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Solubility and Acid-Base Concepts

The document discusses various concepts related to solubility, including the relationship between solubility product and molar solubility, conditions for precipitation, and the acid dissociation constant. It also covers the Henderson-Hasselbalch equation for buffers, gas laws such as Gay-Lussac's and Dalton's laws, and the compressibility factor for ideal and real gases. Key equations and principles are presented in a simplified manner for better understanding.

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0% found this document useful (0 votes)
11 views4 pages

Solubility and Acid-Base Concepts

The document discusses various concepts related to solubility, including the relationship between solubility product and molar solubility, conditions for precipitation, and the acid dissociation constant. It also covers the Henderson-Hasselbalch equation for buffers, gas laws such as Gay-Lussac's and Dalton's laws, and the compressibility factor for ideal and real gases. Key equations and principles are presented in a simplified manner for better understanding.

Uploaded by

negipihu209
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF, TXT or read online on Scribd

I2.

Solubility :
Solubility in 9)a? = Molar solublity Cmol / d m) x Molar mass (9/mai

13. Relation between solubiligy product and Soluliliy:

where se Molar solukility SIMPLI


TAMIL

[Link] pracpitaion :
IP< ksp : the Solution is un Saturated and precipitation

will nok OCCUY.

IP ksp: the Solution is Saturated and soluei liky equili brium 2ziste.

IP > ksp : the Solution is SupersSaturated and hence precipitation

Cormpound will 0ccuY.


7. Ionic Produc ater (Fu) :
k = Lu] [oN]
lohere, a molar Concentaton oç at ibns

OH mnolar Condentraton 1004

8. Acid dissociation Constant:

For diprotic

where,
For tripotic

kai
acd

kaz and
dcid :
:
Kag
ka

Ka

ate
ka

kal

acid
* kaz
x Kaa tas

disso ciation Constant for

primary, secondary and tertiary disociations Yespactively.

4. Relatton pH and poH:

O
between

pH = - log [a] and p "-Log


pH
where,
+ þOH
B-
|
= l4

Molar

3olar
Concentration

Con Centration
H jDns
OH ions .:
lo. Handerson - Hasselbalch equation for acidic and basic buffer

For acidic buffer i


[conjugate base]
BIOLOGY
pH pkat Logo SIMPLIFIED
Cacid] TAMIL
5. GGay Lussac's law :

Po T Cat Constant V and n)

wheres

P= Ini tial pressure

Pa= Finall prescute

T: Initial temperature

Te Final temperature

6. AvogAdre's lau :
V oG n (at Constant P and T)
: |. 987 cal. k moi

Dalton 's lau partial pesufe:

Protal = P, tP,+ p,+ Cat Constant T,V)


where
PTobal Total prest Ure Hhe gas

P,PaP Partial prestune the gace

Percentage 90s tna mixtuTe :


% a gas in mixcture
Portal Precsure gas(P)
Protal

CompTess ibiliy foctor (:


nRT BIOLOGY
SIMPLIFIED
For ideal gas TAMIL

Z= 1

PY = nRT
FoY real gases

PVreal= ZnRT

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