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NMR, ESR, NQR & Mossbauer Spectroscopy Guide

The document outlines a comprehensive curriculum on NMR, ESR, NQR, and Mossbauer spectroscopy, covering fundamental principles, measurement techniques, and applications in chemical analysis. It details concepts such as nuclear spin, chemical shifts, coupling constants, and advanced techniques like FT-NMR and two-dimensional spectroscopy. Additionally, it discusses the principles and applications of ESR, NQR, and Mossbauer spectroscopy, including spectral parameters and their significance in studying various compounds.

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ahbchemistry
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37 views1 page

NMR, ESR, NQR & Mossbauer Spectroscopy Guide

The document outlines a comprehensive curriculum on NMR, ESR, NQR, and Mossbauer spectroscopy, covering fundamental principles, measurement techniques, and applications in chemical analysis. It details concepts such as nuclear spin, chemical shifts, coupling constants, and advanced techniques like FT-NMR and two-dimensional spectroscopy. Additionally, it discusses the principles and applications of ESR, NQR, and Mossbauer spectroscopy, including spectral parameters and their significance in studying various compounds.

Uploaded by

ahbchemistry
Copyright
© All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as DOCX, PDF, TXT or read online on Scribd

Unit-I: NMR Spectroscopy (16 Contact hours)

Basic principles, nuclear spin, spin angular momentum, quantization of angular momentum.
Nuclear magnetic moment, precessional (Larmor) frequency, energy levels in a magnetic field,
resonance absorption of radio frequency radiation. Population of energy levels, Relaxation
processes (T1, T2). Shielding and deshielding of magnetic nuclei. Chemical shift, its
measurement and factors influencing chemical shifts; local paramagnetic and diamagnetic
shielding, neighbouring group anisotropy and ring currents in aromatic systems Spin- Spin
coupling, coupling constants. Examples.
Vicinal coupling and electron correlation. Chemical equivalence and magnetic equivalence.
Fermi contact and Dirac Vector Model. Effect of Chemical exchange on spectra. Double
resonance techniques; spin decoupling, nuclear Overhauser enhancement. Instrumentation; FT-
NMR and its advantages. NMR studies of nuclei other than proton – 13C, 19F and 31P.
Unit I NMR Spectroscopy 16 hours
Basic concepts, Mechanism of Measurements, Chemical shift values for various classes of
compounds. Fourier Transform (FT), Techniques and advantages, Nuclear overhouser effect
(NOE). One bond coupling, two bond coupling, three bond coupling, second order spectra
A2, AB, AX, AB2, ABX, AX2, A2B2. Proton exchange, deuterium exchange, Peak
broadening exchange C-13 NMR: Carbon 13-chemical shifts, proton coupled and decoupled
spectra. Off-Resonance De-coupling, A quick dip into DEPT-45, DEPT-90, DEPT-135.
Introduction to two-dimensional spectroscopy methods, Cosy techniques, HETCOR
technique, NOESY.
Structure elucidation of organic compounds using combined spectroscopic methods.

Unit-II ESR Spectroscopy (16 Contact hours)


Basic principles- electron spin, magnetic moment of an electron and its interaction with applied
magnetic field. Splitting of spin energy states and absorption of microwave radiation. Hyperfine
coupling, Isotropic and anisotropic hyperfine coupling constants, Examples, Fermi contact, Spin
polarization effects, Dipolar coupling, Mc Conell equation.
Spin orbit coupling and significance of g tensors. Zero field splitting and Kramer's degeneracy
(fine structure), Advance Applications

Unit-III NQR & Mossbauer Spectroscopy: 16


hours
(a) Mossbauer Spectroscopy: Basic principles, Nuclear Recoil and Mossbauer Effect,
Spectral parameters such as isomer shift, quadrupole splitting and magnetic splitting,
spectrum display. Determination of Magnetic transition Temperature, Intermediate spin --
Determination of Spin crossover temperatures. Partial Isomer shift and partial Quadrupole
splitting. Application of the technique to the studies of (i) bonding and structure of Fe2+ and
Fe3+ compounds (ii) Sn2+ and Sn4+ compounds— nature of M—L bond, coordination number
and structure, (iii) detection of oxidation state and inequivalent MB atoms.

(b) NQR Spectroscopy: NQR isotopes, Nuclear quadruple moment; Electric field gradient;
nuclear quadruple coupling constant; Axial Symmetry, Asymmetric EFG, Effect of applied
magnetic field, Application

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