S K SAHU PGT CHEMISTRY
KENDRIYA VIDYALAYA NO-3 BHUBANESWAR
(SOLUTIONS)
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[Link] based on solubility of a solid in a liquid, solubility of a gas in a
liquid, Henry law Date 10/04/2025
1. State Henry law with its mathematical expressions. Explain the significance of Henry’s law constant.
At the same temperature, hydrogen is more soluble in water than helium .Which of them will have
larger value of KH and why?
2 Mention some of important applications Henry law.
3. Why do gases always tend to be less soluble in liquids as the temperature is raised?
4. The partial pressure of ethane over a solution containing 6.56 x 10-3 g of ethane is 1 bar. If the
solution contains 5.00 x 10-2 g of ethane, then what shall be the partial pressure of the gas?
5. If N2 gas is bubbled through water at 298 K, how many millimoles of N2 gas would dissolve in 1 litre
of water .Assume that N2 exerts a partial pressure of 0.987 bar .Given that Henry’s law constant for N2
at 293K is 76.48 bar.
6. Aquatic species are more comfortable in cold waters rather than in warm waters. Why
7. What is the effect of rise in temperature on solubility of a gas?
II. Question based on vapour pressure of solutions, Raoults law, Ideal solutions and
Non Ideal solutions, Azeotropes Date 11/04/2025
1. State Raoults law for a solution of volatile liquids .Give its mathematical relationship.
2. Why is vapour pressure of a solution of glucose in water lower than that of Water?
. 3The vapour pressure of pure liquids A and B are 450 and 700 mm Hg respectively at 350 K .Find out
the composition of the liquid mixture if total vapour pressure is 600 mm Hg .Also find the
composition of the vapour phase.
4. What is an ideal solution? What type of solutions are likely to behave as ideal solutions? Draw the
plot of vapour pressure and mole fraction of an ideal solution at constant temperature.
5. Explain along with diagrams the conditions for the Non ideal solutions exhibiting Positive deviations.
Write some examples of Non ideal solutions exhibiting Positive deviations.
.6. What role does the molecular interaction play in solution of alcohol and water?
7. Define and derive Raoult's law for non volatile solute.
8. When X and Y are mixed the solution becomes warmer and Y and Z are mixed the solution becomes
cooler? Which of these solutions will exhibit positive deviation and solutions will exhibit negative
deviation?
9. What type of non idealities are exhibited by cyclohexane –ethanol and acetone-chloroform mixtures?
Give reasons for your answer.
10. What are Azeotropes? Give one example each of minimum boiling and maximum boiling
azeotropes.
11. 10cc of a liquid A is mixed with 10 cc of liquid [Link] volume of resulting solution was found to be
[Link] do you conclude.
1
[Link] based on colligative property, Relative Lowering of vapour
pressure Date 12/04/2025
1. Define colligative properties. Show that Relative Lowering of vapour pressure is a colligative
property.
2. Calculate the mass of a nonvolatile solute (molecular mass = 40) which should be dissolved in 114g
octane to reduce its vapour pressure to 80%.
3. An aqueous solution of 2% nonvolatile solute exerts a pressure of 1.004 bar at the boiling point of the
solvent .what is the molecular mass of the solute? (Vapour pressure of pure water =1atm=1.013 bar)
[Link] based on Elevation in Boiling point Date 12/04/2025
1. Show that Elevation of boiling point is a colligative property
2. How will you determine the molecular mass of a non volatile substance by study of Elevation of
boiling point of a solution?
3. What is molal elevation constant? What are its units? How is it related to enthalpy of vaporization of
solvent?
4. Why common salt is added to water used for boiling eggs to get hard boiled eggs?
5. 10 g of sucrose and 10 g of glucose are dissolved in same volume of water to prepare two solutions X
and Y .will they have same or different boiling points?
6. The boiling point of benzene is [Link] 1.80 g of a non volatile solute was dissolved in 90 g of
benzene, the boiling point is raised to [Link] the molar mass of the solute? Kb for benzene
is 2.53 KKgmol-1.
8. Boiling point of water at 750 mHg is [Link] much sucrose is to added to 500 g water such that
it boils at 100o C.
9. Out of 1M solution of Sugar and 1 M solution of Urea, which will have greater boiling point? Why.
[Link] based on Depression of Freezing point Date 13/04/2025
1. Show that depression of freezing point is a colligative property.
2. How will you determine the molecular mass of a non volatile substance by study of depression of
freezing point of a solution
3. What is molal depression constant? What are its units? How is it related to enthalpy of fusion of
solvent?
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5. What are antifreeze solutions? Which substance is commonly used as antifreeze?
6. Two elements A & B form compounds having molecular formula AB2 & AB4. When dissolved in
20g of C6H6, 1g AB2 lowers the freezing point by 2.3 & 1.0g AB4 lowers it by [Link] molar
depression constant for benzene is 5.1Kg mol-1. Calculate atomic mass A & B.
7. A solution containing 2.56 gm of sulphur in 100 g of carbon disulphide gave a freezing point
lowering of 0.383 K .Calculate the molecular formulae of Sulphur [ kf of carbon disulphide = 3.83 K
kg/mol Atomic mass of S =32 amu]
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8 1.00 g of non-electrolyte solute is dissolved in 50 g of benzene lowered the freezing point of
benzene by [Link] freezing point depression constant of benzene is 5.12KKgmol-1 .Find the
molar mass of the solute.
9A 5% solution (by mass) of cane sugar in water has freezing point of 271 K. calculate the freezing
point of 5% glucose in water if freezing point of water is 273.15 K.11.
2
[Link] based on Osmosis and Osmotic pressure Date 14/04/2025
1. What is osmotic pressure? Show that it is a colligative property.
2. (a)Differentiate between osmosis and diffusion.(b)Define (i)Semi permeable membrane (ii)Edema
3. What is reverse osmosis? Give its application.
4. What are isotonic solution, Hypertonic and Hypotonic solution.
5.CaCO3 shell is removed from the two eggs by treatment with dil HCl .One of the eggs is then ,placed in
pure while the other is saturated solution of NaCl .What will be the observed and why?
7. What care is generally taken during intravenous injection and why?
8. when When fruits and vegetables that have dried are placed in water, they slowly swell. Explain why?
What would be the effect of temperature on this process?
9. How will you determine the molecular mass of a substance by study of osmotic pressure? Why this
method preferred for measuring molecular masses of macromolecules.
10.200 cm3 of an aqueous solution of a protein contains 1.26 g of the protein .The osmotic pressure of such a
solution at 300K is found to be [Link] the molar mass of the protein .
[Link] will happen if RBC are placed in (i)0.5% NaCl Solution (ii)1% NaCl Solution?
12. 100 mg of a protein is dissolved in enough water to make 10ml of a solution. If this solution has an
osomotic pressure of 13.3 mm Hg at 250C,what is the molar mass of protein?(R=0.0821Latmmol-1K-1
and 760mmHg=1atm)
VII. Question based on abnormal molar mass and Van’t Hoff’s factor
Date 15/04/2025
1. What is Van’t Hoff’s factor? What is value of Van’t Hoff’s factor when the solute undergoes (a)
association (b) dissociation?
2. Write the modified equations of colligative properties when Van’t Hoff’s factor is introduced.
3. How is Van’t Hoff’s factor related to degree of dissociation & degree of [Link]
Expressions?
4. Determine the amount of CaCl2 (i = 2.47) dissolved in 2.5 litre of water such that its osmotic
pressure is 0.75 atm at 27° C.
5. Determine the osmotic pressure of a solution prepared by dissolving 25 mg of K2SO4 in 2 litre of
water at 25° C, assuming that it is completely dissociated.
6. 2g of Benzoic acid dissolved in 25 g of benzene shows a depression in freezing point equal to 1.62
K. Kf for benzene is 4.9 K Kg mol-1. What is the percentage association of acid if it forms dimer.