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The document discusses the properties and classifications of solids, specifically crystalline and amorphous solids, including their geometric arrangements and melting points. It also covers the concepts of isotropy and anisotropy in solids, as well as the diffraction of X-rays through crystal structures. Additionally, it touches on the behavior of molecules in different states and the significance of various properties in determining the characteristics of solid materials.
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lid state
jalline _ Solfol
DA substance which constituents|() A substance
ane anranged Tan orale
mamer th accefnite geometric
poert % called o. y
frronphous sotiol
which constituents
ye f 3
talline _soliol Kaw a. céfe
HONGO
g
lof ein doesn't J
= i to
Wh tnotense fn_temp to 0 i ) pleculen
Solid Froneoses J relocules beats % fefon
They hone riototiond mption as emell_4 Changes inte _“Ws fs called Meltfog point Fs
SA crystaliine solid Powe c Shaep melting Paint Fe Chane,
abriucted to Mh State +
i Amorphous meso howe o shen pasate pone -
Teotreepy 4 Aniootttopyy$ pei
> Amerephous. substances nesserble Lauil Such aS decttiicey
conductiity » Normal conductivity + mechanical strength &
wefeockve focleae ane same in alt — substorces ay,
Fsotropic fn naikkene.
> oyu solids ate anisotropic te. eee = Propenties
ATT. th ATES din’s. oe :
-) Th velocity} ot bight passin though _
Crystal varies sith dit? fo which tt Sgt
measune - Thus, & of Gight ing
such sto: ee pik up. Anta 2
Follnaing o diff! sets bsksan oy
Stn as olla cutting § molecules axe _anrangeo| ‘|
aay 4 disonolentyy manne: Soy fll_ the oes Solan
din’ a: £
wee aa oN
# ;
@ cs oct eS Bera. ss
é cnuystaltine Solil hese appeid to. shaw ealgedl kent
giv a clean clevage cia en aR Andy
Frereeqsloue ee —— ja CCU
eI phe ore() Tonic cones +
Tr trese crystals the constituent particle occupied tactic
Fors are sve & VO TONS,
tn case of Nach crys stal-
fau- Not § cl fon ~
“These Tons. axe hold! together by strong electrostatic Force
“of attraction .
electrostatic Forces endst? ingot ® ons,
2 Because of Stra,
they have a Melting 4 B-P -—
Sey oe 9 fs) corancisaf- lechlcy *0 mater state on
“0 the’ aq. ae all =.
> But ant 70 crystal ng atate ohate the % tree.
ons arte not «Free to
_move are Soluble in polar ee te i
| pea SrPicci 4 ect st
“once | ‘ Prtppertier Eexomn ple
= i 1 fice toate ttt
Nach KN ,
UF,
Bas,
Solid carton do otide,
CHy , Wan,
ad. adtu “aoe popere
4¢ ysolegiadl
“fe brandh‘of_sdlence clealy ecith the stucty of
sometitic, preoporctics § st" of cuystals 4 cnystattine Substann
¥ woe etaligrpt ies
upon 3 Rundairrental laws,
ol mange
é depends
ee yThe daw oF eee of mae
a) = a ‘of todloces _1
i
“Intedagal_ angle
ae aint fs, el
ate calle ntorfercfol is
'
“capa of stad af a pandhia os €
| of substancliy axe obtatrect re
the bi jo| ot. S0l)-o%. that «
REESE Bye vee
‘ Keo A_eube eotate h_ ay Pboute are tone
ae pag things the _ Contos st top &_ nag
Appeanance « after SS ts Sindlon E
—t Mie ogee ae pha
j aa x
Te aera antes fratspes “ok pls) of o
? FP enyptal. ole. the qi O10. cithor
! -dhole
ic
— Condtdon 3 code ork, 4.07 now
| hee ABC fs a unit. plone . i ‘
_ Peconding to abow law bmn ane a whole no
abc “one fntertcepts atone May iz Onl
=: = iee f constancy da umes
The la ctates that the crystals od the same substance
ipso [Link] ot Syrometny
ire total a0: ot planes » Une contre A Syenmeinyy possess
= patna Scale [Link] Spence ae
~gphetsteaoo 8 sledgnati cyl. plane 8 ase
2 Seis licen = ig 2 :
ba. face rakes. coher ‘([Link] snc onc
_.coeiticont_ oA En (Lm) cute _ ‘pallea " Woles tnolicess..
— 2h tis_motnd, the plane. ane described by as L mietieop Chotk,L)
Millet Indices
the MT the plore cto. 69 ane. reciprncal. ct Aractiond
eo ee onthe various cogs. _ 2
Peat alle. epnesenting yall the_planes_teenespis( Re
theft mrechproomD »
Solye' Hi clean Axoblton to obtain hy kk.
PY Pat hy KL volues wotthout commas tn Bracket.
sh Hg-h, the Sntercopt met ct Facectoan traction 1312 [Link] recF procol
i we ge a ane, mfller Inctites ot the Face Kilby,
hae Bd
By)
i it te ME ll be 6: Conia te Shaka cae
& | tnponcept (1 1,4-) ‘ A) oe
Ht pba ftw Iie Toba) nt off
2 ge De as pa =3
MDs (8, 2y3)i- wow alt Seay sigan. element, 3, Symmpty .Opseaton =
a Ssy “AIOE 8.0. geomet cat entity. auch as 0
nt, O Line. ape Ort which one ort morte symmetry.
+ PO SH q
Oe rein cs Carnie out +
A cmp. $ to hove a plone ot fae Con,
“ame be ciied_0 by on foarte
ot _cohich fs the. Sancti his reel —
go! ‘s_ _eprresenteo| ge avi ee
_ pany tine. naan ty
r Such that — busin m _rutation ot the
_orystal_thapugh 260° The. cnystal acy Same
i e mpre than one»
_=|#__sivilan _appeonance NCE Ocouts tWice fn One revolution
4 aD It bieyer Thoo_ Fotol_aads
Foun Fol cuiis syevretny
qSS es a8
Ty aso ony. port on the Conte ot the. Crystal
go that ple tary thrpugh tt cub the face a
the opposite side Into equal ollstance ®s _ called centre
tte colled by ® untt colt.
ts collal by 2 unlt cert.
ts no mone unit cell .
Each’ point present on te sn
Foch point paesont on the fac
he ie pa it the itedort
fu for seule,
Norge oe
) cee S, Ne froret
‘on hocly Conte Cube , dl :
Nerd
Need
Mtel So 2 -
for face center cubv, “
Neorg
Ne -6 :
Nie > So,N=4
Xe 1tay ie ns 4
~> Mom Von Laue % 1912 ted) that it ts Possible to
cbiffnact means of stols Crystals arte made up
ot Layers Fa a in ‘apie toshion’.
7 ‘The diffraction ot X- due 10 that the
k of X- nay $% OF game ondlen as ‘%ntenotemic distances
: ina crayytoly \
~> Based on the Property ot aPtinaction oF. %-Kay the st"
cruital hasbeen - olekoremineo boy vordous method .
Sa
os
5
the | Praga! i 4
According to ‘Braga's loun.-vahen the. Xonay alls on tte
erystok Falls Aicryytat Bs Compared Sally platen! atomic plate)
+ | they peremate into the enyttal 8, stidve the atoms in
+ plane: ftom each of these planes X-naye ane reflec
bel Based 7 ‘this an 09”, ‘qliog the notation bet” waeley
| | stance (d) bet” 2 sucressive planes. Angi of Inciclence (6)
Was derived. “This nelation was Bragg’s eg".Lo OAS EN+NM
Since the AdLM4 AONM ane conguusnt
Lo Hence LN= NIMte no =
+ . : . :
set 64” chon
wohole nd.‘ _the -
aa rae Olt" ‘ol’ G5
Kd rf : oS spaeiae ae
ns -_
ce
4!te Finect by sing
i Xo
by motatis the
is change
tubo T Ve passed though
team if obtainay that ig allowed Ce
Tg allowed to Strike a
whieh is. mounted on the tw — table. the
a. to fnctense in. egal
ange: Bean scr.
ah athe _crtytal =
Zeulon 1 fate thee re ‘bea coe “6 values cohich
Fon o
| sabi fnd= ad st) 3 fn which _thtonity will be. mao.
rs — creates with *nctease to. vole ot n_by brody
nsd& 8 .We can _/ caleulate distance bet” s Successive
= Fan Fy iy, Bg ee
=the fecHleotfon occur 8 0n nly dos
“| nel, This 7 catted 18t onclon reflection . Similarky, fox nent
hfaher angle ‘for 2° onden_neHlection (ne2)__
Gi - tn cote ot N
Noch, 18 Order etlectinn toa 3 fates C10), Cia),
aol Sees tec
me ° 9-906
0.705 ° 1.14“These rtattos Suggest that ?n Nacl the tom oust he
“annanged in Yace cents! Oubi'e Lattice ,
PY ‘in case of Nact, the angle of Plas tatlctton bine
(1.00) plane z 6.9", What Ts wavolonyth ?
Ans Peon ‘Breagg’s aq), We [now that
i NA = Bal Bind: hes
DIX AS ANYBWK 1O8 x Sih 5.4"
> Awa Bota
Qin case of Nats: the angle: ot “$8 onclon_acHectfon Ke
(1.00) , (41410)8 Ch44) Faces using. sono chrtpmatic eras. One
6-97.84 ane hat fe Bema of (Natl?taxed ¥-t¢ axe farther detected - by’ using
xeray,_soreittve Fes X= nays ane ta Cl tbe
‘gnh these arte mace t© fall. on a monochtomat'c cruyst abl
~~ 4p got. monpchen matic. beam.
“The “beam fs nen passed h asift 3 trade incictent
sj -[Link] powder. Filed tno. thin -woll. glass capillary
i .
“Spue_t0_eftection “ram vardous Lattice “plane, af Hractfon i
__ mandir. _arise. that _cliffracton can be phatographec! on
fe
the tun» sa ee ee eee.
2 Sirce the _poadter sumplo consist of clon crystal ararqa
$9 all possible orfgertation “
2 fon i és nok _necess
7 2The:_atffnacted ye rays from epncete “cones Oniginate
bee on Sure Sp a ;
so. single onnlen ct offffnaction eo. “fasniLiou
BS Groeten that a. imonne ie | aoe
U Wavelength N 8a Saddent ona. ae -?
es _upit = nar jan)’
<|_wWhich can be connected inte degaee Jo x 130‘
By applytog Boggs of
PY OPPYNA ee
Skereanys | toGde
Monochrnmatte with A> L64 A’ unwe Ne Oy
. a pest “the distance thom capiltart to ‘fay,
way MAYS trace all pate (S) tos Locate at o
dfisnaes — cm. Cabeulate 12 which orem thos.
oe
sae: :
Ley ca
Sea ce a 600.
A an ob ey “eomparrds th (
(acetate CCH3¢ eat) 2
_Gotasoyl bore can Cam CysHus )-4 Prazyiyanisole
~ Fdtp-<@)-Kan oon, ")
— (oxo —o pt= N=Ca)-0GH)
, Bid) ti | ich. turtherc
e Upiaas eat en tong e
ie eas Cage." pola
7h eDhoreer the. lattert 4: pele
ok Eon = Pedro angsole _ ee ——
- Ghangitton point ts 28K 4. Mei pote’ Ygok)
=O pull tte Cleon tiqsdC melt)» the ceveroe clon
if
j takes place Place. Exactly at the same tempt the turbid
Liquid thus chtaired ante found to: be n-esotrwpt:
property possessed| by erysinitfne seubstants .
5a. COONHy 9 ee. ane known a =
4 > cathe on_heating fg melts * hell to wma
Sich dh Eo
~
=Gke nefnactive dex,
etc: are Yound to be diff" i aiff”
thesetturebsel Lic cute catlecl Uiopiiol crystals
i & found that the molecules of o licpsicl
that of a Orystallatice
rohayo Uke rine opts = I
0.3, hawe the property to Flan » x1n__ place of
Tiipid orysal_contain othr names has. leeen _proposect
Such a1 0-%otropic (quik on >= crystal The best name
for tt State is mesomonphic state ext_Intexmecliatzon bie)
» io uy 5 }
a© Nematie « Kouicl crystal * inoue
Notecules have Long ames tek. awe nat. #r layers fe
the conires cue “orcientedl neanalpmnly« ttle _ Molecute s Can
Slide pass each athert: jn £
© a name es Snettice. Lqiiol omystat ~ Molecules
haven't only tong aes likel but arte also Asetanger| 2,
) layers + Molecules reemaiin tn their. can» place ahi
plone _sifde pass ach! other 9258 ne,
D. Sereaticn Vould coypstgl te ea et
Once cnet te mendes ex ooky have thee ong
‘ aaiis lief to Coch other ut one also. arranged fo. Laiser’s
| sight IiLol molecules “wi planes can slp pasted [Link] ‘athe,
m_ the
j The fame‘ smaetic” tad
D qi Soap’ as n ike So 100 are
". Bese “oraKe mn eobile
. e the io
ptt oto las wetted.
atte feng based upon this prepeny. Rings ustng
ligyh Onyat als ane available cahich Charge Coloursoi person's mad fe with ones gn tempt
" AFe rare ‘Chotestenic’ has been gan © these crystals betauss te
— ane ol clesivaties ‘Chelesterol’ -
—utich on tude
peo yeep
00! ing Nematic Gguid ongtals foram’ pureChelastaryl. —12¢s Senet
cnyjcistako aes
Conystalioe Stic) gi Se
There are 8 tnangition — potats 4 | 2
> A_onystalline _ SOUGE D Ie
ting range € “ ¢
Gquid collect ‘ Sent quid oxystals: fhthis State all trp
motecufes have tat
pe the & Bcc : ae ; ol -eruystal
The _temp* above which be ine Gayl
Cleasting. pn fami Dapeng sen ste requires
6 ; Sane wit be se — ol with reflect
Colo in olesine temps range: n_netent carts. the most imp: appUcaton ot thermography
tn the medical fold, As. specially fa early oletection
ont tumour, Besides onetho [Link] such “°
es & back pain ett “The Basie principle ts thot
ores. prenclucect fn_the' affected skin are ott
alin. Canbier the Physicians use 10 pains
the
Uguid crystals “an the _porttion of body. to. be eruannie
Hig _mothod was _ top_tto \ Now this meted is seple
the tiquick onmptals ane thy! Paik 05
ey the pout to be enanined: The colas thotograrrs
= 60
=
0, Crutile)
ate |
| 4 CT -Fola_ ones) Na804-.10H0
ae Na, By Or !0H20
— 5 CMonnetinic’)
baiiay4 “Awe anes ane unegiiabs} KiCn,07 ,
Trlctinge. fore Mrotined! at an angie [2 Mon@ CuSO4 + 5H.0
c Jothon_than..0: fa
A cael arte ct 4 pGRS ES ea :
5 Length in one plane i -. anves) Ma. _ (2ineiys
es espa hind b.
[Link] making an angte IQR ansaat
wth each other.d th naot CP) *-
ett which has the fattice points of
fenenitive unit cell
Or._ prom n
1S ¥
“the simplest unit Ci
connen&s_ Callen! a simple ot
Zt e_ unit Cel
ithe
t thone %& one _porat at. the Centre of
tt fe a ed fam -tentued * cmtangement on Face -
pl. It clea) clenpted by Ff.pet
|
ts
Te scatiored|_ rtays one. Ructhor “aecaye oy ting
X-roys sengttve am; es a
erated from a_tube § thege axe
5 ri clear ‘cr BRD nosertod
steps ot the fim
— Prees appear an the cithen sae be ht spot
ot the. ae equidigtant _“freom the orystol
bond ape en ks 2, aa ee
fF fracton a tantly of planes -OR= SA Suds, clean Riad
detect 37
cle 2,
e ot regular =n the _avutange me
q
£ U
te (atoms, molecules art fons) con: fuuting
ORTEHOS cute Oo RPEKE Oc
ob Thermaolynamic _ olefect » So, ane Ferma
Lr
kon
Ne No. of defects fot pen om? —
N= No. of sftes per em? of the
W © wWork/ reequiiced! 40 prtocluce’ a afetect
Te Temp™ to kelvin , “Univeral gai conpntDue te crystat_ defects. phypteat. Poona
CBleetrical conoluct®Vi i “ya e
onystal Changes £
& affected ° 2
pes _ fee tS.
Tee a eo :
t atfite point + Tolealicatfon of the rial crystal is obith
ie mation of
fncnen JOA oO c o detect Fi Fs x
psa arma $2_voriinton ‘eam: requlacty rate
{ Se a ee
5 bps c 2a teks 36 AEA, =f “jggmeaimemm
I bon 4 |:ton cecupying tater
e _Ffq- % cleaned that _one-ot _+ve fon
1 5%
in tntertitieial £pa0e - thon
n
ral §
“ detects ate obsewed in ZnS ,AgCl & A
reat
rn hor Smaller size & ft adjust
messingTa ka detect whith malin 1 artes hich som
, a ese such ae
i . prents
the latte pont One i
awtol wen. the lattice Vacancie,
which are wn
or gholes “The =i = rete:
eg = oh a de
where calistance OB =4 fs —_ ; 6 om :
gf we fon & othe § > mics no
lattice - .
- It 8. also fo Heory