SOLUTIONS 279

Level 1) Objective Problems

: given liquid will decrease if:
pressure ofia
vapour
1. The decreased
(a) surface area of liquid is
the volume of liquid in the container is decreased
volume of the vapour phase is increased
ie) the
is decreased
(d) the temperature T is 19 mm Hg. If
normal boiling point of water is 373 K. Vapour pressure of water at temperature
2. The vaporisation is 40.67 kJ/mol, then temperature T would be
enthalpy of
R:8.3 JK-mol-l).
(Use : log 2=0.3,
(a) 250 K (b) 291.4 K
(d) 290K
(c) 230 K

3.
law is obeyed by each constituent of a binary liquid solution when:between unlike molecules
Raoult's
greater than those
a) the forces of attractions between like molecules are
) the forces of attractions between like molecules
are smaller than those between unlike molecules
are identical with those between unlike molecules
i) the forces of attractions between like molecules
different
(d) the volume occupied by unlike molecules are
the solution is given as:
A Eora binary ideal liquid solution, the total pressure of
(b) Protal =P; +(Pi-P;) X
(a) Protal =P, +(PÅ -P;)XB
(d) Protal =Pg +(P; -P;) X¡
(c) Protal =P +(P -På) XA of Ain liquid
5. For an ideal binary liquid solution with P
> P, which relation between X, (mole fraction
correct ?
phase) is
phase) and Y, (mole fraction of A in vapour
(a) Y, < Y
(b) X >Xp
(d) YAXA
(C Y X¡
law states that :
6. For a dilute solution, Raoult's
equal to the mole fraction of solute
(a) the lowering of vapour pressure is solute
pressure is equal to the mole fraction of
(b) the relative lowering of vapour of solute in solution
pressure is proportional to the amount
(c) the relative lowering of vapour of solvent
solution is equal to the mole fraction
(d) the vapour pressure of the g, 4.0 g and 6.0 g of the
salt is 4 g in 100 g of water at 25°C. If 2.0
7. The solubility of a specific non-volatile system X, Yand Z. The vapour pressure would be in the order:
salt added of 100g of water at 25°C, in
(b) X> Y>Z
(a) X <Y <Z (d) X>Y =Z
(c) Z> X =Y 184°C and 212°C
boiling point of CsH6, CHOH, C,H,NH, and CH,NO, are 80 C, 65°C,
8. The room temperature :
respectively. Which will show highest vapour pressure at
(b) CH,0H
(a) CH,
(c) CçHNH, (d) CçH,NO2
pure
dissolved in 9.9 moles of water. If the vapour pressure of
9. 6.0 gof urea (molecular weight= 60) was
water is P°, the vapour pressure of solution is:
(a) 0.10 po (b) 1.1O po
(c) 0.90 po (d) 0.99 po
10. An ideal solution was found to have a yapour pressure of 80 torr when the mole fraction of a non-volatile
solute was 0.2. What would be the vapour pressure of the pure solvent at the same temperature?
 280 Physical Chemistry for NEET
(b) 80 torr
a) 64 torr
(c) 100 torr (d) 400torr
is found to be 750 mm H&
11. The vapour pressure of an aqueous solution of sucrose at 373 K
The
the solution at the same temperature will be :
(a) 0.26
(b) 0.73 nolality s
(d) 0.039
(c) 0.74
aqueole
12. Estimate the lowering of vapour pressure due to the solute (glucose) in a 1.0 M
(a) 10 torr
(b) 18 torr solution at 100c,.
(d) 24 torr
(c) 13.45 torr
molecular weight 40, which should
13. Calculate the weight of non-volatile solute having be
S7 gm octane to reduce its vapour pressure to 800: dissolved in
(a) 47.2g (b) 5 g
(d) None of these
(c) 106.2 g
14. The Vapour pressure of a solvent decreased by 10 mm of mercury, when shoulda non-volatile
[Link] be the solute was added
the solvent. The mole fraction of the solute in the solution is mole fraction of o
mercury'? the
Solvent, if decrease in the vapour pressure is to be 20 mm of
(a) 0.8 (b) 0.6
(d) 0.2
(c) 0.4
15. Equal weight of a solute are dissolved in equal weight of two solvents Aand Band formed very
solution. The relative lowering of vapour pressure for the solution Bhas twice the relative dilute
Vapour pressure for the solution A. If M, and Ma are the molecular weights of solvents Aand of B lowering
respectively, then:
(a) MA = Mg (b) M¡ =2 xMA
(c) MA =4MB (d) Ma =2Mg
16. An ideal solution has two components Aand B. Ais more volatile than B, L.e., PA > P and also P ,b
then:
X and YA are mole fractions of components Ain liquid and vapour phases,
(a) XA =YA (b) X >YA
(d) Data insufficient
(c) XA < YA
pure liguid Bie An
17. At 25°C, the vapour pressure of pure liquid A (mol. wt. = 40) is 100 torr, while that of
andB is:
torr, (mol. wt. =80). The vapour pressure at 25°C of a solution containing 20 g of each A
(a) 80 torr (b) 59.8 torr
(c) 68 torr (d) 48 torr
solution. The
18. What is the mole fraction of toluene in the vapour phase at 30°C above a benzene-toluene
mole fraction of benzene in the solution phase is 0.400?
(PR =119 torr and Pf =37.0 torr), B stands for benzene and T stands for toluene.
(a) 0.237 (b) 0.567
(c) 0.428 (d) 0.318
respectively. The mole fraction
19. The vapour pressures of pure benzene and toluene are 160 and 60 mm Hg
of benzene vapour phase in contact with equimolar solution of benzene and toluene is :
(a) 0.073 (b) 0.027
(c) 0.27 (d) 0.73
20. Two liquidsAand Bhave vapour pressure in the ratio P, :Pa =1:3at a certain temperature. ASSunien
Thenthe mole
Bform an ideal solution and the ratio of mole fractions of Ato Bin the vapour phase is 4:3.
fraction of B in the solution at the same temperature is :
1 4
(a) (C
3 5
 SOLUTIONS 281
and Bhave PA and PB In the ratio of 1 : 3 and the ratio of number of
A moles ofA and b
liquids

l :3then mole fraction of Ain vapour phase in

21.
Two

phase
are
equilibrium with the solution is equal to:
liquid (b) 0.2
(a) 0.1
(d) 1.0
(c) 0.5
the following plots correctly representing the varjation in rate of evaporation and rate ol
Which
of with time? (for a liquid in a closed container)
condensation
22. Rate of vaporization

Rate of vaporization

Rate of condensation (b) Rate

(a) Rate
Rate of condensation
Time Time>

Rate of vaporization
Rate of vaporization

(d) Rate
(c) Rate Rate of condensation
Rate of condensation

Time Time>

given diagram, which of the following statements regarding the homogenous solutions of two
Based on the
23.
volatile liquids are correct?

VPr.

A E mole fraction 8
XA = 1 X¡=1
n Plots AD and BC show that Raoult's law is obeyed for the solution in which Bis a solvent and A is the
solute and as well as for that in which Ais solvent and Bis solute.
(2) PlotCD shows that Dalton's law of partial pressures is obeyed by the binary solution of componentsA
and B.
(3) EF +EG =EH; and AC and BD Correspond to the vapour pressures of the pure solvents A and B
respectively.
Select the correct answer using the options given below:
(a) Only 1 (b) 2 and 3
(c) 1and 3 (d) All
24. The vapour pressure curves of the same solute in the same solvent are shown. The curves are parallel to
each other and do not intersect. The concentrations of solutions are in order of:
’([Link]). 1 atm
Pure

solvent

+Temperature(°Cj
(a) I< II < II (b) I= II = II
(c) I> II > II (d) I> II > II
 282 Physical Chemistry for NEE
with
liquid water in
equilibrium
water
25. Acylinder fitted
25°C. Which of thewith
following operation
a movable contains
piston results Vapour
in a decrease in the equilibrium vapour pressure at 25c
pressure,
(a) Moving the piston downward a short distance
(b) Removing asmall amount of vapour
(c) Removing a small amount of liquid water
(d) Dissolving some salt in the water. statement.
26. For ideal binary liquid solutions, select incorrect
(a) no change in interactions when two liquids are mixed
(b) AH mix =0
(c) AV mix =0
(d) AS miy =0
27. Which is correct statement?
(a) For all non-ideal solutions, AV mix >0
(b) For all non-ideal solutions, AH mix <0
azeotrope.
(C) Chloroform and acetone form maximum boiling
heat released.
ethanol and water mixed then
28. (a) boilingliquid
The When point of an azeotropic mixture of water-ethanol is less than that of both water and ethand
Then:
(a) the mixture will show negative deviation from Raoult's law
(b) the mixture will show positive deviation from Raoult's law
(c) the mixture will show no deviation from Raoult's law
(d) this mixture can be considered as true solution
29. Formation of asolution from two components can be considered as :
() Pure solvent ’ separated solvent molecules, AH,
(ii) Pure solute ’ separated solute molecules, AH2
(iii) separated solvent and solute molecules ’ solution, AH3
Solution so formed will be ideal if:
(a) AH soh =AH, + AH, +AH3 (b) AH soln =AH, + AH, - AH,
(c) AH soln =AH, -AH, - AH (d) AH soln = AH - AH, - AH,
In this
30. Total vapour pressure of mixture of 1 mol X(P, =150 torr) and 2 mol Y(Py =300 torr) is 240 torr.
case:
(a) There is a negative deviation from Raoult's law
(b) There is a positive deviation from Raoult's law
(c) There is no deviation from Raoult's law
(d) Can not be decided
31. In a mixture of A and B, components show positive deviation when:
(a) A -Binteraction is stronger than A -A and B -B interaction
(b) A -B interaction is weaker than A -Aand B -B interaction
(c) AV mix < 0, AS mix > 0
(d) AV mix =0, AS mix > 0
32. A mixture of cyclohexane and ethanol shows :
(a) ideal solution behaviour (b) negative deviation from Raoult's law
(c) positive deviation from Raoult's law (d) cannot be predicted
33. A solution of acetone in ethanol :
(a) obeys Raoult's law
(b) shows a negative deviation from Raoult's ]law
(c) shows a positive deviation from Raoult's law
(d) behaves like a near ideal solution
 SOLUTIONS 283
will form
maximum
boiling azeotrope ?
W h i c h

solution (b) HNO, +H,0 solution

34, CçH, + GçH,CH,
(a) Czi,OH
+H,0 solution (d) n-hexane and n-heptane
of mixture of 1 of
(c)
vapour
pressure
mole of volatile component A(PA =100 mm Hg) and 3 mole
a5.
Total
B(PA =80 mm Hg) is 90 mm Hg. For such case:
component
volatile

positive deviation from Raoult's law

there is
(a) point has been lowered
boiling
(b) between AandB is smaller than that between Aand A or
attraction
between B and B
force of
(c) above statemnents are correct
all the
(d)
a z e o t r o
miixture of water (B.P.=100° C) and HCI (B.P = 86C) boils at about 120°C. During
p i c

46. The distillation of this mixture it is possible to obtain:

fractional

(a) pure HCI (b) pure H,0

HCI
well as pure (d) neither H,0 nor HCI
(c) pure Hz0 as
Azeotropic
mixture of water and C,HOH boils at 351 K. By distillingthe mixture it is possible to obtain :
37. C,H,OH only (b) Pure water only
(a) Pure water
C,H,OH nor (a) Both water and C,H,OH in pure state
(c) Neither of
azeotropic mixture two liquids has a boling point higher than either of them when it:
38. An deviation from Raoult's laww (b) shows negative deviation from Raoult's law
(a) shows positive
behaviour (d) is saturated
(c) shows ideal
(P =100 torr) and B(P; =200 torr) are completely immiscible with each other (each one
39, Iftwo liquids A the other) are present in a closed vessel. The total vapour pressure of the
will behave independently of
system will be:
torr (b) greater than 200 torr
(a) less than 100
(c) between 100 to 200
torr (d) 300 torr
40, Which of the following is not a colligative property?
(a) Vapour pressure (b) Depression in [Link].
(c) Elevation in [Link]. (d) Osmotic pressure
41. Which of the following is a colligative property?
(a) Osmotic pressure (b) Boiling point
(c) Vapour pressure (d) Freezing point
42. The degree of dissociation of an electrolyte is a and its van't Hoff factor is i. The number of ions obtained by
complete dissociation of 1 molecule of the electrolyte is:
i +a -1
(a) (b) i-a -1
i-1 i+1+a
(c) (d)
1-a

t3. One mole of a solute A is dissolved in a given volume of a solvent. The association of the solute take place
as follows:
nA A,
Ta is the degree of association of A, the van't Hoff factor i is expressed as:
(a) i=1-a (b) i=1+
n

(c) i= n (d) i=1

 284 Physical Chemistry for N:EET
and
w The van't Hoff factor i for an
electrolvte which undergoes dissociation association in
respectively: (b) less than one and greater than one
solvent ae
(a) greater than one and less than one
(d) greater than one and greater than
(c) less than one and less than one unity? one
be greater than
45. For which of the following van't Hoff factor cannot
(b) AlCl,
(a) K,[Fe(CN)] (d) KNO3
46. (c)Which
NH,CONH,
of the following salt has the same value of van't Hoff factor (i) as that of K4[Fe(CN)]?
(b) NaCl
(a) Al,(S04)3 (d) Al(N03)3
(c) Na,sO4
47. Which solution has the highest vapour pressure (b) 0.03 M sucrose at 15°C
(a) 0.02 M NaCl at 50°C
(d) 0.005 M CaCl, at 25°C
(c) 0.005 M CaCl, at 50°C
pressure of
48. An aqueous solution is 1.00 mojal in KI. Which change will cause the vapour the solution to
increase ?
(b) addition of NaCl
(a) addition of water
(d) Addition of 1.0 molal KI
(c) addition of Na ,SO 4
0.01 m, 0.001 m and 0.0001 m are . .
+9. Four solutions of K,SO, with the concentrations 0.1 m,
maximum value of colligative property corresponds to :
(b) 0.001 m solution
(a) 0.0001 m solution
(d) 0.1 m solution
(c) 0.01 m solution
50. Moles of Na SO, to be dissolved in 12 mole water to lower its vapOur pressure by 10 mm u.
temperature at which vapour pressure of pure water is 50 mm
is:
(b) 2 mole
(a) 1.5 mole
(d) 3 mole
(c) 1mole
51. When 1 mole of a solute is dissolved in 1 kg of H,0, boiling point of solution was found to be 100 5er
for H,0 is:
(a) 0.5 (b) 100
(c) 100.5 (d) 95.5
52. What will be the temperature at which a solution containing 6 g of glucose per 1000 g water willboil if
molal elevation constant for water is 0.52K kg mol?
(a) 1000.173°C (b) 100.0173°C
(c) 100.173°C (d) None of these
53. The rise in the boiling point of a solution containing 1.8g of glucose in l00 g of a solvent is 0.1C. Ihe
molal elevation constant of the liquid is:
(a) 0.01K/m (b) 0.1K/m
(c) 1K/m (d) 10 K/m
54. Chloroform, CHCI,, boils at 61.7C. If the K, for chloroform is 3.63°C/molal. what is the boiling point oid
solution of 15.0kg of CHCl, and 0.616 kg of acenaphthalene, CpHo?
(a) 61.9 (b) 62.0
(c) 52.2 (d) 62.67
55. Acompound has the empirical formula CyGH ,Pe. Asolution of 0.26 gof the compound in 112 goWhat isis thethe
(CçH,) boils at 80.26°C. The boiling point of benzene is 80.10°C; the K, is 2.53°C/molal.

molecular formula of the compound?

(a) CgoHz4 Feg (b) CyoHgFe
(c) CçH4Fe
 SOLUTIONS 285
of azulene in 100.0
0.640 g of g of benzene boils at 80.23°C. The boiling point of benzene is
solution

is 2.53°C//molal. What is the molecular weight of azulene?

A
8 0 . 1 0 ° C :
the K,
56.
(a) 108
(b) 99
(c) 125
(d) 134
of a carboxylic acid in benzene shows the elevation of
boiling point of 1.518 K. The
solution

molal
One for dimerization of the acid in benzene is (K, for
benzene =2.53 K kg mol-):
a s s o c i a t i o n

57. degree of
(a) 60%
(b) 70%
(c) 75%
(d) 80%
The correct relation between the elevation in boiling point and the molar mass of a solute 1s:
respectively weight of solvent and
58. and W, are solute) :
1000
(W,
K, x W, x (b) M, K; xW, x 1000
(a) M2 = AT, x W, AT; x W2
1000
AT, x K; x (d) M, = AT, x W, x 1000
(c) M2 = W, x W; K, x W,
point elevation constant for toluene is 3.32 Kkg [Link] normal boiling point of toluene is
The boiling
110.7°C. The enthalpy of vaporisation of toluene would be nearly:
59.
kJ mol-l (b) 34.0 kJ mol-l
(a) 17.0
kJ mol-1 (d) 68.0 kJ mol
(c) 51.0
Which one of the following aqueous solutions will exhibit highest boiling point:
60.
(a) 0.015 M
urea (b) 0.01 MKNO,
(c) 0.10 M Na,S0, (d) 0.015 M glucose

61.
Calculate the percentage degree of dissociation of an electrolyte XY, (Nomal molar mass = 164) in water if
ohserved molar mass by measuring elevation in boiling point is 65.6:
(a) 75% (b) 25%
(c) 65% (d) None of these
62.
If the elevation in boiling point of a solution of non-volatile, non-electrolytic and non-associating solute in
solvent (K, =[Link]) is yK,then the depression in freezing point of solution of same concentration
would be: (K, of the solvent = z [Link]. mol-)
2xz (b)3
(a)

yz
(c) (d)
y 2x

63. When a solution containing non-volatile solute freezes, which equilibrium would exist?
(a) solid solvent liquid solvent (b) solid solute liquid solution
(c) solid solute liquid solvent (d) solid solvent liquid solution
64. Bromoform has a normal freezing point of 7.734°C/m and it's K, =14.4°C/m. Asolution of 2.60 g of an
unknown in 100 g of bromoform freezes at 5.43°C. What is the molecular weight of the unknown?
(a) 16.25 (b) 162.5
(c) 100 (d) none of these
03.l freezes at 5.5°C. At what temperature will a solution of 10.44 g of C4H in 200 g of C,H, freeze?
K, (CçH6)=5.12°C/m
(a) 4.608°C (b) 0.892°C
(c) 5.5°C (d) none of these
66. The freezing point of a solution containing 4.8g of a compound in 60g of benzene is 4.48. What is the
Cr mass of the compound? (K. =5.1 km-; freezing point of benzene =5.5° C)
(a) 100
(b) 200 (c) 300 (d) 400
 67. 286 point Chemistry
Physical
The freezing for NEET
of a solution prepared from 125g ofa non-electrolyte and 20 o ot water is 27\9K,
mass of the solute will be:
then molar
1.86kg Kmol-
molar depression constant is (b) 106.7

(d) 93.9
68. (a)
The105.7
freezing point of a solution of 2.40 g of biphenyl (C2H0) in 75.0 g of benzene (CH6)is 4.40°C. .
(c) 1153
normal freezing point of benzene is 5.50°C. What is the molal freezing point constant (C/m) for benzene?
(b) 5.1
(a) 5.3 (d) 4.8
69. Asolution containing 1.8 g of a compound(empirical formula CH,0) in 40 g of water is Observeà to freezs
(c) 4.6
water = 1.86 kg K mol-)
is : (K, ofcompound
formula of the
at -0.465°C. The molecular (b) CzH,
(a) C,H,O2 (d) CoHO6
1-electrolyte solute dissolved in 50 g of benzene lowered the freezing Doint of benzene by
(c) C4HgO4
O.40 K. The freezing point depression constant of benzene is 5.12 K kg [Link] molar mass of the solue
70. 1.00 g of a non-

is : (b) 256 g mol

(a) 256 kg/mol (d) 256 mg/mol
(c) 256 g/mol doubled, the value of
molal depression constant (K) will be:
71. If molality of the dilute solutions is (b) tripled
(a) halved (d) doubled
(c) unchanged liquid solvent solid solvent is :
reezing point of the following equilibrium, AH
72 AH - AG (b)
(a) AS
TAS AS
AG (d)
(c) AH
AS solution2
non-volatile solute is present in an ideal
73. Which represents correct difference when
Vapour Vapour

(AS) Solution (I1) (AH) Solution - (aH) solvent

() (AS)
Solvent Solvent or Solution
Solution
Solvent

Solution

B.P.
(1)
Solvent
(b) I, II
(a) I, II, III
(c) II, II
(d) I, II
74. Select correct statement: betweel
than a pure solvent has, the entropy change
(a) Solution has more molecular randomness and solid
solution and solid is larger than the entropy change between pure solventintermolecular forces d
similar since similar forces of
(b) Heat of fusion of solution and solvent are
involved
(c) Sugar containing solution freezes at a lower temperature than pure water
(d) Allare correct statements

75. Select correct statement?

i n t e r m o l e c u l a r

similar
(a) Heats of vaporisation for a pure solvent and for a solution are similar because
forces between solvent molecules must be overcome in both cases
 SOLUTIONS 287
b) Entropy change between solution and vapour is smaller than the entropy change between pure solvent
and vapour

point of the solution is larger than that of

(c)
Boiling
correct statements the pure solvent
All are
(d) point of a solution is smaller than that
Freezing
(a) of asolvent.
It is due to
AH of solution and solvent is almost identical since intermolecular forces between solvent molecules
76.
:
are involved

(b) AS of solution (between solution and solid) is larger than that of the AS of solvent (between solvent
and solid)
(c) AS of the solution is smaller than that of the solvent
(d) AH ofthe solution is much higher than of solvent but AS of solution is smaller than that of the solvent
17. When 36.0 g of a solute having the empirical formula CH,0is dissolved in 1.20 kg of water, the solution
freezes at
What is the molecular formula of
-0.93°C

the solute? (K, =1.86°C kg

mol
(a) C z H , o (b) C,H,O,
(c) C,H,03 () CH,0,
78. Calculatethe molecular weight of a substance whose 7.0% by mass solution in water freezes at -0.93G.
cryoscopic Constant of water is 1.86°C kg mol-:
The
(b) 150.5 g mol
( a ) 1 4 0 g m o l - 1

mol
(c) 160 g (d) 155g mol1
Camphor is often used in molecular mass determination because:
79.
(a) it is readily available (b) has a very high cryoscopic constant
volatile
(c) it is (d) is solvent for organic substances
80. For1 molal solution of each compound minimum freezing point will be assuming complete ionisation in
each case:
(a) [Fe(H,0)6]Cl, (b) [Fe(H,0),CI]Cl, H,0
(c) (Fe(H,0), Cl,jCl-2H,0 () [Fe(H,0),C1,]-3H,0
.. Por 1molal solution of each compound maximum freezing point
will be assuming complete ionisation in
each case:
(a) [Fe(H,0),JCl, (b) (Fe(H,0)Cl]Cl2 -H,0
(c) [Fe(H,0),Cl,]Cl -2H,0 (a) [Fe(H,0),Cl,]-3H,0
82. Acomplex is represented as CoClxNH3. Its 0.1 molal solution in water shows AT,
is 1.86 Kmolality .Assuming 100%o ionisation of complex and co-ordination =0.558 K. K, for H,0
number of Co is six, calculate
formula of complex:
(a) [Co(NH;),]Cl, (b) [Co(NH;) ,Cl]Cl,
(c) [Co(NH,),Cl,]CI (d) none of these
83. The freezing point of equimolal aqueous solutions will be highest for:
(a) CoH,NH CI (b) Ca(NO,),
(c) La(NO3)2 (a) CçHi206
84. The freezing point of a 4% agueous solution of A is equal to the freezing point
of
B. If the molecular weight of A is 60, then the molecular weight of 'B' will be: 10% aqueous solution of
(a) 160
(b) 90
(c) 45
(d) 180
3. Dmer of acetic acid in liguidbenzene is in equilibrium with acetic
acid
and pressure. If 25% of the dimer molecules are separated out then monomer at certain temperature
(a) Freezing point of the solution
(c) Boiling point of solution reduces (b) Average molar mass of solute increases
increases (d) Molar mass of solute decreases
 288 Physical Chemistry for NEET
point of solution wil be
disSociated. The freezing
86. In a 0.5 molal solution KCI, KCI is 50%
mol):
(a) 274.674 K
(b) 271.60K
these
(K=\86k
(d) none of
(c) 273 K
1hefreezing point ot
87. 0.1 Msolution of KCl and CaCl, are separately prepared in water. completely ionized? KClis found to
the freezing point of CaCI, ag. solution if itis be
What is (b) +3°C
(a) -3°C (d) +4°C
(c) -2°C
is dissolved in 25.0 g of water and the
88. A1.0 g sample of Co(NH,CH,CH,NH,),l3 produced per mole of compound? The
solution is -0.87°C. How many ions are
freezingK point of the
of water
1.86°C/molal:
(b) 3
(a) 2
(c) 4 (d) 5
reaction. Asolution 1
89. Phenol associates in benzene to a certain extent in dimerisation

phenol in 1.0 kg of benzene has its freezing point depressed 0.69

K. Hence, degree of containing 0.02 kg of
dimerized will be : (K,(CGH)=5.12 Kkg mol J
association of pheng
(b) 0.73
(a) 0.63
(d) 0.93
(c) 0.83
maximum freezing point will be:
S0. Assuming complete ionisation. the solution having
(a) 1 MCaF, () 1.5 MAl,(SO4)3
(c) 2 M NaCl () 1 MAgNO ,
lowest freezing point?
91. Which of the following 0.10 magueous solution willhave the
(a) Al,(S04)3 (b) CçH,0s
(c) KI (d) CH2011
92. Ina 0.2 molal aqueous solution of a weak acid HX the degree of ionisation is 0.25. The freezing noint ot.,
solution will be nearest to: (K, =1.86 Kkg mol")
(a) -0.26°C (b) 0.465°C
(d) -0.465°C
(c) -0.48°C
would be .
93. An aqueous solution of 0.01 M HAhas van't Hoff factor of 1.01. pH of 0.01M HA (aq.)solution
(a) 2 (b) 3
(c) 4 (d) 5
94. An aqueous solution of 0.01 M KCl causes the same elevation in boiling point as an aqueous solution of
urea. The concentration of urea solution is:
(a) 0.01 M (b) 0.005 M
(c) 0.02 M (d) 0.04 M
95. 0.1 molal aqueous solution of an electrolyte AB, is 90% ionised. The boiling point of the solution at 1atm
is :(Kp(HO) =0.52 Kkg mol)
(a) 273.19 K (b) 374.92 K
(c) 376.4 K (d) 373.19 K
96. Which of the following aqueous solutions has osmotic pressure nearest to pure solvent?
(a) Na,SO4 (b) BaCl,
(c) Al,(SO4)3 (d) CH011 container. For
in a
97. 0.1M NaCl and 0.05M BaCl, solutions are separated by asemi-permeable membrane
this system, ch00se the correct answer :
(a) There is no movement of any solution across the membrane
(b) Water flows from BaCl, solution towards NaCl solution
 SOLUTIONS 289
flows from NaCI
solution towards BaCl,
0.1M NaCl is lower than thesolution
Water
(c) Osmotic pressure of
(d) (assume complete dissociation)
osmotic pressure of BaCl2
solutions, A and B, are separated by a
immediately begins to decrease. Which ofsemi-permeable membrane. The osmotic pressure of
9 8 . T w o a q u e o u s

s o l u t i o n A
the following statement is true ?
(a) The solvent molecules are moving from the solution of higher osmotic pressure to that of
lower oSmotic pressure.
(b) The initial osmotic pressure of solution Bis greater than that of solution A.
Solvent molecules are moving from solution Binto solution A.
(c) (b) are true statements.
(d) Both (a) and
99. Which one of the following pairs of solution can we expect to be isotonic at the same temperaturer
NaC
and 0.1 M (b) 0.1 M urea and 0.2 M MgCl2
(a) 0.1 M urea
NaCI and 0.1 M Na,SO4 (d) 0.1 MCa(NO,) and 0.1 M Na,SO 4
(c) 0.1 M
100. Asemipermeablee membrane used in the measurement of osmotic pressure of a solution allows the passage
of:
through it (b) solvent molecules through it
(a) solute molecules molecules
(c) both solvent and solute (d) either solvent or solute
case of Osmosis, solvent molecules move from :
101. In the
(a) Higher vapour pressure to lower vapour pressure
(h) Higher concentration to lower concentration
(c) Lower vapour pressure to higher vapour pressure
a) Higher osmotic pressure to lower osmotic pressure
102. Pure water can be obtained from sea water by:
(a) centrifugation (b) plasmolysis
(c) reverse osmosis (d) sedimentation
103. The osmotic presures of equimolar solutions of urea, BaCl, and AlCI, will be in the order :
(a) AlCl3 > BaCl2 > urea (b) BaCl, > AlCl, > urea
(c) urea > BaCl, > AlCl (d) BaCl, > urea > AlCl,
104. Which of the following solutions will have maximum osmotic pressure? Assume 90% dissociation of each
salt:
(a) decimolar aluminium sulphate
(b) decimolar barium chloride solution
(c) decimolar sodium sulphate solution
(d) solution of equal volumes of decimolar barium chloride and decimolar sodium sulphate solutions
105. If M,noma is the normal molecular mass and a is the degree of ionization of K,[Fe(CN)6], then the
abnormal molecular mass of the complex in the solution willbe:
(a) [Link] (1+2a) -1 (b) Mnormal (1 +3a)
(c) Mnomal (1 + a)-1 (d) equal to M, normal

106. Equal volumes of 0.1 M urea and 0.1 M glucose are mixed. The mixture will have:
(a) lower osmotic pressure (b) same osmotic pressure
(c) higher osmotic pressure (d) none of these
07.A 5% (w/) solution of cane sugar (molecular weight =342) is isotonic with 1% (w) solution of a
Substance X. The molecular weight of X is:
(a) 34.2 (b) 171.2
(c) 68.4 (d) 136.8
 290 Physical Chemistry for NEET
0.9% soluios
solution of cane-sugar is isotonic with a of an
108. At certain temperature a 5.12%
solute. The molar mass of solute is: (b) 46.17
unknown
(a) 60 (d) 90
(c) 120 concentration of 34.2 gram/litre
109. An aqueous solution of sucrose (C.Ho0,, ) having asolution of glucose (C&H6) to behas an
pressure of 2.38 atmospheres at 17°C. For an aqueous
this solution, its concentration should be :
isotoniOSmoi
c witrh
(b) 17.1 gram per litre
(a) 34.2 gram per litre
(d) 36.0 gram per litre
(c) 18.0 gram per litre mass of proteins (or
110. Which of the following colligative properties can provide molar DolymerS Or colloids)
with greater precision ? (b) Elevation of boiling point
(a) Relative lowering of vapour pressure (d) Osmotic pressure
(c) Depression in freezing point pressure required to
111. Based upon the technique of reverse osmosis the approximate
be:
desalinate sea water
containing 2.5% (mass/volume) KNO, at 27°C will (b) 21 atm
(a) 10.5 atm
(d) 6.09 atm
(c) 12.2 atm
osmotic pressure at 27°
112. A1% (wt/vol) KCl solution is jonised to the extent of 80%. The of the solution
will be:
(b) 5.94 atm
(a) 6.95 atm
(d) 3.30 atm
(c) 2.71 atm
113. Osmotic pressure of blood is 7.40 atm, at 27°C. Number of moles of glucose to be used per litre for an
pressure of blood is:
intravenous injection that is to have same osmotic
(a) 0.3 (b) 0.2
(c) 0.1 (d) 0.4
[Link] relationship between osmotic pressures (7,,T, and T3) at a derimite temperature when 1 g glucose 1.
is (assume i =1 for all):
urea and 1g sucrose are dissolved in 1litre of water
(a) N2>3
115. van't Hoff provedthat osmotic pressure () is a colligative property. For an ideal solution, osmotic pressure
W,RT Law can be show by the curve
(n) is helpful to determine that molecular mass of solute using M¡ =
(C= concentration):
C= constant C= constant

(b)
T

T= constant T= constant

(c) (d)

116.A solution containing 4.0 gof PVC in 2litre of dioxane (industrial solvent) was found to have an osm
pressure 3.0 x 10 atm at 27°C. The molar mass of the polymer (g/mol) will be :
(a) 1.6 x 104 (b) 1.6x 105
(c) 1.6 x 103 (d) 1.6x 102
 SOLUTIONS 291
nressures of 0.010 Msolutions of KI and of sucrose
(C,,H 0.432 atm and 0.24 atm
o s m o t i c

117. respectively.
The
The van't Hoff factor for KI is : 01) are
(a) 1.80 (b) 0.80
(c) 1 . 2 (d) 1.0
is the correct sequence of osmotic pressure of 0.01 M aq. solution
1 1 8 . W h a t

of :
(1) Al,(S0,)3 (2) Na P04
(3) BaCl, (4) Glucose?
T2 3 > t,
(a) T4 >
(d) 1 >Ty>3> T4
119. A0.010 gsample of Cr(NH3)4(S04)Cl is dissolved in 25.0 ml., of water and the osmotic pressure of tne
solution is 59.1 torr at 25°C. How many moles of ions are produced per mole of compound?
(a) 1 (b) 4
(c) 2 (d) 3
[Link]
of the following aqueous solutions should have the highest osmotic pressure?
AIClz at 50°C (b) 0.03 M NaCl at 25°C
(a) 0.011M
25°C
(c) 0.012 M (NH4)2S0, at (d) 0.03 M NaCl at 50°C
121.A 5.8% solution (w/) of NaCl is isotonic with 27%solution (w/) of glucose. Calculate percentage degree
NaCI.
of ionization of
(a) 50% (b) 25%
(c) 100% (d) 75%
=5) when reacted with A,B,(i=5) in aqueous solution gives brown colour. These are separated by
122. aX,Y,(i
semipermeable membrane AB as shown. Due to osmosis there is:
0.5 M 0.01 M
AzB

Side X Side Y:

SPM
(a) brown colour formation in side X (b) brown colour formation in side Y
(c) formation in both of the sides X and Y (d) no brown colour formation
123. Molar solubility of helium, nitrogen and oxygen are plotted against partial pressure of the gas at constant
temperature.

Solubi ty N
He

Partial Pressure

Henry's law constant for these gases will lie in following sequence?
(a) O,> N,>He (b) O, <N, <He
(c) O, =N, =He (d) O, > N, <He
[Link] to Henry's law, the solubility of a gas in a given volume of liquid increases with increase in:
(a) Temperature (b) Pressure
(c) Both (a) and (b) (d) None of these
 292 Physical Chemistry for NEET
gIven below. Arranoe . he
for some gases at 293 Kis
125. The value of Henry's law constant
He: 145 kbar, H,:69
kbar, N,: 76.5 kbar, O2: 34.9 kbar. gases in the
increasing order of their solubility. (b) O, <H, <N, <He
(a) He < N, <H,<O2 (d) He <O, <N, <H,
(c) H, <N, <O,< He
number of moles of 0, from
air dissolved in 100 mol of
126. The mole fraction of O, in air is 0.2. The solubility of O, as in
298K and 10 atm pressure is : (Given Henry's law
constant for the
water is 4.0waterx at
104
atm.) x 10-3
(b) 2
(a) 5 x 10-3 (d) 4x10-2

(c) 2.5 x 10-2

dissolves 0.02 gm of nitrogen at 293
127. 1 kg of water undera nitrogen pressure of 1 atmosphere
Henry's law constant : (b)7.7 x 10°atm
[Link]
(a) 7.7 x 10 atm
(d) 2 x 10atm
(c) 2 x 10- atm
A
a gas Ais 10 atm. The mole fraction of gas in gaseous mixture
128. The Henry's
is 0.4. Calculate constant
law the number of mole ofofgas
for solubility Afrom gaseous mixture dissolved in 25 mol of water at 300 K

and 10 atm pressure.

(b) 0.01
(a) 0.1 (d) 2.5 x 10-3
(c) 0.001
129. According to Henry's law, the partial pressure of gas (P,) is directly proportional to mole fraction of gas in
Henry's constant. Which is incorrect ?
lquid solution, Pons = Ku.X where K is
(a) KH is characteristic constant for a given gas-solvent system
gas
(b) Higher is the value of Ku. lower is solubility of gas for a given partial pressure of
(c) KH has temperature dependence
(d) Kå decreases with increase of temperature
130. At 760 torT pressure and 20C temperature, 1 L of water dissolves 0.04 gm or pure OXygen or 0.02 .
pure nitrogen. Assuming that dry air is composed of 20% oxygen and 80% nitrogen (by volumel
masses (in g/L)of oxygen and nitrogen dissolved by 1 Lof water at 20C expOSed to air at a total pressie
of 760 torr are respectively :
(a) 0.008, 0.016 (b) 0.016, 0.008
(c) 0.16, 0.08 (d) 0.04, 0.02
 sOLUTIONS 309

Answers ?

Level-1
3. (c) 4. (b) 5 6. (b) 7. (d) 9 (d) 10. (c)
2. (b) 8 (b)
(d)
1. (c) 13. (b) 14. (b) 15. (6) 16. (c) 17. (a) 18 (d) 19 (d) 20. (a)
12.
(C
11. 23. (d) 24. (a) 25. (d) 26 (d) 27. (a) 30. (a)
22.
(d) (c) 28. (b) 29.
(a)
21.
(c) 33. (c) 34. (b) 35 36 (d) 37. (c) 38 (b) 39. (d) 40. (a)
32.
(b)
31.
43. (c) 44. (a) 45. (C) 46. (a) 47. (c) 48. (a) 49. (d) 50. (c)
42. (a)
(a)
41.
(6) 53. (c) 54. (d) 55 56. (c) 57. (d) 58 a 59. (b) 60. (c)
52.
(a)
51.
(b) 63. (d) 64 (b 65 (b) 66. (d) 67. (a) 68. (a) 69. (d) 70. (c)
(a)
62.
61.
73. (a) 74. (d) 75. (d) 76. (b) 77. (d) 78. (b) 79. (b) 80. (a)
(c)
72. (b)
71.
83. (d) 84 (a) 85 (b) 86. (b) 87. (a) 88. (c) 89. (b) 90. (d)
(d) 82. (b)
81.

(d) 93. (c) 94 (C) 95 (d) 96. (d) 97. (b) 98. (c) 99. (d) 100. (b)
(a) 92.
91.

(c) 103. (a) 104. (a) 105. (b) 106. (b) 107. (c) 108. (a) 109. (c) 110. (d)
101. (a) 102.

111. (C) 112. (b) 113. (a) 114. (c) 115. (a) 116. (b) 117. (a) 118. (d) 119. (c) 120. (d)

122. (d) 123. (b) 124. (b) 125. (a) 126. (a) 127. (a) 128. (c) 129. (d) 130. (a)
121. (a)

Level-2
1. (a) 2. (a) 3. (a) 4. (c) 5 (b) 6. (c) 7. (d) 8. (c) 9. (d) 10. (d)

11. (c) 12. (b) 13. (a) 14. (c) 15 (b) 16 (a) 17. (a) 18. (a) 19. (d) 20. (c)

21. (b) 22. (a) 23. (d) 24. (b) 25. (b)

Level-3
1 (A) 2. (D) 3. (A) 4 (A) 5 (C) 6 (E) 7. (B) 8. (A) 9. (A) 10. (B)
11, (B) 12. (E) 13. (A) 14. (B) 15. (E) 16. (B) 17. (A) 18. (E) 19. (C) 20. (A)
21, (A) 22. (B) 23. (D) 24. (B) 25. (D) 26. (A) 27. (B) 28. (A) 29. (C) 30. (C)
31. (B) 32. (C) 33. (A) 34 (A) 35. (A)