13-07-2025

1761CJA101029250039 JA

PART-1 : PHYSICS

SECTION-I

1) For the circuit shown in figure, which one of the following equation is correct :-

(A) E1 – i2x + E2 + i1y = 0

(B) E1 – i2x – i1z = 0
(C) E2 + i2y – i2z = 0
(D) –E2 + (i1 + i2)z + i1y = 0

2) Three resistances, each of 1 ohm, are joined in parallel. Three such combinations are put in
series, then the resultant resistance will be :-

(A) 9 ohm
(B) 3 ohm
(C) 1 ohm

(D)

3)

In the network resistors each of value R shown in the figure, calculate the equivalent resistance
between the junctions A and E:-
(A) 12 R
(B) 7 R/12
(C) 12R/7
(D) R/12

4) A ring is made of a wire having a resistance R0 = 15 Ω . Find the points A and B as shown in figure
at which a current carrying conductor should be connected so that the resistance R of the sub circuit

between these point is equal to Ω.

(A)

(B)

(C)

(D)

5) What is the equivalent resistance between points A & B ?

(A)

(B)
(C)

(D)

6) If a particle of mass m is moving in a horizontal circle of radius r with a centripetal force (–k / r2),
the total energy is

(A)

(B)

(C)

(D)

7) Equivalent resistance between pint x and y in the combination of resistance shown is

(A) 2 Ω
(B) 53 Ω
(C) 32 Ω
(D) 35 Ω

8) The resistance of a wire is 10Ω. Its length is increased by 10% by stretching. The new resistance
will now be :-

(A) 12Ω
(B) 1.2Ω
(C) 13Ω
(D) 11Ω

9) In the given circuit find the magnitude of current flowing through arm 'AB' :
(A) 4.5A
(B) 1.5 A
(C) 3.5A
(D) 4 A

10) Masses of three wires of copper are in the ratio of 1 : 3 : 5 & their lengths are in the ratio 5 : 3 :
1. The ratio of their electrical resistance are :-

(A) 1 : 3 : 5
(B) 5 : 3 : 1
(C) 1 : 15 : 125
(D) 125 : 15 : 1

11) The potential difference between points A and B of adjoining figure is :-

(A)

(B)

(C)

(D) 2V

12) A cord is used to lower vertically a block of mass M by a distance d with constant downward

acceleration . Work done by the cord on the block is :

(A)

(B)

(C)
(D) Mgd

13) n equal cell having e.m.f. E and internal resistance r, are connected in circuit of a resistance R.
Same current flows in circuit either they connected in series or parallel, if :

(A) R = nr

(B)
R=
(C) R = n2r
(D) R = r

14) A block of mass m is at rest with respect to a lift when placed on inclined plane of inclination θ
inside the lift. If lift move upward at constant velocity v then work done by friction force on block in t
time is :-

(A) Zero
(B) mgt2vcos2θ
(C) mgtvsin2θ

(D)
mgtvsin2θ

15) A particle is suspended from a string of length R. It is given a velocity at the bottom.
Find velocity at B :-

(A)
(B)
(C)
(D)

16) If a copper wire is stretched to make its radius decrease by 0.1%, then the percentage increase
in resistance is approximately :-

(A) 0.1%
(B) 0.2%
(C) 0.4%
(D) 0.8%

17) The potential difference between points A and B is

(A) 0 V
(B) 10 V
(C) 4 V
(D) 5 V

18) The equivalent resistance between A and H of cube if resistance of each side is 1 kΩ

(A)

(B)

(C)

(D)

19) The resistance between the terminal points A and B of the given infinitely long circuit will be :

(A)
(B)
(C)
(D)

20) For the network of resistance shown in the figure the equivalent resistance of the network
between the points A and B is 18 Ω. The value of unknown resistance R is:

(A) 8Ω
(B) 10Ω
(C) 16Ω
(D) 24Ω

SECTION-II

1) A circular road of radius 1000 m has banking angle 45º. The maximum safe speed of a car having
a mass 2000 kg will be, if the coefficient of friction between tyre and road is 0.5 : (in m/s)

2) A particle is moving on a circular path of radius m in such a way that magnitude of its
2
velocity varies with time as v = 2t + t, where v is velocity in m/s and t is time in s. The acceleration
of the particle at t = 2s is (in m/s2)

3) A pump motor is used to deliver water at a certain rate from a given pipe. To obtain twice as
much water from the same pipe, in the same time, the power of the motor has to be increased .........
times.

4) The total current supplied to the circuit as shown in figure by the 5V battery is __________A

5) The distance covered by a body to come to rest when it is moving with a speed of 4 m/s is s when
a retarding force F is applied. If the kinetic energy is doubled, the distance covered by it to come to
rest for the same retarding force F is n times of s, find n –

PART-2 : CHEMISTRY

SECTION-I

1) Identify most stable carbanion is :

(A)

(B)
(C)

(D)

2) In which of the following most stable carbocation :–

(A)

(B)

(C)

(D)

3) Which of the following molecule is chiral.

(A)

(B)
(C)

(D)

4) Which of following compound has "cis" as well as "Z' stereochemical assignment :

(A)

(B)

(C)

(D)

5) What is the correct IUPAC name of the following :

(A) 4-Cyano hex-2-ene

(B) Hex-4-ene-3-nitrile
(C) 2-Ethyl pent-3-ene nitrile
(D) 2-(prop-1-enyl) butane nitrile

6) The pairs of species of oxygen and their magnetic behaviours are noted below. Which of the
following represents the correct description.

+
(A) O2 , O2 → both paramagnetic
2–
(B) O2 , O2 → both paramagnetic
– 2–
(C) O2 , O2 → both paramagnetic
+ 2–
(D) O2 , O2 → both paramagnetic

7) Correct stability order is : -

(A) Pb+2 < Sn+2
(B) Pb+4 < Pb+2
(C) Sn+4 < Sn+2
(D) Sn+4 < Pb+4

8) Which of the following order is correct for covalent character -

(A) NaCl < CuCl

(B) SnCl2 < SnCl4
(C) KCl < NaCl
(D) All of these

9) Assertion : HC≡C– is more stable than H2C = CH–

Reason : HC≡C– has more s-character than H2C = CH–.

(A) If both assertion and reason are true and the reason is correct explanation of the assertion.
(B) If both assertion and reason are true but reason is not the correct explanations of assertion.
(C) If assertion is true, but the reason is false.
(D) If assertion is false but the reason is true.

10) The least acidic compound is

(A)

(B)

(C)

(D)

11) Statement-I : Excluded volume or co-volume equals to (V–nb) for n moles of a sample of a Van
der waals gas in a vessel of volume V litres..
Because
Statement-II : Co-volume depends on the effective size of gas molecules.

(A) Statement-I is true, Statement-II is true ; Statement-II is correct explanation for Statement-I.
Statement-I is true, Statement-II is true ; Statement-II is NOT a correct explanation for
(B)
statement-I
(C) Statement-I is true, Statement-II is false
(D) Statement-I is false, Statement-II is true
12) Osmotic pressure of blood is 7.38 atm at 27°C. The number of moles of glucose that can be used
per litre of an intravenous injection that have same osmotic pressure of blood is : [R = 0.082 L-
atm/K-mole]

(A) 0.15
(B) 0.3
(C) 0.1
(D) 0.45

13) The shortest distance between an octahedral and tetrahedral void in a FCC metallic lattice in
terms of radius of FCC packed atom (R) would be :

(A)

(B)

(C)

(D)

14) In a hypothetical solid, ‘C’ atoms form CCP lattice. ‘A’ atoms occupy all tetrahedral voids and ‘B’
atoms occupy all octahedral voids, without disturbing the crystal. If a unit cell of the crystal is cut by
a plane shown in the figure, then the cross section of this plane looks like

(A)
(B)

(C)

(D)

15) For which of the following aqueous solutions freezing point is maximum ?

(A) 0.1 M urea

(B) 0.1M NaCl
(C) 0.05 M AlCl3
(D) 0.15 M glucose

16)

Out of the given high diluted solutions at given temperature (I) 0.3 molal KCl (II) 0.2 molal AlCl3 (III)
0.1 molal Na2SO4. The only Incorrect statement is :

(A) Solution (II) has minimum vapour pressure.

(B) Solution (III) has maximum freezing point.
(C) Solution (I) has maximum osmotic pressure.
(D) Solution (II) has maximum boiling point.

17)

List-II
List-I
(Species/Molecules
(Properties)
)
(P) 2pπ–2pπ back bond is present in (1) BeH2(s)
(Q) Overall molecule is non planar (2) N(SiH3)3
(R) 3c–2e bond (3) Al2Cl6
(S) All atoms are sp3 hybridised (4) : CF2
(A) P → 1 ; Q → 2 ; R → 1 ; S → 4
(B) P → 4 ; Q → 3 ; R → 2 ; S → 1
(C) P → 4 ; Q → 2 ; R → 1 ; S → 3
(D) P → 1 ; Q → 4 ; R → 1 ; S → 3

18) Mn2(CO)10 is an organometallic compound due to the presence of :

(A) Mn – Mn bond
(B) Mn – C bond
(C) Mn – O bond
(D) C – O bond

19) For which of the following types of dn configuration, the number of unpaired electrons in
octahedral complexes remains same irrespective of the ligand field strength.

(A) d3
(B) d4
(C) d5
(D) d6

20) Which of the following molecule is chiral in nature?

(A) 2-Bromobutane
(B) 1-Bromobutane
(C) 2-Bromopropane
(D) 2-Bromopropan-2-ol

SECTION-II

1) How many cyclic structural isomers are possible for C5H10.

2) How many species is/are - M/ - R groups

(i) –OH (ii) –NO2 (iii) –CN
(iv) –COOH (v) –CH3 (vi) –CH2–CH3

(vii) (viii) –CH2 – CCl3

3) Certain substance A, tetramerises in water to the extent of 80%. Solution of 2.5 g of A in 100 g of
water lowers the freezing point by 0.3°C. The molar mass of A (in gm/mol) is :-
[Given : Kf (H2O) = 1.86 K-kg mol–1]

4) 0.32 gm of is diffused through a pin hole of rigid vessel in 20 sec. If all the SO2(g) at same
pressure and temperature that will be diffused through same pin hole in 40 sec in separate
experiment is collected in a closed vessel of volume 2.463 L over liquid water at 27°C then calculate
total pressure in container (in torr) [Given : Vapour pressure of water at 27°C is 28 mm of Hg.
Consider SO2(g) is water insoluble and volume of water is negligible w.r.t volume of vessel] (R =
0.0821 lit atm mol–1K–1) [Atomic mass : S = 32]

5)

The difference between spin only magnetic moment values of [Co(H2O)6]Cl2 and [Cr(H2O)6]Cl3 is ____.

PART-3 : MATHEMATICS

SECTION-I

1) Let (sin–1x)2 +(sin–1y)2 + (sin–1z)2 = , then x100 + y100 + z100 is-

(A) 1
(B) 3
(C) 3.2100
(D) 12

2) and equation ax2 + bx + c = d has equal roots then d is-

(A)

(B)

(C) 1
(D) –1

3) is equal to-

(A) e

(B)

(C)

(D)

4) Following questions contains statements given in two columns, which have to be matched. The
statements in List-I are labelled as A, B, C and D while the statements in List-II are labelled as I, II,
III and IV. Any given statement in List-I can have correct matching with one statement in List-II.
 List-I List-II

(A) (I)

(B) (II)

(C) (III)

(D) (IV)

(A) (A) – II, (B) – IV, (C) – II, (D) – III

(B) (A) – IV, (B) – II, (C) – IV, (D) – II
(C) (A) – I, (B) – III, (C) – I, (D) – III
(D) (A) – III, (B) – IV, (C) – I, (D) – II

5) The integer n for which is a finite non-zero number is :

(A) 3
(B) 4
(C) 5
(D) 6

6) The value of tan is equal to

(A)

(B) – 2
(C) 2

(D)

7) If α, β are roots of equation 2x2 + 7x + = 0, then value of cot–1α + cot–1β is equal to -

(A) π – tan–1(14)
(B) 2π – tan–1(7)
(C) π + (tan–12)
(D) π + tan–1(14)

8) Range of is
(A)

(B)

(C)

(D)

9) If ; x > 1, then f (2025) is equal to :

(A)

(B) π

(C)

(D) 4 tan–1 (2025)

10)

If , then equals

(A) 12a
(B) 8a
(C) 6a
(D) 4a

11) Coefficient of x2 in (1 + x)5(1 + 2x)4, is

(A) 74
(B) 88
(C) 96
(D) 108

12) If the coefficients of x7 and x8 in are equal, then n is

(A) 56
(B) 55
(C) 45
(D) 15

13)

If , then k is equal to
(A) 102
(B) 99
(C) 105
(D) 104

14) Number of rational terms in the binomial expansion of is-

(A) 7
(B) 8
(C) 9
(D) 10

15)

In the expansion of then coefficient of x–7 and x–8 are equal then n is :

2
(A) one of the root of equation log2(x – 109) = 2log2(54)
(B) A prime number
(C) Greater than 80
(D) An even number

16) If then value of is :-

(A) 4
(B) 8
(C) 5
(D) 12

17) If f(x) = logx (ℓn x), then f′(x) at x = e is equal to :

(A)

(B) e
(C) 1
(D) Zero

18) For x∈R, is equal to :-

(A) e
(B) e–1
(C) e–5
(D) e5
19)

If

is continuous in the interval [–1, 1] then p equals

(A) – 1
(B) 1
(C) 1/2
(D) –1/2

20) If = 2, then a and b are:

(A) 1, 3
(B) 1, –1
(C) 2, –3
(D) 2, 3

SECTION-II

1) The value of cosec2 + sec2 is :

2) If = , (where p and q are coprime numbers), then |p – q| is

3) Let [t] denote the greatest integer ≤ t. If for some λ ∈ R – {0, 1}, , then
100L is equal to :

4) If and , then the value of , is

5) If f(x) is continuous at x = where f(x) = , then the value of (4a + 3b) is

 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A C B A C A C A D D C C D C A C A A C C

SECTION-II

Q. 21 22 23 24 25
A. 172 10 8 2 2

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C A D C C A B D A D D B C C A C C B A A

SECTION-II

Q. 46 47 48 49 50
A. 5 4 62 180 0

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. B A C A A C D D B C A B D D A B A C D B

SECTION-II

Q. 71 72 73 74 75
A. 4 7 200 6 14
 SOLUTIONS

PART-1 : PHYSICS

1) For upper loop. by KVL

E1 + E2 = i2x – i1y
⇒ E1 – i2x + E2 + i1y = 0

2) ⇒

Now such three resistance are joined in series, hence total

3) Question Explanation :
We have to calculate equivalent resistance between point A and E of given network.

Concept :
This question is based on Combination of Resistor.

Solution :

Current in various branches

AE = 1º – 2i1
AD, AB, EF, HF = I1
OH, BF = I2
DC = FG = (I1 – I2)
CG = 2(I1 – I2)
V = IReq
For branch 4E
V = (I – 2I1)R ........ (1)
For branch 4BFE
V = (2I1 + I2)R ........ (2)
For branch ADCOFE
V = (6I1 – 4I2)R ........ (3)
from equation (1), (2) and (3)

V=
 V=

V=

Req =

Hence,
Option (2) is correct

4)

5)

Req = 0.5 +

6) mv2 = ∴ K.E. = mv2 =

P.E. =

∴ Total energy =

7)

8) Since ⇒ If length is increased by 10%, resistance is increases by almost 20%

Hence new resistance R' = 10 + 20% of 10

9)

Current in branch AB 4 A

10) R = =

R1 : R2: R3 = : :

= : : = : :
= 25 × 5 : 15 : 1
= 125 : 15 : 1

11) The given circuit can be redrawn as follows

For identical resistances, potential difference distributes equally among all. Hence potential

difference across each resistance is and potential difference between A and B is

12) When the block moves vertically downward with acceleration then tension in the cord

T=M = Mg
Work done by the cord = FS cos θ
Td (cos 180°)

= × d = – 3Mg .

13) Current when cells are connected in series

is =

in parallel ip =
According to euesion is = ip

r + nR = nr + R (b – 1)
R = r (n – 1) ⇒ R = r

14)
Wƒ = ƒ.[Link](90 – θ)
= mgsinθ.vt cos(90 – θ)
Wƒ = mgsin2θvt

15)

16)

= – 4(– 0.1%)
= 0.4 %

17) VA – 2 – 2 + 5 – 1 = VB
⇒ VA = VB ⇒ VA = VB ⇒ ΔVAB = 0
18)
By KVL along path ABDHA
(including battery)

⇒ ⇒ =

19) Let equivalent resistance between A and B be R1 then equivalent resistance between C and
D will also be R.

R' = or R2 – 2R – 2 = 0

∴ R=

20) Use series and parallel combination.

21)

22)

a = 10 m/s2
It is the centripetal acceleration of a moving ball.

23) P = Fv
 F∝ v2

24)

Current supplied by 5V battery

25) S ∝ KE
If KE is doubled, S is also doubled.

PART-2 : CHEMISTRY

26)

Stability of carbanion ∝ Electron withdrawing groups (–M / –H / –I)

27)

28)

29)

Correct answer is :

30)

31)

Correct answer is : O2+ , O2 → both paramagnetic

32)

Pb+4 < Pb+2 Inert pair effect.

Down the group {13, 14, 15} e– present is s-orbital don't participate in reaction, due to high
Zeff {Relativistic effect}

33)

Answer is : All of these

34)

Answer is : If both assertion and reason are true and the reason is correct explanation of the
assertion.

35)
Correct answer is :

36)

Correct answer is : Statement-I is false, Statement-II is true

37) π = CRT ⇒ 7.38 = [C] × 0.082 × 300 ⇒ [C] = 0.3

38) Octahedral void present at the centre of cube and tetrahedral void is present at (1/4)th of
the distance along each body diagonal.

∴ = 2 × distance between octahedral and tetrahedral void and a =

39) None of the tetrahedral as well as octahedral voids will be in contact with other
tetrahedral and octahedral voids, respectively.

40) Urea NaCl AlCl3 glucose

[C] 0.1M 0.1M 0.05 M 0.15 M
i = assuming 100% ionisation
i 1 2 4 1
[C]net = i × C
Urea NaCl AlCl3 glucose
[C]net 0.1 0.2 0.2 0.15
ΔTf ∝ [C]net
([C]net = minimum, ΔTf = minimum, freezing point = Maximum)

41)

Correct answer is : Solution (I) has maximum osmotic pressure.

42)

Correct answer is : P → 4 ; Q → 2 ; R → 1 ; S → 3

43) Compounds having at least one bond between carbon and metal are known as
organometallic compounds.

44) In octahedral complex, If electronic configuration is d1, d2, d3 or d8, d9, d10 then number of
unpaired e– same and it is irrespective of nature of ligand.
45)
Having one chiral carbon

46) , , &

47) ii, iii, iv, vii

48)

49)

x = 0.02
PV = nRT

Total pressure = 152 + 28

= 180 torr

50)
0
[Co(H2O)6] Cl2 ⇒ Co2+ ⇒ [Ar] 3d7 4s
H2O ⇒ WFL

unpaired electron = 3
[Cr(H2O)6]Cl3 ⇒ Cr3+ = [Ar] 3d3
 unpaired electron = 3
As number of unpaired electron in both the complexces is same, spin magnetic in both
complex will be same.

PART-3 : MATHEMATICS

51)

52)

C = –1, b = –1,

D=0 ⇒ 1 – 2(d + 1) = 0

53)

54) (A) =

(B)

(C)
(D)

55) l = (l ≠ 0), n ∈ I

=
if n = 2 then l = 0
∴n=3

then l = =

56)

= tan–1 (∞) – tan–1

= tan–12

57) 2x2 + 7x + =0α+β=– & αβ = (αβ < 1)

cot–1 α + cot–1β = +

= π– (tan–1α + tan–1β) = π–

= π– = π+ tan–1 (14)

58)
59)
for x > 1

f(x) = π.

60)

S = 12a – S
2S = 12a
S = 6a

61) 5C2 × 1 + 5C1 × 4C1 × 2 + 4C2 × 22

= 10 + 40 + 24 ⇒ 74

62) nC7 . 2n – 7 . = nC8 2n – 8 .

63) =

= 20 × 29 + 3 × 210 = 13 × 210

64)
G.T ⇒ 711Cr
 from rational term
r = 0,11,22,33,44.....
r = 4,11,18,25.......
common terms ⇒ 11,88,.......
11 + (n – 1)77 ≤ 711
n – 1 ≤ 9.09
n ≤ 10.09
⇒ 10 terms

65)

Tr+1 = nCr (2)n–r

x–r = x–7 ⇒ r = 7 or x–r = x–8 ⇒ r = 8

n
C7(2)n–7 = nC8 (2)n–8
⇒ n = 55

66) exists and finite

so must be form
so ƒ(5) = 8

67) f(x) = logx (ℓnx)

68) For x∈R,

69)

LHL = RHL

P=–

70)
⇒ 1 – a = 0 and a – b = 2
⇒ a = 1 and b = –1

71)

72)

73) LHL :

RHL :
For existence of limit
LHL = RHL

74) If ;

then the value

RHL = ƒ(>2)
2
=2 +2=6
LHL = ƒ(>2)
2
=2 +2=6

So =6

75) ... (1)

 ... (2)

... (3)

∵ f(x) is continuous at x =

So