10-08-2025

1001CJA101024250009 JA

PART-1 : PHYSICS

SECTION-I

1) Let IA and IB be moment of inertia of a body about two axis A and B respectively. The axis of body
A passes through the centre of mass of the body but B does not. Then :-

(A) IA < IB
(B) If IA < IB, the axes are parallel
(C) If the axes are parallel IA < IB
(D) If the axes are not parallel IA > IB

2) A disk having plane parallel to the horizontal is moving such that velocity of point P w.r.t. ground
is m/s as shown in figure. If radius of disk is R = 1 m and the angular speed of disk about vertical
axis passing through disk is ω = 2 rad/sec, the velocity of centre of disc in m/s is :-

(A)
(B)
(C)
(D) None

3) Statement–1 : The motion of a simple pendulum is simple harmonic only for a ≈ ℓ.

Statement–2 : Motion of a simple pendulum is SHM for small angular

displacement.
 Statement–1 is True, Statement–2 is True ; Statement–2 is a correct explanation for
(A)
Statement–1.
Statement–1 is True, Statement–2 is True ; Statement–2 is NOT a correct explanation for
(B)
Statement–1.
(C) Statement–1 is True, Statement–2 is False.
(D) Statement–1 is False, Statement–2 is True.

4)

A block of mass m is moving on a horizontal surface having coefficient of friction µ. A point O is on

the surface so about point O

(A) Net torque of all the forces on the block is zero.

(B) Magnitude of angular momentum increases.
(C) Magnitude of angular momentum decreases.
(D) Magnitude of angular momentum remains same.

5) A series RC combination (capacitor initially, uncharged) is connected to an ideal battery. The time
taken by charge to reach 99.99% of its maximum value is closest to :- (Given : ℓn10 = 2.303)

(A) RC
(B) 9 RC
(C) 90 RC
(D) infinite time

6) Figure shows 3 different capacitors, separately charged by batteries, and then connected as
shown, with initially, switch open. When switch is closed, the charge :-

(A) On all capacitors get equalized.

(B) Becomes zero on all capacitors.
(C) On 2µF capacitor increases by 20%.
(D) On 2µF capacitor decreases by 20%.

7) 4 capacitors are connected as shown, connected with a battery. Breakdown voltages of each
capacitor C1, C2, C3 & C4 are 60 V, 50V, 90 V & 150 V respectively. If potential difference of battery
is increased from zero, then the capacitor which will breakdown first will be (given that C1 = 1 µF,
C2 = 2 µF, C3 = 3 µF, C4 = 4 µF)

(A) C1
(B) C2
(C) C3
(D) C4

8) A galvanometer gives full scale reading of 50 mA, when a p.d., across its terminals is 0.15 V. It
can be used as an ammeter of range 0 - 100 A by connecting a shunt resistance of :-

(A) 0.00075 Ω
(B) 0.00045 Ω
(C) 0.0015 Ω
(D) 3 Ω

9) Consider the electric circuits given in List-I and List-II gives values of some quantities from
electric circuits. Match the corresponding quantities with correct circuit.

List-I List-II

(P) (1)

(Q) (2)
(R) (3)

(S) (4) Va – Vb = 4V

(A) P → 4; Q → 1; R → 3; S → 2
(B) P → 4; Q → 1; R → 2; S → 4
(C) P → 3; Q → 4; R → 3; S → 4
(D) P → 4; Q → 1; R → 1; S → 2

10) In the circuit shown, the current through the 2Ω resistor is 1A. The potential difference between

points A and B is :-

(A)
V

(B)

(C)

(D)

11) In the fig. shown , if power loss in 5Ω resistance is 20 W then power loss in 12Ω resistance will
be :-

(A) 25 W
(B) 5 W
(C) 2 W
(D) 3 W

12) A planet moving around sun sweeps area A1 in 2 days, A2 in 3 days and A3 in 6 days. Then the

relation between A1, A2 and A3 is :-

(A) 3A1 = 2A2 = A3

(B) 2A1 = 3A2 = 6A3
(C) 3A1 = 2A2 = 6A3
(D) 6A1 = 3A2 = 2A3

13) Two infinitely long wires P and Q separated by a distance of 10 cm in air, carry currents I and 2I
in opposite directions as shown in figure. The resultant magnetic field due to currents in these wires

will be zero at :-

(A) Point A
(B) Point B
(C) Point C
(D) None of the points A, B, C

14) An infinitely long straight wire is bent as shown in figure. The circular portion has a radius of 10
cm with its center O at a distance r from the straight part. The value of r such that the magnetic
field at the center O of the circular portion is zero will be

(A)
cm

(B)
cm

(C)
cm

(D)
cm

15) Statement–1 : Mechanical energy of a particle executing SHM is E. Maximum KE of particle

may be greater than E.
and
Statement–2 : Potential energy of a system may be negative.

Statement–1 is True, Statement–2 is True ; Statement–2 is a correct explanation for

(A)
Statement–1
Statement–1 is True, Statement–2 is True ; Statement–2 is NOT a correct explanation for
(B)
Statement–1
(C) Statement–1 is True, Statement–2 is False.
(D) Statement–1 is False, Statement–2 is True.

16) Two conducting spheres of radii r and R carry charges q and Q respectively. When they are
connected by a conducting wire, there will be no loss of energy of the system if :-

(A) qr = QR
(B) qR = Qr
(C) qr2 = QR2
(D) qR2 = Qr2

17) Three point charges +q, –2q and +q are placed at points (x = 0, y = a, z = 0), (x = 0, y = 0, z =
0) and (x = a, y = 0, z = 0) respectively. The resultant dipole moment can be best represented by

. Find α + β.

(A) 2
(B) 3
(C) 4
(D) 5
18) Electric field at the center of the square of side a is :-

(A)

(B)

(C)

(D) None of these

19) Two plane mirrors are inclined at an angle of 72°. An object is kept between them symmetrically,

then number of images of object is

(A) 4
(B) 5
(C) 6
(D) 3

20) If μ is defined as . According to shown situation select the correct statement

(A) The bird will see fish nearer

(B) The bird will see fish farther
(C) The fish will see bird nearer
(D) There will be no difference in the distance when seen from bird or fish.
 SECTION-II

1) A solid cylinder initially at rest of mass 3 kg and radius 1 m rolls down on inclined plane. Friction

force (in N) acting on it will be :- [g = 10 m/s2]

2) Find time constant of circuit shown in figure in microseconds.

3) A square shaped wire with resistance of each side 3Ω is bent to form a complete circle. The
resistance between two diametrically opposite points of the circle in unit of Ω will be ______.

4) In the circuit shown here C1 = 6µF, C2 = 3µF and battery B = 20V. The switch S1 is first closed
and S2 is kept open then S1 is opened and S2 is closed. What is the charge finally on C2 in µC?

5) A particle is projected from bottom of a blind narrow tunnel of depth made along a radius
inside the earth. If minimum velocity needed to escape out of the gravitational field of the earth is

, find n. M and R are mass and radius of the earth respectively.

PART-2 : CHEMISTRY

SECTION-I
1)
Major product of above reaction :

(A)

(B)

(C) H2C=CH2

(D)

2) Major product formed during following reaction :

(A)

(B)

(C)

(D) None of the above

3) (P) R–OH + SOCl2 (I) Swarts reaction

(Q) R–X+NaI in acetone (X=Cl, Br) (II) Darzen process
(R) R–Br + AgF (III) Wurtz fittig

(S) + Na (IV) Finkelstein reaction

Correctly matched option is :
(A) (P) → (IV)
(B) (Q) → (II)
(C) (S) → (II)
(D) (R) → (I)

4) Which of the following dehydration product is not major product ?

(A)

(B)

(C)
CH3CH2CH2CH2OH CH3–CH=CH–CH3

(D)

5) Given below are two statements :

Statement (I) : SN2 reactions are 'stereospecific', indicating that they result in the formation only
one stereo-isomers as the product.
Statement (II) : SN1 reactions generally result in formation of product as racemic mixtures. In the
light of the above statements, choose the correct answer from the options given below :

(A) Statement I is true but Statement II is false

(B) Statement I is false but Statement II is true
(C) Both Statement I and Statement II is true
(D) Both Statement I and Statement II is false

6)
Identify (C)

(A)

(B)

(C)

(D)

7)
The product X and Y are respectively :

(A)

(B)

&

(C)

&
 &
(D)

8) 1 mol of nitrogen is mixed with 3 moles of hydrogen in a litre container where 66.67 % of
nitrogen is converted in to ammonia by the following reaction :

N2(g) + 3H2(g) 2NH3(g) , then the value of KC for the reaction will be -

(A) 2 M
(B) 1/2 M
(C) 4 M
(D) 1/4 M

9)

Boiling point of an ideal liquid solution containing non-volatile solute depends on :

(I) Concentration of non volatile solute in the solution
(II) Boiling point of pure solvent
(III) Enthalpy of vapourisation of pure solvent
(IV) Molar mass of solvent

(A) I, II, III

(B) II, III, IV
(C) I, IV
(D) I, II, III, IV

10) Compound is a hydrated complex. If 1 molal aqueous solution of this complex has
freezing point of 269.28 K assuming 100% ionization of this complex, then formula of the complex is
:
(Kf for water = 1.86 K kg mol–1)

(A)
(B)
(C)
(D)

11) Kinetics of acidic hydrolysis of ester is pseudo I order reaction

CH3COOCH3(aq.) + (ℓ) CH3COOH(aq.) + CH3OH(aq.)

Rate law is given by : r = K[H ] [H2O] [CH3COOCH3] ; K = 1.8 × 10–3 M–2 sec–1
+
where H+ ion concentration is given by acid catalyst. In an experiment 1M CH3COOCH3 is hydrolysed
using 0.1M HCl as catalyst.
Calculate the time at which ester concentration reduce to 0.25M [ln2 = 0.7]
(Given density of pure H2O = 1gm/ml)

(A) 70 sec
(B) 140 sec

(C)
sec

(D)
sec

12) Assertion : Due to adiabatic expansion, the temperature of an ideal gas always decreases.
Reason : During adiabatic expansion against external pressure system generally performs work
without accepting heat.

(A) If both assertion and reason are correct, and reason is the correct explanation of assertion.
(B) If both assertion and reason are correct, and reason is not the correct explanation of assertion.
(C) If Assertion is correct, but Reason is incorrect
(D) If Assertion is incorrect, but Reason is correct

13) For the following reaction,

C (diamond) + O2 → CO2(g) ; ΔH = –97.6 kcal
C (graphite) + O2 → CO2(g); ΔH = –94.3 kcal
The magnitude of heat exchange for the conversion of 1 g of
C (diamond) → C (graphite) is

(A) 1.59 kcal

(B) 0.1375 kcal
(C) 0.55 kcal
(D) 0.275 kcal

14) The heat of combustion of gaseous hydrocarbon C3H8 at constant volume is measured in bomb
calorimeter at 298 K is found to be – 2201.1 KJ/mole. Find the enthalpy of combustion of C3H8(g).
[Given : R = 8.314 J/mol-K]

(A) – 2208.53 KJ/mole

(B) – 2210.35 KJ/mole
(C) – 2193.53 KJ/mole
(D) +2201 KJ/mole

15) Element A has successive ionization energies 8.2, 16.4, 102.5, 122.4 (in eV/atom). Element B has
corresponding values 10.4, 19.2, 35.6, 49.2, 166.5, 208.7 (eV/atom)
What would be the likely formula for a compound that may be formed from A and B

(A) A4B3
(B) A2B
(C) AB2
(D) A2B3

16) Select the CORRECT radii order –

(A) K > Ca > P > Mg > N

(B)

(C)
(D) Co Ni Zn

17)

Match the list:

List-I (complex) List-II (Properties)

Diamagnetic and low spin

P [CoF6]3– 1
complex

Paramagnetic and outer orbital

Q [Cr(C2O4)3]3– 2
complex

Paramagnetic and inner orbital

R [AuCl4]– 3
complex

Paramagnetic and low spin

S [Fe(CN)6]3– 4
complex
The correct option is
(A) P → 1 ; Q → 2 ; R → 3 ; S → 4
(B) P → 2 ; Q → 3 ; R → 1 ; S → 4
(C) P → 2 ; Q → 1 ; R → 3 ; S → 4
(D) P → 1 ; Q → 3 ; R → 2 ; S → 4

18) For Fe4[Fe(CN)6]3 which option is not correct

(A) IUPAC name is Iron(III) hexacyanidoferrate(II)

(B) It has total 12 π bonds
(C) It has coordination number is 6
(D) Ionisation sphere has Fe3+ & coordination sphere has Fe2+ ions are present.

19) When freshly prepared FeSO4 is added to the sodium nitrate solution followed by the addition of
concentrated H2SO4 dropwise then brown ring complex is formed. Which of the following
characteristics is CORRECT for the formed complex

(A) EAN value of complex is 36

(B) IUPAC name of complex is Pentacynidonitrosyliron (I) sulphate
(C) Complex has Fe – N linkage
(D) None of these
20)

Select INCORRECT statement regarding B2H6 ;

(A) It reacts with electron rich molecules

(B) Boron uses it's all valence shell orbitals for bonding
(C) When B2H6 react with Lewis base, boron accepts electron pair into its vacant d-orbital
(D) B2H6 is electron deficient molecule

SECTION-II

1) How many of the following ether can not be synthesized by Williamson ether synthesis

(i) Ph–OCH3 (ii) (iii)

(iv) CH2=CH–O–CH2–CH3 (v) (vi) Ph–O–Ph

2) If K represents rate constant and A represents collision frequency factor of a reaction then
difference between activation energies of two reactions numbered '2' and '1' in
kcal/mole at 227°C is.

(Given : K1 = 100 K2, 10 A1 = A2, ln 10 = , R = 2 cal mol–1 K–1)

3) An ideal gas is expanded from (1L, 10 atm) to (4L , 5 atm) against a constant external pressure of
1 atm. If initial temperature of the gas was 300 K and heat capacity of the process is 50 J/K, and
enthalpy changes in the process is (P × 10–1) kJ then find value of (P) ? (Given : 1 L-atm = 100 J)

4) No. of unpaired electrons in [NiF6]2– = x

No. of inner orbitals involved in hybridization of [Mn(NH3)6]2+ = y
0
No. of geometrical isomers present in [Pd+2(NH2–CH(CH3)– )2] = z

Find

5) Number of unpaired electrons in B2 = x

Number of MO in O2 having less energy than
Then (x + y) ?
(MO = Molecular orbitals)

PART-3 : MATHEMATICS

SECTION-I
1) The distance between the origin and the tangent to the curve drawn at the point x =
0 is

(A)

(B)

(C)

(D)

2) The maximum value of is

(A) e
(B) ee
(C)

(D)

3) Let f : (–∞,∞) → (–∞,∞) be defined by f(x) = x3 + 1.

Assertion A : The function f has a local extremum at x = 0
Reason R : The function f is continuous and differentiable on (–∞,∞) and f'(0) = 0

(A) A is correct but R is not correct

(B) A is not correct but R is correct
(C) Both A and R are correct but R is NOT the correct explanation of A
(D) Both A and R are correct and R is the correct explanation of A

4) Function has

(A) One local maxima & one local minima in (0, 2π)
(B) Two local maxima in (0, 2π)
(C) Two local minima in (0, 2π)
(D) Exactly one minima in (0, 2π)

5) Let f(x) be a non-constant twice differentiable function on R such that f(2 + x) = f(2 – x) and

= f '(1) = 0. Then minimum number of roots of the equation f "(x) = 0 in (0, 4) are

(A) 2
(B) 4
(C) 5
(D) 6

6) If f(x) = 4x3 – x2 – 2x + 1 and then

has the value equal to

(A)

(B)

(C)

(D)

7) (Where 'c' is constant of integration)

(A)
(B)
(C)
(D)

8) = f(x) + C, where f(6) = 72, then value of f(9) is - (Where 'C' is constant of
integration)

(A) 3
(B) 27
(C) 81
(D) 243

9) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(A) (I) 1
is equal to

(B) (II)
is equal to

If y = ƒoƒoƒ(x) is differentiable function

(C) where ƒ(0) = 0 and ƒ'(0) = 2, then value of (III) 0
y'(0) is equal to
 (D) is equal to (Here [.] & {.} (IV) 8
denotes greatest integer & fractional
function respectively)
(A) (A) – II, (B) – III, (C) – IV, (D) – I
(B) (A) – I, (B) – II, (C) – III, (D) – IV
(C) (A) – II, (B) – IV, (C) – III, (D) – I
(D) (A) – III, (B) – I, (C) – IV, (D) – II

10) If f(0) = 0, f'(0) = 2, then the derivative of y = f(f(f(f(x)))) at x = 0 is :

(A) 2
(B) 8
(C) 16
(D) 4

11) Which is correct -

(A) 31/3 < 41/4 < 51/5

(B) 31/3 > 41/4 < 51/5
(C) 31/3 > 41/4 > 51/5
(D) 41/4 > 31/3 > 51/5

12) The coordinates of point P on the line 2x + 3 y + 1 = 0 such that |PA – PB| is maximum, where
A(2,0) and B(0,2) is-

(A) (5,–3)
(B) (7,–5)
(C) (9,–7)
(D) (11,–9)

13) The value of is

(A)

(B)

(C)
(D)

14) Let f(x) is differentiable function in [2, 5] such that f(2) = and f(5) = then their exists a
number x0, 2 < x0 < 5 for which f ' (x0) equals
(A)

(B)

(C)

(D)

15)

Let f : (0,1) → be a function defined by , and g(x) = (f (–x) – f(x)). Consider two
statements
Statement-I : g is an increasing function in (0,1)
Statement-II : g is one-one in (0,1)

(A) Statement-I is true but Statement-II is false

(B) Both Statement-I and Statement-II are false
(C) Both Statement-I and Statement-II are true
(D) Statement-I is false but Statement-II is true

16) If LMVT is applicable on , then

a = –1 ; p =
(A)

(B)
b=2;p= ;q= ​

(C)
b = –1 ; p = ;q=–

(D)
a=1;p= ;q=–

17) If ƒ(x) = 2x2 – kx + 9 is increasing ∀ x ∈ (1, 2), then k cannot be -

(A) 5
(B) 3
(C) 1
(D) 0

18) Suppose g(x) is inverse function of a differentiable function ƒ(x) and If ƒ(5) = 3
and , then G'(3) is equal to -

(A) 1
(B) 2
(C) 4
(D) 8

19) Consider two functions ƒ(x), g(x) as follows

g(x) = ƒ(x + 2) + ƒ(x – 2). The number of points of discontinuity of g(x) is-

(A) 0
(B) 1
(C) 2
(D) 3

20) is equal to-

(A) e

(B)

(C)

(D)

SECTION-II

1) Let . Then the value of f(50).f′(50) is ______

2) Consider the pair of lines ax2 + 2hxy + by2 = 0. If slope of one of the lines is three times that of

other line, then the value of is :

3) Let f : R → R be defined as f (x) = x3 + 2k x2 + (k2 + 12) x – 12. If f(x) is strictly increasing on R,

then the largest value of k is equal to

4) If f(x) = (x – 1)4 (x – 2)3 (x – 3)2 then the value of f"'(1) + f"(2) + f'(3) is :
5) Let f(x) =
If f(x) is continuous and derivable at x = 0, then (20b + 13k) is :
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. C C D C B D B C A B D A A A A B A A A A

SECTION-II

Q. 21 22 23 24 25
A. 5 12 3 40 3

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C B D B C B A D D C B D D A B C B B C C

SECTION-II

Q. 46 47 48 49 50
A. 3 7 157 0 9

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A C B B B D D D A C C B B B C B A D A C

SECTION-II

Q. 71 72 73 74 75
A. 50 3 6 0 79
 SOLUTIONS

PART-1 : PHYSICS

1) ICM is the minimum possible M.I. of body,

Id = ICM + Md2
For Imin, d = 0
When axis are parallel.

2)

3) Conceptual based.

4) Velocity decreases so the angular momentum.

5)

Q = Q0(1 – e–t/τ)

e–t/τ = .0001

t = 4 × 2.303 × τ ≈ 9.2 τ

6)

after redistribution,
Q = 0.8 μC
charge on 2μF capacitor reduces by 20 %
7)
C2 will break first

8) G =
igG = (i – ig)RS
50 × 10–3r3 = (1 – 0.05) × R

9)

(P)

I1 =

I2 =
I3 = 0
Va – Vb = 4
(Q) Using KCL at n (a) I1 + I2 = I3

⇒ 10 + + = Va = Va

Va =

⇒ I1 = , I2 = , I3 = .
(R) refer to NCERT text book part I, page no 117, 118

I1 = 2.5 A, I2 = , I3 =
Va – Vb = 2.5 V
(S)
KVL in upper loop (1)
8I1 + 10I3 = 2v
KVL in lower loop (2)
9I2 + 10I3 = 1v
and at junction (a),
I2 + I1 = I3
solving the three equation

we get, I1 =

I2 = ;I3 =

& Va – Vb =

10)

Voltage drop on 2Ω is V2 = (2) (1) = 2V

Net resistance of 3, 6 and 2Ω is = 1Ω (parallel)

Total voltage between B and C is = = 10V

∴ Current through
Hence voltage on 5Ω i.e., between A and B is

11)

Curent in 12Ω is

12) = constant

13) Conceptual.
14)

15) Conceptual based.

16)

There will be no loss of energy if the potential of the spheres is the same i.e. if

or . Hence the correct choice is (2)

17)

Correct answer is (A)

18)

19)
20)
Actual distance = x + y

distance observed by bird =

21) mgsinθ – Fr = mxa

a = αR
Solving these equation

22)
Req. = 4Ω, τeq = 12

23)
Req = 3Ω

24) Common potential

So, charge on 3µF capacitor

 25)
COE

... (i)

by equation (i)

PART-2 : CHEMISTRY

26)

H2C=CH2 is major product of above reaction

27)

28)

R–Br + AgF → Swarts reaction

29)

30)

SN2 → Inversion
SN1 → Racemisation

31)

Two consecutive SN2 give retention product.

32)

33)
1 3

34) Explain Question :

Boiling of non volatile solute depends on
Concept: Elevation in boiling point ΔTb
Solution:
When a non-volatile solute A is dissolved in a pure solvent B , its vapour pressure decreases
and hence the boiling point increases. The difference

ΔTb of boiling points of the solution and pure solvent is called elevation in boiling point.
If is the boiling point of pure solvent and Tb is the boiling point of the solution then, Tb >
and the elevation in boiling point
Experiments have shown that for dilute solutions, the elevation of boiling point (ΔTb) is directly
proportional to the molal concentration of the solute in a solution. Thus
ΔTb ∝ m
or ΔTb = Kb.m
where Kb = boiling point elevation constant or molal elevation constant or ebulioscopic
 constant.
Molal elevation constant is characteristic of a particular solvent and can be calculated from
the thermodynamical relationship.

Where, R is molar gas constant =2cal/mol-K,M= molar mass of solvent

Final Answer = Option (4)

Boiling point of an ideal liquid solution containing non-volatile solute depends on all the given
factors. hence all options are correct.

35) ΔTf = i × Kf × m
(273 – 269.28) = i × 1.86 × 1
3.72 = i × 1.86
i=2

or n = 2

36) r = K1 [CH3COO(CH3)] where K1 = K [H+][H2O]

K1 = (1.8 × 10–3) × 0.1 × = 10–2

t=

37)

The correct answer is option (D)

38) C (diamond) + O2 → CO2(g) ; ΔH = – 97.6 kcal

C (graphite) + O2 → CO2(g) ; ΔH = – 94.3 kcal
C (diamond) → C (Graphite) ΔH = –3.3 kcal
Heat to convert 12 gram diamond to graphite = –3.3
∴ Heat to convert 1 gm diamond to graphite

= = 0.275

39)
Δng= 3 – (1 + 5) = – 3

ΔH = – 2201.1 – 7.432
ΔH = – 2208.53 KJ
40)

A ⇢ 8.2, 16.4 , 102.5, 122.4 …….

Valence e– = 2
B ⇢ 10.4, 19.2 , 35.6, 49.2, 166.5, 208.7
Valence e– = 4
∴ Formula is A2B1

41)

(A) Mg > P
(B) S–2 > Cl–
(C) Due to higher charge it will have larger Hydrated Radius
(D) Fe≈Co≈ Ni are near equal in size

42)

The correct answer is option (B)

43)

(A) IUPAC name is Iron (III) hexacyanido ferrate (II)

(B) One CN contain 2π-bonds and there are 18CN ligands total in whole molecule.
So total number of π-bonds are 36.
(C) Co-ordination number = 6. Since in complex [Fe(CN)6]4–
One Fe (central metal atom) is coordinated by 6 ligand of CN– anion.
(D) Fe4[Fe(CN)6]3
Ionization sphere
↑
Fe3+[Fe(CN)6]4
↓
Co-ordination sphere
Fe + 6X(–1) = –4
Fe = +2
Fe+2 from co-ordination sphere.
So only (B) option is incorrect.

44)

The correct answer is option (C)

45) Boron does not have d-orbital.

46) (ii), (iii) and (vi)

 47)

⇒ 100 =
⇒ 1000 =

⇒ 3 ln10 = ⇒
⇒7

48) w = – 1 atm (4 – 1) = – 3 L-atm = –300 Joule

q = CΔT

T2 = = 2T1 = 600 K
q = 50 × 300 = + 15000 J
ΔH = (q + w) + (P2V2 – P1V1)
= + 15000 – 300 + (20 – 10) × 100
= 16000 – 300 = 15700 Joule

49)

The correct answer is 0

50) x = 2
y=7

PART-3 : MATHEMATICS

51) Putting x = 0 in the given curve, we obtain y = 1.

So, the given point is (0,1)

Now,

The equation of the tangent at (0,1) is

Required distance

52) Let
Taking log on both sides, we get

Differentiate w.r.t. x, we get

For maximum / minimum,
Differentiate (i) w.r.t. x, we get

53) Let f : (–∞,∞) → (–∞,∞) be defined by f(x) = x3 + 1.

Clearly, f(x) is symmetric along y = 1 and it has neither maxima nor minima.
∴ Statement-1 is false.
Hence, option (B) is correct.

54)

Local maxima at

55) f (2 + x) = f(2 – x)
f '(2 + x) = – f '(2 – x)
Put
x = 0, f '(2) = 0
x = – 1 f '(1) = – f '(3) = 0

x= , =– =0

∴ = 0 = f '(1) = f '(2) = f '(3) =

Using Rolle's theorem in y = f '(x).
Minimum number of roots of f "(x) = 0 are 4

56) f(x) = 4x3 – x2 – 2x + 1

f ′ (x) = 12x2 – 2x – 2

f ′ (x) = 0 x= ,

is point of minima
Graph

57)

58)

59) (A)

(B)
(C) y = ƒƒƒ(x)
y' = ƒ'(ƒ(ƒ(x))).ƒ'(ƒ(x)).ƒ'(x)
y'(0) = ƒ'(ƒ(ƒ(0))).ƒ'(ƒ(0)).ƒ'(0)
= 2.2.2 = 8

(D)

60) y'(x) = f'(f(f(f(x))) f'(f(f(x))) f'(f(x)) f'(x)

⇒ y'(0) = f'(f(f(f(0)))) f'(f(f(0))) f'(f(0)) f'(0)
= f'(f(f(0))) f'(f(0)) f'(0) f'(0)
= f'(f(0)) f'(0) f'(0) f'(0)
= f'(0) f'(0) f'(0) f'(0)
= (f'(0))4 = 24 = 16

61) Let y = x1/x

⇒
 ⇒

62) PA – PB < AB
⇒ P,A,B are collinear
P is point of intersection of AB and 2x + 3y +1 = 0
equation of AB is x + y = 2 and P is (7,–5)

63)

0 0
64) Using LMVT, f '(x ) = = f '(x ) =

65)

⇒ g is increasing in (0,1)
⇒ g is one-one in (0,1)

66) a = –1 ; p = , q = – , b = 2

67)

ƒ'(x) = 4x – k > 0 ∀ x ∈ (1, 2)

⇒ 4 – k > 0 ⇒ k < 4; 8 – k > 0 ⇒ k < 8

∴ k<4

68) ƒ(g(x)) = x ∴ ∴

Hence

69) The graph of

ƒ(x)
ƒ(x – 2)

ƒ(x + 2)
Then graph of g(x) will be

No point of discontinuity

70)

71)

or
(f(x))2 – x2 = 1
2f(x) . f′(x) = 2x
f(50) f′(50) = 50

72)

bm2 + 2hm + a = 0, where m = y/x

roots of this equation are m1 & 3m1

3m1 + m1 = ⇒ m1 =

3m1. m1 = ⇒ 3
⇒ 3h2 = 4ab

73) f '(x) ≥ 0 ∀ x ∈ R
⇒ 3x2 + 4kx + (k2 + 12) ≥ 0 ∀ x ∈ R
Put D ≤ 0
⇒ k ∈ [–6, 6]

74) f'(x) will have (x –3)' so f'(3) = 0

and similarly f'' (x) will have (x –2)' so finally f'''(1) + f''(2) + f'(3) = 0

75) For continuity

0+0+2=b=2 ⇒ b=2
For derivability

=
2 = –1 + k ⇒ k = 3
∴ b+k=5