Lakshya JEE (2025)

JEE
JEE Advanced Test - 03 Advanced
Paper-01
DURATION ::180
DURATION Minutes
90 Minutes DATE : 29/09/2024 [Link] : 180

Topics Covered
Physics: Mechanical Properties of Solids-Class 11th (Complete Chapter), Mechanical Properties of Fluids-Class
11th (Complete Chapter), Thermal Properties of Matter-Class 11th (Complete Chapter), Kinetic Theory
Class 11th (Complete Chapter), Electromagnetic Induction (Complete Chapter), Alternating Current
(Complete Chapter), Electromagnetic Waves (Complete Chapter)
Chemistry: P-block Elements (Group 13 and 14) Class 11 th (Complete Chapter), Some Basic Principles and
Techniques: IUPAC Nomenclature Class 11th (Complete Chapter), Some Basic Principles and Techniques:
Isomerism-Class 11th (Complete Chapter), Some Basic Principles and Techniques: General Organic
Chemistry-Class 11th (Complete Chapter), Aldehydes, Ketones and Carboxylic Acids (Complete Chapter),
Amines (Complete Chapter), Biomolecules (Complete Chapter), Coordination Compounds (Complete
Chapter)
Mathematics: Conic Sections: Parabola Class 11th (Complete Chapter), Conic Sections: Ellipse Class 11th (Complete
Chapter), Conic Sections: Hyperbola Class 11th (Complete Chapter), Complex Number-II Class 11th
(Complete Chapter), Method of Differentiation (Complete Chapter), Limit, Continuity and
differentiability (Complete Chapter)
General Instructions:

1. Immediately fill in the particulars on this page of the test booklet.

2. The test is of 3 hours duration.
3. The test booklet consists of 51 questions. The maximum marks are 180.
SECTION-1 (Maximum Marks: 12)
 This section contains THREE (03) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four option(s) is(are)
correct answer(s).
 For each question, choose the option(s) corresponding to (all) the correct answer(s).
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks : +3 If all the four options are correct but ONLY three options are chosen;
Partial Marks : +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct;
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –2 In all other cases.

 For example, in a question, if (A), (B) and (D) are the ONLY three options corresponding to correct answers, then
choosing ONLY (A), (B) and (D) will get +4 marks;
choosing ONLY (A) and (B) will get +2 marks;
choosing ONLY (A) and (D) will get +2 marks;
choosing ONLY (B) and (D) will get +2 marks;
choosing ONLY (A) will get +1 mark;
choosing ONLY (B) will get +1 mark;
choosing ONLY (D) will get +1 mark;

[1]
 choosing no option (i.e. the question is unanswered) will get 0 marks; and
choosing any other combination of options will get –2 marks.
SECTION-2 (Maximum Marks: 12)
 This section contains FOUR (04) questions.
 Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the correct answer.
 For each question, choose the option corresponding to the correct answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : –1 In all other cases.

SECTION-3 (Maximum Marks: 24)

This section contains SIX (06) questions.
 The answer to each question is a NON-NEGATIVE INTEGER.
 For each question, enter the correct integer corresponding to the answer using the mouse and the onscreen
 virtual numeric keypad in the place designated to enter the answer.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If ONLY the correct integer is entered;
Zero Marks : 0 In all other cases.

SECTION-4 (Maximum Marks: 12)

 This section contains FOUR (04) Matching List Sets.
 Each set has ONE Multiple Choice Question.
 Each set has TWO lists: List-I and List-II.
 FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY ONE of these
four options satisfies the condition asked in the Multiple Choice Question.
 Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 ONLY if the option corresponding to the correct combination is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered)
Negative Marks : –1 In all other cases.
OMR Instructions:
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completely. Half-filled or over-filled bubbles will not be read by the software.
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create problems during the evaluation.
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Name of the Student (In CAPITALS) : _______________________________________________________________

Roll Number : _____________________________________________________________________________________________

OMR Bar Code Number : ________________________________________________________________________________

Candidate’s Signature : _______________________________ Invigilator’s Signature _____________________

[2]
 IMPORTANT CONSTANTS

Speed of light in free space, : 3.00 × 108 ms–1

Permeability of free space, : 4 × 10–7 Hm–1
Permittivity of free space, : 8.85 × 10–12 Fm–1
The Planck constant, : 6.63 × 10–34 Js
Rest mass of electron, : 9.1 × 10–31 kg
Rest mass of proton, : 1.67 × 10–27 kg
Molar gas constant, : 8.31 JK–1 mol–1
The Avogadro constant, : 6.02 × 1023 mol–1
The Boltzmann constant, : 1.38 × 10–23 JK–1
Gravitational constant, : 6.67 × 10–11 N m2kg–2
Acceleration of free fall : 9.8 ms–2
Rydberg Constant : 1.097 × 107 m–1
Atomic mass unit : 1.67 × 10–27 kg
Charge on proton : 1.6 × 10–19 C

IMPORTANT VALUES

2 = 1.414 ln 10 = 2.303
3 = 1.732 log102 = 0.3010
5 = 2.236 log103= 0.4770
 = 3.142 log107 = 0.845
e (Euler’s constant) = 2.718

* Use above values unless otherwise specified in a question.

  

[3]
 PART-I (PHYSICS)
SECTION-1 1000 droplets to that of energy of big drop is .
One or More Than One Correct Type Questions
1. The area of two holes and are and , The value of is _____
respectively. The holes are at height ( ) and (A) 1 (B) 2
( ) from the surface of water. Find the (C) 3 (D) 4
correct option(s):
5. A copper rod long has a circular cross section
of radius 1 . One end is kept at and the
other at , and the surface is insulated so that
negligible heat is lost through the surface.
Thermal conductivity of copper is .
(A) The velocity of efflux at hole is 2 times the Find the temperature gradient .
velocity of efflux at hole . (A) (B)
(B) The velocity of efflux at hole is √ times (C) (D)
the velocity of efflux at hole .
(C) The discharge is same through both the holes. 6. A rod of length moves in plane with a
(D) The discharge through hole is √ times the velocity ( ̂ ̂) in a magnetic field
discharge through hole .
(̂ ̂ ̂ ) . The magnitude of induced
2. Refer to the plot of temperature versus time e.m.f. along the rod is:
showing the changes in the state of ice on heating
(not to scale).
Which of the following is correct?

(A) (B)
(C) (D)

7. Select the incorrect option

(A) The Youngs modulus and modulus of rigidity
exist only for solids
(B) The value of modulus of elasticity is
(A) The region represents ice and water in
independent of the magnitude of stress and
thermal equilibrium.
strain
(B) At B water starts boiling.
(C) The value of modulus of elasticity depends
(C) At C all the water gets converted into steam.
only on the nature of material of the body
(D) C to D represents water and steam in
(D) Only gases cannot exhibit a shearing stress
equilibrium at boiling point.
SECTION-3
3. A metal wire of length area of cross-section Non-Negative Integer Type Questions
and Young's modulus is stretched by a variable 8. A small spherical ball of radius and
force such that is always slightly greater than density falls freely under gravity
the elastic force of resistance in the wire. When through a a distance before entering a tank of
the elongation of the wire is : water. If after entering the water the velocity of
(A) the work done by is ball does not change and it continue to fall with
same constant velocity inside water, then the
(B) the work done by is value of will be m. (Given ,
(C) the elastic potential energy stored in the wire viscosity of water )
is
9. Glycerine of density is
(D) heat is produced during the elongation
flowing through the conical section of pipe. The
area of cross-section of the pipe at its ends is
SECTION-2
and and pressure drop across its
Single Correct Type Questions
4. A big drop is formed by coalescing 1000 small length is . The rate of flow of glycerine
droplets of water. The ratio of surface energy of through the pipe is . The value
of is
[4]
10. A spherical tungsten piece of radius is Newton’s law
(B)  = 3 (2)
suspended in an evacuated chamber maintained at of cooling
300 . The piece is maintained at by 1
C Ideal gas
heating it electrically. The rate at which the (C)  Q (3)
equation
electrical energy must be supplied Watt. Find P T
(Nearest integer). The emissivity of tungsten is dQ Coefficient of
and the stefan constant is (D)   k (T2  T1 ) (4)
dt expansion
(A) (A) → (4); (B) (2); (C) → (3); (D) → (1)
(B) (A) → (1); (B) → (2); (C) → (3); (D) → (4)
11. Figure shows a square loop of resistance 1 Ω of
(C) (A) → (3) ; (B) → (4); (C) → (1); (D) → (2)
side being moved towards right at a constant
(D) (A) → (3); (B) → (4); (C) → (2); (D) → (1)
speed of . The front edge enters the
wide magnetic field ( ) at . Find the
16. Apply Kirchhoff’s laws to the circuit given below:
value of current induced in the loop as time
passes. For 0 < t < 1 sec.

12. The equation of alternating current for a circuit is

given by . Calculate frequency of
a.c. applied.
Given

13. A uniform material rod of length L is rotated in a

Now, match the following columns and select the
horizontal plane about a vertical axis through one
correct option from the codes given below.
of its ends. The angular speed of rotation is . It
Column-I Column-II
is given that density and Young’s modulus of the
rod are and Y respectively. The increase in
Current through
length of the rod is . Find the value of x. i. p.
inductor

SECTION-4
Matrix Match Type Questions Potential drop
ii. q.
14. A liquid is flowing through a pipe of non-uniform across inductor
cross-section of the pipe is less, match the Potential
following columns. difference
Column-I Column-II iii. r.
between points a
Volume of liquid and c.
A. p. is less
flowing per second Potential
B. Speed of Liquid q. Is more difference
C. Pressure of liquid r. Is same iv. s.
between points a
s. None of these and b.
(A) A-(q); B-(p); C-(r)
Potential
(B) A-(p); B-(q); C-(r)
difference
(C) A-(r); B-(q); C-(p) v. t.
between points c
(D) A-(r); B-(q); C-(s) and d.

15. Match the column I and column II. i ii iii iv v

(A) p q r s t
Column I Column II (B) p r q t s
Molar specific (C) t s r q p
(A) PV = RT (1)
heat (D) t s q p r

[5]
17. Match the following:

Ratio of
longitudinal or
Modulus of
(A) tensile stress to (p)
Rigidly
longitudinal
strain
Ratio of
normal or
hydrostatic Poisson’s
(B) (q)
stress to ratio
volumetric
strain
Ratio of lateral
strain to Bulk
(C) (r)
longitudinal modulus
strain
Ratio of
tangential Young’s
(D) (s)
stress to shear modulus
strain
(A) A→s; B→r; C→q; D→p
(B) A→r; B→s; C→p; D→q
(C) A→q; B→s; C→p; D→r
(D) None of these
PART-II (CHEMISTRY)
SECTION-1 (D) In metal carbonyls extent of synergic
One or More Than One Correct Type Questions bonding will increase with increase in
18. Benzyl isocyanide can be obtained by: positive charge on central metal ion.

(A)
20. Which of the following reactions will yield
benzaldehyde as a product?
(B) (i)SOCl , Quinoline
(A) 
2 
(ii) H 2 /Pd/BaSO 4

(C)

CrO /H SO
(B) 
3 2 4

(D)

19. Select the correct statement about metal carbonyl (i) NaBH
complex compounds: (C) 
4
(ii) PCC
(A) Metal carbon bond in metal carbonyls
possess both  and  character.
(i) CrO , (CH CO) O
(B) Due to synergic bonding metal carbon bond (D) 
3 3

2

(ii) H3O , 
becomes weak.
(C) Due to synergic bonding carbon oxygen
bond becomes weak.

[6]
 SECTION-2
Single Correct Type Questions
21. Silica dissolves in excess of HF due to formation
of
(A) SiF4 (B) SiH4
(C) H2SiF6 (D) H2SiF4
27. Consider the following chemical reaction.
22. The structure of A in the given reaction is: (1) Re d hot Fe tube, 873K
HC  CH  Product
(2) CO  HCl/AlCl 3
The number of sp2 hybridized carbon atom(s)
present in the product is________

28. Total number of stereoisomer of [M(AB)3] is:

(A) (B)
29. In the following reaction sequence, the amount of
D (in g) formed from 10 moles of acetophenone
is____.
(C) (D) (Atomic weight in g mol–1: H = 1, C = 12,
N = 14, O = 16, Br = 80. The yield (%)
corresponding to the product in each step is given
23. IUPAC Name of the compound in the parenthesis).

(A) 2-Hydroxy-3-bromo butanoic acid NaOBr NH / 


  A 
3
 B
(B) 3-Hydroxy-2-bromo butanoic acid H3O (60%) (50%)
(C) 2-Bromo-3-hydroxy butanoic acid Br /KOH Br (3 equiv)

2 C 
2  D
(D) 3-Bromo-2-hydroxy butanoic acid (50%) AcOH (20%)

24. Benzene diazonium chloride on reaction with 30. How many purine bases are present in DNA?
aniline in the presence of dilute hydrochloric acid
gives: SECTION-4
Matrix Match Type Questions
(A) 31. Match the following:
List-I List-II

Gatterman
(B) P. 1. Koch
reaction

(C) Etard
Q. 2.
reaction

(D)
Stephen
R. 3.
reaction

SECTION-3
Non-Negative Integer Type Questions
25. Consider the following transformation Rosenmund
S. 4.
Cr(CO)x  Cr(CO)y(NO)z reaction
If both reactant and product follow EAN rule,
then calculate value of x + z – y Aldol
5.
(where x, y and z are natural numbers). condensation
(A) P-4, Q-2, R-5, S-1
26. The number of aromatic species in given (B) P-1, Q-3, R-2, S-4
compound is ______ (C) P-5, Q-1, R-3, S-2
(D) P-4, Q-3, R-2, S-1
[7]
32. Match List-I with List-II. reaction
List-I List-II Secondary
5.
P. SO 2- 1. Chelating agent amine
4
(A) P-2, Q-3, R-4, S-5
Q. SCN– 2. Tridentate
(B) P-2, Q-3, R-1, S-4
R. dmg– 3. Ambidentate
(C) P-1, Q-3, R-4, S-5
S. NO+ 4. Flexidentate
(D) P-3, Q-2, R-1, S-5
5. Positive ligand
(A) P-4, Q-3, R-1, S-2
34. Match List-I with List-II.
(B) P-3, Q-1, R-2, S-5
List- I List- II
(C) P-4, Q-3, R-1, S-5
P. Glucose + HI 1. Gluconic acid
(D) P-1, Q-5, R-4, S-3
Glucose + Br2 /
Q. 2. Benzoic acid
water
33. Match List-I with List-II.
Glucose + acetic
List-I List-II R. 3. Hexane
anhydride
Tertiary
P. C6H5SO2Cl 1. S. Glucose + HNO3 4. Saccharic acid
amine
Glucose
Conversion of amide Hinsberg's 5.
Q. 2. pentacetate
to amine Reagent
(A) P-1, Q-3, R-5, S-4
Conversion of primary Hofmann's
(B) P-3, Q-1, R-5, S-4
R. amine to isocyanide 3. bromamide
(C) P-3, Q-2, R-1, S-5
reaction reaction
(D) P-1, Q-3, R-2, S-4
Carbyl
S. Dimethyl amine 4.
amine

PART-III (MATHEMATICS)
SECTION-1  5x , x2
One or More Than One Correct Type Questions x
35. Let f : R  R be a non-zero polynomial 37. Let f  x    , then :
   4|2  t| dt , x2
function of least degree such that f(3x) = f '(x).f 0
"(x) then (A) f (x) is continuous but not differentiable at x = 2.
(A) Degree of f(x) is 3 (B) f(x) is not continuous at x = 2.
(B) f (2) = 12
(C) f(x) is differentiable everywhere x   2,  
(C) f (x) is a bijective function
(D) f (2) = 8 (D) The right hand derivative of f (x) at x = 3
does not exist.
 a  x  b  x2 , 1 x  2

36. Let f  x   3 x    a  b  x  c , 2  x  4 SECTION-2
 Single Correct Type Questions
 bx 2  ax , x4
 1 
(where [ ], { } denotes greatest integer function 38. If y  tan 1  +
 cos x  cosx  1 
2
and fractional part function respectively) then
 1 
which of the following is/are true? tan 1   +... upto n terms then
(A) f (x) is continuous at x = 2 then a + b = 0  cos x  3cosx  3 
2

(B) f (x) is never be continuous at x = 3 y ' (0) is equal to

(C) For a = 2, b = –2 and c = 0, f(x) has jump (A) 0
discontinuity at x = 2
(B) 1
(D) If lim f  x   lim f  x 
x 3 x  4 
(C)
= lim f  x   lim f  x  , then c = 20b – 12
2
x 3 x  4 (D) 

[8]
39. Let A  z1  , B  z2  , C  z3  be the vertices of an 45. If y = y(x) is an implicit function of x such that

equilateral triangle ABC. The argument of the d2y

loge(x + y) = 6xy, then at x = 0 is equal to
 z  z  2 z1  dx 2
complex number  2 3  can be equal
 z3  z2 
1  1 
to
   
3
e x  1  x3 3   1  x2 2  1 sinx
   
(A) (B) 46 If   lim  
4 2 x 0 xsin 2 x
  18
(C) (D) then the value of  is equal to
3 6 5

20 x 21  21x 20  1 47. The number of points of non-differentiability of

40.
e 
lim is equal to
x 1 x
 e  sin  x  function f(x) = max{sin–1 |sin x|, cos–1 |sin x|} in
the interval (0, 100) is
210 210
(A) (B) SECTION-4
e e
Matrix Match Type Questions
105 105
(C) (D) 48. Match the List-I with List-II
e e
List-I List-II
xm f  x   h  x   1
41. If g  x   lim is continuous  ln2 
 
m 2 x m  3x  3 P. lim x 1 lnx  is 1. 0
x 
at x = 1, then the value of 2g(1) + 2f (1) – h(1) is
equal to
  
(given that f (x) and h (x) are continuous at x = 1) sec 
     2 x 
(A) 0 (B) –1 If L  lim sin  
Q. x 0   2  4 x  2. 1
(C) 1 (D) 3
then value of L is

SECTION-3
Non-Negative Integer Type Questions
42. The points of discontinuity cos2 x
If L  lim then the
1 1 x
1 e2 x  2ex
of y  g  u   2 , where u  2
u u2 x 1 R. value of [L] is (where [.] 3. 2
are x1 , x2 , x3 find the value of 2  x1  x2  x3  deontes greatest integer
function)
43. If f (0), f '(0), f "(0) exists and non zero such
 x
af  2 x   2bf    3 f  x 
2  3, x 2020
–2
 
that lim S. lim is 4.
x 0 
sin x 2
1 x  e 2021x

then a 2  b2 is equal to 5. –1
(A) P-3, Q-2, R-2, S-1
44. The function f : R  R satisfies
(B) P-1, Q-4, R-3, S-5
   
f x 2 f "( x)  f ( x) f  x 2 x  R, given that (C) P-1, Q-2, R-3, S-4
f (l) = 1 and f '''(1) = 8, then f ' (1) + f " (1) is equal to (D) P-4, Q-1, R-5, S-3

[9]
49. Match the list. List-I List-II
Number of possible values
List-I List-II P. 1. 0
of b is
If the mid-point of Sum of all possible values
Q. 2. 1
chord of of a is

x2 y 2 3 7 Value of

d g  f  x 
at x
P. ellipse   1 , is 1. R. dx 3. 2
25 36 2
= 4 is
(0, 2) then the length of If f (x) is non differentiable
the chord is: S. at k points, then the value 4. 4
of k is
The line 2x + y = a greater
5.
touches the than 4
Q. 2. 2 3 (A) P-1, Q-2, R-4, S-3
hyperbola x 2  2 y 2  9, (B) P-1, Q-2, R-5, S-3
if |a| is equal to (C) P-3, Q-1, R-5, S-4
(D) P-3, Q-2, R-4, S-3
If y  2 x   is a
normal to the 20 2
R. 3. 51. Match the List-I with List-II
parabola y  4 x, then
2
3 List-I List-II

value of  is :
P.
If y  n x
2
   1
then y'    is
 2 1. 4
The product of length equal to
of the perpendicular 1 3 
If f  x   x  tan 1 x 
from the two focii on 2 4
S. any tangent to the 4. 30 Q. and g  x   f 1  x  , 2. 5

x2 y 2 1
hyperbola  1 then 16 g "   is equal to
9 15 2

If f  x   x
is k, then k is: xx
R. , f "(1) is equal 3. 2
5. 15 to
If

 
(A) P-4, Q-2, R-1, S-5
n  e  1 e xy  x 2  x 2  y 2 ,
(B) P-3, Q-2, R-5, S-1 S. 4. 1
(C) P-1, Q-5, R-2, S-4 dy
then is
(D) P-3, Q-1, R-2, S-5 dx 1, 0 
Harmonic
 x  a , x0
Let f  x   
mean of 3
50. 5.
 x  2 x 1 , x  0 3
2
and
2
 x 1 , x0
and g  x    2 , a, b are (A) P-4; Q-2; R-5; S-3,5
 x  2  b  x   1 , x  0 (B) P-1,5; Q-2; R-3; S-5
non-negative real numbers. If (gof)(x) is (C) P-1; Q-2; R-3,5; S-3,5
continuous for all real x (D) P-4; Q-1;R-3,5; S-3,5

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