Bohrs model
Dr. Sonawane
Models of the Atom Review
e
e + +
e -
e
+ + -
+e e
+ e - +
- -
e
+ e + e
Dalton’s model
Greek model Thomson’s plum-pudding Rutherford’s model
(400
(1803)
B.C.) model (1897) (1909)
Bohr’s model Charge-cloud model
(1913) (present)
Dorin, Demmin, Gabel, Chemistry The Study of Matter , 3rd Edition, 1990, page 125
The Bohr Model of the Atom
I pictured the
electrons orbiting
the nucleus much
like planets
orbiting the sun.
However, electrons
are found in
specific circular
paths around the
nucleus, and can
jump from one
Niels Bohr level to another.
The Bohr Model
•Niels Bohr studied the hydrogen
atom because it was the most
simplistic.
•Bohr proposed that an electron is
found only in specific circular
paths, or orbits, around the
nucleus.
•Each possible electron orbit in
Bohr’s model has a fixed energy.
The fixed energies an electron
can have are called energy levels.
Ground State vs. Excited State
•ground state: all electrons in lowest
possible energy levels
•excited state: an electron that has
absorbed energy and moved to a
higher energy level
This is a temporary state!!
The Bohr Model
• The energy levels get closer together as you
move farther from the nucleus.
• The energy levels also get higher in energy
as you move farther from the nucleus.
Electrons Jump
•Electrons can jump from
one energy level to
another.
•A quantum of energy is
the amount of energy
required to move an
electron from one energy
level to another.
Electrons Jump
• An electron must gain energy to jump to a
higher energy level.
• When an electron has jumped to a higher
energy level, it is in an excited state.
• An electron must lose energy to fall to a
lower energy level.
• When an electron is at the lowest energy
level possible, it is at ground state.
Niels Bohr
Explanation of Line Spectra &
Equation
Niels Bohr
•Energy of an
electron is
quantized: can
only have specific
values.
•Energy
proportional to
energy level.
Explanation of Line Spectra
Electron will drop from excited
state to ground state and will
emit energy as a photon.
Explanation of Line Spectra
•Type of photon emitted by electron
depends on energy difference of energy
levels
Elevel = h = hc/
(h: Planck’s constant, 6.626 x 10-34 J
sec/photon)
Flaw in Bohr’s Model
Only works well for 1 electron species (H
atom).
Does not explain fine structure of line
spectra.