Refrigenation
Re fn igenation
Ain Conditioning
Cryogenics —> Liy Na
we ee f retnigenamts
" Ha
Ain as nefrijenant (used in ainenaft)
Ly Cold Setecton (Softwane)
TR on TOR
amt of
1T0R is defined as Pre, refrigenal® elfed produced bY
f ice fnemed
tre anifoner meliy ef) 1 Amenican donn ©
at o'c @ in 24 houns
JTR= 2000x144 iM 2K Ans l4on= 2000 pounds
Lodent heat _ eer
[TR 2000% 144 elie as ce
60 % G5 24
}erus 0 252 Kea)
ee ae
6
200 BTU/min
50:4 Keal/min
© 50 Keat /min[TR = SOXA4 NEF KAlmin
(eS? Sts daw.
= RE
cop = Ty
Relave cof
Relative COP =
Ideal CoP
beat Engine Rofniganat on
-, pane >
> a &
E> We oF wie
a a
TH Te
Sink
T>Ta T. < Ta
= RE
1 We Ca = “We
a2 = _&
Qi a) Q2- %
= "@ oa
et cae
Te
x
Actual CoP
| Keat = 418% KS
Heat > Pump
LJ
&
Da w,
a
7
T= Ta
8
CO, = Wap
- _&
2-4,
aan
" Ta=TCOP, = 1+ CoP,
Revensed cannot Refniyenation oycleEnengy jaansden during pnocess Q-3
Gos = ftas
2-3
= Ty (S37 $2)
Refrigenasing effect,
an Bn Stes
Spe CS sa)
From te finst law of thenmo dynamics fon a oyctic pastes,
w= ter —ofq,
w: $ &
= Vos + ee
TH USs-S2) @ + Te Cr Sa)
"
— Ta CSa- Sa) a + 1 (Sr - $4)
w
(Ta - Te) (S)- Sa)
RE
\Wret 1
a Te (Si - Sd
CoP =
(Ta - Te) (St Se)fon AlN nr enation — (Revense Brayton ayele rn Joule cycle on
Bel colemen cycle)
ne 7" ay
1-2: Rev. adiabatic
Rev Fs obanic
225) |
3-A% Rev odiadatre
4-12 Rev isebanic
Process 2
Wir2 = me (Te 1)
and Si = Sz
=. [B)* 5
Tw bp, oe
Pnocess 2-3
Yas 2 -MG (R- Ta)
= Mcp (Te- T3)
3, Poa Pe
Sp- S32 cp la (=)Poocess 3-4:
W3, = MG (T3-T) 4
and Ss= Se
Bb. (fe ¥
The = Pe
Poocess 4-1:
Ver = mep (T — Ta)
ond Py = Pe
S,-54= Gln (2)
App wing finst law of Hreamodynamics fo the entine oycle,
bays ta ~ deg =~ Woe
+
CoP of the cycle,
eRe en
COPS wet Tea taal
malt - TH)
-mg [(F-W~ (%-78)]Tat
@ ORE Taye Cheek)
1% (4 :
>a capl S ee
gee B&B (B)- (4
Now,
st
o
4: tB)
me, Py .
- (2)*¥
B (RIF.
Ts
7
=-
a
GB. ae,
% GE-1)
ee
<) CoP= En) TEEN
mai
CO eo
oe,
one 7 (Fea
: >
s CPs —® dense ain is used as nefnigenant in
emp al He end of heat absoabtion
O°C amd
Ball ecoloman eycle- Jf the
and heat Reject ang
30°
Respectively, Pressung jn Pre Condensen 1S
A ban and pness® ratio is 4+, delenmine the fempr af alc
Sdote points and vol” few nate in He intel of dre compnessen
and at tre axibof dunbine fon 1 TR cooling copacity -
Ass: ne
3
fw
2
7 ©
4 ty
Te
Given, T= 0° = 243K
Tl = 30°C = 303K
P= Ps = 4 ban
Po
Rie =
As Pi = |ban
Yay = 1 TR
= 3:5 kwProcess |-22
x) acs
Pr Tr
“
> Te = 273«K 4%
iu
> Ta? 405. 676 R Y
Pnocess 3-4:
(2). =
Pa, 7 eo
303 4
=3, =F qua
S-n Tapio R032 1M
Now,
Yan = hep (THT)
D>3.5 = Mx 1-.004x (273- 203.9)
> m= 9:05 ieee
At exit of tunbine,
QAM = MRT
D> 1K109X Y= O-O5x 267 x 203.9
(m2) ke/, (Shag
0.029 m/s4+ inlet of compnesson,
Pi = mRT
D Lew rt 0.0Sx WRX ZB
D> We 0. 0098 mis
@) A dense ain ne frigenation machine openaring om Pell coleman
Cycle openates bly 3.4 ban and IH ban = “The dempe of
ain after coolen is 15°C and aftan tre nefaigenaten #s
bc: Sf me nefnigenat™ capacity iS 6 TR, Caleulate
ti demps atten compnesrion and expansion
Gi) Aro Gncalatr pen minute
Gi’) Wonk f con on compnesson anh enpanden
Gv) Theontkcal COP
(v) Rate Bt waten cinculation rept in Hee Ceslen tw Ky dmin
if wre nise in fempe 55 limited fo 30°C:3)
tates
Given, f,= Pe = 3.4 ban
fa = Pg = 1% ban
T3 = IS’C = 288K
Thy =) 69 = 22 9%k
V1 = 6TR= Qkw
Process I-2:
(¥- &
> The 441. 88K
PnocesS 3-4:
GE > te). ae
:Gi) Vi =
= me (1 - )
D> AL wx 1005 x (279-181: 84)
D Me 0-215 Kyis
9 Ky Peni
12 gimin 2
Ga Compnesson wonk ,
We = wi (m- 7)
0.218 1008 (441. 88 279)
Wee
35.19 Rwy,
“Tunbine wonk,
Wr =f Gp ( T3- Td
| = 0-21Sx 1:005x (288- 161. 84)
Wr = 22.94 kw,
(iv) cop ,
iv! ops
np ~1
t
" sH-y
COP=w
™s Ce (T=) = Ww Ch * 30
VR 1005 (44). 5k 265) = Ww X 4.187 x29
> mw = 15. 91 by non
Ain Refaigenat system
Heat Jenznaton
1. Due te equipment + human
2. Radiation
3. due te very high speed —> skin friction high tempenatune
os (Bye
7 Pe
Advantages
1 Ara Fs used as working fuss: Ain is cheapy nom flammable ,
mon toxic:
2- Outside (old ain Can dinechy uced fon cooling, etiminaking Hre
used use for low Jemp™ heat exchangen , educing wei gh:
B. Extna compnegsin is not neqd + aincnaft engine alneadyy uses
high pm funbo Compnesson, hence sepenate Ccompnesson is
not neqd: which reduces Wi: of the nefnigenat” unit -
4. Simplen designTees of ain nefriyenation ucla
Ir Simple ain nefnigenation oycle
2 Boot stap ” o
3. Reduced ambient u “”
A. Reg enenahve
” ”
1} Simple ain ne faigenat™ oy cle
MC> Main compassson
CO comdus{® chamben
Ram ain
eee
> SS
Ain
nm.
Tw awe
Ram ¢ fect
.
:
3
’BP, Clompnesin £%)
adeat ROM PA
Actual Ram PR
Pr (atm pnessn)
s Te cabin Jampr
RE = ma Cp (Te - Tr)
2. Bool stnap ain nef enation system.
(used fon tnanspont aincnaft)
Fan is eliminated
HE
3 4
a ee
\ a
Cobth3. Renenenaive ain nefnigenation system
Cused in supen sonic jeis)
ond Nockels
|
4. Reduced Ambient ain nefaigenation system
(used in high speed ain craft)@) Tre conepit of a jet plane ts fo 62 cooled by & simple ain
refrigeration system: The data available ane:
Cockpit eiels load = 20TR
speed of plane = 1000 Km/hn
Ambient ain pnesst = O- 35 ban
Aenbienk arn tempn = = ISS
Ram 2ficieny = qo.
Pressuae nate in main compnesson = 3
Preseuine onoplin, Hie wanOyeeam
Aseninopic efficiency of main compnersen and funtine = SO.
costing
Temp: of ain entonivg the tunbine = 20°C
Presse of air leaving the cooling Hunbines | 06 ban
Pressn in the cocnpit = J ban
Sf cockpi} *5 te be Proinkotars” ot 25°C, find() Stagnation temp and press” ef ain entening He mein
Compnesson -
(b) Mass few nate of ain to Cock pit
Ce) Powen nega fo dive He nefnigenation system
(a) cop of the system:
Ty = 30°C
Ly = 807.
Fe = |-06 ban
Tye-iste Neen = 707 L
Ve yok ml/h [¢] P= fban
P,= 0-35 ban
RE = 20TR
= FoOKW
Te = 25°C
= 298KAdeat nan pn (Pe)
Actual Rom fo (p, 1)
Pr
7 -
Bee it = mM Loe cist28
= 258K
Mach no,
ie ee ~ Q44- Fs
= Seam VAR 2B FX CIT RAD
M= O 863
BL yy ok 0.863"
Is +292
t
> R= 27643 K = Ta
Now,
‘Leon *(8) fr. me
nN
Jey
fee (2e8 oo
iE Olscpeeal 2 sa
d R= 0.56F% bon
igs =e a
ii: sateen
m— P
PB’ - 0.35
0-56} - 0735
> Pr = 0.545 ban
o.
va
D Tee 26-43% oy?Now,
iy Biszalleg
eae emer
ates 5 7
SB [Link]) ae sseesies
Tp! — 29-6
> Ty! = 433,085 K
Now,
R= R-o.
P= 1-53 ban
ped ie = 20icH i= S03
(e)* | ot
Ps Ts
> = re 388
08 ~ Ts
Now qos SOS 5 08s 303- Ts’
T- Ts 303- 272.9%Now,
RE= mep (Te - B')
> Foa= mx 1008 (298- 278-67)
D> w= 3.64 kgs
a
Powen Mey to nun the system,
Powen = mep (34 _ tr)
= 3. 00S (433. 025 - 296-43)
P= 499.9 KY
cop,
coi BEE
iwi
= 2
= Gantwr = mo (T- Ts)
% 3. b4x |:00Sx (303 - 278-87)
"
=> 38. 2zF Kw
\
'
“Tuesday 2209 PM,
th
~ class dest
a) A negene native ain nefaigenation system for an Genoplane is
designed do ane a load of BOTR~ The temp and press? condition
of tre atmosprante are 5°C and O85 Kyf/ume- The press? of
oe ee ee fiem? due to
ont
Ramming actor: she pressure ef oin leaving tke main compnesson
is 4.8 Kyflomnt 60% of the fotal heat ef ain leaving the
main Compnesson is namoved 1 He HE “land then if iS passed
Hhaown the cooling funbina- The temp™ of Ramming ain
whics is used fon cooling puapose in the HE is neduced by
50°C by Micivg Me ain coming ow from the cooling tunbing -
the isentnopic efficiency oft tre comp resson and tunbine ang
Ot. and EOI respectively. The pness® and tampr neyd in the
Win oar Ma freme- and 25°C respectively. Assuming
isentropic ramming and wi- of cooling ain passed from tHe
Cooling tundine eynal fo tre wi. of cooling ain, Pad:(a) “the natio of bypassed ain to mam ain used fen, noting
punpose:
Q@) The power neqd fon maintaining +e cabin at neqyd
Condition:
Sy
a2) Tre Poltowina gata nefon 10 reduced ambient ne frigenation
system * Pressune of nam ain is Il ban at 20°C. Pressune
or Me end of main compnesson 3-3 ban-
Main compaesson offrcienuy, To = 0-8
Heat exchangen #ffectiveness = 0-6
The pressune at tre gepeeaf exit of Pre auxiliany
funbine ts 0-8 ban, efficeny = 0-85
Temp: of ain leaving A asco
Pnessund’ in fre cabin = 1015 ban
train tundine effictensy = O: 84
Fiow nate se ain Hrnvagh cabin =| Kals
Obtain the COP, ard powen needed fo openata the
system °me 5°C
P= 08S Ky fem?
60%. of total
heat removed
in HE
Py = 4 SKyflont
Tre 08
Ta Ty= 50%
THs Stc = 278K
= 0.85 Kyfleme
(apacty > 307R
Ree 1K Plone
To 25°C = Q98kmB h
Cn
Now,
(B)* 2 Ts
Pa “pee T3) i
2
> (48 ye ests
‘ Che 306-78Now,
1 3 = Te
ear
Se tonppe sab s:8ses soar
Te’ — 306-48
S hl = 472.43 K
Now (Ts - Ts)
ee ™ Cp Ca-aw9
mee (73/- Te)
Now,
T= Th- 50%
= 306.78 - 50
= 256.78 K
From 442.43 ~ T
og = we
442-63 - 256-TE
ota 343.04 kK
Now, va
ea
Ps a,
2\ 343.04
3 ()" o6 a Be Te R173. K
Ts1 Smash
Ta ar oe
> (0-2 = 343.04 -_ Ts!
343.06 — 21913
D> Tye = 243-91 KR
Qe mee (Tr - Gi)
D BOKB5 = mx 10035 ( 278 - 243.91)
By rhe 0 828K gts
> me 1-73 KlsReforgenamts
Requmement
b Tne nefryenant used Should nol cause O77 nisk of injunies,
fine on pnepenty domaye in case of leakage:
2. Tre chemical, physical, Hrenmodynam’c Propenties of tee
nedaigenart musf suit in the system and the woaking conditon
ab a Acasonanle Cost:
Seleckon CG
1. Chemreal caitenin > Stable and inent
2. Health , Safely and envinenment —> Non toxic, Non frammable,
Enyinonment foiendly:
3. Thenmal >
G Grikicol demp and Boittay ph dempr.
Gi) Low vopoun heat Capacity:
(ji) Low viscosity -
(iv) High anmol Con ductivily.
4 Ovun>
(i) Satisfactony oil solubomiliky
(i) High dietwnic stnengin of vapoun.
(iil) Lows faseging point -
(n) Easily Easy leak detection
W) Low costPrimony and Secondary Resnigenant
Paimany nef ane those feds whicn ane used dineely as working
Druid >
Example- RB4a, Ri, R-IZ ete
Secondary nefaryenant ane those Wyids ubichane used fon dnansfoomen
tnansponiing trenmal onenyy from one location to anothan:
Ext waten, Ain, ice ete+
“They ane also Known unden the name ‘Bnines’ on ‘Antifneegens
Boines— waten -gbycol solution
waten- ethanol Soluhion
Designakion of nefrigenants
R, ae Ro Refrigenant
X41 9 No. of canbon atoms
Yo { > No» of Hydnegen atoms
Z > no of Fluenine atoms
ex: Ru
ao cet '(®) The majnane, ethane and Propane Senies
G) Methane Senies
u F
L \
Hecate ete
V
ui a
CH COS F
{Tavchtono mono fursne methane)
(Rv)
CORR
dichiono difiane methane
cat H=O0 F=2
axel y Y-120 OEE
Ay x0 Svel
QR ola
= RIZ
bi) Zthane _Senies
foe
Aon
vod 1 ;
foc - CHK SS UH Cm GH
eT “aa
eae fea
Ca Cla Fe
(Dicholono tenta fins ethane )a KHz > y-1F0 S224
Sxel Dyed
RIW4
FOF
fe
H-~C-c-H
t \
POOF
22 H=2 Fe
> XHN=R >Y-1=2 Soa8
x ol aye.
R134
[iii] Phopane Series
eed HOOK 4
‘ ) ’ \
H Sos Meee ix F- C- C=C -F
' roto
HOR YW Foe oF
C3 Hs Co Hs
CPenta fiuane propane)
c=3 He 3 FES
> x1203 dried 2255
Dd X22 oye 6
we RAS(B) Zeotnopic and Azeotnopic ne igenant
A Zeoknopic on gree nrefosgenant Contains two of mone 1988
' ie i ontneal
nafnnenant whose eqyitiboiam vap. phase ard Sip phase ee
Composit” differs: The sempr “f s200 Zeodnopic mix hung
charges as it evapenales on condenses at Const pnessung
Barn ‘nefens to Beotnopic mixtune + The Comporents in Hay
mistane have di flenent boil points and hence tre nefnizenent
mixtung has a Jemp? ese:
Ex: R404 A = WR Rigs (4a) + RIZE (52%) +RI3Ka (44)
ams,
Glide =1K
R143
z
xsl ys 3
x=l yer xne2 yeleB Pe 2z3
KIED yo = 2s
cee Heat FES atk
Wak F- C7 C-H
Cnr t f
io
e & CoH F;
coHE, Be
Penia fume ethaneR407 4 = :
a R32 (a3) + RIS (ast) + 1340 (S24)
Glide> #K
A3e0%no pic neforjenant anc blend that contains two on mane nofarenan's
whose cqillboium vap 3 liz, phase Composil"s ane tre same ab
A Given pnessung’ Te temp of Apeotne pic nedrizenan | remains
const as it evagonates on condenses at cons} pnessnr.
xX = 5 nefens do Azeotopic mixtunes This Nefacyenaht oxct
like home yeneous, Substances with one boiling point and trenefone
Th Nave no give:
\e
@ R-50FA = RiAS(sok¥) + R143q(50+-)
@) Rsog Be = Rezger R23 (464) + RIGA(S4/)
Tnonyanic ne faigenant
Raye
x="F yY&Z_ nefens to molan mass
Ex: waren
Heo > RFE
CO, > Rt44
Ammonia NH; 2 R717High_erganic compounds
x=6
REOO S Butane
Unsatunated onganec compounds
RIISO 3. Emylene
—
by R134@)
small lelten indicates iSomen f that suvstance*
RISA 3 nonmal bps 19%
(c2He Fe)
RISA > nowmal bp = — 26°C
(C2 Fe)
ly R404)
copital leer ‘A’ denotes iF 15 © Zeohmope on agestnope Ne fnigeneat-Envinonmental impact *f nefoigenant
1 Ogene dapleion potential (oor)
Refrigenant comlosning Chlorine on Bromine contnibutes te
He breakdown af He eZene loyen »
Ch+ Os— > ClO + 2
Howeven His ClO molecule iS unstable. 94 breaks down and
Reack wit eone Moleatle Mepeadelly until @ mone Stable ,
t
Compound is created
“The ODP ig the patio of impack on gone of A chemical
Companed fo fre impact on of A Similan. mass of R-Ils
RQ > opp=!
2. Global wanming potential CGWP)
ne GWP is He nate of Wanming Coused by a Substance to
dre wanming Caused by a Similan mass of Canbon dtonda
Gwe of Cor is |
Gwe of RIL = S000
RI2 = 8500Vapoun compnession Re igenalvon Gycle
Component S:
condensan
1. Compaesson Sgt Eee
| L 2
2. Condensen
3. Expansion valug
Expansin 7
4. @yaponaton val ‘
4 Evapanaton
T
f \
3
G 1
s
Considering ideal protess
frocess "22g, = 9
3
Process 2-3? Van = Jan = hs-hg
2
Process 3-4~ Yan =O
'
Process 4-02 Vy = L dh = hin heFrom frost tay eto Menene
we Fay
2 3