Unit-20 NEET/JEE

Principles related to practical chemistry

Detection of elements a) Carboxylic acids liberates CO2 gas from

NaHCO3 solution.
1) Sodium nitroprusside Na2[Fe(CN)5NO] is used b) The produce smell of esters when heated with
as reagent for detection of……..and the compound alcohol in presence of conc. H2SO4
formed is……. c) Both (a) and (b)
a) Sulphur, Na2[Fe(CN)5NOS] d) Iodoform test.
b) Nitrogen, Na4[Fe(CN)6]
c) Sulphur, Na2[Fe(CN)4NOS] 9) Phenol and benzoic acid can be separated by
d) Sulphur, Na2[Fe(CN)5NOS] a) NaHCO3 b) NaOH solution
c) FeCl3 solution d) all of these
2) The Prussian blue colouration obtained in the
test for nitrogen in the organic compound is 10) Fehling solution can be used to make
a) K4[Fe(CN)6] b) Fe4[Fe(CN)6]3 distinction between
c) Fe[Fe(CN)6] d) Fe3[Fe(CN)6]2 a) CH3CHO and C6H5CHO
b) C6H5CHO and C6H5CH2OH
3) Which of the following will give blood red c) HCOOH and CH3CHO
colour with FeCl3 in sodium extract (Lassaigne’s d) HCOOH and HCHO
extract)
a) NH2CONH2 b) NH2CSNH2 11) Reagent than can be distinguished a set of
c) C6H5NHNH2 d) CH3CN benzaldehyde and acetophenone is
a) Iodine and NaOH b) Tollen’s reagent
4) An organic compound contains C, H, N, S and c) Lucas test d) Both (1) and (2)
Cl. For the detection of chlorine, the sodium
extract of the compound is first heated with a few 12) Which of the following compounds can be
drops of conc. HNO3 and then AgNO3 is added to detected using neutral FeCl3 solution
get a white precipitate of AgCl. The digestion with a) CH3COCH2COOCH3 b) CH3COCOCH3
HNO3 before the addition of AgNO3 is to c) H3C-C6H4-CH2OH d) CH3CHOHC6H5
a) Prevent the formation of NO2
b) Create a common ion effect 13) An organic compound X is oxidized by using
c) converts CN– and S2– to volatile HCN and H2S acidified K2Cr2O7. The product obtained reacts
or else they will interfere with the test forming with phenyl hydrazine but does not answer silver
precipitate of AgCN and Ag2S mirror test. The possible structure of X is
d) Prevent the hydrolysis of NaCN and Na2S a) CH3CH2OH b) CH3COCH3
c) (CH3)2CHOH d) CH3CHO
Detection of Functional groups
5) Primary amines on treatment with excess of 14) Iodoform test is not given by
NaNO2, concentrated HCl and  Naphthol in a) 2-Pentanone b) Acetone
alkaline medium gives c) Ethanol d) 3-Pentanone
a) green colour b) orange colour
c) violet colour d) red colour 15) Benzaldehyde and acetone can be best
distinguished using
6) Acetaldehyde when heated with ammonical a) Fehling’s solution
silver nitrate solution gives b) Sodium hydroxide solution
a) red ppt b) silver mirror c) 2,4-DNP d) Tollen’s reagent
c) red colour d) grey colour
16) Which of the following organic compounds
7) The distinguish test between alcohol and phenol will give white precipitate with aqueous AgNO3 ?
is a) C6H5NH3+Cl- b) Butyl chloride
a) bicarbonate test b) neutral FeCl3 test c) 4-nitrochlorobenzene d) Benzyl chloride
c) sodium nitroprusside test d) red colour
17) HCOOH and HCHO may be distinguished by
8) Which of the following observations is correct a) Tollen’s reagent b) Sodium bicarbonate
and is used in the identification of carboxylic acid? c) NaOH solution d) Benedict’s solution

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Unit-20 NEET/JEE
18) Which of the following will evolve CO2 on a) crystallization b) fractional crystallization
reaction with NaHCO3? c) purification d) evaporation
a) Salicylic acid b) Picric acid
c) Benzoic acid d) All of these 27) The cooling of concentrated solution of F.A.S.
is always done slowly
19) Observe the following compound and select a) To get good colour b) to get shining crystals
+ve and -ve test respectively c) to get good yield d) to get minimum crystal

28) Why should we avoid prolong heating while

preparing crystals of ferrous ammonium sulphate?
a) To increase the solubility of the compound
b) To prevent oxidation of ferrous ions
c) To remove impurities from the compound
a) +,+,+ - b) +,+,+,+ c) +, - , +, - d) +, -, - , + d) Too speed up the crystallization process

20) Which of the following statements is incorrect 29) Which of the following best describes the
a) Phenol gives positive bromine water test nature of Mohr’s salt
b) Aniline gives foul smelling compound on a) Coordination compounds b) Double salts
reaction with CHCl3 + KOH c) simple ionic compound
c) Formic acid gives positive Tollen’s test d) simple covalent compound
d) Nitrobenzene gives positive Tollen’s test
30) The correct formula of Mohr’s salt is
21) Column I and column II and choose the a) 2KAl(SO4)2.12H2O
correct combination from the options given b) K2SO4.Al2(SO4)3.24H2O
c) FeSO4. (NH4)2(SO4)3.6H2O
Column I (F.G.) Column II (Test) d) FeSO4.Na2SO4.12H2O
A Ketonic group (i) Lucas test
B Alcohol group (ii) Neutral FeCl3 test 31) Potash alum and Mohr’s salt both are double
C Phenolic group (iii) Carbyl amine test salts, The ration of water of crystallization in
D Amino group (iv) Sodium nitroprusside potash alum and Mohr’s salt is
a) A (iv) B (i) C (ii) D (iii) a) 1 : 6 b) 6 : 1 c) 1 : 4 d) 4 : 1
b) A (i) B (iv) C (ii) D (iii)
c) A (iv) B (ii) C (i) D (iii) 32) Water of crystallization present in aluminium
d) A (i) B (ii) C (i) D (iii) sulphate are…
a) 24 b) 18 c) 6 d) 1
22) The compound which can reduce Fehling
solution is 33) Shape of potash alum crystal is
a) HCHO b) HCOOH c) CH3CHO d) CH3COOH a) Monoclinic b) octahedral
c) cubic d) hexagonal
preparation of inorganic &organic compounds
23) The mineral acid used in the preparation of 34) Potash alum is
Mohs’s salt is ….. a) Double salt b) coordination complex
a) dil HCl b) conc. HCl c) 3D complex d) inorganic base
c) dil H2SO4 d) conc. H2SO4
35) Dilute sulphuric acid is added during
24) Molar mass of mohr’s salt is … preparation of potash alum to
a) 392 g / mol b) 278 g/ mol c) 132g/ mol d) 3.5 g a) Prevent hydrolysis of aluminium sulphate
b) Prevent hydrolysis of potassium sulphate
25) The shape of ferrous ammonium sulphate c) Prevent oxidation of potassium sulphate
crystal is.. d) Dissolve both the salts K2SO4 and Al2(SO4)3
a) monoclinic b) octahedral c) hexagonal d) cubic
36) The process occurs when crystals of potash
26) Concentration of filtrate leads to formation of alum is heated
pure crystals of Mohr’s salt, the process involved a) burns the crystals b) the crystals melts
is known as c) loose the water of crystallization
d) no change occurs in crystal

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Unit-20 NEET/JEE
37) The functional group present in acetanilide 48) The indicator used in redox titration is
is… a) Phenol phthalein b) methyl orange
a) Oxime b) amide c) amino d) ketone c) methylene blue d) potassium permanganate

38) Preparation of acetanilide is known as 49) Select the titrant used in redox titration
a) acetylation b) ammonolysis a) oxalic acid b) F.A.S c) KMnO4 d) H2SO4
c) alkylation d) peptide formation
50) The oxidation state of Mn in KMnO4 in redox
39) Acetylation with CH3COCl is usually carried titration before titration is +7, the oxidation state
out in the presence of of Mn after completion of titration is….
a) Benzene b) Pyridine a) +2 b) +3 c) +4 d) +7
c) KOH d) Cu at 573 K
51) The oxidation state of iron in Mohr’s salt is +2,
40) The colour of acetanilide crystals is….. the oxidation state of iron after completion of
a) White b) blue c) yellow d) red titration is
a) +1 b) +2 c) +3 d) +4
41) During preparation of acetanilide, replacement
of hydrogen of aniline takes place by…. 52) The role of Mn2+ ion during oxidation
a) hydrogen atom b) acetyl group reduction titration of KMnO4 by oxalic acid is..
c) amino group d) carboxylic acid a) indicator b) reductant c) oxidant d) reactant

42) Shape of acetanilide crystals is 53) What is the pH range of phenolphthalein

a) triclinic b) monoclinic indicator is
c) needle shaped d) tetragonal a) 3.2 – 4.5 b) 8.3 – 10.5 c) 6.0 – 7.0 d) 4 - 5

43) In the preparation of p-nitroacetanilide from 54) Methyl orange indicator is a

nitration of acetanilide, the electrophile which a) Weak organic base indicator
attacks the benzene ring is b) weak organic acid indicator
a) NO3+ b) NO+ c) NO2+ d) NO2+ c) weak inorganic acid indicator
d) Perfectly neutral indicator
Chemistry involved in the titration
55) In the redox titration of Mohr’s salt versus
44) To prepare 1M solution of oxalic acid KMnO4, the change in oxidation number of
a) 126 g of oxalic acid dissolves in distilled water manganese is from
and diluted to 1 L. a) +2 to +5 b) +7 to +2 c) +7 to +5 d) +2 to +3
b) 12.6 g of oxalic acid dissolves in distilled water
and diluted to 1 L. 56) 10 ml of 0.1 MHCl is titrated with 0.1 M
c) 1.26 g of oxalic acid dissolves in distilled water NaOH. When the volume of NaOH added from
and diluted to 1 L. the burette is from 9.99 to 10.01 ml, the pH of the
d) 0.126 g of oxalic acid dissolves in distilled solution jumps approximately from
water and diluted to 1 L. a) 4 to 10 b) 6 to 8 c) 6.9 to 7.1 d) 1 to 14

45) water of crystallization present in oxalic acid 57) In oxalic acid versus KMnO4 titration acidified
is /are oxalic acid solution is
a) 1 b)2 c) 3 d) 5 a) taken at 0oC b) taken as 25oC
c) taken at very hot conditions
46) Oxalic acid is used to prepare standard d) take at sub zero temperature.
solution because it is a …
a) substance b) primary standard substance 58) Given below are few statements regarding
c) secondary standard substance titration of KMnO4 solution against 00.1M
d) tertiary standard substance standard solution of oxalic acid
P) potassium permanganate acts as a powerful
47) The quantity of oxalic acid required to prepare oxidizing agent.
100 ml of 0.1M standard solution of oxalic acid Q) The oxidizing action of KMnO4 in the acidic
a) 126g b) 12.6 g c) 1.26 g d) 0.126 g medium can be represented by the following
equations: MnO4- + 8H+ + 5e → Mn2+ + 4H2O

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Unit-20 NEET/JEE
R) The acid used in titration is dilute sulphuric a) [Fe(H2O)6]2+ b) Na2[Fe(CN)5NO]
acid c) [Fe(H2O)5NO]2+ d) [Fe(H2O)(NO)5]2+
S) Nitric acid is not used as it is itself an oxidizing
agent and hydrochloric acid is usually avoided 69) When CCl4 layer containing I2 is shaken with
because it reacts with KMnO4 excess Cl2 + H2O, the violet disappears due to the
T) MnO4– is reduced to Mn2+ and C2O42– is formation of
oxidized to CO2. The oxidation number of carbon a) I3– b) IO3– c) ICl2– d) I–
in C2O42– changes from +3 to +4.
The correct statements among the above are 70) (A) + KMnO4 + H2SO4   colour less
a) P,Q and T only b) P,Q,R and T only solution. (A) may be
c) P, Q, R and S only d) P,Q,R, S and T a) SO32– b) S2– c) NO3– d) All of these

59) How many grams of KMnO4 are contained in 71) X + H2SO4   a colourless gas with
4 litre of 0.05N solution when KMnO4 is to be
irritating smell
used as an oxidant in acidic medium.
Y + K2Cr2O7 + H2SO4   Green colour
a) 1.58 g b) 15.8 g c) 6.32 g d) 31.6 g
solution, X and Y are
60) To an acid solution of an anion, a few drops of a) SO32-, SO2 b) Br- , Br2 c) S2-, H2S d) CO32-, CO2
KMnO4 solution are added. Which of the
following if present will not decolourise the 72) NaI + Cl(H2O) + CS2 
KMnO4 solution? a) purple b) orange brown c) yellow d) green
a) NO2– b) S2– c) Cl– d) CO32–
73) Find total no. of radicals which produce gas or
Qualitative salt Analysis vapours with dil H2SO4
C2O42–,Br–, NO2–, CO32–, S2–, PO42–, SO42–,HCO3–
61) The anion does not give positive test with dil. a) 4 b) 3 c) 2 d) 5
H2SO4 and conc. H2SO4
a) Cl– b) CO32– c) CH3COO– d) SO42– 74) Brown ring test is made for
a) NO3– b) Cl– c) I– d) Br–
62) When moisten oxalic acid is taken between the
fingers, it smell like vinegar, indicates the 75) Which of the following salts will produce a
presence of following anion gas on reaction with conc. H2SO4 ?
a) sulphates b) nitrates c) acetate d) nitrite a) ZnSO4 b) barium phosphate
c) magnesium borate d) sodium iodide
63) Canary yellow ppt of ammonium phospho
molybdate indicates the presence of …..radicals 76) Which of the following radicals produce a
a) Cl– b) SO42– c) PO43– d) NO3– reddish brown gas on reaction with conc. H2SO4
a) Br– b) CO32– c) NO2– d) I–
64) Smell of rotten eggs of a substance with dil
H2SO4 indicated the presence of ………radicals 77) An aqueous solution of a sodium salt having
a) SO32– b) SO42– c) S2– d) C2O42– anion Xn– gave the following results
K 2 Cr2 O7 /H +
Xn–   Green solution + Gas
65) Br2 vapours turn starch paper Pb(NO3 )2
Gas   Black ppt, Xn– is
a) violet b) yellow c) Blue d) red
a) I–
b) NO2– c) S2– d) SO42–
66) A mixture on heating with conc. H2SO4 and
78) Which reagent is used to remove SO42– & Cl–?
MnO2 liberates violet vapours of
a) NaOH b) Pb(NO3)2 c) BaSO4 d) KOH
a) Br2 b) NO2 c) HBr d) I2
79) Which of the following reaction(s) gives(s)
67) A white solid is first heated with dil H2SO4
coloured gases?
and then conc. H2SO4. No action was observed in Heat
either case. The solid salt contains a) K2Cr2O7 + KCl + H2SO4(conc)  
Heat
a) S2– b) SO32– c) SO42– d) S2O32– b) I + H2SO4(conc) 
–

Heat
c) NO3 + H2SO4(conc) 
–

68) The brown ring test for NO2– and NO3– is due d) All of these
to the formation of complex ion with formula

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Unit-20 NEET/JEE
80) A white sodium salt dissolves readily in water lead acetate paper black
to give a solution which is neutral to litmus. When B S 2–
(ii) Colourless gas which turns
a silver nitrate solution is added to the solution, a acidified potassium
white precipitate is obtained which doesnot dichromate solution green
dissolve in dil HNO3. The anion could be C SO32– (iii) Brown gas which turns
a) CO32– b) Cl– c) SO42– d) S2– acidified KI solution
containing starch blue
81) A salt gives effervescence with dil H2SO4. D NO2– (iv) Colourless gas evolved with
The gas released gives white turbidity with lime brisk effervescence, which
water which slowly disappears on prolonged turns lime water milky
passage. The anion radical present in salt is a) A (iii) B (i) C (ii) D (iv)
a) NO2– b) CO32– c) S2– d) NO3– b) A (i) B (i) C (iv) D (iii)
c) A (iv) B (i) C (iii) D (i)
82) Which of the following statements is / are d) A (i) B (i) C (ii) D (iii)
incorrect when a mixture of NaCl and K2Cr2O7 is
gently warmed with conc. H2SO4 88) Which of the following are the tests for
a) A deep red vapour is evolved sulphate ion?
b) The vapour when passed into NaOH solution a) Potassium dichromate test
gives a yellow solution of Na2CrO4. b) Barium chloride and silver nitrate test
c) Chlorine gas is evolved a) Potassium dichromate test
d) Chromyl chloride is formed
89) During the presence of SO32- and S2- in a
83) A gas ‘X’ is passed through water to form a mixture, with addition of dil. H2SO4, one notice
saturated solution. The aqueous solution on that
treatment with silver nitrate solution gives a white a) SO2 and H2S are not formed
precipitate. The saturated aqueous solution also b) SO2 and H2S formed undergo a redox change
dissolves magnesium ribbon with evolution of forming colloidal solution and thus, no smell
colourless gas ‘Y’. Identify ‘X’ and ‘Y’ emanates
a) X = CO2, Y = Cl2 b) X = Cl2, Y = CO2 c) A smell of rotten egg
c) X = Cl2, Y = H2 d) X = H2, Y = Cl2 d) A smell of burning sulphur

84) A solution of colourless salt A on boiling with 90) Soda extract is prepared by
excess NaOH produces a non flammable gas. The a) Fusing soda and the mixture in dil. HCl
gas evolution ceases after some times. Upon b) Dissolving NaHCO3 and the mixture in dil. HCl
addition of Zn dust to the solutions, the gas c) Boiling Na2CO3 and the mixture in dil. HCl
evolution restarts. The colourless salt (A) is d) Boiling Na2CO3 and the mixture in distilled
a) NH4NO3 b) CH3COONH4 water
c) NH4Cl d) (NH4)2SO4
91) Which of the following compounds is formed
85) The anion which does not react with dil. when a mixture of K2Cr2O7 and NaCl is heated
H2SO4 is with conc. H2SO4.
a) CO32– b) S– c) NO2– d) NH4+ a) CrO2Cl2 b) CrCl3 c) Cr2(SO4)3 d) Na2CrO4

86) Carbon dioxide turns 92) On addition of a solution A to a strongly

a) Lime water milky and clears it again when CO2 acidified solution of barium nitrate, a white
is in excess precipitate was obtained which donot dissolve
b) To prevent oxidation of ferrous ions even after large addition of water. Solution A
c) To remove impurities from the compound contained
d) To speed up the crystallization process a) Sodium phosphate b) Sodium carbonate
c) Sodium sulphate d) sodium chloride
87) Column I and column II and choose the
correct combination from the options given 93) Mixture is heated with dil H2SO4 and lead
Column Column II (Gas evolved on acetate paper turns black by the evolved gases.
I reaction with dil. H2SO4) The mixture contains
(anion) a) Sulphite b) Sulfide c) sulphate d) thiosulphate
A CO32– (i) Colourless gas which turns

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Unit-20 NEET/JEE
94) When MnO2 and H2SO4 are added to NaCl, a) Copper nitrate b) zinc nitrate
the greenish yellow gas liberated is c) silver nitrate d) lead nitrate
a) Cl2 b) NH3 c) N2 d) H2
107) Which sulphides is/are only soluble in aqua
95) When Cl2 water is added to a salt solution regia
containing chloroform, chloroform layer turns a) NiS b) CoS c) HgS d) all of these
violet. The salt contains
a) Cl– b) I– c) NO3– d) S2– 108) The ion which is not precipitated by H2S in
the presence of HCl is
96) Na2CO3 cannot be used to identify a) Cu2+ b) Ag+ c) Pb2+ d) Al3+
a) CO32– b) SO32– c) S2– d) SO42-
109) Na2CO3 cannot be used in place of
97) Sodium nitroprusside when added to an (NH4)2CO3 for the precipitation of V group
alkaline solution of sulfide ions produces a because
a) Red colour b) Blue colour a) NaI interferes in the detection of V group
c) Purple colour d) Brown colour b) conc. of CO32- is very low
Basic radicals c) Na will react with acid radicals
98) Which one of the following pairs of ions can d) Mg will be precipitated
not be separated by H2S in dil. HCl?
a) Bi3+, Sn4+ b) Al3+, Hg2+ 110) Ca and Ba ions are precipitated in fifth group
c) Zn , Cu
2+ 2+
d) Co2+, Cu2+ as their
a) Oxides b) Sulphates c) Carbonates d) Sulphides
99) Nessler’s reagent is used to detect
a) CrO42- b) MnO4- c) SO42- d) NH4+ 111) When H2S is passed through an ammonical
salt solution X, a white precipitate is obtained.
100) Which is soluble in yellow ammonium Then X can be
sulphide solution a) Co2+ solution b) Mn2+ solution
a) CuS b) Bi2S3 c) As2S3 d) PbS c) Ni solution
2+
d) Zn2+ solution

101) Passing H2S gas into a mixture of Cd2+, Zn2+, 112) In group IV analysis, NH4OH is added before
Ni2+, Hg2+ ions in a acidified solution precipitates passing H2S gas because
a) CdS, HgS b) ZnS, CuS a) The sulphides of IV group are insoluble in
c) CdS, NiS d) NiS, HgS NH4OH
b) The sulphides of other metals are soluble in
102) The colour of carbonate cation precipitate of NH4OH
group V is… c) The concentration of S2- ions is increased
a) Black b) green c) white d) yellow d) The sulphides of second group are soluble in
NH4OH
103) Which of the following is not a preliminary
test 113) Disodium hydrogen phosphates is used to test
a) Charcoal cavity test b) flame test the presence of
c) NaOH test d) brown ring test a) Mg2+ b) Zn2+ c) Ba2+ d) Cu2+

104) The colour of precipitate observed, when 114) Which of the following statements is/are not
potassium iodide is added to water soluble lead true
salts is a) Fe2+(aq) gives brown colour with NH4CNS
a) Black b) white c) yellow d) red b) Fe2+(aq) gives yellow colour or precipitate with
K3[Fe(CN)6]
105) Which of the following sulphides is c) Fe3+(aq) gives brown colour with K4[Fe(CN)6]
completely precipitated in acidic medium d) All of these
a) HgS b) PbS c) CdS d) CuS
115) An aqueous solution contains Zn(CH3COO)2
106) A colourless solid ‘A’ produces black spots and Cu(CH3COO)2. On passing H2S gas there is a
on the skin. It’s aqueous solution gives brown precipitation of ……as sulphides
ring test and also gives yellow ppt. with KI a) Only Zn2+ b) Only Cu2+
solution ‘A’ could be c) Neither Zn or Cu d) Both Zn2+ and Cu2+

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Unit-20 NEET/JEE
116) Lake test is meant to identify which of the 126) A mixture of NH4Cl, NH4OH and H2S
following ions precipitates the radicals of group IV as their
a) Cr3+ b) Bi3+ c) Sb3+ d) Al3+ a) Chlorides b) Hydroxide c) Sulphides d) None

117) When H2S gas is passed through aqueous 127) When H2S gas is bubbled through a solution
HCl solution containing CuCl2, PbCl2, BiCl3 and of a metal salt in an acidic medium of HCl, no
ZnCl2, then we do not get a precipitate of precipitation takes place. But a white precipitate is
a) CuS b) PbS c) Bi2S3 d) ZnS formed under the same conditions but in weakly
basic medium. The cation present in the metal salt
118) Which of the following compounds does not is possibly
leave any residue on heating ? a) Zn2+ b) As3+ c) Pb2+ d) Cu2+
a) Pb(NO3)2 b) NH4NO3
c) Cu(NO3)2 d) NaNO3 128) A solution acidified with acetic acid is
employed to separate Ca2+ and Ba2+ by use of
119) A mixture of two salts is not soluble in water potassium chromate. Which of the following
but soluble in dilute HCl solution. Mixture can be statements is correct ?
a) NaNO3 and KBr b) BaCO3 and ZnS a) Barium chromate is soluble in acetic acid
c) FeCl3 and CaCO3 d) Mn(NO3)2 and MgSO4 b) Calcium chromate is insoluble in acetic acid
c) Barium chromate is a blue precipitate in acetic
120) Three samples of the same salts are taken acid
separately. Excess of NH4OH gives white d) Calcium chromate is soluble in acetic acid
precipitate with first sample. Second sample gives
white precipitate with NaCl. Third sample gives 129) A white solid (X) produces reddish brown
black precipitate when H2S gas is passed through fumes when warmed with concentrated sulphuric
the solution. Possible salt is acid. Addition of a copper piece of the test tube
a) AgNO3 b) Pb(NO3)2 c) Ca(NO3)2 d) ZnSO4 intensifies the evolution of fumes. The aqueous
solution of (X) produces an yellow precipitate
121) Black sulphides is not formed by (soluble in hoot water) on reaction with potassium
a) Cu2+ b) Zn2+ c) Pb2+ d) Ni2+ iodide. (X) is
a) Lead bromide b) Silver nitrate
122) Which of the following statements is correct c) Copper nitrate d) None of these
with reference to ferric ions?
a) Fe3+ gives brown colour with potassium 130) Column I and column II and choose the
ferricyanide correct combination from the options given
b) Fe3+ gives blue precipitate with potassium Column I Column II
ferrocyanide A Co2+ and Ni2+ (i) Group – II
c) Fe3+ gives yellow colour with potassium B Al and Fe
3+ 3+
(ii) Group – III
thiocyanate C Cu2+ and Cd2+ (iii) Group – V
d) Fe3+ gives white colour with ammonium D Ca2+ and Sr2+ (iv) Group - IV
hydroxide a) A (ii) B (i) C (iii) D (iv)
b) A (i) B (iv) C (ii) D (iii)
123) An aqueous solution of a substance gives c) A (iv) B (ii) C (i) D (iii)
white precipitate on treatment with dilute d) A (i) B (ii) C (iv) D (iii)
hydrochloric acid, which dissolves on heating.
When hydrogen sulfide is passed through the hot 131) The solubility products of Al(OH)3 and
acidic solution, a black precipitate is obtained. The Zn(OH)2 are 8.5 x 10-23 and 1.8 x 10-14
substance is respectively. If NH4OH is added to a solution
a) Hg22+ salt b) Cu2+ salt c) Ag+ salt d) Pb2+ salt containing Al3+ and Zn2+ ions then substance
precipitate first is
124) Lead(II) ions reaction with potassium iodide a) Al(OH)3 b) Zn(OH)2 c) Both d) No ppt.
gives a yellow ppt of
a) PbO b) PbI2 c) PbI4 d) PbCrO4 132) An acidic solution contains Cu2+, Pb2+ and
Zn2+. If H2S(g) is passed through the solution, the
125) K2[HgI4] helps in the detection of precipitate will contain
a) Cu2+ b) Pb2+ c) Mg2+ d) NH4+ a) CuS and ZnS b) PbS and ZnS
c) CuS and PbS d) CuS, PbS and ZnS

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Unit-20 NEET/JEE
133) In quantitative analysis, in order to detect 141) The enthalpy of solution of hydrated
second group basic radicals, H2S gas is passed in copper(I) sulphate can be determined by
the presence of dilute HCl to measuring the temperature changes when a
a) Increase in dissociation of H2S known amount of copper(I) sulphate is added to a
b) Decrease in dissociation of salt solution fixed volume of water in a calorimeter. What
c) Decrease in dissociation of H2S assumption is not made when calculating the
d) Increase in dissociation of salt solution enthalpy change?
a) There is negligible heat loses in the calorimeter
134) A white crystalline substance dissolves in b) The specific heat capacity of the solution is the
water. On passing H2S in this solution, a black same as water
precipitate is obtained. The black precipitate c) The density of solution is the same as water
dissolve completely in hot HNO3. On adding a few d) The specific heat capacity of solution is
drops of conc. H2SO4, a white precipitate is different from water.
obtained. This precipitate is of
a) BaSO4 b) SrSO4 c) PbSO4 d) CuSO4 142) 10 ml of 0.1M HCl is titrated with 0.1M
NaOH. When the volume of NaOH added from
135) For the detection of ammonia in Nesseler’s the burette is from 9.99 to 10 ml, the pH of the
reagent, the active species is solution jumps approximately from
a) Hg2Cl2 b) Mg2+ c) Hg2I2 d) HgI42– a) 4 to 10 b) 6 to 8 c) 6.9 to 7.1 d) 1 to 14

136) Reagent used in the quantitative analysis of 143) The enthalpy of neutralization of a strong
IV group is dibasic acid by a dilute solution of NaOH is
a) HCl b) H2S(alkaline) c) (NH4)2S d) None nearly
a) -27.4 kcal/eq b) 13.7 kcal/eq
137) A mixture containing Cu2+ and Ni2+ can be c) -13.7 kcal/eq d) -13.7 kcal/mol
separated for identification by
a) Passing H2S in acid medium 144) Which of the following statement regarding
b) Passing H2S in alkaline medium the enthalpy of neutralisation of a strong acid
c) Passing H2S in neutral medium (HCl) with a strong base (NaOH) is not true
d) Passing H2S in dry mixture a) A neutralization reaction involves the
combination of H+(aq) ions furnished by an acid
138) How do we differentiate between Fe3+ and and OH-(aq) ions furnished by a base
Cr3+ in qualitative analysis of group III? b) Since the reaction envisages bond formation,
a) By taking excess of NH4OH therefore, this reaction is always endothermic.
b) By increasing NH4+ ion concentration c) If both the acid and the base are strong, then
c) By decreasing OH– ion concentration for the formation of 1 mol H2O(l), always a fixed
d) Both (b) and (c) amount of heat viz 57 kJ mol-1 is liberated.
d) Enthalpy of neutralization is defined as the
139) Passing H2S gas into a mixture Mn2+, Ni2+, amount of heat liberated when 1 mol of H+ ions
Cu2+ and Hg2+ ions in an acidified aqueous furnished by acid combine with 1 mol of OH-
solution precipitate ions furnished by base to form water.
a) CuS and HgS b) MnS and CuS
c) MnS and NiS d) NiS and HgS 145) The heat of neutralization of oxalic acid
-25.4 kcal mol-1 using strong base, NaOH. If heat
140) Which of the following statements regarding of neutralization of strong acid and strong base is
precautions in determining the enthalpy of -13.7kcal mol-1, the the enthalpy change of the
dissolution of copper sulphate experiment is true  2H+ + C2O42-
process. H2C2O4 
a) In determining of calorimeter constant, record a) 2.0 kcal/ mol b) -11.8 kcal/ mol
the temperature of hot water just after mixing c) 1.0 kcal/ mol d) -1.0 kcal/ mol
b) We use very large amounts of copper sulphate
c) We stir the solution vigorously to dissolve the 146) 100 cm3 of 0.1 NH4Cl solution is mixed
solid and record the temperature with 100 cm3 of 0.2 N NaOH solution. The
d) In determining of calorimeter constant, record resulting solution is
the temperature of hot water just before mixing a) 0.1N and the solution is basic
b) 0.05 N and the solution is basic

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Unit-20 NEET/JEE
c) 0.1N and the solution is acidic 154) Select the incorrect statement about
d) 0.05N and the solution is acidic lyophilic sol
a) Egg albumin sol is lyophilic
147) 100 cm3 of 0.5NHCl solution at 299.95K b) Stability of lyophilic sols is primarily due to
were mixed with 100 cm3 0.5 N NaOH solution at the solvation of colloidal particles by the solvent
299.75K in a thermos flask. The initial c) The lyophilic sol can directly formed by
temperature was found to be 302.65K. the mixing and shaking the substance with a suitable
enthalpy of neutralisation of HCl (Given: water liquids
equivalent of neutralisation of thermos flask is d) Ferric hydroxide is not a lyophilic
44g)
a) 36.08 kJ b) 28.50 kJ c) 57.17 kJ d) 48.18 kJ 155) Which of the following is not a method to
prepare colloids
Lyophilic and Lyophobic sols a) Chemical method b) Distillation
148) Arsenious sulphide sol is prepared in the c) Peptization d) Electrical disintegration
laboratory by
a) Peptisation method Principles involved in the experiments
b) Double decomposition method 156) The reaction of acidified KI solution with
c) Reduction method hydrogen peroxide is
d) Oxidation method a) Redox reaction b) a reduction reaction
c) a disproportionation reaction d) hydrolysis
149) Choose the correct statement the following
a) Fe(OH)3 is a lyophilic sol, and is prepared by 157) Regarding the study of effects of variation in
peptisation method concentration of iodide ions on the rate of
b) As2S3 is a lyophobic sol and is prepared by reaction of iodide ions with H2O2 at room
Bredig arc method temperature, the correct statement is
c) Starch sol is lyophobic sol and is prepared by a) The reaction between iodide ions and hydrogen
mechanical dispersion method. peroxide occurs in the acidic medium as
d) Fe(OH)3 sol is a lyophobic sol and is prepared 2I-(aq) + H2O2(l) + 2H+(aq)   I2(g) + 2H2O(l)
by hydrolysis method b) The liberated iodine reacts with thiosulphates
ions as fast as it is formed and is reduced back to
150) Which of the following is a lyophilic sol? iodide ions till all the thiosulphates ions are
a) Egg albumin sol b) Gum sol oxidised to tetrathionate ions
c) Starch sol d) All of these I2(g) + 2S2O32-(aq)   S4O62- + 2I-(aq)
c) After the complete consumption of
151) Which of the following statements is not thiosulphates ions iodine forms intense blue
correct ? complex with starch
a) Lyophilic sols are more stable as compared to d) None of the above
lyophobic sols
b) Two factors responsible for the stability of sols 158) For kinetic study of the reaction iodide ion
are - charge and the solvation of the colloidal with H2O2 at room temperature
particles by the solvent 1) Always use freshly prepared starch solution
c) Stability of lyophilic sols is primarily due to 2) Always keep the concentration of sodium
the solvation of colloidal particles by the solvent thiosulphates solution less than that of KI solution
d) Lyophobic sols are stabilised due to the 3) Record the time immediately after the
solvation of colloidal particles by the solvent appearance of blue colour
4) Record the time immediately before the
152) Which of the following is lyophobic sol appearance of blue colour
a) Ferric hydroxide b) Egg albumin sol 5) Always keep the concentration of sodium
c) Arsenious sulphide d) Aluminium hydroxide thiosulphates solution more than that of KI
solution
153) Lyophilic sols are a) 1, 2, 3 only b) 1, 4, 5 c) 4, 5 d) 1,2 , 5 only
a) Irreversible sols
b) They are prepared from inorganic compounds 159) What is the colour of the complex formed in
c) Coagulated by adding electrolytes kinetic study of the reaction iodide ion with H2O2
d) Self stabilizing a) Red b) White c) Blue d) Yellow

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Unit-20 NEET/JEE
160) What is the purpose of varying the 161) Which ions are completely consumed before
concentration of iodide ions in the reaction with the appearance of intense blue colour in the
hydrogen peroxide at room temperature? reaction between iodide ion and hydrogen
a) To investigate the effect of temperature on the peroxide?
reaction site a) Hydroxide ion b) Starch ion
b) To observe the effect of pH on the reaction site c) Thiosulphate ions d) Hydrogen ions
c) To measure the volume of of oxygen produced
d) To study the effect the concentration on the
reaction rate

ANSWER KEY

1– A 2–B 3–B 4–C 5–B 6–B 7- B 8–C 9–A 10 – A

11–D 12 – A 13 – C 14 – D 15 – D 16 – A 17– B 18– D 19 – A 20 – D
21– A 22 – D 23 – D 24 – A 25 – B 26 - A 27– C 28– B 29–B 30 – C
31–D 32 – A 33 – B 34 – A 35 – A 36 - C 37– B 38– A 39– B 40 – A
41–B 42 – C 43 –C 44 – A 45 – B 46 - B 47– C 48– D 49– C 50 – A
51–C 52 – A 53 –B 54 – B 55 – B 56 - A 57– B 58– D 59– C 60 – D
61– D 62 – C 63 –C 64 – C 65 – B 66 - D 67– C 68– C 69– B 70 – D
71–A 72 – A 73 –A 74 – A 75 – D 76 - A 77– C 78– B 79– D 80 – B
81–B 82 – C 83 –C 84 – A 85 – C 86 - A 87– D 88– D 89– B 90 –D
91–A 92 – C 93 –B 94 – A 95 – B 96 - A 97– C 98– A 99– D 100 - C
101–a 102 – C 103 –D 104 – C 105–C 106 -C 107– C 108– D 109–D 110 -C
111–D 112 – C 113 –A 114 –D 115–D 116 -D 117– D 118–B 119–B 120 -B
121–B 122 – B 123 –D 124 – B 125–D 126-C 127– A 128– D 129–D 130 -C
131–D 132 – C 133 –C 134 –C 135–D 136 - B 137– A 138– C 139–A 140 -D
141–D 142 – A 143 –A 144 – B 145–A 146 - B 147– C 148– B 149–D 150 -D
151–D 152 – B 153 –D 154 – C 155–B 156 - A 157– D 158– A 159–C 160 -D
161–C

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