02-11-2025

9610ZJA802322250012 JA

PART 1 : PHYSICS

SECTION-II

1)
A mercury arc lamp provides 0.1 watt of ultra-violet radiation at a wavelength
of only. The photo tube (cathode of photo electric device) consists of potassium and has an effective
area of 4 cm2. The cathode is located at a distance of 1m from the radiation source. The work
function for potassium is
According to classical theory, the radiation from arc lamp spreads out uniformly in space as
spherical wave. What time of exposure to the radiation should be required for a potassium atom

in the cathode to accumulate sufficient energy to eject a photo-electron? Give answer

in S.I. units. (round off to two significant figure)

2) The orbital radius of a hydrogen atom is 0.847nm. The electron makes a transition from this state
to ground state. The maximum possible number of wavelengths that can be emitted are :

3) When radiation of wavelength λ is used to illuminate a metallic surface, the stopping potential is
V. When the same surface is illuminated with radiation of wavelength 3λ, the stopping potential
is . If the threshold wavelength for the metallic surface is nλ then value of n will be _______.

4) A block of mass m is connected to a spring having spring constant as shown in figure.

Initial compression in spring is . Another ball of same mass m is going to be released

from some height above block simultaneously with block. It is found that ball falls a height h before

colliding elastically with block that then just reaches same initial height. Then find C.

5) A rod of mass m = 3 kg and length ℓ hinged at one end is connected by two springs of spring
constant k1 and k2 so that it is horizontal at equilibrium. What is angular frequency (in rad/sec) of
system?

6) One end of an ideal spring is fixed to a wall at origin O and axis of the spring is parallel to x-axis.
A block of mass 1 kg is attached to the free end of the spring and is performing SHM. Equation of
position of the block in co-ordinate system shown in figure is x = 10 + 3 sin (10t), where t is in
second and x in cm. Another identical block B, moving towards the origin with velocity 0.6 m/s
collides elastically with the block A at t = 0. The new amplitude (in cm) of oscillations will be :

7) A ball is suspended by a thread of length l at the point O on the wall, forming a small angle α with
the vertical. Then the thread with the ball was deviated through 2α and set free. Assuming the
collision of the ball against the wall to be perfectly elastic, the oscillation period of such a pendulum

is approximately how much multiple of

8) A hemisphere of radius R is lying on a surface as shown. For small oscillations of this without slip,

the time period is 2π then the value of n is ?

 SECTION-I (i)

1) A particle executes SHM with an equation of motion given by

(A) Magnitude of maximum velocity of particle is 240 π cm/s

(B) Magnitude of maximum acceleration of particle is 2880 π2 cm/s2

(C)
Displacement of the particle from its mean position will be minimum at t =

(D)
Net force acting on the particle will be minimum at t =

2) A sample of iodine I127 is irradiated by a neutron beam with a flux such that 107 atoms of
radioactive iodine I128 (half life 25 min) are formed per second. Choose the correct statement(s) :-

(A) The number of I128 atoms 25 min after the start of the irradiation is 7.5 × 109.
(B) The number of I128 atoms 25 min after the start of the irradiation is 7.5 × 109/ln2.
The maximum number of I128 atoms after long-term irradiation (i.e. irradiation to saturation)
(C)
is 1.5 × 1010/ln2.
The maximum number of I128 atoms after long-term irradiation (i.e. irradiation to saturation)
(D)
is 1.5 × 1010.

3) The magnetic moment due to an electron (charge : e, mass : m) moving in the nth Bohr orbit is µn
while the angular momentum is Ln. As the electron makes a transition from the nth Bohr orbit to the
mth Bohr orbit (m < n), it emits a photon of radiation of wavelength λ. Then :-

(A)

(B)

(C)

(D) (Ln – Lm) ∝ (µn – µm)

4) The displacement (in m) of a particle of mass 100 g from its equilibrium position is given by the
equation :-
y = 0.05 sin 3π (5t + 0.4)

(A) the time period of motion is 1/30 sec.

(B) the time period of motion is 1/7.5 sec.
(C) the maximum acceleration of the particle is 11.25π2 m/s2.
(D) the force acting on the particle is zero when the displacement is 0.05 m.

5) A scientist measures the time period of a simple pendulum as T in a lift at rest. If the lift moves up
with acceleration as one fourth of the acceleration of gravity, the new time period is :-
(A)

(B) 4T

(C)

(D)

6) Two particles A and B oscillate in SHM having same amplitude and frequencies fA and fB
respectively. At t = 0 the particle A is at positive extreme position while the particle B is at a
distance half the amplitude on the positive side of the mean position and is moving away from the
mean position.

(A)
The minimum time after which the two particles will be in same phase is if fA > fB

(B)
The minimum time after which the two particles will be in same phase is if fA > fB

(C)
The minimum time after which the two particles will be in same phase is if fA< fB

(D)
The minimum time after which the two particles will be in same phase is if fA < fB

SECTION-I (ii)

1) For small oscillations, a simple pendulum can be treated as a linear oscillator. When pendulum is
displaced by an angle θ from vertical, then its linear displacement from mean position is x = ℓθ and

restoring force . If potential energy is assumed to be zero at mean

position, then . Consider a situation in which two simple

pendulum are connected by an elastic rubber band. When pendulums are at their mean positions,
then rubber band is in natural length. In extension rubber band behaves like a spring having
stiffness K = mg/ℓ. Pendulums are given equal small speed v0 at their mean position as shown in

diagram. List I gives some physical quantities and List II gives

some possible values of these physical quantities corresponding to linear displacement x of a particle
from mean position.

List -I List -II

(I) Restoring force acting on one of the particle. (P)

(II) Total energy of system. (Q)

2
(III) Potential energy of system when displacement is x from mean position. (R) mv0

(IV) Restoring force due to string when displacement is x from mean position. (S)

(T)

During outward journey, when linear displacement is x, then CORRECT match is

(A) I → S;II → R;III → P;IV → S
(B) I → T;II → R;III → Q;IV → S
(C) I → T;II → R;III → P;IV → S
(D) I → S;II → Q;III → P;IV → S

2) In list-I different configurations of object and spring are shown. In list-II corresponding time
periods (in second) of small oscillations are given.

List-I List-II

(P) (1)
mass m = 1kg, spring constant k = 5 N/m. There
is no friction between string & pulley.
String & pulley are massless. String
is inextensible. There is no friction between block
and surface.
 (Q) (2) 8π

A uniform disc of mass m can roll without slipping.

C is the centre of disc m = 3kg, k = 10 N/m.

(R) (3)

mass m = 1kg, spring constant k = 1 N/m. There

is no friction between string & pulley. String &
pulley are massless. String is inextensible.

(S) (4) 2π

L is the length of rod. Mass of rod is m, spring

constant k = m = 1kg, k = 1N/m

(A) P → 2;Q → 4;R → 1;S → 3
(B) P → 2;Q → 4;R → 3;S → 1
(C) P → 4;Q → 3;R → 2;S → 1
(D) P → 4;Q → 2;R → 1;S → 3

3) Answer the following by appropriately matching the lists based on the information given
in the list.

If potential energy interaction between electron & nucleus (infinite mass) is given by
(Bohr's theory is valid), where n represents nth orbit. then :

List-I List-II

(P) Electric current due to electron moving in a orbit (1)

(Q) Magnetic field due to electron at centre of atom (2) n7

0
(R) Angular momentum of nth orbit (3) n

(S) Magnetic moment create due to revolving electron (4) n5

(5) n
(A) P → 4;Q → 2;R → 5;S → 5
(B) P → 1;Q → 2;R → 5;S → 5
(C) P → 4;Q → 2;R → 5;S → 1
(D) P → 4;Q → 2;R → 1;S → 5
4) Answer the following by appropriately matching the lists based on the information given in the
paragraph.
A photo electric cell is shown in the figure. The emitter plate (cathode) is made of copper (ϕ = 4.7
eV) and emitter is illuminated by a source of monochromatic light of wavelength 200 nm. Saturation
current is observed when potential difference between cathode and anode is 1V and anode at higher

potential. [Range of ammeter is large] [Take hc = 1240 (ev)nm]

List-I List-II

Minimum kinetic energy of

(I) photoelectrons, reaching the (P) 2.5 eV
collector is

Maximum kinetic energy of

Remain
(II) photoelectrons reaching the (Q)
same
collector is

If wavelength of incident light is

decreased (no. of incident photon
(III) (R) 1 eV
same), then reading of current
as shown by ammeter will

If number of incident photons

increases, then reading of
(IV) (S) Increase
current as shown by ammeter
will

(T) 0

(U) Decrease
If only S2 is closed, then :-
(A) I → P;II → Q;III → S;IV → Q
(B) I → T;II → R;III → Q;IV → S
(C) I → S;II → T;III → P;IV → U
(D) I → T;II → T;III → S;IV → Q

PART 2 : CHEMISTRY

SECTION-II

1) Number of stereocentres in linear and cyclic structure of glucose are X and Y, respectively
calculate X + Y ?
2) If x = DOU of Aspirin
y = Number of phenolic OH group present in Morphine
z = Number of sp3 carbons in Terpineol then value of x + y + z =?

3)

In a 3.27 L closed cylindrical container, the following equilibrium is established at 0ºC.

The equilibrium constant for the above reaction is 4 × 10–9. At equilibrium, solution
occupies height of container and contains 0.5 M I– and other species. If gaseous matter weighs 2
gram then calculate (– log [OH–]) (Given : 0.083 × 273 = 22.7, R = 0.083 bar-L/K-mol)

4)

The value of Kp for the reaction at 27°C

Br2(l) + Cl2(g) ⇌ 2BrCl(g)

is '1' atm. At equilibrium in a closed container partial pressure of BrCl gas is 0.1 atm and at this
temperature the vapour pressure of Br2(l) is 0.13 atm. Then what will be minimum moles of Br2(l) to
be added to 1 mole of Cl2 , initially, to get above equilibrium situation :

5) A buffer of pH 9.26 is made by dissolving x moles of ammonium sulphate and 0.1 mole of ammonia
into 100 mL solution. If pKb of ammonia is 4.74, calculate value of 100 x.

6) Calculate the pH of a solution which results from the mixing of 50.0 ml of 0.3 M HCl with 50.0 ml
of 0.4 M NH3. [Kb (NH3) = 1.8 × 10–5, pKb = 4.74] (nearest integer)

0
7) For the reaction A2(g) 2A(g) at 298 K, Kp = 1 , if we start with pure A2(g) the % dissociation of
A(g) at 25kPa is.

8) If the equilibrium constant for the reaction of weak acid HA with a strong base is 109, then
determine pH of 0.1 M NaA solution.

SECTION-I (i)

1) In the following reaction

(A) A is an acid, B is a base

(B) A is a base, B is an acid
(C) C is conjugate acid of B and D is conjugate base of A
(D) C is conjugate base of B and D is conjugate acid of A
2) Considering the reaction sequence given below, the correct statement(s) is(are)

(A) P can be reduced to a primary alcohol using NaBH4.

(B) Treating P with conc. NH4OH solution followed by acidification gives Q.
(C) Treating Q with a solution of NaNO2 in aq. HCl liberates N2.
(D) P is more acidic than CH3CH2COOH.

3) With reference the scheme given, which of the given statement(s) about T, U, V & W is/are correct
:–

(A) 'T' is soluble in hot aq NaOH

(B) 'U' is optically active
(C) molecular formula of W is C10H18O4
(D) V gives effervescence with aq NaHCO3

4) Given :

The compound(s), which on reaction with HNO3 will give the product having degree of rotation [α]D
= –52.7° is (are)
(A)

(B)

(C)

(D)

5) Schiff's reagent gives pink colour with :

(A) Acetaldehyde
(B) Formic acid
(C) Acetic acid
(D) Methyl acetate

6) Which one is/are used as food preservative?

(A) Sodium benzoate

(B) Vegetable oil
(C) Sorbic acid
(D) Propanoic acid
 SECTION-I (ii)

1) Match the list -I and List- II

List-I List-II

C6H5N2Cl + C6H5 OH
(P) Electrophilic substitution (1)

(Q) Nucleophilic substitution (2) Toluene + NBS →

(R) Free radical substitution (3) Dow’s process

(S) Coupling reaction (4) Phenol → picric acid

(5) C6H5ONa + CH3Br →

Which is correct option?

(A) P → 1;Q → 2;R → 3;S → 4
(B) P → 2;Q → 3;R → 4;S → 5
(C) P → 4;Q → 5;R → 2;S → 1
(D) P → 1;Q → 2;R → 4;S → 5

2) Match each species in List-I with List-II and choose correct option :

List-I List-II

(P) A carbohydrate which yields only glucose on hydrolysis (1) Sucrose

(Q) A carbohydrate which yields glucose and fructose on hydrolysis (2) Lactose

(R) A carbohydrate which yields glucose and galactose on hydrolysis (3) Amylose

(S) A carbohydrate which can reduce Fehling solution (4) Mannose

(5) Cellulose
(A) P → 3,5;Q → 2;R → 1;S → 2,4
(B) P → 5;Q → 1;R → 2;S → 2,3
(C) P → 3;Q → 1;R → 2;S → 2,5
(D) P → 3,5;Q → 1;R → 2;S → 2,4

3) Match the list.

List-I List-II

on increasing
(P) (1) Forward shift.
volume at constant temperature

on addition of Concentration of
(Q) (2)
inert gas at constant P & T. reactant decreases.
 on Concentration of
(R) decreasing pressure at constant (3)
product decreases.
temperature.

on increasing Equilibrium is not

(S) (4)
pressure at constant temperature. disturbed.

(5)
KP > KC
(A) P → 1;Q → 2;R → 5;S → 2
(B) P → 1;Q → 2;R → 5;S → 1
(C) P → 3;Q → 1;R → 4;S → 1
(D) P → 1;Q → 4;R → 3;S → 5

4)

LIST-I List-II
(10 mL of 0.1 M NaOH + 20 mL of 0.1 M
P 1 the value of [H⊕] does not change on dilution
acetic acid) diluted to 60 mL
(20 mL of 0.1 M NaOH + 20 mL of 0.1 M the value of [H⊕] change to half of its initial value on
Q 2
acetic acid) diluted to 80 mL dilution
⊕
(20 mL of 0.1 M HCl + 20 mL of 0.1 M the value of [H ] changes to two times of its initial
R 3
ammonia solution) diluted to 80 mL value on dilution

10 mL saturated solution of Ni(OH)2 in 4 ⊕

the value of [H ] changes to times of its initial
equilibrium with excess solid Ni(OH)2 is
S value on dilution
diluted to 20 mL (solid Ni(OH)2 is still present
⊕
after dilution). 5 the value of [H ] changes to times of its initial
value on dilution
(A) P → 4;Q → 2;R → 3;S → 1
(B) P → 4;Q → 3;R → 2;S → 3
(C) P → 1;Q → 4;R → 5;S → 3
(D) P → 1;Q → 5;R → 4;S → 1

PART 3 : MATHEMATICS

SECTION-II

1) If ℓx + my = 1 is tangent to circle S1 such that 25(ℓ2 + m2) = (3ℓ + 4m + 1)2 ∀ ℓ,m ∈ R, then
radius of circle S1 is

2) A circle touches the line y = x at a point P such that OP = 4 where O is the origin. The circle
contains the point (-10, 2) in its interior and the length of its chord on the line x + y = 0 is 6 . If

the equation of the circle x2 + y2 + 2g x + 2fy + c = 0, then equals to

3) Let where θ is the angle between and . If volume of the

parallelopiped whose coterminous edges are represented by the vectors and

(Where angle between and is taken from the equation 2g(θ)–l = 0) is then the least value of p
+ q is _____ mention & are unit vectors where p, q ∈ N

4) Let and be two unit vectors such that . For some x, y ∈ , let . If
= 2 and the vector is inclined at the same angle α to both and , then the value of is

5) The plane denoted by is rotated through a right angle about its line of
intersection with the plane . If the plane in its new position be denoted by
Π, and the distance of this plane from the origin is where k ∈ N, then find k.

6) The shortest distance between (1 – x)2 + (x – y)2 + (y – z)2 + z2 = and 4x + 2y + 4z + 7 = 0 in 3-

dimensional coordinates system is equal to

7) Let be the areas of the triangular faces of a tetrahedron and be the

corresponding altitudes of the tetrahedron. If volume of tetrahedron is 5 cubic units, then the

minimum value of (in cubic units) is

8) If < a, b, c > are direction cosines of line of intersection of three planes x + y – z = 1, ( m – 1)x +

(3m – 7) y – 5z = –3 and ( m – 2)x + (2m – 5) y = –4 for some m R, then value of is

SECTION-I (i)

1) Let S1 and S2 be two circles touching each other externally at R. Let ℓ1 be a line which is tangent
to S2 at P and passing through centre C1 of circle S1. Similarly let ℓ2 be a line which is tangent to S1
at Q and passing through centre C2 of circle S2. ℓ1 and ℓ2 are not parallel and intersect at K. If KP =
KQ, then

(A) P and Q lie on opposite sides of the line joining C1 and C2

(B) P and Q lie an same side of the line joining C1 and C2
(C) Triangle PQR is an equilateral triangle
(D) Triangle PQR is not necessarily an equilateral triangle

2) Let and be two fixed points on xy plane and R(h, k) is a point such that PR :
QR = k (k ≠ 1) and locus of R for different values of k be curves S1, S2 … Further
let be circles such that Si is orthogonal of Let number of common tangents of Si and Sj (i ≠
j) is ‘m’ and number of common tangents of S i′ and Sj′ (i ≠ j) is ‘n’ then m+n may be :

(A) 2
(B) 4
(C) 6
(D) 8

3) In a triangle ABC points D, E lie on sides AC and AB respectively. M and N are mid points of side
BD and CE respectively. If Δ1 is area of triangle AMN, Δ2 be the area of triangle ADE, Δ be area of
triangle ABC, Δ3 be area of quadrilateral BCDE, Δ4 be area of quadrilateral MNDE. Which of the
following is/are always true ?

(A) 4Δ1 = Δ3
(B) 4Δ1 + Δ2 = Δ
(C) Δ1 = Δ4
(D) 4Δ4 = Δ2 + Δ

4) OABC is a tetrahedron of volume cubic unit. Also BC = , and OA + OB = 4, then

(A) area of triangle AOB cannot exceed sq. unit

(B) the length of altitude drawn from vertex C to the opposite base is units
(C) OC = 2 unit
(D) AC > ( – 1)

5) Consider two planes and intersected by the

line at points P & Q respectively. An insect has to move from P to Q

without leaving the planes. Which of the following is/are correct.

(A)
Equation of line is
(B) Foot of perpendicular drawn from P on the line of intersection of is (4,5,6)

(C)
Minimum distance travelled by the insect is
(D) Minimum distance travelled by the insect is

6) The vertices of triangle ABC are and . The point D and E divide AB
and CA in the ratio 1 : 2 respectively. Another point F is taken in space such that perpendicular
drawn from F to the plane containing ΔABC, meets the plane at the point of intersection (point P) of
the line segment CD & BE. If the distance of F from the plane of triangle ABC is units then

(A)
(B)
Volume of tetrahedral ABCF = cubic units
(C) Equation of line AF is

(D) Equation of line AF is

SECTION-I (ii)

1) Let , and and be two vectors such that and . Let α, β, γ and t
be real numbers such that , –tα + β + γ = 0, α – tβ + γ = 0, and α + β – tγ = 0.
Match each entry in List-I to the correct entry in List-II and choose the correct option.

List-I List-II

(P) is equal to (1) 0

(Q) If , then γ2 is equal to (2) 1

(R) If , then (β + γ)2 is equal to (3) 2

(S) If , then t + 3 is equal to (4) 3

(5) 5
(A) P → 2;Q → 1;R → 4;S → 5
(B) P → 2;Q → 4;R → 3;S → 5
(C) P → 2;Q → 1;R → 4;S → 3
(D) P → 5;Q → 4;R → 1;S → 3

2) Let ℓ1 and ℓ2 be the lines and , respectively. Let X be the

set of all the planes H that contain the line ℓ1. For a plane H, let d(H) denote the smallest possible
distance between the points of ℓ2 and H. Let H0 be plane in X for which d(H0) is the maximum value
of d(H) as H varies over all planes in X.
Match each entry in List-I to the correct entries in List-II.

List-I List-II

(P) The value of d(H0) is (1)

(Q) The distance of the point (0,1,2) from H0 is (2)

(R) The distance of origin from H0 is (3) 0

The distance of origin from the point of

(S) (4)
intersection of planes y = z, x = 1 and H0 is

(5)

The correct option is :

(A) P → 2;Q → 4;R → 5;S → 1
(B) P → 5;Q → 4;R → 3;S → 1
(C) P → 2;Q → 1;R → 3;S → 2
(D) P → 5;Q → 1;R → 4;S → 2

3) Let and be the equations of two circles. Tangents are

drawn from any point P on touching at A and B respectively. If Q be variable point on and
L, M, N are the feet of perpendiculars from Q on PA. AB, PB respectively. Then match the following.

List-I List-II

If 'd' is the maximum distance of P from the radical axis of C1 and C2, then
(P) (1) 2
(where [.] denote greatest integer function)

(Q) If , then is equal to (where G is the foot of perpendicular from P on the radical axis of (2) 4
C1 and C2)

(R) (3) 8
If and , then QL. QM >

(S) (4) 16
If a line through intersects at R and Q then

(A) P → 1,2,4;Q → 4,5;R → 2,3;S → 1,2

(B) P → 1,2,3;Q → 4;R → 1,2,3,4;S → 3,4
(C) P → 2,3;Q → 4;R → 1,2,3;S → 2
(D) P → 2;Q → 3;R → 1,2;S → 3,4

4) Let A and B are points on the line L1, L2 respectively such taht d = OA + OB + AB is minimum (O
being the origin), match the following List - I with List-II.

List - I List - II

(A) (P)
L1 : x – 1 = y – 1 = , L2 : x + 2 = 4 – y =

(B) (Q)
L1 : = 1 – y = 1 – z, L2 : x – 2 = y – 2 =

(C) L1 : x = y = z – , L2 : x = y = z + (R)

(D) (S)
L1 : 2x – 3 = 6 – y = , L2 : x + 3 = 2y =

(T)
(A) A → P;B → S;C → Q;D → R
(B) A → Q;B → S;C → P;D → R
(C) A → W;B → S;C → R;D → P
(D) A → S;B → P;C → Q;D → R
 ANSWER KEYS

PART 1 : PHYSICS

SECTION-II

Q. 1 2 3 4 5 6 7 8
A. 350.00 6.00 9.00 48.00 8.00 6.00 0.67 1.14

SECTION-I (i)

Q. 9 10 11 12 13 14
A. A,B,D B,C C,D B,C C A,C

SECTION-I (ii)

Q. 15 16 17 18
A. C C A B

PART 2 : CHEMISTRY

SECTION-II

Q. 19 20 21 22 23 24 25 26
A. 9.00 15.00 5.00 3.00 5.00 9.00 70.70 to 70.72 9.00

SECTION-I (i)

Q. 27 28 29 30 31 32
A. A,C B,C,D A,C,D C,D A,B A,B,C,D

SECTION-I (ii)

Q. 33 34 35 36
A. C D D D

PART 3 : MATHEMATICS

SECTION-II

Q. 37 38 39 40 41 42 43 44
A. 5.00 4.00 5.00 3.00 212.00 2.00 4.00 1.00

SECTION-I (i)

Q. 45 46 47 48 49 50
A. B,C A,C A,B,C A,B,D A,B,C B
 SECTION-I (ii)

Q. 51 52 53 54
A. A B B B
 SOLUTIONS

PART 1 : PHYSICS

1) Explain Question: Explore time needed for K-atom to accumulate enough energy from UV
temp to eject e.
Concept :Use PEE with classical wave energy distribution

Solution : UV energy flux at a distance of Cross section (effective area) of atom

Energy required to eject a photoelectron from potassium

Exposure time

2)

Explain Question: Max. no. of spectral lines emitted when an e in hydrogen, transitions from
excited to ground state.

Concept :

Solution :
0.847 × 10–9 = n2 (0.529 × 10–10

n2 = 16
n=4

3)

Explain Question: Value of n related to λ0 of metal, given its stopping potentials for two diff.
λ.
Concept : Use PEE

Solution : .....(i)

.....(ii)

....(iii)
From (i) & (iii)
9λ = λ0
n=9

4)

Explain Question: It asks to find c when a falling ball collides with spring block system.
Concept : Use elastic collision + Energy conservation
Solution :

x = –A cos ωt;

... (i)

... (ii)
Now velocity of block must be

at time

⇒ C = 48

5)

Explain Question: It asks for w of hinged rod supported by two springs

Concept : Use rotational/Angular SHM
Solution :
 = 8 rad/s

6) Explain Question: Spring block system collides with block & asked to find A new.
Concept : Vmax occurs at mean position
Solution :
v = aω
0.6 = a × 10
a = 0.06 m

7) Explain Question: We need to find time period of given situation.

Concept : Time taken to go from mean to half of extreme is

Solution :

Final Answer (0.67)

8) Explain Question: We need to find time period of oscillation at hemisphere.

Concept : Calculation of net torque about point of contact after small angular displacement.

Solution :
 Final Answer (1.14)

9)

Explain Question: Equation of SHM is given & standard relation is asked

Concept : Vel. is max at M.P. & a is max. at extreme
Solution : Velocity of the particle is maximum at mean position

⇒t=

∴ vmax = (at t = )
acceleration of the particle will be maximum at extereme position

⇒ ⇒t=

amax = (at t = )

10)

Explain Question: First order reaction

Concept : Use standard half life equation
Solution :

11)

Explain Question: Relate λ emitted in Bohr transition with change in μ

Concept : Energy m n use Bohr model

Solution : Use units & dimensions

12) Explain Question: We need to find time period and maximum acceleration based on
equation.

Concept : SHM equation y = A sin

Solution :

; ω = 15π
Final Answer (BC)

13) Explain Question: We need to find time period of simple pendulum when point of
suspension is accelerating.

Concept :
Solution :

∵ Time period =

When lift is at rest

When lift is moves up with acceleration

Time period =

Final Answer (C)

14)

Explain Question: We need to find minimum time in which both particles will be in same
phase.

Concept :

Solution :
The SHM equations for A and B are xA=Acoswt and xB=Acos(wt-π/3) .It is clear that A is ahead
of B by π/3 or B is ahead of A by 5π/3 .If fA > fB , A will catch B by covering extra phase angle

of 5π/3 taking a time = = .

If fB > fA , B will catch A by covering extra phase angle of π/3 taking a time

= =
Final Answer (AC)

15) Explain Question: We need to find different parameters for shown situation.

Concept : Net force along the line of SHM will be due to gravity and spring.

Solution :

T.E. mv02

P.E.

Final Answer (C)

16) Question Explanation: Matching SHM systems to their corresponding time periods.
Concept: Time period of a spring-mass system and a simple pendulum.
Solution: The time period depends on the effective mass and effective spring constant. We
need to find the equivalent values for each system.

(P) E=

E=

T=

T=

(Q) E=

T=

T=

T= =

T=
Final Answer: (C)

17) Explain Question: We need to find dependency on 'n' of different parameters in Bohr's
model.

Concept : ,

Solution :

.... (1)

.... (2)

(A)

(B)
(C)
(D)

Final Answer (A)

18) Explain Question: we need to match correct option based on photoelectric effect.

Concept : Saturation current depends on no. of photons incident and maximum KE of

electrons reached on anode decreases if anode is at lower
potential w.r.t. cathode.

Solution :

= 1.5 + 1 = 2.5 eV
= 1 eV
 Final Answer (B)

PART 2 : CHEMISTRY

19) Explain Question: Calculate number of stereocenters in Fischer and Haworth projection
of glucose.
Concept: Concept of chirality
Trick: (All four valueless of 'C' are different)
Solution:

Final Answer: (9.00)

20) Explain Question: Draw structures of Aspirin, morpline & Terpineol and calculate the
value of (x + y + z).
Concept: Structures of Aspirin, Morphine & Terpineol.
Solution:
x = 6, y = 1, z = 8

Aspirin (C9H8O4)

DOU = C –
 y = 1 z = terpinol →
Final Answer: (15.00)

21) Explain Question: Equilibrium constant is given for a reaction and asking about the value
of - log (OH–)
Concept: Apply concept of equilibrium constant & Ideal gas equation.
Formula : PV = nRT
Solution:

4 × 10–9 = ⇒ [OH–] = 10–5 Final Answer: (5.00)

22)

Explain Question: Kp is given for the reaction & equilibrium pressure is also gives by using
given data are hour to calculate initial moles of Br2(l).
Concept: Apply equilibrium concept & Dalton's law

Solution:

∴ Initial pressure of Cl2 = 0.05 + 0.01 = 0.06 atm and initial

moles of Cl2 = 1 mole ∴ 0.06 atm = 1 mole

Also moles of Br2 corresponding to its vapour pressure.

Final Answer: (3.00)

 23) Explain Question: We have a buffer solution of (NH4)2 SO4 + NH3 and pH = 9.26. Now we
have to calculate moles of (NH4)2SO4 in the solution
Concept: pH of buffer solution

Formula : pOH = pKb + log

Solution:
(NH4)2 SO4 —→ 2NH4+ + SO42–
x mol - -
0 2x x

pOH = pKb + log

(14 – 9.26) = 4.74 + log

x=
⇒ 100 x = 100 × 0.05 = 5
Final Answer: (5.00)

24) Explain Question: We have to calculate pH for the mixing of (WB + SA) solution.
Concept: pH of buffer solution

Formula : pOH = pKb + log

Solution:
NH3 + HCl —→ NH4Cl
20 15 -

pOH = pKb + log = 4.74 + log = 4.74 + log 3

pH = 14 – pOH = 8.7782
Final Answer: (9.00)

25)

Explain Question: Calculate % dissociation of A2 (g)

Concept: Apply concept of equilibrium constant

Solution:

4Peq

α = 0.7071
= 70.71%
Final Answer: (70.70-70.72)

26)
Explain Question : Question is asking about pH of NaA.
Concept : This question is based on pH of salt of wASB.
Solution : HA + NaOH NaA + H2O; or HA + OH– A– + H2O

Keq. = 109 = (Hydrolysis is reverse of neutralization)

–
A + H2O HA + OH

[OH–] = Ch = C = = = 10–5 M
∴ [H+]= 10–9 M ∴ pH = 9
Final answer : 9

27) Explain Question: In the following reaction find acid & base
Concept: Based on Arrhenius theory of acid & base
Solution:

&
Final Answer: (AC)

28) Explain Question: Identify the product P & Q

Concept: HVZ reaction
Solution:

Final Answer: (BCD)

29) Explain Question: Identify the products U,V,W in the given reactions,
Concept: Reduction of cyclic ester followed by oxidation.
Solution:
 Final Answer: (ACD)

30)

Explain Question: Identify the compound 'P'

Concept: Oxidation of aldehyde and alcohol by HNO3

Solution:

(C) It is mirror image of product P.

(D)
Final Answer: (CD)

31)

Explain Question: Which compound gives pink colour with schiff's reagent

Concept: Schiffs reagent test

Solution:

Shiff Reagant Test

Final Answer: (AB)

32) Explain the question

Identify the compound(s) used as a food preservative.

Concept
This question is based on classification of food additives (Preservatives).

Solution
Food preservatives prevent food spoilage by inhibiting microbial growth. All listed substances
are used for this purpose:

A. Sodium benzoate and Sorbic acid are common chemical preservatives (antimicrobials).
B. Propanoic acid (and its salts) primarily prevents mold in baked goods.
C. Vegetable oil is a natural preservative, inhibiting aerobic microbes by excluding oxygen (e.g.,
in pickles).

Final Answer (ABCD)

33) Explain Question: Find the correct match.

Concept: Apply concept of ESR, NSR, FRS & coupling reaction
Solution:
Final Answer: (C)

34) Explain Question: Match the correct option

Concept: Hydrolysis of sucrose, lectose, Amylose and mannose
Solution:
Sucrose α-D-glucose + β-D-fructose
Lactose β-D-glucose + β-D-galactose
Amylose α-D-glucose + α-D-glucose + ...
Mannose cannot be hydrolysed.
Lactose and mannose can reduce Fehling’s solution due to presence of hemiacetal and
aldehyde group.
Final Answer: (D)

35) Explain Question: Match the correct answer

Concept: Based on Le-chatlier’s principle.
Solution:
Kp or Kc are not affected when Δng = 0 on increasing pressure.
For (P) effect of increased volume dominates over effect of increased moles of NO2.
(S) Kp = Kc (RT)Δn
g

Δng = 2
Kp > Kc
Final Answer: (D)

36) Explain Question: Match the correct option.

Concept: Apply the concept of mixing of different solutions.
Tip : (WA + SB) & (SA + WB)
Solution:
P. CH3COOH + NaOH → CH3COONa + H2O
0.1 M, 20 ml 0.1 M, 10 ml
pH = pKa ⇒ [H⊕] will not change on dilution
 correct match : P-1
Q. CH3COOH + NaOH → CH3COONa + H2O
0.1 M, 20 ml 0.1 M, 20 ml
— — 0.05 M

correct match : Q-5

R. NH4OH + HCl → NH4Cl
0.1 M, 20 ml 0.1 M, 20 ml 0.05 M

correct match : R-4

S. Because of dilution solubility does not change so [H⊕] = constant.
Final Answer: (D)

PART 3 : MATHEMATICS

37) Explain Question : Question based on perpendicular distance of a point from a line
Concept : Perpendicular distance of a point from a line
Solution :
25(ℓ2 + m2) = (3ℓ + 4m + 1)2

Perpendicular distance from (–3, –4) on

ℓx + my – 1 = 0 is 5 ∀ ℓ, m ∈ R
Final Answer : (5.00)

38) Explain Question : Question based on family of circles touching a fixed line at a specific
point
Concept : Family of circles touching a fixed line at a specific point
Solution :
By family of circle equation of circle touching y = x at p(4, 4)
(x – 4)2 + (y – 4)2 + λ(x – y) = 0
⇒ x2 + y2 + x(λ – 8) – y(λ + 8) + 32 = 0

radius = =
2λ2 + 128 – 128 = 200 ⇒ λ = ±10
λ = 10 x2 + y2 + 2x – 18y + 32 = 0
λ = –10 x2 + y2 – 18x + 2y + 32 = 0
as (–10, 2) lies inside x2 + y2 + 18x – 2y + 32 = 0. Final Answer : (4.00)

39) Explain Question : Question based on volume of parallelopiped

Concept : Scalar triple product
Solution :

∴ 2g(θ) = 1 ⇒ 4sin2θ = 1

∴ p + q = 5 is least
Final Answer : (5.00)

40) Explain Question : Question based on linear combination of vectors

Concept : Dot product
Solution :

and x = 2cosα
and y = 2cosα
Also, =1
∴

+ 2cosα .
2
4 = 8cos α + 1
8cos2α = 3
Final Answer : (3.00)

41) Explain Question : Question based on rotation of a plane

Concept : Family of planes
Solution :
Equation of the plane P is 4x + 7y + 4z + 81 + λ(5x + 3y + 10z – 25) = 0 (5λ + 4)x + (3λ + 7)y
+ (10λ + 4)z + (81 – 25λ) = 0 Now 4(5λ + 4) + 7(3λ + 7) + (10λ + 4)4 = 0 (20 + 21 + 40)λ = –

(16 + 49 + 16) 81λ = – 81 ⇒ λ = – 1

equation of the plane – x + 4y – 6z + 106 = 0 p = = = ⇒

k = 212
Final Answer : (212.00)

42) Explain Question : Question based on shortest distance between a curve and a plane
Concept : Shortest distance between a curve and a plane
Solution :
Let a = 1 – x
b=x–y
c=y–z
d=z

then a + b + c + d = 1 and a2 + b2 + c2 + d2 =
⇒ (a – b)2 + (a – c)2 + (a – d)2 + (b – c)2 + (b – d)2 + (c – d)2 = 0
⇒a=b=c=d

So the distance from the point

From the plane 4x + 2y + 4z + 7 = 0 is

Final Answer : (2.00)

43) Explain Question : Question based on tetrahedron

Concept : Volume of tetrahedron and A.M./H.M. inequality
Solution :

Volume

Similarly and
So
Now using A.M. H.M. inequality in we get

Hence the minimum value of

Final Answer : (4.00)

44) Explain Question : Question based on intersection of three planes

Concept : Line of intersection of three planes
Solution :
P1 : x + y – z = 1
P2 : ( m – 1)x + (3m – 7)y –5z = –3
P3 : (m – 2)x + (2m –5)y = –4
all the three planes intersects at a line

⇒ m = 3, –2
At m = 3

System does not have any solution

but at m = – 2

⇒ 5P1 + P2 = 2P3
⇒Direction ratio of line of intersection are given by

⇒a = 9λ, b = –4λ, c = 5λ

Final Answer : (1.00)

45) Explain Question : Question based on two circles touching each other externally
Concept : Position of one circle with respect to another circle
Solution :
Let us suppose that P and Q lie on opposite sides of line joing C1 and C2
then KP > KC1 > KQ which is contradiction
⇒ P and Q lie on same side of line joining C1 and C2. Since KP = KQ ⇒ K lies on radical axis.

Since KR = KP = KQ ⇒ K is circum centre of ΔPQR also KP ⊥ QR and KQ ⊥ PR ⇒ K is

orthocentre
⇒ ΔPQR is equilateral Δ.
Final Answer : (B,C)

46) Explain Question : Question based on a series of orthogonally intersecting circles

Concept : Orthogonal circles
Solution :

(Which is a circle for different values of k centre of S1, S2, S3 are an PQ none intersects with
other Hence common tangents are either 0 or 4)
Also are the circles passing through P and Q. Hence have two common tangents.
Final Answer : (A,C)

47) Explain Question : Question based on geometrical aspect of vectors

Concept : Expressing a triangle in terms of vectors
Solution :

;
Final Answer : (A,B,C)

48) Explain Question : Question based on tetrahedron

Concept : Area of a face of tetrahedron and its altitude
Solution :

∵ OA + OB = 4
⇒ [Link] ≤ 4

∴ ar (ΔAOB) = (OA)(OB) ×
Let h = altitude drawn from the vertex C to the base AOB.
So,

∴
But ⇒ equality holds everywhere
So, OA = OB = 2 &
Also, BC ⊥ base AOB ⇒ ∠OBC = 90°
So,

And,

∴
Final Answer : (A,B,D)

49) Explain Question : Question based on line and plane

Concept : Intersection of a line and a plane and intersection of two planes
Solution :

Equation of line

Which is also written as

Point P is the intersection point of

Let P be
Put on
for foot of perpendicular
Let foot of perpendicular is

is perpendicular to line of intersection

Similarly
& its foot of perpendicular S is (1,2,3) insect has to move P to Q minimum path
to do that make question is in form, make plane horizontal

Minimum distance

Final Answer : (A,B,C)

50) Explain Question : Question based on geometry of vectors

Concept : Volume of tetrahedron and its altitude
Solution :

CD; +

BE;
∵ Point of intersection of CD & BE is P
Area of tetrahedral ABCF =

AF; ;
Final Answer : (B)

51) Explain Question : Question based on dot product and cross product of two vectors
Concept : Dot and cross product
Solution :

t = –1 or 2
t = –1
α+β+γ=0
t=2
α=β=γ
Also

Case-1
t=2
α=β=γ
α2 + β2 + γ2 = 6

(S) t + 3 = 5
Case-2
t = –1
α+β+γ=0
α + β – 2γ = 0
γ = 0, α = –β
(Q) , γ2 = 0,
(R) (γ + β)2 = β2 = 3
Final Answer : (A)

52) Explain Question : Question based on plane containing a line

Concept : Distance between line/point and plane
Solution :

Let system of planes are

ax + by + cz = 0 ..... (1)
∵ It contain L1
∴a+b+c=0 …. (2)
For largest possible distance between plane (1) and L2 the line L2 must be parallel to plane (1)
∴a+c=0 …. (3)

∴ Plane H0 :
Now d(H0) = ⊥ distance from point (0, 1, –1) on L2 to plane.

∴P→5

for 'Q' distance =

∴Q→4
∴ (0, 0, 0) lies on plane
∴R→3
for 'S' x = z ; y = z ; x = 1
∴ point of intersection p(1, 1, 1).
∴
∴S→2
Final Answer : (B)

53) Explain Question : Question based on system of circle

Concept : Tangents drawn from a point on a circle to another circle
Solution :

(P) Equation of radical axis of and is

Maximum distance is obtained when P coincides with H.
(Q) Using the property (Here )
(R) Using the property equation of AB is

.
(S) Using property
Final Answer : (B)

54) Explain Question : Question based on reflection of a point in a line

Concept : Reflection of a point in a line
Solution :

(A)
(B) These lines are skew and O lies on shortest distance
(C) Lines are parallel and O lies mid way between them
(D) Lines are coplanar and perpendicular
Final Answer : (B)