Enthalpy of Formation and Combustion Reactions
Enthalpy of Formation and Combustion Reactions
7501CMD303021250030 MD
PHYSICS
1) One mole of monoatomic gas is brought from state A to state B such that temperature at A is T0.
(1)
(2)
(3)
(4)
2) If two rods of length L and 2L having coefficients of linear expansion α and 2α respectively
are connected so that total length becomes 3L, the average coefficient of linear expansion of the
composition rod equals:
(1)
α
(2)
α
(3)
α
(4) none of these
3) Two short dipole of dipole moment's P1 and P2 are placed parallel to each other :
(1)
(2)
(3)
(4)
4) Three rods of the same dimension have thermal conductivities 3K, 2K and K. They are arranged as
shown in fig. Given below, with their ends at 100° C, 50° C and 20° C. The temperature of their
junction is
(1) 60° C
(2) 70°C
(3) 50°C
(4) 35°C
5) If a metallic sphere gets cooled from 62°C to 50°C in 10 minutes and in the next 10 minutes gets
cooled to 42°C, then the temperature of the surroundings is
(1) 30°C
(2) 36°C
(3) 26°C
(4) 20°C
6) A gas mixture consists of 2 moles of oxygen and 4 moles argon at temperature T. Neglecting all
vibrational modes, the total internal energy of the system is
(1) 4 RT
(2) 15 RT
(3) 9 RT
(4) 11 RT
(1)
(2)
(3)
(4)
8) Two identical metal plates are given positive charges Q1 and Q2 (< Q1) respectively. If they are
brought close together to form a parallel plate capacitor with capacitance C, the potential difference
between them is :-
(1)
(2)
(3)
(4)
9) The plates of a parallel plate capacitor are charged up to 100 volt. A 2 mm thick plate is inserted
between the plates, then to maintain the same potential difference, the distance between the
capacitor plates is increased by 1.6 mm. The dielectric constant of the plate is :
(1) 5
(2) 1.25
(3) 4
(4) 2.5
10) A capacitor is charged by using a battery which is then disconnected. A dielectric slab is then
slipped between the plates, which results in
(1) Reduction of charge on the plates and increase of potential difference across the plates
Increase in the potential difference across the plates, reduction in stored energy, but no change
(2)
in the charge on the plates.
Decrease in the potential difference across the plates, reduction in stored energy, but no change
(3)
in the charge on the plates
(4) None of the above
11) The plates S and T of an uncharged parallel plate capacitor are connected across a battery. The
battery is then disconnected and the charged plates are now connected in a system as shown in the
figure. The system shown in the equilibrium. All the strings are insulting and massless. The
magnitude of charge on one of the capacitor plates is : [Area of plates = A]
(1)
(2)
(3)
(4)
12) An infinite number of identical capacitors each of capacitance 1 mF are connected as in the
(1) 1 μF
(2) 2 μF
(3)
(4) ∞
14) 5 Conducting plates each are placed face to face & equi-spaced at distance d. Area of each plate
is half the previous plate. If area of first plate is A. Then the equivalent capacitance of the system
shown is :-
(1)
(2)
(3)
(4)
15) A conductor wire having 1029 free electrons/m3 carries a current of 20 A. If the cross-section of
the wire is 1mm2, then the drift velocity of electrons will be :- (e = 1.6 × 10–19 C)
(1) 10 W
(2) 20 W
(3) 30 W
(4) 40 W
(1) kΩ
(2) kΩ
(3) kΩ
(4) kΩ
(1) 0.2 A
(2) 0.3 A
(3) 0.4 A
(4) 0.6 A
19) Consider a thin square sheet of side L and thickness t, made of a material of resistivity ρ. The
resistance between two opposite faces, shown by the shaded areas in the figure is
(1) zero
(2) 1 amp
(3) 2 amp
(4) 4 amp
22) If the given wire is in equilibrium then the value of current in the conductor is (mass of wire is
m)
(1)
from a to b
(2)
b to a
(3)
from a to b
(4)
from a to b
23) A wire carrying a current i is placed in a magnetic field in the form of the curve
(1)
(2) iBLπ
(3) 2iBL
(4) Zero
24) If a proton, deutron and α particle on being accelerated by the same potential difference enters
perpendicular to the magnetic field, then the ratio of their kinetic energies is
(1) 1 : 2 : 2
(2) 2 : 2 : 1
(3) 1 : 2 : 1
(4) 1 : 1 : 2
25) A thick current carrying cable of radius R carries current I uniformly distributed across its cross-
section. The variation of magnetic field B due to the cable with the distance r from the axis of the
cable is represented by
(1)
(2)
(3)
(4)
26) Two similar coils of radius R are lying concentrically with their planes at right angles to each
other. The currents flowing in them are I and 2I, respectively. The resultant magnetic field induction
at the centre will be :-
(1)
(2)
(3)
(4)
27) When a ferromagnetic material is heated to temperature above is Curie temperature, the
material:-
28) Two identical particles having the same mass m and charges +q and –q separated by a distance
d enter in a uniform magnetic field B directed perpendicular to paper inwards with speeds v1 and v2
(1)
(2)
(3)
(4) V1 = V2
29) The magnetic susceptibility of a medium is –0.08, what will be its relative permeability?
(1) 1.8
(2) 1.08
(3) 0.08
(4) 0.92
30) A thin ring of radius r meter has charge Q coulomb uniformly spread on it. The ring rotates
about its axis with a constant frequency of w rad/s. The value of magnetic induction in Wb/m2 at the
centre of the ring is :-
(1)
(2)
(3)
(4)
31) The current flows from B to A as shown in the figure. The direction of the induced current in the
(1) clockwise
(2) anticlockwise
(3) straight line
(4) none of these
32) A metallic square loop ABCD is moving in its own plane with velocity v in a uniform magnetic
field perpendicular to its plane as shown in the figure. An electric field is induced :-
33) A transformer is used to light 140 watt 24 volt lamp from 240 volt AC mains, the current in the
main cable is 0.7 amp. The efficiency of the transformer is
(1) 63.8%
(2) 84%
(3) 83.3%
(4) 48%
34) A square coil having total 'n' turns is kept at the centre of a circular loop of radius 'b'. Side of the
square coil is 'a' and it is placed coaxially in the plane of the loop. If 'I' current flows through the
loop, calculate the flux of magnetic field passing through square coil. (Assume a << b) :-
(1)
(2)
(3)
(4)
35)
Assertion (A): The electric field created by time-varying magnetic field is non-conservative.
Reason (R): The line integral of induced electric field in a closed loop is always equal to zero.
In the light of the above statements, choose the most appropriate answer from the options given
below:
(1) Both (A) and (R) are true and (R) is the correct explanation of (A).
(2) Both (A) and (R) are true and (R) is NOT the correct explanation of (A).
(3) (A) is true but (R) is false.
(4) (A) is false but (R) is true.
36) Three inductances are connected as shown below. Assuming no coupling, the resultant
inductance will be
(1) 0.25 H
(2) 0.75 H
(3) 0.01 H
(4) 1 H
37) For an adiabatic process graph between PV & V for a sample of ideal monoatomic gas will be :-
(1)
(2)
(3)
(4)
(1) 1.4 A
(2) 1 A
(3) 2 A
(4) none of these
(1) 390 k
(2) 290 k
(3) 190 k
(4) 300 k
40) The magnitude and direction of current I (in A) indicated in the following circuit is :-
(1) 14 →
(2) 8 →
(3) ← 4
(4) ← 8
(1) 2A, 1A
(2) 1A, 2A
(3) 3A, 3A
(4) 1A, 1A
42) In the circuit shown, the cell is deal. The coil has an inductance of 4 H and zero resistance. F is a
fuse of zero resistance and will blow when the current through it reaches 5 A. The switch is closed at
43) A rectangular loop with a sliding connector of length l = 1.0 m is situated in a uniform magnetic
field B = 2T perpendicular to the plane of loop. Resistance of connector is r = 2Ω. Two resistors of
6Ω and 3Ω are connected as shown in figure. The external force required to keep the connector
44) The mutual inductance between a long straight wire and a square loop of side a as shown In
figure will be :-
(1) ℓn
(2) ℓn
(3) ℓn
(4)
ℓn
(1)
Bp = [sinθ + 1]
(2)
Bp = [sinθ]
(3)
Bp = [sinθ + sinθ]
(4)
Bp = [sin 90 + sin 90]
CHEMISTRY
(1) –165 kJ
(2) +54 kJ
(3) +219 kJ
(4) –219 kJ
of Fe2O3 and CO2 are –824.2 kJ mol–1 and –393.7 kJ mol–1 respectively. The reaction is
(1) Endothermic
(2) Exothermic
(3)
(4) None of the above
3)
For the reaction, Fe0.95O (molar mass : M) → Fe2O3. What is the eq. wt. of Fe0.95O?
(1)
(2)
(3)
4) A 0.004 M solution of Na2SO4 is isotonic with a 0.010 M solution of glucose at same temperature.
The apparent degree of dissociation of Na2SO4 is
(1) 25%
(2) 50%
(3) 75%
(4) 85%
5) Identify the mixture that shows positive deviations from Raoult's Law
6) If solubility of any gas in the liquid at 1 bar pressure is 0.05 mol/lit. What will be its solubility at 3
bar pressure, keeping the temperature constant? (in mol/lit)
(1) 0.15
(2) 0.25
(3) 3
(4) 2.5
7) A certain reaction obeys the rate equation (in the integrated form) = (n – 1) kt
where n is the order of the reation; C0 the initial concentration of reactant and C, the concentration
of reactant after time t. What is the unit of k for n = 3 :-
(1) sec–1
(2) litre mol–1 sec–1
(3) mol litre–1 sec–1
(4) litre2 mol–2 sec–1
(1) 1 : 2
(2) 2 : 1
(3) 3 : 1
(4) 3 : 10
9) Consider the reaction A → B, graph between half life (t1/2) and initial concentration (a) of the
(1)
(2)
(3)
(4)
10) Conductivity of an aqueous solution of 0.1 M HX (a weak mono-protic acid) is 5 × 10–4 Sm–1.
Given :
(1) 6
(2) 7
(3) 8
(4) 9
13)
In the above diagram, the standard electrode potentials are given in volts (over the arrow). The
value of is
(1) 1.7 V
(2) 1.2 V
(3) 2.1 V
(4) 1.4 V
14) During the charging of lead storage battery, the reaction at anode is represented by
(1)
(2)
(3)
(4)
15) The weight of silver (eq. wt. = 108) displaced by that quantity of current which displaced 5600
ml. of hydrogen at STP is :
(1) 54 g
(2) 108 g
(3) 5.4 g
(4) None of these
(1) An increase in pH
(2) A decrease in pH
(3) Either decrease or increase
(4) None
(1) 20 kJ/mol
(2) 7.98 kJ/mol
(3) 28 kJ/mol
(4) None of these
18) Heat absorbed in the reaction H2(g) + Cl2(g) → 2HCl(g) is 182 kJ. Bond energies of H—H = 430
kJ/mole and Cl—Cl = 242 kJ/mole.
The H—Cl bond energy is
19) Which among the following reaction gives directly the value of heat of formation of the product?
20) Heat of combustion of C2H6 and C2H2 is –341.1 and –310.0 Kcal mol–1. Which one is best fuel.
(1) C2H6
(2) C2H2
(3) both
(4) None of these
21) In which of the following neutralisation reactions, the heat of neutralisation will be highest?
(1) q1 + q2 + q3
(2) 2q1 + 2q2 + 3q3
(3) 2(q1 + q2 + 2q3)
(4) 2(q1 + q2 + q3)
23) Two liquids A (HNO3) and B (H2O) form a maximum boiling azeotrope when mixed in the ratio of
68% and 32% respectively. It means
(1) A – B interactions are stronger than A – A and B – B interactions
(2) A – B interactions are weaker than A – A and B – B interactions
(3) vapour pressure of solution is more than the pure components
(4) All option are correct
24) Total vapour pressure of mixture of 1 mol volatile component A( = 100 mmHg) and 3 mol of
volatile component B ( = 60 mmHg) is 75 mm. For such case :-
25) Nitric Acid (70% by mass) has a specific gravity of 1.42. Find the molarity of the acid.
(1) 15.8
(2) 1.58
(3) 0.158
(4) 158
26) For producing the effective collisions, the colloiding molecules must posses :
27) According to the following figure the magnitude of the enthalpy change of the reaction A + B →
M + N in kJ/mol is equal to :
(1) 20
(2) 65
(3) 60
(4) 45
(1) 1, 2
(2) 2, 1
(3) 1, 1
(4) 2, 2
(1) 2.20 V
(2) 2.40 V
(3) 1.10 V
(4) 1.24 V
32) The enthalpy of combustion at 25°C of H2(g), cyclohexene (C6H10)(ℓ) and cyclohexane (C6H12)(ℓ) are
–241, –3800 and –3920 kJ/mol respectively. The heat of hydrogenation of cyclohexene(ℓ) is :
(2) NH2OH –1
(3) (N2H5)2SO4 +2
(4) Mg3N2 –3
(1) 1
(2) 2
(3) 3
(4) 4
(1) 1
(2) 2
(3) 3
(4) 4
36)
Product will be :
(1)
(2)
(3)
(4)
37)
Which statement is not incorrect for above reaction?
(A) It involves a dehydration reaction
(B) Intermediate carbanion is formed
(C) One of the step is Nucleophilic addition
(D) One of the step is Electrophilic addition
(1) A, B, C
(2) only A, D
(3) only B, C
(4) All
38) Which of the following compound can be prepared in good yield by Gabriel phthalimide synthesis
:-
(1)
(2)
(3)
(4) CH3–CH2–NH–CH3
39)
The major product 'P' formed in this reaction:-
(1)
(2)
(3)
(B)
(D) PhMgBr
Which reaction among above is incorrect ?
(1) A
(2) B
(3) C
(4) D
(1)
(2)
(3)
(4)
(1)
(2)
(reactivity for SN2)
(3)
(reactivity for hydrogenation)
(4) All
(1)
(2)
(3)
(4)
45) A compound (X) with molecular formula C3H9N reacts with C6H5SO2Cl to give a solid which is
insoluble in alkali. (X) is:
(1) CH3CH2CH2NH2
(2)
(3) CH3–NH–CH2CH3
(4)
BIOLOGY
1) Which of the following enzymes is required to make complementary DNA (cDNA) from RNA?
3) When taken up by a cell, which of the following molecules binds to a repressor so that
the repressor no longer binds to the operator?
(1) inducer
(2) promoter
(3) repressor
(4) corepressor
4) The central rule of molecular biology states that ____.
5) Which one of the following structures, if missing, would usually prevent translation from starting?
(1) exon
(2) 5′ cap
(3) AUG codon
(4) poly-A tail
(1) GTP
(2) DNA
(3) tRNA
(4) ribosomes
(1) a protein
(2) mRNA
(3) tRNA
(4) rRNA
(1) A = C
(2) A = G and C = T
(3) A + C = G + T
(4) G + C = T + A
11) Which of the following statements correctly describes the difference between ATP and
the nucleotides used during DNA synthesis?
(1) The nucleotides have the sugar deoxyribose; ATP has the sugar ribose.
(2) The nucleotides have two phosphate groups; ATP has three phosphate groups.
(3) ATP contains three high-energy bonds; the nucleotides have two.
(4) ATP is found only in human cells; the nucleotides are found in all animal and plant cells.
12) Which of the following order is correct in terms of the hierarchy of the organization?
13) As N approaches K for a certain population, which of the following outcomes is predicted by the
logistic equation?
14) A population of ground squirrels has an annual per capita birth rate of 0.06 and an annual
per capita death rate of 0.02. Using these birth and death rates, calculate an estimate of the
total number of individuals added to (or lost from) a population of 1,000 individuals in one year.
15) Which of the following causes populations to shift most quickly from an exponential to a logistic
population growth?
(1) arrow A
(2) arrow B
(3) arrow C
Carrying capacity cannot be found in the figure because species under density-dependent
(4)
control never reach carrying capacity.
17) How many phosphodiester bonds are present in a DNA molecule if its one strand has 60
nucleotides ?
(1) 120
(2) 59
(3) 119
(4) 118
18) Which of the following graphs illustrates the population growth curve starting with a single
bacterium growing in a flask of ideal medium at optimum temperature over a two-hour period ?
Assume resources do not become limiting over this time frame.
(1)
(2)
(3)
(4)
(1) Sugarcane
(2) Maize
(3) Sorghum
(4) All of these
21) In photosynthesis, the electrons that are moved from photosystem- II must be replaced. This is
achieved by electrons available :-
22) Given below is the diagrammatic sketch of chemiosmotic hypothesis. Identify the A, B, C and D
and select the right option about them:-
Options :-
A B C D
23) C4 plants consume _____ molecules of NADPH.H+ to fix 4 CO2, while C3 plants require _____
molecules of NADPH.H+ for fixation of same amount of CO2 :-
(1) 8, 8
(2) 4, 4
(3) 6, 6
(4) 8, 12
24)
25) Consider the following four statements (a–d) and select which includes the correct ones only :-
(a) The splitting of water is associated with the PS–II.
(b) During Photophosphorylation ATP are form in down hill process.
(c) When only PS–II is functional the electron is circulated with in the photosystem.
(d) In noncyclic phosphorylation only PS–II is involves.
(1) Statement a, b, c
(2) Statement a, b
(3) Statement a, b, c, d
(4) Statement a, c, d
28) Assertion (A): The possibility of a female becoming haemophilic is extremely rare
Reason (R): A female to be haemophilic, her mother should be haemophilic and father should be
carrier
(1) Both (A) and (R) are correct but (R) is not the correct explanation of (A)
(2) Both (A) and (R) are correct and (R) is the correct explanation of (A)
(3) (A) is not correct but (R) is correct
(4) (A) is correct but (R) is incorrect
30) Which of the following RNA polymerase enzyme catalyses the formation of precursor of m-RNA
(hnRNA) ?
31) If m-RNA base sequence is 5' AUG GAC GCG AUC UGC 3'. What is the possible number of
codons in case of non-overlapping and overlapping repectively ?
(1) 4, 13
(2) 5, 13
(3) 4, 12
(4) 13, 5
(1) P, Q, R, S
(2) P, Q, R
(3) P, R, S
(4) Only P, S
33) The experimental proof for semi-conservative replication of DNA in chromosomes by Taylor was
shown in :
(1) [Link]
(2) Vicia faba
(3) λ phage
(4) Mangifera indica
35) Given below are two statements, one is label3eed as Assertion (A) and the other is labelled
as Reason(R).
Assertion (A) : In HGP, DNA fragments were sequenced using automated DNA sequencers that
worked on the principle of sanger's method.
Reason (R) : HGP was a mega project.
In the light of the above statements, choose the correct answer from the options given below :
(1) Both (A) and (R) are correct but (R) is not the correct explanation of (A).
(2) (A) is correct but (R) is not correct.
(3) (A) is not correct but (R) is correct
(4) Both (A) and (R) are correct and (R) is the correct explanation of (A)
36) Match the terms in column I with their description in column II and choose the correct option.
Column I Column II
Which of the following conclusion can be drawn from the given age pyramid ?
38) Select the correct statement from the ones given below with respect to dihybrid cross.
(1) Tightly linked genes on the same chromosomes show higher recombinations.
(2) Genes far apart on the same chromosome show very few recombinations.
Genes loosely linked on the same chromosome show similar recombinations as the tightly linked
(3)
ones.
(4) Tightly linked genes on the same chromosome show very few recombinations.
(1) does not code for proteins and is same in all members of the population
(2) codes for enzymes needed for DNA replication
(3) codes for proteins needed in cell cycle
shows high degree of polymorphism in population and also the same degree of polymorphism in
(4)
an individual, which is heritable from parents to children
40) Which of the following is not an adaptation of parasites for assurance of parasite host interaction
41) In the following human pedigree, the filled symbols represent the affected individuals. Identify
the type of given pedigree.
(1) Predation
(2) Competetion
(3) Mutualism
(4) Commensalism
Column-I Column-II
Brood
(C) (c) Cuscuta
parasitism
(1) Tuberculosis
(2) Dengue
(3) Cholera
(4) Typhoid
48) Read the statements A and B carefully and choose the correct option.
Statement-A : Common cold is a bacterial disease.
Statement-B : Common cold is one of the most infectious ailment in humans caused by Rhino virus.
(1) Nose
(2) Respiratory passage
(3) Lungs
(4) All of these
50) Select on option which represents correct sequence of stages in the life cycle of plasmodium.
(A) Sporozoites are injected in human blood, through mosquito bite.
(B) Sexual stages develop in red blood cells.
(C) Female mosquito takes in gametocytes with blood meal.
(D) The parasite reproduces asexually in liver cells.
(E) Parasites reproduce asexually in RBCs, bursting RBCs and causing cycles of fever.
(F) Fertilization and development take place in mosquito's gut.
(1) A,D,E,B,C,F
(2) A,B,C,D,E,F
(3) A,D,E,C,B,F
(4) A,E,D,B,C,F
51)
(1) Houseflies act as mechanical carriers and serve to transmit the parasite from faeces
(2) It is a parasite of small intestine of man
(3) It is a protozoan parasite of human
(4) It is characterised by constipation and abdominal pain
(1) only A
(2) A & B
(3) B & C
(4) A, B & C
(1) a
(2) a, b
(3) a, c
(4) a,b,c
55) "Don't die of ignorance" is being said for which of the following disease :-
(1) Cancer
(2) Typhoid
(3) AIDS
(4) Common cold
(1) Five
(2) Four
(3) Two
(4) Three
(1) Macrophage
(2) TH cells
(3) TK cells
(4) both 1 and 2
58) AIDS is the global issue of concern and pandemic disease which requires concern of the society.
Some preventive measures taken by NACO to control it's. Spread extensively which does not include
:-
61)
(1) There is always a time-lag between the infection and appearance of AIDS symptoms.
(2) AIDS is not a congenital disease
(3) MALT constitutes about 50% of lymphoid tissues
Both bone marrow and thymus provide micro environment for the maturation of B-lymphocytes
(4)
only
62) The figure below shows steps A, B & C of replication of retrovirus. Select the option giving
correct Identification
(1) B–Incorporation of viral DNA into host genome with intregase enzyme
(2) C–Production of new viral DNA by infected cell
(3) A–Replication of viral RNA by protease enzyme
(4) C–Viral RNA replication by reverse transcriptase enzyme
64)
(1) Psoriasis
(2) Rheumatoid arthritis
(3) Alzheimer's disease
(4) Vitiligo
65) The body is able to differentiate "Self" and "non self". Rejection of non self organs can be
prevented by ?
(1) Syphillis
(2) Gonorrhoea
(3) Hepatitis–B
(4) Polio
67) Statement-I :- Among non-infectious diseases, AIDS is the major cause of death.
Statement-II :- Some of the infectious diseases like cancer are fatal.
Choose the correct answer from the given options :
68) Read the following Assertion (A) and Reason (R) and choose the correct option
Assertion (A): More and more children in metro cities of India suffer from allergies and asthma.
Reason (R): Children in metro cities of India are provided protected environment early in life.
(1) Both (A) and (R) are correct and (R) is the correct explanation of (A)
(2) Both (A) and (R) are correct but (R) is not the correct explanation of (A)
(3) (A) is correct but (R) is incorrect
(4) Both (A) and (R) are incorrect
(1) Anti-histamines
(2) Steroids
(3) Adrenaline
(4) All of the above
70) Fish like reptile (Ichthyosaurs) which go back into the water from it's land ancestors evolved
before how many years :-
(1) Australopithecus
(2) Apes
(3) Tree shrews
(4) Prosimians
73)
(E) Australopithecus
(1) E→D→B→A→C
(2) E→B→D→A→C
(3) E→A→B→D→C
(4) E→A→D→B→C
(1) Cromagnon
(2) Homo habilis
(3) Homo erectus
(4) Neanderthal man
75) In a species, the weight of newborn ranges from 2 to 5 kg. 97% of the newborn with an average
weight between 3 to 3.3 kg survive whereas 99% of the infants born with weight from 2 to 2.5 kg or
4.5 to 5 kg die. Which type of selection process is taking place ?
77) Which is not true for non-steroidal drug developed by CDRI, Lucknow ?
(1) a, b, c, d
(2) a, b, c only
(3) a and c only
(4) c only
79) In the given list how many factors can be used for the treatment of cancer : Vincristine, Taxol,
Iodine-131, N-nitrosodimethylene, soot
(1) 4
(2) 3
(3) 2
(4) 1
(1) 3
(2) 4
(3) 2
(4) 1
(1) a only
(2) a, b only
(3) c only
(4) a, b, c
(1) a, b
(2) a, c & d
(3) a, b & c
(4) a, b, c & d
85) Which drug is not normally used as medicines to help patients cope with mental illnes like
depression and insomnia ?
(1) Barbiturates
(2) Benzodiazepines
(3) Amphetamines
(4) LSD
86) Natural cannabinoids are obtained from the ____ of Cannabis sativa.
87) The drugs, which are commonly abused are opioid, cannabinoids and coca alkaloid. Majority of
these are obtained from......... while some are obtained from .........
(1) 3
(2) 4
(3) 2
(4) 1
Diabetes
(II) Thyrocalcitonin (b) Hypothalamus (ii)
mellitus
Anterior Diabetes
(III) Insulin (c) (iii)
pituitary insipidus
Growth
(IV) (d) Pancreas (iv) Dwarfism
hormone
(1) I-b-ii, II-a-i, III-d-iii, IV-c-iv
(2) I-b-iii, II-a-i, III-d-ii, IV-c-iv
(3) I-c-iii, II-a-i, III-d-ii, IV-b-iv
(4) I-c-ii, II-a-i, III-d-iii, IV-b-iv
PHYSICS
Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. 1 3 3 2 3 4 2 4 1 3 1 2 4 4 4 4 2 3 3 3
Q. 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40
A. 1 1 3 4 3 1 4 3 4 1 1 4 3 1 3 4 2 1 2 2
Q. 41 42 43 44 45
A. 1 4 3 1 1
CHEMISTRY
Q. 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65
A. 4 1 1 3 4 1 4 2 3 4 4 2 1 2 1 2 1 2 4 2
Q. 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85
A. 2 3 1 4 1 4 4 1 2 3 4 1 3 3 1 4 1 2 1 3
Q. 86 87 88 89 90
A. 1 4 2 3 3
BIOLOGY
Q. 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110
A. 4 2 1 1 3 1 3 2 2 3 1 4 2 2 4 3 4 3 3 4
Q. 111 112 113 114 115 116 117 118 119 120 121 122 123 124 125 126 127 128 129 130
A. 3 3 1 4 2 4 3 4 2 3 2 3 2 4 1 4 3 4 4 4
Q. 131 132 133 134 135 136 137 138 139 140 141 142 143 144 145 146 147 148 149 150
A. 1 1 2 1 2 4 3 4 3 1 2 4 4 4 3 2 1 4 3 1
Q. 151 152 153 154 155 156 157 158 159 160 161 162 163 164 165 166 167 168 169 170
A. 4 1 4 3 4 4 1 1 4 3 3 1 1 3 2 3 4 1 2 2
Q. 171 172 173 174 175 176 177 178 179 180
A. 3 4 4 4 4 2 2 2 2 4
SOLUTIONS
PHYSICS
1) dQ = dU + dW
0 0 0 0
= 1 × R × (4T – T ) + 1 × P × V
0 0 0
= RT + RT = RT
2) Δℓ = Δℓ1 + Δℓ2
3Lαav ΔT = L α ΔT + 2L (2α)ΔT
⇒ αav = α
3)
4) i1 + i2 + i3 = 0
5)
For 62° C to 50°C
--------(1)
--------(2)
From equation (1) & (2)
QS = 26°C
6) u = n1w1T + n2w2T
= 11 RT
7) We use
and
As these fields are in opposite directions and Q1 > Q2, the net electric field within the plates is
E = E 1 – E2 =
9)
Ed = V = (d + 1.6–2)E + .2
C → KC, E = CV2
V → V/K , E = E/K
Q = CV = constant
V → Decrease, Energy decrease.
Q → Remain constant
11)
12) C = 1μF
Ceq. = C +
= =
= 2C = 2 μF
It is Geometric progression
sum of infinite terms
S∞ = Here a = C, r = 1/2
13)
14)
16) 2 + 4 = 6W
3Ω || 6Ω = 2Ω
Req = 2 + 8 = 10Ω
17)
Req = r ,
rR + 2Rr + 2R2 = r2 + Rr
r2 – 2Rr – 2R2 = 0
I1 : I2 : I3 =
I1 : I2 : I3 = 3 : 2 : 1
I2 =
=
= 0.4 A
19)
20)
21)
zero
22)
23) = 2L
so F = iB
F = 2iBL
24) Kinetic energy in magnetic field remains constant and it is (V =
constant)
25) Magnetic field inside the conducting cylindrical cable . Here, R is the radius of
the cylindrical cable, r is the distance from the axis of the cylinder, I is the current carrying in
the cylindrical cable.
The graph of magnetic field B with r is a straight line passing through origin. For a point
The graph of magnetic field (B) with r is a rectangular hyperbola passing through the outer
surface of the cylinder. The variation of the magnetic field B due to the
cable with the distance r from the axis of the cylindrical cable is as shown in the figure.
26) The magnetic field (B) at the centre of circular current carrying coil of radius R and
current I is
27)
or
or
29)
We know that
Relative permeability = magnetic susceptibility + 1
30) I =
The question asks to determine the direction of the included current in a loop when the
current flowing from point A to B decreases with time. The setup involves electromagnetic
induction, and we need to apply Lenz's Law to find the direction of the induced current.
Concept -
This question pertains to Electromagnetic Induction. According to Lenz's Law, the induced
current will always oppose the change in the magnetic flux. When the current decreases in the
wire, the magnetic flux created by the current will decrese, and the loop will induce a current
in such a direction as to try to oppose that decrease.
Formula Used -
A. Lenz's Law : The direction of the induced current opposes the changes in magnetic flux.
Explanation -
A. When the current from A to B decreases, the magnetic field produced by the current also
weakens.
B. To oppose the decrease in the magnetic field, the induced current in the loop will flow in such
a direction as to create a magnetic field that strengthens the original magnetic field.
C. The induced current will flow in the clockwise direction in the loop to oppose the reduction
in the magnetic flux.
Level - Easy
32) Both AD and BC are straight conductors moving in a uniform magnetic field and emf will
be induced in both. This will cause electric fields in both, but no net current flows in the
circuit.
33)
34)
35)
38) ⇒
39)
40)
41)
by simplification
Rq = 6Ω ⇒ I =
& I1 + I2 = I = 3
⇒ I1 = 2A
I2 = 1A
42)
44)
dϕ = BdA
=ϕ=
MI = ℓn
M= ℓn
CHEMISTRY
47)
= 476.3 kJ/mole
48)
x = 0.85
Equivalent weight =
49)
i × 0.004 = 0.010
i = 2.5 = or 75%
⇒
∴ x = 0.05 × 3 = 0.15 mol/litre
52) = (n – 1) kt
put n = 3 = 2 kt
concentration i.e. =
= K × second
k = ℓ mol–2 sec–1
2
53) xA yB
ROR =
...(i)
from question
...(ii)
compare the equation (i) & (ii)
=2
x:y=2:1
54)
t1/2 ∝ a1–n
1–n = 1 ⇒ n = 0
0th order reaction
rate = k
55) α =
=
Ka = α2C = 10–9
pKa = 9
56) Tl + Cu+2 → Tl+ + Cu
s 10–2M 10–4M s
E = E° +
58)
59)
During charging, the lead storage battery behaves like an electrolytic cell. So, at anode the
reaction is
w = 54 gm
– –
61) 4OH → 2H2O + O2 + 4e (At anode)
[OH–] ↓, pOH ↑ , pH ↓
62)
= 16 + 4 = 20 kJ/mole
63)
64) One mole substance formed from its elements in their most abundant naturally occurring
form/stable state is known as Heat of formation.
65)
Calorific value =
66) H2SO4 and Ba(OH)2 are strong acid and base respectively.
68)
Maximum boiling azeotrope are show negative deviation in raoult law so the interactions
between solute and solvent is grater than solute - solute and solvent - solvent.
69)
Generated by Allie
Problem Statement: The question gives a mixture of two volatile liquids A and B with known
pure component vapour pressures and mole amounts. It asks which statements about the
mixture's vapour pressure behavior and intermolecular forces are correct based on the
observed total vapour pressure.
Underlying Concept: The problem uses Raoult's law to predict the total vapour pressure of
an ideal liquid mixture based on mole fractions and pure component vapour pressures.
Deviations from Raoult's law occur when intermolecular forces between different components
differ from those within the pure components. Positive deviation means the mixture's vapour
pressure is higher than predicted, indicating weaker A-B attractions and a lowered boiling
point.
Relevant Formulas: Raoult's Law for total vapour pressure of an ideal mixture: \[ P_{total} =
x_A P_A^0 + x_B P_B^0 \] where are mole fractions, and are pure component
vapour pressures.
Tips and Tricks: Remember that a positive deviation indicates weaker intermolecular
attractions between different components, causing easier evaporation and higher total vapour
pressure, which also lowers the boiling point.
Common Mistakes: Students may incorrectly calculate mole fractions or confuse positive
deviation with negative deviation (where vapour pressure is lower than predicted). Or they
may forget to compare observed and theoretical vapour pressures.
Why Other Options Are Incorrect?: Options that deny positive deviation or claim stronger
attraction between different molecules contradict the fact that observed pressure is higher
than predicted, which only happens if A-B forces are weaker than A-A or B-B.
70)
Generated by Allie
Problem Statement: The question asks to find the molarity of nitric acid (HNO₃) when the
acid solution is 70% by mass and has a specific gravity (density relative to water) of 1.42.
Molarity is the number of moles of solute (HNO₃) dissolved per liter of solution.
Step-by-Step Calculation: Step 1: Calculate the mass of 1 liter of solution using density:
Step 2: Calculate the mass of HNO₃ in this solution using the percentage by mass:
Step 3: Convert the mass of HNO₃ to moles using its molar mass (63 g/mol):
Tips and Tricks: Specific gravity can be treated as the density in g/mL since water is 1 g/mL.
Converting percent by mass to actual mass in solution volume is crucial before calculating
molarity.
Common Mistakes: Assuming the percentage is volume percent rather than mass percent,
forgetting to use the density to find the total mass of solution for 1 L, or not converting mass of
solute to moles properly.
Why Other Options Are Incorrect?: Answers like 1.58 or 0.158 likely come from misreading
percentage or incorrect unit conversion. The option 158 is too high and likely results from an
error in decimal placement or misunderstanding molarity units.
71)
Explanation
A. Effective collisions lead to a reaction.
B. For this, molecules need enough energy (threshold energy) and the correct alignment.
Concept
A. Collision theory: Reactions occur when molecules collide with sufficient energy and proper
orientation.
Solution:
ΔH = (Ea)f – (Ea)b
(Ea)f = x, (Ea)b = x + y
ΔH = (Ea)f – (Ea)b
ΔH = x – (x + y) = –y
ΔH = –45 KJ/mol
|ΔH|= magnitude is = 45 KJ/mol
73) Reaction is pseudo first order reaction, order is one and molecularity is two.
75)
Generated by Allie
Problem Statement: The question asks which metal container (vessel) can safely store a
given aqueous solution of metal ions without the vessel corroding. It provides standard
electrode potentials and asks to determine which statements about storing certain solutions in
specific metal vessels are correct or not.
Underlying Concept: The core concept involves redox reactions and standard electrode
potentials (E°). Corrosion of a metal vessel by an ion solution depends on the spontaneity of
the reaction where the vessel's metal oxidizes and the ion reduces. If the overall cell potential
for the reaction is positive, corrosion occurs; if negative, the vessel remains safe.
Tips and Tricks: Compare the reduction potentials: the vessel metal must have a more
positive reduction potential than the ions in solution to be safe.
Common Mistakes: One common mistake is to confuse oxidation and reduction potentials or
to reverse the order when calculating E°cell.
Why Other Options Are Incorrect?: Statements 1, 2, and 4 predict a positive cell potential,
meaning the metal of the vessel will oxidize and corrode, hence those storage combinations
are unsafe.
76) Efficiency =
ΔG = –nFE
77)
78)
79)
80)
81)
82)
Explaining the Question :- Analyze the reaction and determine which statements about its
mechanism are correct.
Concept:- Intramolecular Aldol condensation reaction.
Solution :-
(A) It involves a dehydration reaction – correct.
(B) Intermediate carbanion is formed – correct.
(C) One of the step is Nucleophilic addition – correct.
(D) One of the step is electrophilic addition – Incorrect.
Final Answer :- Option (1)
84)
86)
(A) (B)
(C) (D)
87)
BIOLOGY
91)
reverse transcriptase
92)
93)
inducer
94)
AUG codon
96)
Turner syndrome
97)
98)
DNA
99)
mRNA
100)
A+C=G+T
101)
The nucleotides have the sugar deoxyribose; ATP has the sugar ribose.
102)
103)
104)
40 individuals added
105)
106)
arrow C
107)
108)
109)
110)
All of these
112)
114)
115)
Concept :
SCA → Autosomal recessive disorder
→ Glutamic acid replaced valine
Solution / Explanation :
Point Mutation, change in β - chain.
117)
118)
NCERT [Link]. 74
119)
Explanation: The mRNA sequence is complementary to the template strand of DNA and
identical to the coding strand, except that uracil (U) replaces thymine (T). Therefore, the
mRNA sequence is the same as the given coding strand with T replaced by U.
120)
RNA polymerase - ΙΙ
121)
5, 13
122)
Concept :- Translations
Solution :- During Process of Translation energy needed for
(P) Amino acid activation - Attaching amino acid with t- RNA required ATP
(R) T-RNA to P-site - initial t-RNA binding during ignition need of GTP.
(S) t-RNA to A site - subsequent t-RNA binding during elongation need -GTP
⇒ Binding of large ribosomal sub unit does not need energy .
Answer :- 3 P, R, S
123)
NCERT-XII, Pg. # 87
124)
Both (A) and (R) are correct but (R) is not the correct explanation of (A).
126)
127)
128)
Tightly linked genes on the same chromosome show very few recombinations.
129)
shows high degree of polymorphism in population and also the same degree of polymorphism
in an individual, which is heritable from parents to children
130)
131)
Autosomal recessive
132)
Predation
133)
1.4 million
134)
136) Explanation: The Widal test is a serological test used to diagnose typhoid fever, also
known as enteric fever. It detects antibodies against Salmonella typhi, the bacteria that causes
typhoid.
137)
Explanation : Sustained high fever (39° to 40°C), weakness, stomach pain, constipation,
headache and loss of appetite are some of the common symptoms of this [Link] answer :
3
139)
Lungs
140)
Correct option is 1
141)
142)
A, B & C
143)
a,b,c
146)
148)
149)
150)
152)
153)
154) Question Explanation : The question asks which one among the listed conditions is not
an autoimmune disease.
Solution :
The correct answer is option 3.
Autoimmune Disorders – Involve immune system attacking [Link] Disorders –
Affect nerve cells without autoimmunity.
Hence,
Option (3) is correct : Alzheimer's disease.
155)
Immunosuppressant
156)
NCERT XII, Pg # 63
157)
158)
160)
NCERT-XII, Pg # 124
161)
162)
Australopithecus
163)
E→D→B→A→C
164)
Homo erectus
165)
Stabilizing selection
166)
167)