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Solid State

The document discusses the properties and classifications of solids, specifically crystalline and amorphous solids, including their geometric arrangements and melting points. It also covers the concepts of isotropy and anisotropy in solids, as well as the diffraction of X-rays through crystal structures. Additionally, it touches on the behavior of molecules in different states and the significance of various properties in determining the characteristics of solid materials.
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0% found this document useful (0 votes)
7 views30 pages

Solid State

The document discusses the properties and classifications of solids, specifically crystalline and amorphous solids, including their geometric arrangements and melting points. It also covers the concepts of isotropy and anisotropy in solids, as well as the diffraction of X-rays through crystal structures. Additionally, it touches on the behavior of molecules in different states and the significance of various properties in determining the characteristics of solid materials.
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
Available Formats
Download as PDF or read online on Scribd
lid state jalline _ Solfol DA substance which constituents|() A substance ane anranged Tan orale mamer th accefnite geometric poert % called o. y frronphous sotiol which constituents ye f 3 talline _soliol Kaw a. céfe HONGO g lof ein doesn't J = i to Wh tnotense fn_temp to 0 i ) pleculen Solid Froneoses J relocules beats % fefon They hone riototiond mption as emell_4 Changes inte _ “Ws fs called Meltfog point Fs SA crystaliine solid Powe c Shaep melting Paint Fe Chane, abriucted to Mh State + i Amorphous meso howe o shen pasate pone - Teotreepy 4 Aniootttopyy$ pei > Amerephous. substances nesserble Lauil Such aS decttiicey conductiity » Normal conductivity + mechanical strength & wefeockve focleae ane same in alt — substorces ay, Fsotropic fn naikkene. > oyu solids ate anisotropic te. eee = Propenties ATT. th ATES din’s. oe : -) Th velocity} ot bight passin though _ Crystal varies sith dit? fo which tt Sgt measune - Thus, & of Gight ing such sto: ee pik up. Anta 2 Follnaing o diff! sets bsksan oy Stn as olla cutting § molecules axe _anrangeo| ‘| aay 4 disonolentyy manne: Soy fll_ the oes Solan din’ a: £ wee aa oN # ; @ cs oct eS Bera. ss é cnuystaltine Solil hese appeid to. shaw ealgedl kent giv a clean clevage cia en aR Andy Frereeqsloue ee —— ja CCU eI phe ore () Tonic cones + Tr trese crystals the constituent particle occupied tactic Fors are sve & VO TONS, tn case of Nach crys stal- fau- Not § cl fon ~ “These Tons. axe hold! together by strong electrostatic Force “of attraction . electrostatic Forces endst? ingot ® ons, 2 Because of Stra, they have a Melting 4 B-P -— Sey oe 9 fs) corancisaf- lechlcy *0 mater state on “0 the’ aq. ae all =. > But ant 70 crystal ng atate ohate the % tree. ons arte not «Free to _move are Soluble in polar ee te i | pea Sr Picci 4 ect st “once | ‘ Prtppertier Eexomn ple = i 1 fice toate ttt Nach KN , UF, Bas, Solid carton do otide, CHy , Wan, ad. adtu “aoe popere 4 ¢ ysolegiadl “fe brandh‘of_sdlence clealy ecith the stucty of sometitic, preoporctics § st" of cuystals 4 cnystattine Substann ¥ woe etaligrpt ies upon 3 Rundairrental laws, ol mange é depends ee yThe daw oF eee of mae a) = a ‘of todloces _ 1 i “Intedagal_ angle ae aint fs, el ate calle ntorfercfol is ' “capa of stad af a pandhia os € | of substancliy axe obtatrect re the bi jo| ot. S0l)-o%. that « REESE Bye vee ‘ Keo A_eube eotate h_ ay Pboute are tone ae pag things the _ Contos st top &_ nag Appeanance « after SS ts Sindlon E —t Mie ogee ae pha j aa x Te aera antes fratspes “ok pls) of o ? FP enyptal. ole. the qi O10. cithor ! -dhole ic — Condtdon 3 code ork, 4.07 now | hee ABC fs a unit. plone . i ‘ _ Peconding to abow law bmn ane a whole no abc “one fntertcepts atone May iz Onl =: = i ee f constancy da umes The la ctates that the crystals od the same substance ipso [Link] ot Syrometny ire total a0: ot planes » Une contre A Syenmeinyy possess = patna Scale [Link] Spence ae ~gphetsteaoo 8 sledgnati cyl. plane 8 ase 2 Seis licen = ig 2 : ba. face rakes. coher ‘([Link] snc onc _.coeiticont_ oA En (Lm) cute _ ‘pallea " Woles tnolicess.. — 2h tis_motnd, the plane. ane described by as L mietieop Chotk,L) Millet Indices the MT the plore cto. 69 ane. reciprncal. ct Aractiond eo ee onthe various cogs. _ 2 Peat alle. epnesenting yall the_planes_teenespis( Re theft mrechproomD » Solye' Hi clean Axoblton to obtain hy kk. PY Pat hy KL volues wotthout commas tn Bracket. sh Hg-h, the Sntercopt met ct Face ctoan traction 1312 [Link] recF procol i we ge a ane, mfller Inctites ot the Face Kilby, hae Bd By) i it te ME ll be 6: Conia te Shaka cae & | tnponcept (1 1,4-) ‘ A) oe Ht pba ftw Iie Toba) nt off 2 ge De as pa =3 MDs (8, 2y3)i- wow al t Seay sigan. element, 3, Symmpty .Opseaton = a Ssy “AIOE 8.0. geomet cat entity. auch as 0 nt, O Line. ape Ort which one ort morte symmetry. + PO SH q Oe rein cs Carnie out + A cmp. $ to hove a plone ot fae Con, “ame be ciied_0 by on foarte ot _cohich fs the. Sancti his reel — go! ‘s_ _eprresenteo| ge avi ee _ pany tine. naan ty r Such that — busin m _rutation ot the _orystal_thapugh 260° The. cnystal acy Same i e mpre than one» _=|#__sivilan _appeonance NCE Ocouts tWice fn One revolution 4 aD It bieyer Thoo_ Fotol_aads Foun Fol cuiis syevretny q SS es a8 Ty aso ony. port on the Conte ot the. Crystal go that ple tary thrpugh tt cub the face a the opposite side Into equal ollstance ®s _ called centre t te colled by ® untt colt. ts collal by 2 unlt cert. ts no mone unit cell . Each’ point present on te sn Foch point paesont on the fac he ie pa it the itedort fu for seule, Norge oe ) cee S, Ne froret ‘on hocly Conte Cube , dl : Nerd Need Mtel So 2 - for face center cubv, “ Neorg Ne -6 : Nie > So,N=4 Xe 1tay ie ns 4 ~> Mom Von Laue % 1912 ted) that it ts Possible to cbiffnact means of stols Crystals arte made up ot Layers Fa a in ‘apie toshion’. 7 ‘The diffraction ot X- due 10 that the k of X- nay $% OF game ondlen as ‘%ntenotemic distances : ina crayytoly \ ~> Based on the Property ot aPtinaction oF. %-Kay the st" cruital hasbeen - olekoremineo boy vordous method . Sa os 5 the | Praga! i 4 According to ‘Braga's loun.-vahen the. Xonay alls on tte erystok Falls Aicryytat Bs Compared Sally platen! atomic plate) + | they peremate into the enyttal 8, stidve the atoms in + plane: ftom each of these planes X-naye ane reflec bel Based 7 ‘this an 09”, ‘qliog the notation bet” waeley | | stance (d) bet” 2 sucressive planes. Angi of Inciclence (6) Was derived. “This nelation was Bragg’s eg". Lo OAS EN+NM Since the AdLM4 AONM ane conguusnt Lo Hence LN= NIM te no = + . : . : set 64” chon wohole nd.‘ _the - aa rae Olt" ‘ol’ G5 Kd rf : oS spaeiae ae ns -_ ce 4! te Finect by sing i Xo by motatis the is change tubo T Ve passed though team if obtainay that ig allowed Ce Tg allowed to Strike a whieh is. mounted on the tw — table. the a. to fnctense in. egal ange: Bean scr. ah athe _crtytal = Zeulon 1 fate thee re ‘bea coe “6 values cohich Fon o | sabi fnd= ad st) 3 fn which _thtonity will be. mao. rs — creates with *nctease to. vole ot n_by brody nsd& 8 .We can _/ caleulate distance bet” s Successive = Fan Fy iy, Bg ee =the fecHleotfon occur 8 0n nly dos “| nel, This 7 catted 18t onclon reflection . Similarky, fox nent hfaher angle ‘for 2° onden_neHlection (ne2)__ Gi - tn cote ot N Noch, 18 Order etlectinn toa 3 fates C10), Cia), aol Sees tec me ° 9-906 0.705 ° 1.14 “These rtattos Suggest that ?n Nacl the tom oust he “annanged in Yace cents! Oubi'e Lattice , PY ‘in case of Nact, the angle of Plas tatlctton bine (1.00) plane z 6.9", What Ts wavolonyth ? Ans Peon ‘Breagg’s aq), We [now that i NA = Bal Bind: hes DIX AS ANYBWK 1O8 x Sih 5.4" > Awa Bota Qin case of Nats: the angle: ot “$8 onclon_acHectfon Ke (1.00) , (41410)8 Ch44) Faces using. sono chrtpmatic eras. One 6-97.84 ane hat fe Bema of (Natl? taxed ¥-t¢ axe farther detected - by’ using xeray,_soreittve Fes X= nays ane ta Cl tbe ‘gnh these arte mace t© fall. on a monochtomat'c cruyst abl ~~ 4p got. monpchen matic. beam. “The “beam fs nen passed h asift 3 trade incictent sj -[Link] powder. Filed tno. thin -woll. glass capillary i . “Spue_t0_eftection “ram vardous Lattice “plane, af Hractfon i __ mandir. _arise. that _cliffracton can be phatographec! on fe the tun» sa ee ee eee. 2 Sirce the _poadter sumplo consist of clon crystal ararqa $9 all possible orfgertation “ 2 fon i és nok _necess 7 2The:_atffnacted ye rays from epncete “cones Oniginate bee on Sure Sp a ; so. single onnlen ct offffnaction eo. “fasniLiou BS Groeten that a. imonne ie | aoe U Wavelength N 8a Saddent ona. ae -? es _upit = nar jan)’ <|_wWhich can be connected inte degaee Jo x 130 ‘ By applytog Boggs of PY OPPYNA ee Skereanys | toGde Monochrnmatte with A> L64 A’ unwe Ne Oy . a pest “the distance thom capiltart to ‘fay, way MAYS trace all pate (S) tos Locate at o dfisnaes — cm. Cabeulate 12 which orem thos. oe sae: : Ley ca Sea ce a 600. A an ob ey “eomparrds th ( (acetate CCH3¢ eat) 2 _Gotasoyl bore can Cam CysHus )-4 Prazyiyanisole ~ Fdtp-<@)-Kan oon, ") — (oxo —o pt= N=Ca)-0GH) , Bid) ti | ich. turtherc e Upiaas eat en tong e ie eas Cage." pola 7h eDhoreer the. lattert 4: pele ok Eon = Pedro angsole _ ee —— - Ghangitton point ts 28K 4. Mei pote’ Ygok) =O pull tte Cleon tiqsdC melt)» the ceveroe clon if j takes place Place. Exactly at the same tempt the turbid Liquid thus chtaired ante found to: be n-esotrwpt: property possessed| by erysinitfne seubstants . 5a. COONHy 9 ee. ane known a = 4 > cathe on_heating fg melts * hell to wma Sich dh Eo ~ = Gke nefnactive dex, etc: are Yound to be diff" i aiff” thesetturebsel Lic cute catlecl Uiopiiol crystals i & found that the molecules of o licpsicl that of a Orystallatice rohayo Uke rine opts = I 0.3, hawe the property to Flan » x1n__ place of Tiipid orysal_contain othr names has. leeen _proposect Such a1 0-%otropic (quik on >= crystal The best name for tt State is mesomonphic state ext_Intexmecliatzon bie) » io uy 5 } a © Nematie « Kouicl crystal * inoue Notecules have Long ames tek. awe nat. #r layers fe the conires cue “orcientedl neanalpmnly« ttle _ Molecute s Can Slide pass each athert: jn £ © a name es Snettice. Lqiiol omystat ~ Molecules haven't only tong aes likel but arte also Asetanger| 2, ) layers + Molecules reemaiin tn their. can» place ahi plone _sifde pass ach! other 9258 ne, D. Sereaticn Vould coypstgl te ea et Once cnet te mendes ex ooky have thee ong ‘ aaiis lief to Coch other ut one also. arranged fo. Laiser’s | sight IiLol molecules “wi planes can slp pasted [Link] ‘athe, m_ the j The fame‘ smaetic” tad D qi Soap’ as n ike So 100 are ". Bese “oraKe mn eobile . e the io ptt oto las wetted. atte feng based upon this prepeny. Rings ustng ligyh Onyat als ane available cahich Charge Colours oi person's mad fe with ones gn tempt " AFe rare ‘Chotestenic’ has been gan © these crystals betauss te — ane ol clesivaties ‘Chelesterol’ - —utich on tude peo yeep 00! ing Nematic Gguid ongtals foram’ pure Chelastaryl. —12¢s Senet cnyjcistako aes Conystalioe Stic) gi Se There are 8 tnangition — potats 4 | 2 > A_onystalline _ SOUGE D Ie ting range € “ ¢ Gquid collect ‘ Sent quid oxystals: fhthis State all trp motecufes have tat pe the & Bcc : ae ; ol -eruystal The _temp* above which be ine Gayl Cleasting. pn fami Dapeng sen ste requires 6 ; Sane wit be se — ol with reflect Colo in olesine temps range : n_netent carts. the most imp: appUcaton ot thermography tn the medical fold, As. specially fa early oletection ont tumour, Besides onetho [Link] such “° es & back pain ett “The Basie principle ts thot ores. prenclucect fn_the' affected skin are ott alin. Canbier the Physicians use 10 pains the Uguid crystals “an the _porttion of body. to. be eruannie Hig _mothod was _ top_tto \ Now this meted is seple the tiquick onmptals ane thy! Paik 05 ey the pout to be enanined: The colas thotograrrs = 60 = 0, Crutile) ate | | 4 CT -Fola_ ones) Na804-.10H0 ae Na, By Or !0H20 — 5 CMonnetinic’) baiiay 4 “Awe anes ane unegiiabs} KiCn,07 , Trlctinge. fore Mrotined! at an angie [2 Mon@ CuSO4 + 5H.0 c Jothon_than..0: fa A cael arte ct 4 pGRS ES ea : 5 Length in one plane i -. anves) Ma. _ (2ineiys es espa hind b. [Link] making an angte IQR ansaat wth each other.d th na ot CP) *- ett which has the fattice points of fenenitive unit cell Or._ prom n 1S ¥ “the simplest unit Ci connen&s_ Callen! a simple ot Zt e_ unit Cel ithe t thone %& one _porat at. the Centre of tt fe a ed fam -tentued * cmtangement on Face - pl. It clea) clenpted by Ff. pet | ts Te scatiored|_ rtays one. Ructhor “aecaye oy ting X-roys sengttve am; es a erated from a_tube § thege axe 5 ri clear ‘cr BRD nosertod steps ot the fim — Prees appear an the cithen sae be ht spot ot the. ae equidigtant _“freom the orystol bond ape en ks 2, aa ee fF fracton a tantly of planes - OR= SA Suds, clean Riad detect 37 cle 2, e ot regular =n the _avutange me q £ U te (atoms, molecules art fons) con: fuuting ORTEHOS cute Oo RPEKE Oc ob Thermaolynamic _ olefect » So, ane Ferma Lr kon Ne No. of defects fot pen om? — N= No. of sftes per em? of the W © wWork/ reequiiced! 40 prtocluce’ a afetect Te Temp™ to kelvin , “Univeral gai conpnt Due te crystat_ defects. phypteat. Poona CBleetrical conoluct®Vi i “ya e onystal Changes £ & affected ° 2 pes _ fee tS. Tee a eo : t atfite point + Tolealicatfon of the rial crystal is obith ie mation of fncnen JOA oO c o detect Fi Fs x psa arma $2_voriinton ‘eam: requlacty rate { Se a ee 5 bps c 2a teks 36 AEA, =f “jggmeaimemm I bon 4 |: ton cecupying tater e _Ffq- % cleaned that _one-ot _+ve fon 1 5% in tntertitieial £pa0e - thon n ral § “ detects ate obsewed in ZnS ,AgCl & A reat rn hor Smaller size & ft adjust messing Ta ka detect whith malin 1 artes hich som , a ese such ae i . prents the latte pont One i awtol wen. the lattice Vacancie, which are wn or gholes “The =i = rete: eg = oh a de where calistance OB =4 fs —_ ; 6 om : gf we fon & othe § > mics no lattice - . - It 8. also fo Heory

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