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Pendulum Motion and Minimum Distance Analysis

The document contains a series of physics, chemistry, and mathematics problems, primarily aimed at assessing knowledge for an examination. Each section includes multiple-choice questions covering various topics such as mechanics, thermodynamics, chemical bonding, and calculus. The problems require analytical thinking and application of concepts to solve for specific values or understand relationships between physical quantities.

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0% found this document useful (0 votes)
58 views37 pages

Pendulum Motion and Minimum Distance Analysis

The document contains a series of physics, chemistry, and mathematics problems, primarily aimed at assessing knowledge for an examination. Each section includes multiple-choice questions covering various topics such as mechanics, thermodynamics, chemical bonding, and calculus. The problems require analytical thinking and application of concepts to solve for specific values or understand relationships between physical quantities.

Uploaded by

aishikidas567
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

25-09-2025

7650CJA101001250010 JA

PART - 1 PHYSICS

SECTION-I

1) A pendulum of mass m and length ℓ is released from rest in a horizontal position. A nail at a
distance d below the pivot, causes the mass to move along the path indicated by the dotted line. The
minimum distance such that the mass will swing completely round in the circle shown in figure is d

then is :-

(A) 2
(B) 3
(C) 4
(D) 5

2) A block of mass m is being pulled up the rough inclined by an agent delivering constant power P.
The coefficient of friction between the block and the inclined is µ. The maximum speed of the block

during the course of ascent is:

(A)

(B)

(C)

(D)

3) The potential energy of a particle is determined by the expression U = a(x2 + y2), where a is a
positive constant. The particle begins to move from a point with coordinates (3, 3), only under the
action of potential field force. Then its kinetic energy T at the instant when the particle is at a point
with the coordinates (1, 1) is :

(A) 8a
(B) 24a
(C) 16a
(D) Zero

4) In the figure the variation of components of acceleration of a particle of mass 1 kg is shown w.r.t.
time. The initial velocity of the particle is m/s. The total work done by the resultant
force on the particle in time interval from t = 0 to t = 4 seconds is:

(A) 22.5 J
(B) 10 J
(C) 0
(D) None of these

5) A block of mass M has to be dragged up a hill of height h that does not have uniform slope from
bottom to top. The externally applied force (P) is always applied to parallel to the surface, block
moves with negligible velocity and the coefficient of kinetic friction (µk) is same everywhere. Slope of

hill varies from α to β as shown in figure. Work done by force P is given by :-

(A) Mg(µkh cotα + µkb cotβ)


(B) Mg(µkh tanα + µkb tanβ)
(C) Mgh + µkMgb

(D)

6) All blocks are in equilibrium. If block ‘B’ is pulled upwards very slowly so that lower spring comes
to its natural length, what is the displacement of block B ?

(A)

(B)

(C)

(D)

7) A small bead of mass m can move on a smooth circular wire (radius R) under the action of a force

directed (r = position of bead from P & K = constant) towards a point P within the circle at

a distance from the centre. What should be the minimum velocity of bead at the point of the wire

nearest the centre of force (P) so that bead will complete the circle?

(A)

(B)

(C)

(D) None of these

8) A block is simply released from the top of an inclined plane as shown in the figure above. The
maximum compression in the spring when the block hits the spring is :
[JEE (Main) 2024]

(A)
(B) 2 m
(C) 1 m
(D)

9) A body of mass m was slowly hauled up the hill by a force F which at each point was directed
along a tangent to the path. The work done by this force ,if the height of the hill is h, the length of its

base is and the coefficient of friction is μ, is

(A)
(B)
(C)
(D) Can't determined

10) A force of 0.5 N is applied on the upper block as shown in figure. The coefficient of static friction
between the two blocks is 0.1 and that between the lower block and the surface is zero. The work
done by the lower block on the upper block for a displacement of 3 m of the upper block is :-

(A) 1 J
(B) –1 J
(C) 2 J
(D) –2 J

11) A particle is moving along a vertical circle of radius R. At P, what will be the velocity of particle
(assume critical condition at C) :-
(A)
(B)
(C)

(D)

12) A 1500 kg car moving on a flat road negotiates a curve whose radius is 35 m. If the coefficient of
static friction between the tyres and the dry pavement is 0.5. Find the maximum speed, the car can
have in order to make the turn successfully

(A) 13.1 m/s


(B) 15.1 m/s
(C) 20 m/s
(D) 25 m/s

13) A car of mass 'm' moves on a banked road having radius 'r' and banking angle θ. To avoid
slipping from banked road, the maximum permissible speed of the car is v0. The coefficient of friction
µ between the wheels of the car and the banked road is :-

(A)

(B)

(C)

(D)

14) A particle of mass m is fixed to one end of a light spring having force constant k and un
stretched length l. The other and fixed. The system is given an angular speed ω about the fixed and
of the spring such that it rotates in a circle in gravity free space. Then the stretch in the spring is :

(A)

(B)

(C)
(D)

15) A man of mass 50 kg is pulling on a plank of mass 100 kg kept on a smooth floor as shown with
force of 100 N. If both man & plank move together, find force of friction acting on man.

(A)
N towards left

(B)
N towards right

(C)
N towards left

(D)
N towards right

16) Two particles of mass m each are tied at the ends of a light string of length 2a. The whole system
is kept on a frictionless horizontal surface with the string held tight so that each mass is at a
distance ‘a’ from the center P (as shown in the figure). Now, the mid-point of the string is pulled
vertically upwards with a small but constant force F. As a result, the particles move towards each
other on the surfaces. The magnitude of acceleration, when the separation between them becomes

2x, is :-

(A)

(B)

(C)

(D)

17) In the figure shown, the mass of the man = mass of the platform = 60 kg. All pulley are ideal &
strings are light. Then find minimum force applied by the man on string so that system remains in
equilibrium (g = 10 m/s2) :-
(A) 120 N
(B) 240 N
(C) 480 N
(D) 100 N

18) In the given diagram, if the spring connecting D and C is cut then what will be the accelerations

of blocks A, B, C, D at that instant ?

(A)

(B)

(C)

(D)
19) Referring to figure (A) & (B) :-

(A) Reading of spring balance in (A) is 8 g and in (B) is also 8 g


(B) Reading in (A) is less than 8 g and in (B), it is 8 g
(C) Reading of spring balance in (A) is 8 g and in (B), it is less than 8 g
(D) Reading in both (A) and (B) is less than 8 g

20) In a given figure two masses m1 & m2 (m2 > m1) are at rest in equilibrium position. Find the

tension in string AB

(A) m1g
(B) m2g
(C) (m1+m2)g
(D) (m2–m1)g

SECTION-II

1) A particle moves with a velocity under the influence of a constant force


. The instantaneous power applied to the particle is (in J/s) :

2) If the work done by when particle is taken from D to C and then from C to B (in
joule) is _____. All data is given in SI units.

3) A particle is taken from point O to point P (1, 2) through three different paths as shown in figure.
Path OCP is parabolic having equation y = 2x2. The work done by force on particle
along path OCP is :- (x & y are in meters & F is in N) (Round off the answer to nearest integer value)

4) A water Pump (rated 800W) has efficiency of 75%. If it is used to rise water through a height 50m,

volume of water drawn in 10 min is V (in m3). Find 200V

5) A closed circular tube of average radius 15 cm, whose inner walls are rough, is kept in vertical
plane. A block of mass 1 kg just fit inside the tube. The speed of block is 22 m/s, when it is
introduced at the top of tube. After completing five oscillations, the block stops at the bottom region
of tube. The work done by the tube on the block is ______ J. [Given g = 10 m/s2]

PART - 2 CHEMISTRY

SECTION-I

1) In which of the following molecule, C-atom shows two covalency -

(A) CO2
(B) CH2Cl2
(C) COCl2
(D) None of these

2) Which of the following is INCORRECT characteristics regarding to calcium phosphite


(A) Formula is Ca3(PO3)2
(B) P–H bond is present
(C) Oxidation state of phosphorus is +3
(D) All O – – O bond angle are same

3) Pair of molecules or ions which are isostructural (similar molecular structure) is :


(A) CO2, I3
+
(B) PCl4 , PCl5
(C) XeO4, XeO3
+ –
(D) NO2 , NO2

4) Which of the following oxy acid does not contain (S– O – S) linkage
(I) H2S2O6
(II) H2S2O4
(III) H2S2O3

(A) I, II
(B) II, III
(C) I, III
(D) I, II, III

5)

The bond order of C – O bond in is -

(A) 4
(B) 3
(C) 1.33
(D) 5

6)

The number of possible resonance structures for CO32- is

(A) 2
(B) 3
(C) 6
(D) 9

7)

As the s-character of hybridized orbital decreases, the bond angle

(A) Decreases
(B) Increases
(C) does not change
(D) Becomes zero

8) Correct order of extend of overlapping is :-

(A) 2s – 2s > 2p – 2p > 2s – 2p


(B) 1s – 1s > 2p – 2p > 2s – 2p
(C) 1s – 1s < 2s – 2s < 3s – 3s
(D) 3s – 3s > 3s – 3p > 3p – 3p

9) In which of the following options, both species are paramagnetic and have same no. of unpaired
electrons

(A) O2 and B2
(B) O2 and ClO2
(C) N2 and O2
(D) None of these

10) Which of the following pairs of species would you expect to have largest difference in spin only
magnetic moment ?

(A)
(B)
(C)
(D)

11) Which of the following molecules has both pπ-pπ and pπ-dπ bonds

(A) XeO2F2
(B) SO2Cl2
(C) SO3
(D) XeO3

12) Which of the following order is incorrect

(A) NaCl < MgCl2 < AlCl3 (Covalent character)


(B) Na+ < Mg2+ < Al3+ (Polarising power)
(C) (size of cation)
(D) AgCl > AgBr > AgI (Lattice energy)

13) Which of the following has been arranged in order of decreasing dipole moment?

(A)
(B)
(C)
(D)

14) Which of the following is not correct order w.r.t the given property

(A) N–N > O–O > F–F Bond length


(B) Cl–Cl > Br–Br > F–F Bond Energy
(C) N–N > O–O > F–F Bond Energy
(D) N≡N < C≡N < C≡C Bond Energy

15)

Which of the following true order of bond energy :-

(A) Cl2 > Br2 > F2 > I2


(B) Br2 > Cl2 > F2 > I2
(C) F2 > Cl2 > Br2 > I2
(D) I2 > Br2 > Cl2 > F2

16) The xenon compound(s) that are iso-structural with and respectively are :

(A) Linear XeF2 and pyramidal XeO3


(B) Bent XeF2 and pyramidal XeO3
(C) Bent XeF2 and planar XeO3
(D) Linear XeF2 and tetrahedral XeO3

17)

The percentage of s-character in the orbitals forming P–P bonds in P4 is

(A) 25
(B) 33
(C) 50
(D) 75

18) Maximum change in %s character of bonding orbital of central atom occurs in which of the
following transformation.

– –
(A) BF3 + F → BF4
+ +
(B) NH3 + H → NH4

(C) N2O5 → NO2 + NO3
2–
(D) BeF2 → [BeF4]

19) Identify the correct match ?


(i) XeF5+ (cation of XeF6(s))
(ii) PBr4+ (cation of PBr5(s))
(iii) ICl2+ (cation of I2Cl2(l))
(iv) PCl6– (anion of PCl5(s))
(a) Central atom has sp3 hybridization and bent shape
(b) Central atom has sp3d2 Hybridization and octahedral
(c) Central atom has sp3 Hybridization and Tetrahedral
(d) Central atom has sp3d2 Hybridization and square pyramidal.

(A) (i - a); (ii - b) ; (iii - c) ; (iv - d)


(B) (i - d); (ii - c) ; (iii - a) ; (iv - b)
(C) (i - c); (ii - d) ; (iii - a) ; (iv - b)
(D) (i - d); (ii - c) ; (iii - b) ; (iv - a)

20) Which of following species have maximum number of peroxide linkages per molecule?

(A) CrO5
(B)
(C)
(D) H2SO5

SECTION-II

1) How many of the following elements have lesser ionization energies than nitrogen ?
B, C, O, P, Mg, Al, Si, S, Cl

2) How many of the following processes are exothermic ?

(vi)

3) Ionization energy = 201 kJ/mol


Ionization energy = 440 kJ/mol

Ionization energy = 700 kJ/mol

If the difference between IE3 – IE2 is X, then the value of is :-

4) How many elements have more ionisation energy as compared to their next higher atomic number
element ?
Na, Mg, Al, Si, P, S, Cl, Ar

5) Find the total number of correct orders among the following.


(1) Order of electron affinity : S > O–
(2) Order of ionic radius : Al3+ < Mg2+ < O2–
(3) Order of Electronegativity : Si < P < C < N
(4) Order of atomic radius : O < C < S < Se
(5) Order of second ionization energy :
C<N<F<O
(6) Order of ionic radii : S2– < Cl– < K+ < Ca2+

PART - 3 MATHEMATICS

SECTION-I

1) The value of is

(A) 4
(B) 3
(C) 2
(D) 1

2) is -

(A) 1
(B)
(C)

(D)

3) Let θ is interior angle of a regular polygon of n sides, then is -

(A)

(B)

(C)

(D)
4) Numerical value of + sin is equal to

(A) 0
(B) 1

(C)

(D)

5) The sum of the series &nbsp.....∞ is :

(A) 2
(B) 3
(C) 10
(D) 8

6) The smallest positive value of x satisfying the equation

is equal to -

(A)

(B)

(C)

(D)

7) The sum of the series 1(n) + 2(n– 1) + 3(n – 2) + ....... upto 10 terms is (where n ∈ N, n = 10) -

(A) 220
(B) 440
(C) 385
(D) 770

8) If a, b and c are positive real numbers and a2 + b2 + c2 = 1, then maximum value of ab + bc + ca


is equal to

(A) 1
(B) 2
(C) 3
(D) 4

9) The sum of infinite number of terms of a G.P. is 2 and the sum of their cubes is 24, then second
term of G.P. is -
(A)

(B)

(C)

(D)

10) The coefficient of x49 in the product (x – 1)(x – 3)(x – 5)..... (x – 99) is equal to :

(A) -992
(B) 1
(C) -2500
(D) None of these

11) Find the sum of n terms of sequence 1,3,7,13,21...

(A) n(n2 + 2)
(B) n2 – n + 1

(C)

(D)

12) If (5n + 4) :(9n + 6) is the ratio of the sum of 2 APs of n terms, then find ratio of their 13th terms

(A)

(B)

(C)

(D)

13) In the expansion of (1 + 3x + 2x2)6, the coefficient of x11 is

(A) 144
(B) 288
(C) 216
(D) 576

14) In the expansion of , the number of integral terms is

(A) 128
(B) 129
(C) 130
(D) 131

15) The co-efficient of x4 in the expansion of (1 – x + 2x2)12 is

12
(A) C3
13
(B) C3
14
(C) C4
12
(D) C3 + 3 13C3 + 14C4

16) Let represents the combination of 'n' things taken 'k' at a time, then the value of the sum

equals -

(A)

(B)

(C)

(D)

17) The coefficient of x101 in the expression


x > 0, is

(A)
(B)
(C)
(D)

18) The last three digits of 350 will be

(A) 249
(B) 259
(C) 349
(D) 241

19) The value of , is where


(A)
(B)
(C)
(D)

20) If the term independent of x in the expansion of is 105, then a2 is equal to :

(A) 4
(B) 9
(C) 6
(D) 2

SECTION-II

0
1) If Cr = 20Cr and 1.C 2 + 3.C12 + 5.C22 + ... + (41)C202 = then value of a – b is

2) If (40C0) + (41C1) + (42C2) +...+ (60C20) = 60


C20, m and n are coprime, then m + n is equal to___.

3)

The difference between maximum and minimum value of the expression y = 1 + 2sinx + 3cos2 x is ,
then find the value of k

4) Find the number of values of θ satisfying the equation sin3 θ = 4sin θ. sin 2θ. sin 4θ in 0 ≤ θ ≤ 2π

5) A class consists of a number of boys whose ages are in A.P., the common difference being four
months. If the youngest boy is just eight years old and if the sum of the ages is 168 years, then
number of boys in the class, are
ANSWER KEYS

PART - 1 PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B A C B C B B B B B B A C B A B B B B D

SECTION-II

Q. 21 22 23 24 25
A. 140.00 0.00 2.00 144.00 245.00

PART - 2 CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. D A A D C B A B A B C C A D A A A D B A

SECTION-II

Q. 46 47 48 49 50
A. 8.00 3.00 3.00 2.00 5.00

PART - 3 MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. C D C C A C A A A C C C D B D D A A A A

SECTION-II

Q. 71 72 73 74 75
A. 20.00 102.00 16.00 15.00 16.00
SOLUTIONS

PART - 1 PHYSICS

1)

Explain Question : The problem asks to determine the minimum distance d for the mass m to
complete a full circle and calculate the ratio 5d/ℓ. When a pendulum of mass m and length ℓ. It
released from rest in a horizontal position. A nail at a distance d below the pivot causes the
mass to more along the path.
Concept : Energy conservation and circular motion dynamics.
Solution :
Energy conservation from release to lowest point

mgℓ =
v=
Energy conservation from lowest point to top of the circle
r=ℓ-d
For the mass to complete a full circle, it must have a minimum speed at the top of the circle.
This minimum speed Vtop is achieved when the tension in the thing between zero, and the
centripetal force is provided solely by gravity.

mg =
Vtop =
Now, we apply the conservation of energy from the lowest point (where the speed is V
= ) to the top of the new circular path (where the speed is Vtop = )
2mgr = 2mg (ℓ – d)

+ 2mg(ℓ – d)

m(2gℓ) = m (g(ℓ–d)) + 2 mg(ℓ – d)

ℓ and (3/5ℓ) = 3
Final answer : Correct option (2).

2) wNet = – (mg sinθ + m mg cosθ) dx + Fent dx


by WET
Δ k.ε. = wNet
⇒ k.ε.f – 0 = wNet
For max. speed

⇒ – (mg sinθ + m mg cosθ)


⇒ P = (mg sinθ + m mg cosθ) v
3) usign conservation of M.ε.
ΔU + Δk.ε = 0
⇒ Δk.ε = ΔU = – [a(12+12) – a(32+32)]
⇒ Δk.ε = 16a

4) Area of the graph ;

=6 = ⇒ V(x)f = 3.

and = –10 = ⇒ V(y)f = – 6. Thus, u = 5 m/s and v = m/s.


Now work done = Δ KE = 10 J

ax = t ay = ⇒ vx = t2 + C
t = 0 : vx = – 3 ⇒C=–3

∴ vx = t2 – 3

⇒ dx = .... (1)

dy = .... (2)
dw = =


∴ W = 10 J

=6= ⇒ V(x)f = 3.

= –10 = ⇒ V(y)f = – 6.
u = 5 m/s, v = m/s.
= ∆ KE = 10 J

5) Wforce + Wmg + Wfriction = 0


Wforce – Mgh – µMgb = 0
Wforce = Mgh + µMgb

6) When lower spring comes to natural length, T2k = mg

⇒ extension in upper spring =

Initial compression in upper spring =

Initial compression in lower spring =

∴ Total displacement of block B =


7)

Value of F at any angular position 'θ' is given by

, here r is given by

Also i.e.
For small angular displacement 'dθ' work done by this fore
dw = F R dθ cos(90 – α)
= –F R sin α dθ

∴ work done in moving bead from A to B

∴ Energy provided at point A must be equal to this work done.

8) wg + wFr + ws = Δ KE

5 × 10 × 5 – 0.5 × 5 × 10 × x – Kx2 = 0 – 0
250 = 25 x + 50 x2
2x2 + x – 10 = 0
x=2

9) By using W = ΔKE
⇒ Wf + Wg + Wext = 0

⇒ Wext =

10)
0.5 = 3a ⇒ a = 5/30
f = 2a = 2(5/30)= 1/3N
fmax = 0.1 × 10 = 10N
∴ f = 1/3 N will act
work done by lower block
= –f(s) = –1/3(3) = –1 Joule

11) m Rg + mgR = m +
[Using energy conservation].

12)

...(1)
N = mg
(f)L = µsN
= 0.5 × mg ⇒ 0.5 × 1500 × 10 = 7500 N


Vmax = 13.1 m/s
∴ option (A) is correct.

13)
Ncosθ – f sinθ = mg

Rgtanθ + µRg = v2 – v2µtanθ

14)
kx = mlω2 + mxω2

15)
fmax = µmg 100 + f = 50 a
100 – f = 100 a
200 = 150 a

a=

Hence on man towards left 100 – f =

f=

16)
F = 2Tsinθ
Tcosθ = mf
Here f = acceleration
17)
FBD of platform + man

Force applied by man = 2T = 240 N

18) Before string is cut

k1x1 = 1g
T = k1x1 + 2g = 3g

k2x2 = T + 3g = 6g
k3x3 + 4g = 10g
when spring between D and C is cut k2x2 = 0
as spring force does not changes instantaneously
aD = =
aA = 0

T + 3g = 3a .....(1) (for block C)


3g – T = 2a .....(2) (for block B)
(1) + (2)
6g = 5a

a=

19)

20) Question Explanation: The problem asks to find the tension in a string AB when the
system is in equilibrium.

Concept: This question is based on Newton's second law.

Solution:
FBD of m2
T2 = m2g

FBD of m1
T2 = m1g + T1
T1 = m2g – m1g
TAB = T1 = (m2 – m1)g
Final Answer: The correct option is (4).

21)
P = 50 – 30 + 120
P = 140 Watt

22)

W=0

23)

y = 2x2

w=

24)
25) +245

PART - 2 CHEMISTRY

26) Covalency of carbon in COCl2, CO2 & CH2Cl2 is four.

27) The correct molecular formula of calcium phosphite is CaHPO3

28)

A. Question Explanation: The question asks us to identify a pair of molecules or ions that are
isostructural, meaning they have the same or very similar shapes.

B. Given Data: We are given four pairs of molecules/ions and need to determine their
structures.

C. Concept: VSEPR (Valence Shell Electron Pair Repulsion) theory

D. Solution:

A. CO₂, I₃⁻: CO₂ has a linear structure (O=C=O). I₃⁻ also has a linear structure (I-I-I) due to
the central iodine having 3 lone pairs and 2 bond pairs. This pair is isostructural.

B. PCl₄⁺, PCl₅: PCl₄⁺ has a tetrahedral shape. PCl₅ has a trigonal bipyramidal shape. Not
isostructural.

C. XeO₄, XeO₃: XeO₄ has a tetrahedral shape. XeO₃ has a pyramidal shape. Not
isostructural.

D. NO₂⁺, NO₂⁻: NO₂⁺ is linear. NO₂⁻ is bent or angular. Not isostructural.

E. Final Answer:
The pair of molecules/ions that are isostructural is CO₂ and I₃⁻ (option 1).

29) Ans - option (4)


Explanation - To determine which oxyacid does not contain an S-O-S linkage, let's analyze the
given sulfur oxyacids.
Concept -
(i) H2S2O6 →
S-O-S is not present

(ii) H2S2O4 →
S-O-S is not present

(iii) H2S2O3 →
S-O-S is not present

30)

Question Explanation:

Bond order in .

Concept:

This question is based on Resonance.

Solution:

Bond Order = = 1.33

Final Answer:
The correct option is (3).

31)

There are 3 structures are possible.

32)

[Link] α Bond - angle


33)

Extent of overlapping ∝ directional character Extent of overlapping

34) In O2 number of unpaired electron in O2 = 2


In ClO2 number of unpaired electron in ClO2 = 1
In N2 number of unpaired electron = 0
so option (A) is correct as B2, O2 both have two unpaired electron.

35)

Species No. of unpaired

O2 2

36)

37) Theoretical

38) Bond length of 'Cl' dominates over Bond length of 'F'.

39) C ≡ N < N ≡ N < C ≡ N Bond energy

40) F–F, small size more repulsion b/w electron pair, less bond energy.

41)
42)
sp3 percentage s = 25

43) ⇒ BF3 + F– → BF4–


sp2 → sp3
33% → 25%
⇒ NH3 + H+ → NH4+
sp3 → sp3
25% → 25%
⇒ N2O5 → NO2+·NO3–
sp2 → sp, sp2
⇒ BeF2 → [BeF4]–2
sp → sp3
50% → 25%

44)

45)

46) Except Cl remaining all elements have lesser ionization energies than nitrogen.

47) Conceptual

48) I.E1 = 201 kJ/ mol


I.E2 = 440 – 201 = 239 kJ/ mol
I.E3 = 700 – I.E1 – I.E2
= 700 – 201 – 239
= 260 kJ/ mol
IE3 – IE2 (X) = 260 – 239 = 21 kJ/mol

= =3

49) 2.0 Order of ionization energy


Na < Mg > Al < Si < P > S < Cl < Ar

50) (6) correct order is S2– > Cl– > K+ > Ca2+

PART - 3 MATHEMATICS

51)

52)

53)

α = 1, β = 1, n = 97

54) + sin

= +

= sin = +0=

55)
– – – –
________________________________________

⇒S=2

56)

Given equation can be written as

57)

⇒ sum = 220

58)
similarly b2 + c2 > 2bc, c2 + a2 > 2ac
Hence 2(a2 + b2 + c2) > 2(ab + bc + ca)
⇒ ab + bc + ca < 1​

59) ...(1)

...(2)

on solving

∴ ar =

60) (x – 1) . (x – 3) . (x – 5) ......... (x – 99)


Coefficient of
x49 = –(1 + 3 + 5 + .... + 99)
= –25 × [2 + 49 × 2] = –2500
Ans. (C)

61) 1, 3, 7, 13, 21 .............


S = 1 + 3 + 7 + 13 + 21 + ......... + Tn
Diff. of series S is
2, 4, 6, 8, ........ A.P.
Tn = ax2 + bx + c
T1 = 1 = a + b + c ..... (1)
T2 = 3 = 4a + 2b + c ..... (2)
T3 = 7 = 9a + 3b + c ..... (3)
(2) – (1) 3a + b = 2 ..... (4)
(3) – (2) 5a + b = 4 ..... (5)
(5) – (4) 2a = 2
By eq. (4) ⇒ b = –1, c = 1
Tn = n2 – n + 1
Sn = Σn2 – Σn + Σ1

Ans. (C)

62)

Putting = 12 in eq. (1)


n = 25

Ans. (C)

63) (1 + 3x + 2x2)6 = [1 + x(3 + 2x)]6


= 1+ 6C1x (3 + 2x) + 6C2x2 (3 + 2x)2 +
6
C3x3 (3 + 2x)3 + 6C3x4 (3 + 2x)5 +
6
C5x5 (3 + 2x)3 + 6C6x6 (3 + 2x)6
We get x11 only from 6C6 x6 (3 + 2x)6. Hence, coefficient of x11 is 6C5 × 3 × 25 = 576.

64)
1024 – r = an even integer
r = 0, 8, 16, 24, .......... 1024
n = 129
65) (1 – x + 2x2)12
General term =
r2 + 2r3 = 4 ⇒ r3 = 0, r2 = 4, r1 = 8
r3 = 1, r2 = 2, r1 = 9
r3 = 2, r2 = 0, r1 = 10

Co-efficient of x =
4

= 12C3 + 3·13C3 + 14C4 (after solving)

66)

Hence option (D) is the answer.

67)

Therefore coefficient x101 in the given expression

68)

= Multiple of 1000 + 249


Hence the last three digits of 350 will be 249 .

69)

70)

General term =
20 – 2r – 3r = 0
r=4

a3 = 8
a2 = 4

71) Method-1 :
C0 + 3C1 + 5C2 + ... + (2n + 1)Cn

= 2.(n.2n–1) + 2n = n.2n + 2n = 2n(n + 1)


Method-2 :
C0 + 3C1 + 5C2 + ... + (2n + 1)Cn
= (C0 + C1 + C2 + ... + Cn) + (2C1 + 4C2 + ... + 2nCn)
= (C0 + C1 + C2 + ... + Cn) + 2(C1 + 2C2 + ... + [Link])
= 2n + 2(n.2n–1)
= 2n + n.2n
= 2n(n + 1)

72) 40C0 + 41C1 + 42C2 +.....59C19 + 60C20

14
C1 + 42C2 +.....

42
C2 + 43C3 +....

42
C2 + 43C3 +.....

43
C3 + 44C4 +.......

43
C3 +.......

Similarly:
⇒ m = 61 ; n = 41
m + n = 102

73)

y = 1 + 2sinx + 3cos2 x
⇒ y = 1 + 2 sinx + 3 - 3sin2x

⇒ y = 1 – 3(sin2x – sinx + – – 1)

y=1–3 =–3 +
ymax = , ymin = – 3 + = –1

74) sin 3θ = 4 sin θ sin 2θ sin 4θ ⇒ sin 3θ = (2 sin θ) (2 sin 2θ sin 4θ)
⇒ 3 sin θ – 4 sin3 θ = 2 sin θ (cos 2θ – cos 6θ) ⇒ 3 – 4 sin2 θ = 2(cos 2θ – cos 6θ) or sin θ = 0
⇒ 3 – 2(1 – cos 2θ) = 2 cos 2θ – 2 cos 6θ or sin θ = 0

⇒ 1 = –2 cos 6θ ⇒ cos 6θ = or sin θ = 0 ∴ sin θ = 0 or cos 6θ =

⇒ θ = nπ or θ = = ⇒ θ = 0, π, , , ,
So eight solutions.

75) Here years

[2a + (n – 1)d]

On solving we get
n = 16

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