of
reactants and products:
....PtCl4 + ....XeF2 → PtF6 + ....ClF + ....Xe

5) Radiations of 2480 Å falls on metal surface of work function 2eV. Stopping potential (in volt) for
the ejected photoelectrons is _______.
(Answer to the nearest integer)

6) When the excited electron of a H atom from n = 5 drops to the ground state, the maximum
number of emission lines observed are _____

7) A mineral having the formula AB2 crystallises in the cubic close - packed lattice, with the A atoms
occupying the lattice points. The co-ordination number of A atoms is x, that B atoms is y. Reprot your
answer (x – y).

8) If the coordination numbers of cations and anions in Fluorite [CaF2] are (x & y) respectively and in
Zinc blende [ZnS] structures are (a & b) respectively then find value of (x + y + a + b).

9) Molecular formula of starch can be represented as (C6H10O5)n. If the gold number of one such
starch molecule is 6.48 and 0.01 millimoles of the above starch are required to be added to 10ml of
gold sol to prevent coagulation by 1 ml of 10% sodium chloride solution, then calculate the value of
'n'.

10) Graph between log vs log P is provided for adsorption of NH3 gas on metal surface.
Calculate weight of NH3 gas adsorbed by 50 gm of metal surface at 2 atm pressure
 PART 3 : MATHEMATICS

SECTION-A

1) The number of real solutions of the equation is -

(A) 2
(B) 4
(C) 6
(D) None of these

2)

If the quadratic polynomial is negative for at least one real x, then

greatest integral value of a is -

(A) 1
(B) 2
(C) 3
(D) 4

3) If are the distinct roots of the equation , then the value of

is equal to:

(A)
(B)
(C)
(D)

4) The complete set of values of 'a' for which the equation 2x2 – 2(2a + 1)x + a(a – 1) = 0 has roots α
and β satisfying the condition α < a < β are -

(A) (–3,0)
(B) (0,∞)
(C) (–∞,–3)
(D) (–∞,–3) ∪ (0,∞)
5) Value of is -

(A)

(B)

(C)

(D)

6) Let a, b, c be the three numbers such that (a – b)2, (b – c)2, (c – a)2 are in A.P. Then a – b, b – c, c –
a are always in (a ≠ b ≠ c)

(A) A.P.
(B) G.P.
(C) H.P.
(D) A.G.P.

7) . Find value of 2S.

(A) 12
(B) 8
(C) 6
(D) 10

8) If 1, log9(31–x + 2), log3(4.3x – 1) are in arithmetic progression then x-equal to

(A) log34
(B) 1 – log34
(C) 1 – log43
(D) log43

9) If , and h(x) = |x| then find f(g(h(x))) :

(A) 1
(B) 0
(C) –1
(D) does not exists

10) If , then
(A) a = 1, b = 1
(B) a = 1, b = 2
(C) a = 1, b = –2
(D) None of these

11) If then the value of a and b are respectively

(A) 1/2, 3/2

(B) 3/2, 5/2
(C) -5/2, -3/2
(D) None of these

12) The value of where r is a non-zero real number and denotes the
greatest integer less than or equal to r, is equal to

(A) r

(B)

(C) 0
(D) 2r

13) The value of cos (cot–1 sin(tan–1x)) is -

(A)

(B)

(C)

(D)

14) The range of the function , where [] is the greatest integer

function, is:

(A)

(B)

(C)

(D)

15) Find the sum of

(A)

(B)

(C)

(D) None of these

16) The complete solution set of is:

(A)
(B)
(C)
(D)

17)

Number of value(s) of x satisfying the equation log3log2 is (are) -

(A) 0
(B) 1
(C) 2
(D) 3

18) If , then the value of x is equal to -

(A)

(B)

(C)

(D)

19) Solution set of the inequality

is

(A) (–4, –3) ∪ (8, ∞)

(B) (–∞, –4)
(C) (–∞, –4) ∪ (3, ∞)
(D) (3, ∞)

20) Sum of all the real values of x satisfying the equation

is
(A)

(B) 5

(C)

(D) 7

SECTION-B

1) If \(N = \frac{{{{\log }_3}135}}{{{{\log }_{15}}3}} - \frac{{{{\log }_3}5}}{{{{\log

}_{405}}3}}\), then number of zero between decimal and first significant digit in N–20 is
(where log103 = 0.4771)

2) If M= + log2 3 . log3 5 . log5 2 + log2 64. Then the value of is :

3) If for all , then how many integral values of exist?

4) The sum of all real values of x satisfying the equation

is

5) Let a,b,c be positive integers such that is an integer. If a,b,c are in geometric progression and

the arithmetic mean of a,b,c is b + 2, then the value of is

6) If S1, S2, S3 are the sum of first n, 2n, 3n terms respectively of an A.P. then equals

7) The value of is :

8) If = , then find the value of |a + 2b|.

9) If the value of [sin(sin–1(0.5) + sin–1(0.4)) × sin(sin–1(0.5) – sin–1(0.4))] can be expressed as

(where p, q ∈ N are relatively prime), then is

10)

Number of solution(s) of the equation sin–1(x2 – 2x + 2) + cos–1(x2 – 2x + 2) = is

 ANSWER KEYS

PART 1 : PHYSICS

SACTION-A

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B C A D B B D A D B C A A B B C D A C A

SECTION-B

Q. 21 22 23 24 25 26 27 28 29 30
A. 5 8 1 6 1 2 8 5 5 2

PART 2 : CHEMISTRY

SECTION-A

Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
A. A D A C D B D B C B C A D A B D D B B B

SECTION-B

Q. 51 52 53 54 55 56 57 58 59 60
A. 7 3 2 16 3 4 4 20 4 200

PART 3 : MATHEMATICS

SECTION-A

Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
A. B B C D C C A B B C C B B C A A D A A A

SECTION-B

Q. 81 82 83 84 85 86 87 88 89 90
A. 9 8 4 5 4 3 1 3 7 1
 SOLUTIONS

PART 1 : PHYSICS

1)

2)

3) The ammeter reads 0.

The potential above the ammeter and above the 5V battery is 0.
Hence current through 1 Λ resistor = 0
Voltmeter reading = 10 + 0
= 10 Volts

4)

Here Req = R' =

Now,

or

5)
Q = 3C0V0 = (KC0 + 2C0)V

6)

J = σE, i = JA = σEA

Now,

At, t = 0, i = 1 A, K = 4.26

7)

f1 = µmg
f2 = µ(2mg)
when alone
µmg = mω02r
when both
µmg + µ(2mg) = mω2r

8)

9)

10)
For B : T = mg
For A : 5T = 15g

11)

From figure

12)

13)

14)
R cos 37 + F cos 53 = 50
F sin 53 – R sin 37 = 25
F = 50

15)

f = µN (Just to start sliding)

f = µ(mg – F sin 37°) =

f = F cos 37°

16)

R2 & Rv are in parallel

so

v = 1.2 × 40 = 48 V

17)
T sin θ = ma ...(1)
T cos θ = mg ...(2)

tan θ = ∴ θ = tan–1

18)

Let current density be J.

∴ Applying Ampere's law.

Similarly,

19)

+3=R
solve it (10R + 30) = (R – 3) (R + 13)
10R + 30 = R2 – 39 + 10R
or R = Ω

20)
Cd = 3C

21)

22)

Let in new equilibrium the upper plate is displaced by x units. If we get real x less than L then only
new equilibrium is achieved :

maximum value of Kx (L – x)2 = ?

K (L – x)2 + 2Kx(L – x)(–1) = 0
x = L/3

maximum value of Kx (L – x)2 =

so for real x
 23)

…(1)

…(2)

…(3)

24)

Vmax = ω(2R) = 2 × 2 × 1.5 = 6 m/sec

25)

In the given situation

ω ⇒ r

0
So, required 'r' = r = 1 cm.

26)

Tangential acceleration α = 6
Centripetal acceleration = ω2R = 9
⇒ ω = 3 rad/s

27)

= N23 sin θ ... (1)

... (2)
Thus, minimum value of N2 = 8N

28)
14 – Fs = 1 × 4
Fs = 10N

Fs = 2a2
Fs = 10N
⇒ 10 = 2a2
a2 = 5 m/s2

29) F = 15N ≤ fℓ = µN
⇒ f = F = 15N

30)
2T2 – 50 = 10a ...(1)
T1 – T2 = 5(2a) ...(2) × 2
60 – T1 = 10(2a) ...(3) × 2
——————————————
120 – 50 = 70a
a = 1 m/s & aB = 2a

PART 2 : CHEMISTRY
 31)

N × V = ([Link])KMnO4 + (n. nf)K2Cr2O7

N = 0.4 (or) M = 0.4

32)

n–factor of CNS = 7
n–factor of
∴

33)
X2 X1 Molecular wt.
Y2 Y1 Equivalent wt.

34)

Change in O.N. during reduction = (O.N)i – (O.N)f

35)

Etotal = (N = no. of photons)

P×t=N×

80 Watt × 1 sec. = N ×
N = 20.2 × 1019 photons/sec.

36)

For H : ...(1)

....(2)

From (1) & (2)

 37)

q1 and q2 are substituted with sign

As per Rutherford’s formula : diameter ∝ (A)1/3, Beam of α-particle used.

38) λ0 = 330 nm (given)

0
w = hυ =
w = 0.06 × 10–17
w = 6 × 10–19 J

39) The plane will look like this :

40)

Z=8×

7.2 =

⇒ No. of atom in 200 gm = = 3.472 × 1024 atoms

41)

Number of O2– ions (FCC or CCP packing) = 4

Number of Ti cations = of octahedral voids =

So charge at Ti ion =

% Mass of Ti2+ =

42)

As equal number of Na+ and Cl– ions are missing from their lattice site so it is Schottky defect.

43)
Size of colloidal particles : 1 nm to 1000 nm.

44)

For micelle formation, ΔS > 0 (hydrophobic effect) This is possible because, the decrease in entropy
due to clustering is offset by increase in entropy due to desolvation of the surfactant, Also ΔH > 0

45)

Adsorption is an exothermic process in which entropy of gas decreases?

(ΔS = –ve). from ΔG = ΔH – TΔS, ΔG = –ve (at low temp.)

46)

On Increasing temperature decreases.

Q adsorption is generally exothermic

(T1 > T2)

47)

2A(g) + B(g) → P(g)

Initially 2a a ntotal = 3a
moles

Ptotal/initially = 120 torr

PB = 40 torr
Initially 80 40
presence
time = t 80–2P 40–P P
(Ptotal)t = 120 – 2P = 80
P = 20

Average rate of reaction =

= 4 torr/min.

48)

]
 49)

aA + bB → Product

= k[A]a [B]b
(i) As on doubling concentration of A rate become four time so a = 2.

(ii) On four time concentration of B rate become double so b = .

So, Given equation : 2a + b → Product

– =–2

– =–4

50) From given graph

For Ist reaction :-
For forward (Ea)ƒ = 40 KJ/mol
Backward, (Ea)b > 40 KJ/mol
For 2nd reaction :-
For forward, (Ea)ƒ = 28 KJ/mol
Backward, (Ea)b < 28 KJ/mol
Ea is highest for Ist reaction (Backward)
So
For same increase in temperature, reaction-(I) backward will show greater % increase in rate
become higher the Ea higher % increase in rate.

51)

KI =

KII =

=X

52) Given

t90% = xt1/2 = x

x=
Similarly t99% = yt1/2 = y.

y=
t99.9% = z.t1/2 = z.
 z=

53)

4FeS2 + 11O2 → 2Fe2O3 + 8SO2

n.f = 11 n.f = 4
2H+ + 3SO2 + Cr2O72– → 3SO42– + 2Cr+3 + H2O
n.f = 2 n.f = 6

1×

V=

54)

Balanced reaction is
PtCl4 + 5XeF2 → PtF6 + 4ClF + 5Xe
∴ Sum o stoichiometric coefficients
= 1 + 5 + 1 + 4 + 5 = 16

55)

Einc = w + K.E.

K.E. = 3 eV = e × Vstopping
Vstopping = 3 volt

56)

Since only a single H atom is present, maximum number of spectral lines = 4

57)

AB2 is similar to CaF2 so co-ordination number of A = 8

and co- ordination number of B = 4

58) The coordination number of cation and anion in Fluorite CaF2 = 8 : 4

The coordination number of cation and anion in Fluorite ZnS = 4 : 4

59)
Since 0.01 millimole of starch solution weigh 6.48 mg.
So, 1 millimole of starch solution weight = 6.48 × 100 = 648 mg

Molar mass of starch =

Formula of starch = (C6H10O5)n
(6 × 12 + 10 × 1 + 5 × 16) × n = 648

60)

From Freundlich's adsorption isotherm equation:

= KP1/n
Taking log on both sides;

(y = mx + c form)

slope =

Intercept = logk = 0.3 = log2

So, weight of NH3 adsorbed by 50 gm metal surface at 2 atm

PART 3 : MATHEMATICS

61)

Let,

If, then
If, , then
4 real solutions

62)
 63)
[ squaring both sides and simplifying]
[squaring both sides and simplifying]

and

Similarly,

64)

2ƒ(a) < 0 ⇒ ƒ(a) < 0

∴ 2a2 – 2(2a + 1)a + a(a – 1) < 0

65)

66) (b – c)2 – (a – b)2 = (c – a)2 – (b – c)2

(b – c + a – b)(b – c – a + b)
= (c – a + b – c)(c – a – b + c)
⇒ (a – c)(b – c) + (a – c)(b – a)
= (b – a)(c – a) + (b – a)(c – b)
divide by (a – b)(b – c)(c – a), then
 67)

⇒
Now, S∞ = 6

68) If a, b, c in A.P. then 2b = a + c.

∵ 2log9(31–x + 2) = 1+ log3(4.3x – 1)

31–x + 2 = 3(4.3x – 1)

3 + 5.3x = 12.32x
let 3x = t
∴ 12t2 – 5t – 3 = 0
12t2 – 9t + 4t – 3 = 0

or (reject)

⇒ = 1 – log34

69)

LHS f(g(h(0 – λ))) = f(1–)

=

RHS f(g(h(0 + λ)))

70)

⇒
⇒ 1 – a = 0 and –b = 2
⇒ a = 1, b = –2

71)
by comparing the two sides
= 1+a-b=0
a - b = -1 .... (1)

b - 3a = 6 ..... (2)
from (1) and (2)
a = -5/2 and b = -3/2

72)

Adding

73)

Let tan–1x = θ

74)

can be 0 & 1 only.

when

when
 .

75)

Tn = tan–1(2n + 1) – tan–1(2n – 1)

76)

77) x3 – 6x2 + 11x – 6 = 0

x = 1,2,3

78)

(log23)xlog22 = (log32)x(log23)

= (log23)2x = (log23)1

79)
∴ x ∈ (–4, –3) ∪ (8, ∞)

80) ⇒
⇒ (log2x + log2(x – 1))(log2(x – 1) – log2x) + (log2x)2 = 4
⇒ (log2(x – 1))2 – (log2x)2 + (log2x)2 = 4
(log2(x – 1))2 = 4
log2(x – 1) = 2, –2

81)

N = log3135.log315 – log35.log3405
= log3(33 × 5).log3(3 × 5) – log35log(34 × 5)
= (3 + log35)(1 + log35) – log35(4 + log35)
Let log35 = x
N = (3 + x)(1 + x) – x(4 + x)
= 3 + 3x + x + x2 – 4x – x2 = 3
logN–20 = log3–20 = –20.log3 = –9.542
⇒ number of zeros = 9

82)

M= + (log2 3 . log3 5) log5 2 + 6

4
M = 7 + (log2 5 . log5 2) + 6
M = 74 + log2 2 + 6
M = 2408
M / 301 = 8

83)

Given inequality

From 1st inequality

From 2nd inequality

Combining the above two results we get

Number of integral value is 4
 84)

x2 – 5x + 5 = 1 ⇒ x = 1, 4
x2 – 5x + 5 = – 1 ⇒ x = 2, 3
x2 + 5x – 50 = 0
⇒ (x + 10) (x – 5) = 0
⇒ x = – 10, 5
Sum = 5.

85)

Let a,b,c are a, ar, ar2 where r ∈ N

also
⇒ a + ar + ar2 = 3(ar) + 6
⇒ ar2 – 2ar + a = 6

⇒ (r – 1)2 =

∵ must be perfect square & a ∈ N

∴ a can be 6 only.
⇒ r –1 = ±1 ⇒ r = 2

⇒ Ans.

86)

S1 = [2a + (n – 1)d]; S2 = n[2a + (2n – 1)d]

S2 – S1 = na + (3n – 1) = [2a + (3n – 1)d]

S3 = [2a + (3n – 1)d]

87)

88)

=
⇒ a + b = 0 and a = –3, b = 3
∴ Answer = |a + 2b| = 3

89)
sin(x – y) sin(x + y) = sin2x – sin2y
∴ E = sin2(sin–1(0.5)) – sin2(sin–1(0.4)) = 0.09

90) sin–1((x – 1)2 + 1) + cos–1((x – 1)2 + 1) =

∴x=1
Number of solution is one