11th Chemistry Chapter 4 Exercise Structure of Atom

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Structure of Atom Class 11 Exercise Question Answers Solutions

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Balbharti Maharashtra State Board 11th Chemistry Textbook Solutions Chapter 4

Structure of Atom Textbook Exercise Questions and Answers.

Class 11 Chemistry Chapter 4 Exercise Solutions Maharashtra Board

Chemistry Class 11 Chapter 4 Exercise Solutions

1. Choose the correct option.

Question A.
The energy difference between the shells goes on ……….. when moved away from
the nucleus.
a. Increasing
b. decreasing
c. equalizing
d. static
Answer:
b. decreasing

Question B.
The value of Plank’s constant is
a. 6.626× 10-34 Js
b. 6.023× 10-24 Js
c. 1.667 × 10-28 Js
d. 6.626× 10-28 Js
Answer:
a. 6.626× 10-34 Js

Question C.
p-orbitals are ……. in shape.
a. spherical
b. dumb bell
c. double dumb bell
d. diagonal
Answer:
b. dumbbell

Question D.
“No two electrons in the same atoms can have identical set of four quantum
numbers”. This statement is known as
a. Pauli’s exclusion principle
b. Hund’s rule
c. Aufbau rule
d. Heisenberg uncertainty principle
Answer:
a. Pauli’s exclusion principle

Question E.
Principal Quantum number describes
a. shape of orbital
b. size of the orbital
c. spin of electron
d. orientation of in the orbital electron cloud
Answer:
b. size of the orbital

2. Make the pairs:

A B

a. Neutrons i. six electrons

b. p-orbital ii. -1.6 × 10-19 C

charge on
c. iii. Ultraviolet region
electron

d. Lyman series iv. Chadwick

Answer:
a – iv,
b – i,
c – ii,
d – iii
3. Complete the following information about the isotopes in the chart given below :

(Hint: Refer to Periodic Table if required)

Answer:
4. Match the following :

Answer:
a – iv,
b – iii,
c – ii,
d–i

5. Answer in one sentence :

Question A.
If an element ‘X’ has mass number 11 and it has 6 neutrons, then write its
representation.
Answer:
The representation of the given element is 115X .

Question B.
Name the element that shows simplest emission spectrum.
Answer:
The element that shows simplest emission spectrum is hydrogen.

Question C.
State Heisenberg uncertainty principle.
Answer:
Heisenberg uncertainty principle states that “It is impossible to determine
simultaneously, the exact position and exact momentum (or velocity) of an
electron”.
Question D.
Give the names of quantum numbers.
Answer:
The four quantum numbers are: principal quantum number (n), azimuthal or
subsidiary quantum number (l), magnetic quantum number (ml) and electron spin
quantum number (ms).

Question E.
Identify from the following the isoelectronic species:
Ne, O2-, Na+ OR Ar, Cl2-, K+
Answer:
Atoms and ions having the same number of electrons are isoelectronic.

Species No. of electrons

Ne 10

O2- 8 + 2 = 10

Na+ 11 – 1 = 10

Ar 18

Cl2- 17 + 2 = 19

K+ 19 – 1 = 18

Hence, Ne, O2-, Na+ are isoelectronic species.

6. Answer the following questions.

Question A.
Differentiate between Isotopes and Isobars.
Answer:

No. Isotopes Isobars

Isobars are atoms of different

i. Isotopes are atoms of same element.
elements.
 They have same atomic mass
They have same atomic number but
ii. number but different atomic
different atomic mass number.
numbers.

They have same number of protons They have different number of

iii.
but different number of neutrons. protons and neutrons.

They have different number of

iv. They have same number of electrons.
electrons.

They occupy same position in the They occupy different positions in

V.
modem periodic table. the modem periodic table.

They have similar chemical They have different chemical

vi.
properties. properties.

e.g. 126C and 146C 146C and 147 N

Question B.
Define the terms:
i. Isotones
ii. Isoelectronic species
iii. Electronic configuration
Answer:
i. Isotones: Isotones are defined as the atoms of different elements having same
number of neutrons in their nuclei. e.g. 115B and 126C having 6 neutrons each are
isotones.

ii. Isoelectronic species:

soelectronic species are defined as atoms and ions having the same number of
electrons.
e. g. Ar, Ca2+ and K+ containing 18 electrons each.

iii. Electronic configuration:

Electronic configuration of an atom is defined as the distribution of its electrons in
orbitals.

Question C.
State and explain Pauli’s exclusion principle.
Answer:
Pauli’s exclusion principle:
i. Statement: “No two electrons in an atom can have the same set of four quantum
numbers”. OR “Only two electrons can occupy the same orbital and they must have
opposite spins. ”
ii. The capacity of an orbital to accommodate electrons is decided by Pauli’s
exclusion principle.
iii. According to this principle, for an electron belonging to the same orbital, the
spin quantum number must be different since the other three quantum numbers
are the same.
iv. The spin quantum number can have two values: + 12 and – 12 .
v. Example, consider helium (He) atom with electronic configuration 1 s2.
For the two electrons in Is orbital, the four quantum numbers are as follows:
Electron number Quantum number Set of values of quantum numbers

Thus, in an atom, any two electrons can have the same three quantum numbers, but
the fourth quantum number must be different.
vi. This leads to the conclusion that an orbital can accommodate maximum of two
electrons and if it has two electrons, they must have opposite spin.

Question D.
State Hund’s rule of maximum multiplicity with suitable example.
Answer:
Hund’s rule of maximum multiplicity:
i. Statement: “Pairing of electrons in the orbitals belonging to the same subshell
does not occur unless each orbital belonging to that subshell has got one electron
each.”
ii. Example, according to Hund’s rule, each of the three-degenerate p-orbitals must
get one electron of parallel spin before any one of them receives the second electron
of opposite spin. Therefore, the configuration of four electrons occupying p-orbitals
is represented as
iii. As a result of Hund’s rule, the atom with fully filled and half-filled set of
degenerate orbitals has extra stability.

Question E.
Write the drawbacks of Rutherford’s model of an atom.
Answer:
Drawbacks of Rutherford’s model of an atom:
i. Rutherford’s model of an atom resembles the solar system with the nucleus
playing the role of the massive sun and the electrons are lighter planets. Thus,
according to this model, electrons having negative charge revolve in various orbits
around the nucleus. However, the electrons revolving about the nucleus in fixed
orbits pose a problem. Such orbital motion is an accelerated motion accompanied
by a continuous change in the velocity of electron as noticed from the continuously
changing direction. According to Maxwell’s theory of electromagnetic radiation,
accelerated charged particles would emit electromagnetic radiation. Hence, an
electron revolving around the nucleus should continuously emit radiation and lose
equivalent energy. As a result, the orbit would shrink continuously and the electron
would come closer to the nucleus by following a spiral path. It would ultimately fall
into the nucleus. Thus, Rutherford’s model has an intrinsic instability of atom.
However, real atoms are stable.

ii. Rutherford’s model of an atom does not describe the distribution of electrons
around the nucleus and their energies.

Question F.
Write postulates of Bohr’s Theory of hydrogen atom.
Answer:
Postulates of Bohr’s theory of hydrogen atom:
i. The electron in the hydrogen atom can move around the nucleus in one of the
many possible circular paths of fixed radius and energy. These paths are called
orbits, stationary states or allowed energy states. These orbits are arranged
concentrically around the nucleus in an increasing order of energy.

ii. The energy of an electron in the orbit does not change with time. However, the
electron will move from a lower stationary state to a higher stationary state if and
when the required amount of energy is absorbed by the electron. Energy is emitted
when electron moves from a higher stationary state to a lower stationary state. The
energy change does not take place in a continuous manner.

iii. The frequency of radiation absorbed or emitted when transition occurs between
two stationary states that differ in energy by ΔE is given by the following
expression:
ν = ΔEh=E2−E1h ………….(1)
Where E1 and E2 are the energies of the lower and higher allowed energy states
respectively. This expression is commonly known as Bohr’s frequency rule.

iv. The angular momeñtum of an electron in a given stationary state can be

expressed as mvr = n × h/2π
where, n 1,2, 3
Thus, an electron can move only in those orbits for which its angular momentum is
integral multiple of h/2π.
Thus, only certain fixed orbits are allowed.

Question G.
Mention demerits of Bohr’s Atomic model.
Answer:
Demerits of Bohr’s atomic model:

Bohr’s atomic model (theory) failed to account for finer details of the atomic
spectrum of hydrogen as observed in sophisticated spectroscopic experiments.

Bohr’s atomic model (theory) was unable to explain the spectrum of atoms other
than hydrogen.

Bohr’s atomic model (theory) could not explain the splitting of spectral lines in
the presence of a magnetic field (Zeeman effect) or electric field (Stark effect).
Bohr’s atomic model (theory) failed to explain the ability of atoms to form
molecules by chemical bonds.

Question H.
State the order of filling atomic orbitals following Aufbau principle.
Answer:
Aufbau principle:
i. Aufbau principle gives the sequence in which various orbitals are filled with
electrons.
ii. In the ground state of an atom, the orbitals are filled with electrons based on
increasing order of energies of orbitals, Pauli’s exclusion principle and Hund’s rule
of maximum multiplicity.
iii. Increasing order of energies of orbitals:

Orbitals are filled in order of increasing value of (n + l)

In cases where the two orbitals have same value of (n + l), the orbital with lower
value of n is filled first.

iv. The increasing order of energy of different orbitals in a multi-electron atom is:
1s < 2s < 2p < 3s < 3p < 4s < 3d < 4p < 5s < 4d < 5p < 6s < 4f < 5d < 6p < 7s and so on.
Question I.
Explain the anomalous behavior of copper and chromium.
Answer:
i. Copper:

Copper (Cu) has atomic number 29.

Its expected electronic configuration is 1s2 2s2 2p6 3s2 3p6 4s2 3d9.

The 3d orbital is neither half-filled nor fully filled. Hence, it has less stability.

Due to interelectronic repulsion forces, one 4s electron enters into 3d orbital.

This makes 3d orbital completely filled and 4s orbital half-filled which gives
extra stability and the electronic configuration of Cu becomes, 1s2 2s2 2p6 3s2 3p6
4s1 3d10.

ii. Chromium:

Chromium (Cr) has atomic number 24.

Its expected electronic configuration is 1s2 2s2 2p6 3s2 3p6 4s23d4.
The 3d orbital is less stable as it is not half-filled.

Due to inter electronic repulsion forces, one 4s electron enters into 3d orbital.
This makes 4s and 3d orbitals half-filled which gives extra stability and the
electronic configuration of Cr becomes, 1s2 2s2 2p6 3s2 3p6 4s1 3d5.

Question J.
Write orbital notations for electrons in orbitals with the following quantum
numbers.
a. n = 2, l =1
b. n = 4, l = 2
c. n = 3, l = 2
Answer:
i. 2p
ii. 4d
iii. 3d
Question K.
Write electronic configurations of Fe, Fe2+, Fe3+
Answer:

Species Orbital notation

1s2 2s2 2p63s2 3p6 4s2 3d6 OR [Ar] 4s2

Fe
3d6

Fe2+ Is2 2s2 2p6 3s2 3p6 3d6 OR [Ar] 3d6

Fe3+ 1s2 2s2 2p6 3s2 3p6 3d5 OR [Ar] 3d5

Question L.
Write condensed orbital notation of electonic configuration of the following
elements:
a. Lithium (Z = 3)
b. Carbon (Z=6)
c. Oxygen (Z = 8)
d. Silicon (Z = 14)
e. Chlorine (Z = 17)
f. Calcium (Z = 20)
Answer:

Condensed orbital
No. Element
notation

i. Lithium (Z = 3) [He] 2s1

ii. Carbon (Z = 6) [He] 2s2 2p2

iii. Oxygen (Z = 8) [He] 2s2 2p4

iv. Silicon (Z = 14) [Ne] 3s2 3p2

v. Chlorine (Z = 17) [Ne] 3s2 3p5

vi. Calcium (Z = 20) [Ar] 4s2

Question M.
Draw shapes of 2s and 2p orbitals.
Answer:
2s orbital:

2p orbital:

Question N.
Explain in brief, the significance of azimuthal quantum number.
Answer:
Azimuthal quantum number (l):
 Azimuthal quantum number is also known as subsidiary quantum number and
is represented by letter l.

It represents the subshell to which the electron belongs. It also defines the shape
of the orbital that is occupied by the electron.
Its value depends upon the value of principal quantum number ‘n’. It can have
only positive values between 0 and (n – 1).
Atomic orbitals with the same value of ‘n’ but different values of ‘l’ constitute a
subshell belonging to the shell for the given ‘n’ The azimuthal quantum number
gives the number of subshells in a principal shell. The subshells have l to be 0, 1,
2,3 … which are represented by symbols s, p, d, f, … respectively.

Question O.
If n = 3, what are the quantum number l and ml?
Answer:
: For a given n, l = 0 to (n – 1) and for given l, ml = -l……, 0…….. + l
Therefore, the possible values of l and ml for n = 3 are:

Question P.
The electronic configuration of oxygen is written as 1s2 2s2 2px2 2py1 2pz1 and not
as 1s2 2s2 2px2 2py2 2pz0. Explain.
Answer:

According to Hund’s rule of maximum multiplicity “Pairing of electrons in the

orbitals belonging to the same subshell does not occur unless each orbital
belonging to that subshell has got one electron each.”

Oxygen has 8 electrons. The first two electrons will pair up in the Is orbital, the
next two electrons will pair up in the 2s orbital and this leaves 4 electrons, which
must be placed in the 2p orbitals.

Each of the three degenerate p-orbitals must get one electron of parallel spin
before any one of them receives the second electron of opposite spin. Therefore,
two p orbitals have one electron each and one p-orbital will have two electrons.
Thus, the electronic configuration of oxygen is written as 1s2 2s2 2px2 2py1 2pz1 and
not as 1s2 2s2 2px2 2py2 2pz0.

Question Q.
Write note on ‘Principal Quantum number.
Answer:
Principal quantum number (n):
i. Principal quantum number indicates the principal shell or main energy level to
which the electron belongs.
ii. It is denoted by ‘n’ and is a positive integer with values 1, 2, 3, 4, 5, 6, ….
iii. A set of atomic orbitals with given value of ‘n’ constitutes a single shell. These
shells are also represented by the letters K, L, M, N, etc.
iv. With increase of ‘n’, the number of allowed orbitals in that shell increases and is
given by n2.
v. The allowed orbitals in the first four shells are given below:

vi. As the value of ‘n’ increases, the distance of the shell from the nucleus increases
and the size of the shell increases. Its energy also goes on increasing.

Question R.
Using concept of quantum numbers, calculate the maximum numbers of electrons
present in the ‘M’ shell. Give their distribution in shells, subshells and orbitals.
Answer:
i. Each main shell contains a maximum of 2n2 electrons.
For ‘M’ shell, n = 3.
Therefore, the maximum numbers of electrons present in the ‘M’ shell = 2 × (3)2 =
18.

ii. The distribution of these electrons in shells, subshells and orbitals can be given as
follows:
Note: Orbital distribution in the first four shells:
Question S.
Indicate the number of unpaired electrons in :
a. Si (Z = 14)
b. Cr (Z = 24)
Answer:
i. . Si (Z = 14): 1s2 2s2 2p6 3s2 3p2
Orbital diagram:
Number of unpaired electrons = 2

ii. Cr (Z = 24): 1s2 2s2 2p6 3s2 3p6 4s1 3d5

Orbital diagram:

Number of unpaired electrons = 6

Question T.
An atom of an element contains 29 electrons and 35 neutrons. Deduce-
a. the number of protons
b. the electronic configuration of that element.
Answer:
a. In an atom, number of protons is equal to number of electrons.
The given atom contains 29 electrons.
∴ Number of protons = 29
b. The electronic configuration of an atom of an element containing 29 electrons is:
1s2 2s2 2p6 3s2 3p6 4s1 3d10
[Note: Given element is copper (Cu) with Z = 29]

11th Chemistry Digest Chapter 4 Structure of Atom Intext Questions and

Answers

Can you recall? (Textbook Page No. 35)

Question i.
What is the smallest unit of matter?
Answer:
The smallest unit of matter is atom.
Question ii.
What is the difference between molecules of an element and those of a compound?
Answer:
The molecules of an element are made of atoms of same element while the
molecules of a compound are made of atoms of different elements.

Question iii.
Does an atom have any internal structure or is it indivisible?
Answer:
Yes, an atom has internal structure. Different subatomic particles such as protons,
electrons and neutrons constitute an atom. So, it is divisible.

Question iv.
Which particle was identified by J. J. Thomson in the cathode ray tube experiment?
Answer:
Electron was identified by J.J. Thomson in the cathode ray tube experiment.

Question v.
Which part of an atom was discovered by Ernest Rutherford from the experiment of
scattering of α-particles by gold foil?
Answer:
Nucleus of an atom was discovered by Ernest Rutherford from the experiment of
scattering of α-particles by gold foil.

Just Think (Textbook Page No. 41)

Question 1.
What does the negative sign of electron energy convey?
Answer:
Negative sign for the energy of an electron in any orbit in a hydrogen atom
indicates that the energy of the electron in the atom is lower than the energy of a
free electron at rest. A free electron at rest is an electron that is infinitely far away
from the nucleus and is assigned the energy value of zero.

As the electron gets close to the nucleus, value of ‘n’ decreases and En becomes large
in absolute value and more negative. The negative sign corresponds to attractive
forces between electron and nucleus.
Internet my friend (Textbook Page No. 44)

Question 1.
Collect information about structure of atom.
Answer:
Students can use links given below as reference and collect information about
structure of atom on their own.
[Link]
[Link]
[Link]

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