14-09-2025

0999DJA161103250009 JA

PART-1 : PHYSICS

SECTION-I (i)

1) In the circuit shown, when the switch S is closed :

(A) no charge flows through S

(B) charge flows from A to B
(C) charge flows from B to A
(D) None of these

2) In the given circuit which resistor consumes max power ?

(A) 2Ω
(B) 3Ω
(C) 4Ω
(D) All consumes equal power

3) A small ball of mass m is suspended from a light rod as shown. The ball is given a horizontal
velocity at A equal to twice the minimum velocity required by the ball to complete the loop. Find the

tension in the rod when the ball passes through the topmost point.

(A) 15 mg
(B) mg
(C) 11 mg
(D) 12 mg

4) In the below arrangement, all the string and pulleys are massless and the inclined plane is
frictionless. At t = 0, spring is unstretched and a constant force F = mg starts to act. Find the
maximum extension in the spring. (Assume incline to be sufficiently long).

(A)

(B)

(C)

(D)

SECTION-I (ii)

1) A hollow, insulating spherical shell has a surface charge distribution placed upon it, such that the
upper hemisphere has a uniform surface charge density +σ, while the lower hemisphere has a
uniform surface charge density –σ, as shown in the figure. Their interface lies in x-y plane. Which of

the following statement (s) is / are correct?

(A) The field at all points of x-y plane within the sphere points in the – ve z-direction.
(B) All points of the x-y plane within the sphere are equipotential.
(C) The field at all points on z-axis outside the sphere point along positive z-direction.
The field at points on z axis which are on either side of origin outside the sphere is in opposite
(D)
directions.

2) Orbital velocity of a satellite in its orbit (around earth) of radius 'r' is 'v'. it collides with another
body in it orbit and comes to rest just after the collision. Taking the radius of earth as R, the speed
with which it will fall on the surface of earth will be . Then :

(A) a = 1
(B) a = 2
(C) b = 1
(D) b = 2

3) A variable force F = 10 t is applied to block B placed on a smooth surface. The coefficient of

friction between A & B is 0.5. (t is time in seconds. Initial velocities are zero)

(A) Block A starts sliding on B at t = 5 seconds.

(B) Block A starts sliding on B at t = 10 seconds.
(C) Acceleration of A at 10 seconds is 15 m/s2.
(D) Acceleration of A at 10 seconds is 5 m/s2.

4) A projectile is projected at an angle of elevation α. After t seconds, it appears to have an angle of

elevation β as seen from the point of projection. Which of the following is/are correct?

(A) the y-coordinate of the position of the projectile at time t is , where v is the
velocity of projection.
the x-coordinate of the position of projectile at time t is , where v is the velocity of
(B)
projection.

(C)
tan β = tan α – , where v is the velocity of projection.

(D)
velocity of projection is .

SECTION-II

1) Figure shows an equiconvex lens of µ = 1.50, in contact with a liquid layer on the top of a plane
mirror. When a point object is placed at 45 cm from lens, it is found that image coincides with
object. When liquid is removed and experiment is repeated, the new distance for object and image to

coincide is found to be 30 cm. Then refractive index of liquid would be . Find the value of n.
2) A ray of light from a liquid is incident on a system of two right angled prism of
refractive indices and as shown in the figure. The light suffers zero net deviation when it
emerges into air from surface CD. If the angle of incidence (in degrees) is θ, find θ.

3) A spherical surface is fixed on ground. Its radius is 5 m. A block is placed some height below the
top most point. The acceleration of block at given instant is 6 m/s2. If the height (in m) of the block

above ground at that instant is h then find the value of .

4) Two blocks A and B each of mass m are placed on a smooth horizontal surface. Two horizontal
force F and 2F are applied on both the blocks A and B, respectively, as shown in figure. The block A
does not slide on block B. Find the normal reaction acting between the two blocks (in N) if F = 10 N.

5) A collar B of mass 2kg is constrained to move along a vertical smooth and fixed circular track of
radius 5m as shown in figure. The spring is in plane of the track and has a spring constant of 200
N/m. It is underformed when collar is at A. It starts from rest at B. What is the normal force (in N)
exerted by the track on the collar when it passes through A ? (g = 10 m/s2)
6) Half hemispherical shell (one fourth of total spherical shell) of radius r is charged uniformly such
that surface charge density is σ. Charge is on the curved surface only. Then the electric field

intensity at the O as shown in figure is given by , value of α is :-

7) Three dielectric of relative primitivities , and are introduced in a parallel

plate capacitor of plate area A and separation d. The effective capacitance between P and Q is .

Then will be :

8) The current developed in a real conductor is given as I = aV1/2, where V is the potential difference
across the conductor. When it is connected with a resistance of R Ω in series with a battery of 6 Volt
as shown in the figure, the power developed in the conductor is twice the power generated in

resistance of R Ω. Find the value of R. [a = 0.2 A volt–1/2]

PART-2 : CHEMISTRY

SECTION-I (i)
1) Which of the following bond angle order is NOT correct.

H2O < OCl2

(A)

(B) N(SiH3)3 > P(SiH3)3

(C) PH3 < PCl3

H2S > PH3
(D)

2) The major product in the following reaction is :

(A)

(B)

(C)

(D)

3) If molar entropy of Br2(g) and Br2(l) are 265 J/mol-K and 141 J/mole-K respectively. Calculate
normal boiling point for Br2(l).
ΔHvap.[Br2(l)] = 31 kJ/mole.

(A) 250 K
(B) 200 K
(C) 130 K
(D) 70 K

4)
Major product is :
(A)
(B)

(C)

(D)

SECTION-I (ii)

1) In which of the following major product is/are correct ?

(A)

(B)

(C)

(D)

2) Choose the correct statement(s) among the following.

2–
(A) [Pd(Cl)4] is tetrahedral geometry & paramagnetic.
(B) [Cr(NH3)3(Cl)3] has 2 geometrical isomers & 2 optical isomers.
3+ 3–
(C) [Co(H2O)6] is low spin while [CoF6] is a high spin complex & both cant show G.I.
3 2
(D) [Fe(H2O)5(NO)]SO4 has sp d hybridisation and can’t show optical isomers.

3) In the following gaseous phase first order reaction :

A(g) → 2B(g) + C(g)
initial pressure was found to be 400 mm of Hg and it changed to 1000 mm of Hg after 20 min. Then :

(A) half life for A is 10 min

(B) rate constant is 0.0693 min–1
(C) partial pressure of C at 30 min is 350 mm of Hg
(D) total pressure after 30 min is 1100 mm of Hg

4) How many of the following statement is/are INCORRECT ?

3–
(A) EAN of [Rh(ox)3] is 56
(B) dC–C in Zeise's salt is less than that of C2F4 molecule
(C) Red bauxite consists of Fe2O3 as minor impurity
(D) In Hall-Heroult process, the produced Al floats at the top of the electrolyte

SECTION-II

1) Find sum of d-orbitals used in the hybridisation in [PtCl4]–2, K4[Fe(CN)6], [Zn(NH3)4]+2, [Cr(OX)3]–3

2) A certain substance A tetramerises in water to the extent of 80%. A solution of 5gm of A in 100gm
of water lowers the freezing point by 0.6 °C. Then molar mass of A is (in gm mol–1)
[Kf = 1.86K mol Kg–1]

3) A gaseous mixture of C3H8 and CH4 exerts a pressure of 320 mm Hg at temperature TK in a V liter
flask. On complete combustion of mixture, flask containing only CO2 exerts a pressure of 448 mm Hg
under identical condition. The mole fraction of C3H8 in the given mixture is

4) How many isomer of C4H10O when react with PCC, carbonyl compound will be formed as a
product? (Excluding stereo isomer). Note : PCC – Pyridinium chloro chromate

5) The total number of alkenes possible by dehydrobromination of 3-bromo-3-cyclopentylhexane

using alcoholic KOH (by E2 mechanism) is :

6) Calculate the magnitude of resonance enthalpy (in kJ/mole) of CO2(g) from following data

= – 390 kJ/mol

= 715 kJ/mol
= 500 kJ/mol
= 800 kJ/mol

7) If x → Number of pπ-dπ bonds is XeO4.

y → Number of electrons having ℓ = 2 in La

z → Difference in effective nuclear charge on C and O Then value of is.

8) In ionic compound cation A+ and anion B– are arranged in following arrangement in cubic closed
packed structure as shown in one face. If number of unit cells present in 200 g of solid is Y × 1023,
then find value of Y.
Atomic mass of A = 10 amu
Atomic mass of B = 20 amu
Avogadro number (NA) = 6 × 1023

PART-3 : MATHEMATICS

SECTION-I (i)

1) The smallest positive value of x satisfying the equation

is equal to -

(A)

(B)

(C)

(D)

2) The set of value (s) of ‘a’ for which the function possess a
negative point of inflection :

(A)
(B) {–4/5}
(C) (–2,0)
(D) empty set

3) Let x1, x2, x3, x4, x5 are positive numbers such that x1 + x2 + x3 + x4 + x5 = 15. If M is maximum
value of (1 + x1).(2 + x2).(3 + x3).(4 + x4).(5 + x5) then the value of log6M is

(A) 3
(B) 4
(C) 5
(D) 6

4) If the three linear equations x + 4ay + az = 0, x + 3by + bz = 0 and x + 2cy + cz = 0 have a non-
trivial solution, then, (a, b, c ∈ R)

(A) 2ac = bc + ab
(B) b2 = ac
(C) 2b = a + c
(D) None of these

SECTION-I (ii)

1) The sum is equal to :

(A) tan–12 + tan–13

(B) 4tan–11

(C)

(D)

2) If then (Where 'C' is constant

of integration)

(A) Maximum value of f(x) is –2 when x < 0

(B) Minimum value of f(x) is 2 when x > 0
(C) f(0) is not defined
(D) f(e) < f(π)

3) The expression simplifies to :

(A) an irrational number

(B) a prime number
(C) a natural number which is not composite
(D) a real number of the form where a and b prime

4) If , where , then

(A)
(B) a & b are any real numbers
(C)

(D)

SECTION-II

1) Let f(x) = ax3 + bx2 + cx + d and g (x) = x2 + x – 2.

If = 1 and = 4, then find the value of .

2) If the straight lines x + y – 2 = 0, 2x – y + 1 = 0 and px + qy – r = 0 are concurrent then the slope

of member of family of lines 2px + 3qy + 4r = 0 which is farthest from origin is 'm'. Then |10m| is :

3) Let k1 & k2 be two values of k for which is

differentiable at x = 0, then value of is equal to

4) If α and β are non-zero real roots of equation 3αx2 + 3βx – (α – β) = 0, then the value of

is

5) The number of integral values of x satisfying equation is equal to

Here sgn x, [.] and {.} denotes signum, greatest integer and fractional function respectively

6)

The value of is (Where [.] and {.} is denotes greatest integer function and fractional part
function respectively)

7) P is a point on positive x-axis. Q is a point on the positive y-axis and 'O' is the origin. If the line
passing through P and Q is tangent to the curve y = 3 – x2 then the minimum area of the
triangle OPQ is

8) Let A = {x : x2 – 10|x| + 16 ≤ 0, x ∈ I} and B = {x : (|x – 2| – 3) (|x + 1| – 2) ≤ 0, x ∈ I}

then find the cardinality of A ∪ B.
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4
A. A B C D

SECTION-I (ii)

Q. 5 6 7 8
A. A,B,C B,C A,D A,B,C,D

SECTION-II

Q. 9 10 11 12 13 14 15 16
A. 4.00 45.00 1.80 30.00 1480.00 8.00 3.00 5.00

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 17 18 19 20
A. D A A A

SECTION-I (ii)

Q. 21 22 23 24
A. A,B,D C,D A,B,C,D A,B,C,D

SECTION-II

Q. 25 26 27 28 29 30 31 32
A. 5.00 62.00 0.20 3.00 5.00 5.00 13.15 24.00

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 33 34 35 36
A. C A C A

SECTION-I (ii)

Q. 37 38 39 40
A. A,D A,B,C,D B,C A,D
 SECTION-II

Q. 41 42 43 44 45 46 47 48
A. 16.00 3.00 8.00 6.00 7.00 9.00 4.00 16.00
 SOLUTIONS

PART-1 : PHYSICS

1)

So

So when switch is connected no charge flows through AB

2)
R 2Ω 3Ω 4Ω

3)

we know, for a rod for looping, vmin =

v = 2vmin =
By energy conservation, velocity at top most point will be

v=

⇒ Ttop =

4)

Here F1 = 2 mg – mg × = mg

F2 = 2 mg × =
 ∴F=

∴ xmax =

5) Due to symmetric charge distribution, the electric

field intensity at any point on the x-y plane will be along z-axis. It means field lines are
perpendicular to the x-y plane. It further explains x-y plane is equipotential plane as electric
field lines are always perpendicular to equipotential surface.

6) ..... (i)

...... (ii)

From (i) and (ii) we have v' =

7)

For 'A' starts sliding on 'b'

for t ≥ 5 sec
aA = 5 m/sec2

8) y-coordinate is

y = v sin α t [Therefore A is correct]

x –coordinate is
x = v cos α t [Therefore B is correct]
Equation of trajectory is
⇒

⇒ [C is correct]

Rearrenging

⇒ [∴ D is correct]

9)
Forcal length of convex lens

f=R
focal length of lens made of liquid

f'=
case-2

⇒ f 'eq = –2fL
= –2R [∵ fm → ∞]
⇒ R = 30
case-1

⇒ =

⇒ = (µ – 2) ⇒ µ =

⇒µ=
10)
Snell's Law

...(i)
Snell's Law

...(ii)
Squaring & adding

i = 45°

11)

12) Acceleration of two mass system is a = leftward.

F.B.D. of block A

N cos60° – F = ma =
Solving we get N = 3F = 30N

13) l0 + x = = 13
 x = 6m

mg × 5 + k (02 – 02) = mv2

100 + × 200 × 36 = × 2 ×v2

v2 = 3700

N= = = 1480 N

14)

2E cos 45° =

α=8

15)

The correct answer is 3.00

16) ....(1)

According question Pcon = 2PR

Divide (2) by (1)

V = 2(6 – V)
⇒ 3V = 12 ⇒ V = 4 Volt

PART-2 : CHEMISTRY
 17)

B.A. ⇒ N(SiH3)3 > P(SiH3)3

Trigonal planar Trigonal planar
B.A. ⇒ H2O < OCl2
Non-bonding e– bonding pair repulsion
B.A. ⇒ PH3 < PCl3
Drago’s molecule
B.A. ⇒ H2S < PH3

18)

19) Step-1: Given Data

A. Entropy of Br2(g) = 265 J/mol⋅K

B. Entropy of Br2(l) = 141 J/mol⋅K
C. Enthalpy of vaporization (ΔHvap) = 31 kJ/mol = 31000 J/mol

Step-2: Calculate Entropy change (ΔSvap)

ΔSvap = Sgas – Sliquid
ΔSvap = 265 – 141
ΔSvap = 124 J/mol

Step-3: Calculate Boiling point (Tb)

Tb = 250 K

Final Answer:
Option (1) : 250 K

20)

21)
(A)

(B)

(C)

(D)

22) [PdCl4]2– dsp2 → square planar

[Cr(NH3)3Cl3] → 2 geometrical isomers only (facial & meridional) no optical isomers.
[CoF6]3– → high spin as F– is weak field ligand.
[Fe(H2O)5(NO)]SO4 → Brown ring complex → sp3d2.

23) A(g) → 2B(g) + C(g)

t = 0 400
t = 20 400 – x 2x x
so 400 – x + 2x + x = 1000
x = 300 mm Hg

24) Explanation - Mixed statements from complex and extraction processes.

Concept - Different basic fundamentals are used to answer the questions.
Solution -
(A) Incorrect ∵ EAN = 54
(B) Due to synergic bonding the C-C bond length in the Zeise’s salt is more compared to C2F4.
Hence, it is incorrect.
(C) Incorrect because Fe2O3 is major impurity in red bauxite.
(D) Incorrect, because produced Al is heavier than electrolyte and sinks at the bottom.
Final Answer - 1,2,3,4

25) hybridisation
 [PtCl4]–2 ⇒ dsp2 ⇒ (1)
K4[Fe(CN)6] ⇒ d2sp3 ⇒ (2)
[Zn(NH3)4]+2 ⇒ sp3 ⇒ (0)
[Cr(OX)3]–3 ⇒ d2sp3 ⇒ (2)

26)

i = 1 – 0.6 = 0.4

27)

p ∝ n at constant v & T
C3H5 + 5O2 —→ 3CO2 + 4H2O
p 3p
CH4 + 2O2 —→ CO2 + 2H2O
320 – p 320 – p
Total CO2 pressure = 3p + 320 – p = 448
2p = 128
p = 64

mole fraction of C3H8 =

28) Explain Question : Asking about the isomers of C4H10O that oxidises into carbonyl
compounds by PCC.
Concept : Based on counting of isomers and oxidation of alcohols
Solution :
Degree of unsaturated (DV or DBE) of C4H10O is zero Possible isomers of C4H10O are 4 alcohols
and 3 ethers. Alcohols may oxidized by PCC but ethers do not

(i) (Ald.) (ii) (Ketone)

(iii) (Ald.) (iv) No reaction

Final answer : 3

29) Explain Question :

Question is asking about the total alkenes (including stereo isomers) formed in the given
 compound.
Concept :
This question is based on mechanism of E2 reaction.
Solution :
E2 is stereospecific anti elimination reaction. In E2 β-H and leaving group eliminate in one
step process.

Total 5 different alkenes are formed.

Final Answer :(5)

30)
715 + 500 – 2 × 800 + R.E. = – 390
|R.E| = 5 kJ/mole

31) x = 4; y = 21; z = 1.30

32) Number of effective ions of A+ =

Number of effective ions of B– =

Mass of one unit cell = 3 × 10 + 1 × 20 = 50 amu

Number of unit cell = = 24 × 1023

PART-3 : MATHEMATICS
 33) Given equation can be written as

34) f ′(x) = ax2 + 2(a + 2)x + (a + 1)

f ′′(x) = 2ax + 2(a + 2)x
f ′′(x) = 0

for negative point of inflection

⇒ a ∈ (–∞, –2) ∪ (0, ∞)

35)

Apply A.M. ≥ G.M.

≥ (1 + x1)(2 + x2)(3 + x3)(4 + x4)(5 + x5)

So maximum value of

(1 + x1)(2 + x2)(3 + x3)(4 + x4)(5 + x5) M = 65

36) For a non-trivial solution, we must have,

(Applying R2 → R2 – R1, R3 → R3 – R1)

⇒ (3b – 4a) (c – a) – (2c – 4a) (b – a) = 0

⇒ bc + ab – 2ac = 0 ⇒

37)

T1 = tan–14
T2 = tan–19 – tan–11
T3 = tan–116 – tan–14
Tn = tan–1(n+1)2 – tan–1(n–1)2

S=

38)

⇒ x = ±1
Maximum occur at x = –1 and minimum occur at x = 1

39) Assume 37.5o = θ , then

= |cos − 2θ + 1|
Similarly

∴
|cos–2θ + 1| + |sin2θ + 1|
∵ cos θ & sin θ > 0 for θ = 37.5o
= cos2θ + 1 + sin2θ + 1
=3

40) For for form

For

Now,
 and

41) g (x) = x2 + x – 2 = (x + 2)(x – 1)

Now and

both exist
hence f (x) = (x – 1)(x + 2)(k1x + k2)

∴ (k1x + k2) = 1 ⇒ k1 + k2 = 1 ....(1)

and (k1x + k2) = 4 ⇒ k2 – 2k1 = 4 ....(2)

On solving (1) and (2),we get
k1 = – 1 and k2 = 2
Hence cubic f (x) = (x – 1)(x + 2)(2 – x)
= – x3 + x2 + 4x – 4
∴ a = – 1, b = 1, c = 4, d = – 4

Hence = = 16

42)

so,

so fixed point is

so the slope of required line

43)
& ƒ(0+) = 0
∴ function is always continuous.

& ƒ'(0+) = k2 – 3k – 1
∵ function are differentiable at x = 0

⇒ k2 – 3k – 1 = 0
k1 + k2 = 3, k1k2 = –1
∴

44) α + β = .......(i)

&

⇒
⇒

⇒
Put this value in (i)
3α3 – 2α – 1 = 0
(3α2 + 3α + 1)(α – 1) = 0

⇒ α=1&β=

45) RHS = 1

∴
1 + x2 < 15
∴

46)

Ans.

47)
 Tangent at A
y – (3 – a2) = –2a(x – a)

48) x2 – 10|x| + 16 < 0 ⇒ (|x| – 8) (|x| – 2) < 0 A = {–8,–7,–6, –5,–4,–3,–2,2,3,4,5,6,7,8} ∴ n(A) =

14
Also, (|x – 2| – 3) (|x + 1| – 2) < 0
⇒ {(x – 2)2 – 32} {(x + 1)2 – 22} < 0
⇒ (x – 2 – 3) (x – 2 + 3) (x + 1 – 2) (x + 1 + 2) < 0
⇒ (x – 5) (x + 1) (x – 1) (x + 3) < 0

∴ B = {–3, –2, –1,1,2,3,4,5}

∴ n(B) = 8 & A ∩ B = {–3, –2, 2, 3, 4, 5} ∴ n(A ∩ B) = 6
A ∪ B = n(A) + n(B) – n(A ∩ B)
= 14 + 8 – 6
= 16