05-10-2025

9610ZJA802263250008 JA

PART 1 : PHYSICS

SECTION-I (i)

1) A smooth sphere A of mass m collides elastically with an identical sphere B at rest. The velocity of
A before collision is 8 m/s in a direction making 60° with the line joining the centres at the time of
impact. Which of the following is/are possible?

(A) The sphere A comes to rest after collision.

(B) The sphere B will move with a speed of 8 m/s after collision
(C) The directions of motion of A and B after collision are at right angles.
(D) The speed of B after collision is 4m/s

2) A particle strikes a horizontal smooth floor with a velocity u making an angle θ with the floor and
rebounds with velocity v making an angle ϕ with the floor. If the coefficient of restitution between
the particle and the floor is e, then:

(A) the impulse delivered by the floor to the body is mu(1 + e) sinθ.
(B) tan ϕ = e tan θ.

(C)

(D) the ratio of the final kinetic energy to the initial energy is (cos2θ + e2 sin2θ)

3) Figure shows seven identical blocks kept equidistant on a frictionless floor. Initially, blocks a and
b are moving rightward and block g is moving leftward, each with speed v = 3m/s. The other blocks
are stationary. A series of elastic collisions occurs. After the last collision the speed and direction of

motion of

(A) A will be at rest

(B) D will be 1.5 m/s towards left
(C) E will be at rest
(D) G will be 3 m/s towards right

SECTION-I (ii)

1) A particle A with a mass 2m is moving with a velocity u and hits a particle B of mass m at rest
(one dimensional motion). Find the value of n if change in the de-Broglie wavelength of the particle

A is . Treat the collision as elastic.

(A) 1
(B) 2
(C) 3
(D) 4

2) A spring block system with mass of block m and spring constant k is placed on a smooth
horizontal plane as shown in the diagram. The surface area of the block is A. A light beam of
intensity I is switched on from rightwards. Assuming completely reflective surface, the amplitude of

oscillations of the block is : (c speed of light in vaccum)

(A)

(B)

(C)

(D) Zero

3) Protons and singly ionized atoms of U235 & U238 are passed in turn (which means one after the
other and not at the same time) through a velocity selector and then enter a uniform magnetic field.
The protons describe semicircles of radius 10 mm. The separation between the ions of U235 and U238

after describing semicircle is given by

(A) 60 mm
(B) 30 mm
(C) 2350 mm
(D) 2380 mm

4) The given graph shows the variation of vs z for characteristics X-rays, lines 1, 2, 3, 4 shown in
the graph corresponds to any one of , Kβ, , Lβ, then Lβ is represented by (f = frequency, z =

Atomic number)

(A) line 1
(B) line 2
(C) line 3
(D) line 4
 SECTION-II

1) A system of uniform cylinders and plates is shown in figure. All the cylinders are identical and
there is no slipping at any contact. Velocity of lower & upper plate is V and 2V respectively as shown
in figure. Then the ratio of angular speed of the upper cylinders to lower cylinders is

2) Two blocks of masses m1 = 1kg and m2 = 2kg are connected by a spring of constant k = 100 N/m
and placed over a plank as shown. The coefficient of friction between m2 and plank is 0.5 and there
is no friction between m1 and plank. Initially the whole system, is at rest. The plank is now pulled to
right with constant acceleration a = 2 m/s2. Find the amplitude (in cm) of oscillation of block m1

relative to plank.

3) Two sources of sound S1 and S2 produce sound waves of same frequency 660 Hz. A listener is
moving from source S1 towards S2 with a constant speed u m/s and he hears 10 beats/s. The velocity
of sound is 330 m/s. Then, 2u (in m/s) is :

4) A tuning fork of frequency 480 Hz is used in an experiment for measuring speed of sound (ν) in air
by resonance tube method. Resonance is observed to occur at two successive lengths of the air
column, ℓ1 = 30 cm and ℓ2 = 70 cm. Then ν (in m/s) is equal to:

5) In an interference experiment the ratio of amplitudes of coherent waves is . The ratio of

maximum and minimum intensities of fringes will be :

6) There are three sources of sound of equal intensity with frequencies 400, 401, 402 vib/sec. The
number of beats heard per second is :

SECTION-I (iii)

1) Assume that a universe exists where plank's constant h, mass of electron, permittivity of free
space, electronic charge may be different from our universe. Predict the effect of each of the
constant on parameters of hydrogen atom.

List-I List-II

(P) h is more (1) Radius of atom is more

 (Q) me is lesser (2) Radius of atom is less

(R) ∈0 is lesser (3) Wavelength of first line of lyman series is larger.

(S) e is more (4) Speed of electron in 1st orbit is more.

(5) Angular momentum in ground state is more

(A) P → 1,3,5;Q → 1,5;R → 2,4;S → 2,4
(B) P → 1,3;Q → 1,3;R → 2,4;S → 2,4
(C) P → 1,3,5;Q → 1,3;R → 2,3,4;S → 2,3,4
(D) P → 1,3,5;Q → 1,3;R → 2,4;S → 2,4

2) Match list-I of nuclear process with list-II containing parent nucleus and one of end product of
each process and then select the correct answer using codes given below the lists.

List-I List-II

(I) Alpha decay (P)

(II) decay (Q)

(III) β⊕ decay (R)

(IV) neutron emission (S)

(T)
(A) I → T;II → S;III → P;IV → R
(B) I → T;II → P;III → Q;IV → S
(C) I → T;II → R;III → P;IV → S
(D) I → Q;II → R;III → S;IV → P

3) Answer the following by appropriately matching the lists based on the information given
in the paragraph.
A point source S emitting monochromatic light having wavelength λ is placed at a very small height
h above flat reflecting surface AB as shown in diagram. The intensity of the reflected light is 36% of
incident intensity. Interference fringes are observed on a screen placed parallel to the reflecting
surface at a large distance D (>>h) from it. The nature of interference fringes formed on screen is

circular. List-I gives some physical quantities and List-II gives some
possible values of these physical quantities (I0 is incident intensity)

List-I List-II

(I) Intensity of maxima (P)

(II) Intensity of minima (Q) 2.56 I0

 (III) Radius of first maxima (R) 0.16 I0

(IV) Radius of second maxima (S)

(T)

(U)
If h = 3λ, then CORRECT match is :
(A) I → Q;II → R;III → P;IV → U
(B) I → Q;II → R;III → T;IV → U
(C) I → Q;II → R;III → T;IV → S
(D) I → Q;II → R;III → U;IV → U

4) Consider a body rolling on a horizontal surface as shown in figure (Symbols have their usual

meaning)

List-I List-II

(P) Velocity is zero. (1) Point P

(Q) Speed is maximum (2) Point Q

(R) 0 < speed < vcm (3) Point R

(S) 1.3vcm < speed < 2 vcm (4) Point S

(5) Point T
(A) P → 3;Q → 2;R → 4;S → 1
(B) P → 3;Q → 1;R → 5;S → 2
(C) P → 3;Q → 1;R → 4;S → 2
(D) P → 1;Q → 2;R → 1;S → 2

PART 2 : CHEMISTRY

SECTION-I (i)

1) "Aspartame" is roughly 100 times as sweet as cane sugar. On complete hydrolysis of aspartame,
products obtained is/are :
(A)

(B)

(C) CH3OH

(D)

2)

Which of the following will give product having one chiral atom after reaction is completed -

(A)

(B)

(C)

(D)

3) In which of the following reaction deuterium exchange is observed?

(A)

(B)
(C)

(D)

SECTION-I (ii)

1) At 25°C, Ka of weak monobasic acid, HA, is 5 × 10–6. Kb of A– is -

(A) 5 × 10–6
(B) 2 × 105
(C) 2 × 10–9
(D) 5 × 10–8

2) + Salt of acid, A is :

(A) CH4
(B) CHI3
(C) CHCl3
(D) CH3–COONa

3) can be prepared in better way by reacting :

(A)
with C2H5OΘNa⊕

(B)
with C2H5Cl
(C) Both
(D) None of these

4) For a reversible adiabatic ideal gas expansion is equal to :

(A)

(B)
(C)

(D)

SECTION-II

1) Enthalpy for the reaction, A+(aq.) + B–(aq) → AB(s) is –20 kcal. Magnitude of enthalpy of
formation of A+(aq) and B–(aq) are in the ratio 4 : 5. Formation of A+(aq) is an endothermic process
whereas formation of B–(aq) is an exothermic process enthalpy of formation of AB(s) is –21.5 kcal
mol–1. Calculate the enthalpy of formation of A+(aq) in Kcal mol–1.

2) The standard enthalpy and standard entropy of decomposition of N2O4 to NO2 are 55.0 kJ mol–1
and 175.0 J/K/mol respectively. The standard free energy change for this reaction at 25°C in J mol–1
is _______ (Nearest integer)

3) When 0.05 mole of HC1 is added in 200 ml of a buffer solution, the pH of the solution
decreases by 0.05 unit. What is the buffer capacity of the solution?

4) A homogeneous ideal gaseous reaction AB2(g) ⇌ A(g) + 2B(g) is carried out in a 25 litre flask at 27°C.
The initial amount of AB2 was 1 mole and the equilibrium pressure was 1.9 atm. The value of KP is x
× 10–2. The value of x is______.
(Integer answer)

5) Total number of enol possible for the compound formed during given reaction will be (Including
stereoisomer):

6)

Consider the following (X):

If 0.5 moles of the compound (X) are hydrolysed in a alkaline medium and then heated. How many
moles of CO2 are produced ?

SECTION-I (iii)
1) Match the compounds in Column I with their characteristics test(s) / reaction(s) given in
Column II.

Column-I Column-II

Sodium fusion extract of the compound

(P) (1)
given blood red solution with FeCl3 aqueous solution

(Q) (2) Gives white ppt with Pb(NO3)2 aqueous solution

(R) (3) Gives coloured ppt with AgNO3 aqueous solution

Sodium fusion extract of the compound

(S) (4) obtained from limited / excess of sodium
gives prussian blue colour test

(5) Gives coloured ppt with aldehyde

Identify the CORRECT option in the following

(A) P → 2,3,5;Q → 2,4;R → 1,4,5;S → 2,5
(B) P → 3,4;Q → 2,5;R → 2;S → 1,5
(C) P → 3,4;Q → 2;R → 1,2,4;S → 2,3,4,5
(D) P → 3,5;Q → 1,2,5;R → 3,4;S → 1,2,3,4,5

2) Match the column :

Column - I Column - II
(Carbohydrate) (Properties)

(A) Starch (P) Mutarotation

(B) Sucrose (Q) Non reducing sugar

(C) Lactose (R) β-glycosidic bond

(D) Maltose (S) α-glycosidic bond

(T) Reducing sugar

(A) A → QS;B → QRS;C → PRT;D → PST

(B) A → QR;B → SQT;C → PQRT;D → PQT
(C) A → QS;B → QRS;C → PQRS;D → PQS
(D) A → QT;B → RST;C → QRST;D → PST

3) Match the columns.

 Column-I Column-II

Introduction of hydrogen gas at constant volume shift

(A) 2NH3(g) N2(g) + 3H2(g) (P)
equilibrium back.

(B) PCl5(g) PCl3(g) + Cl2(g) (Q) α increases on increasing temperature.

On adding inert gas at constant volume, equilibrium

(C) 2HI(g) H2(g) + I2(g) (R)
state does not change.

On increasing the pressure, concentration of all

(D) NH4HS(s) NH3(g) + H2S(g) (S)
reactants increases.

(T) α is independent of equilibrium pressure.

(A) A → P;B → Q;C → R;D → T
(B) A → P;B → Q;C → R;D → S
(C) A → T;B → S;C → T;D → P
(D) A → P;B → Q;C → T;D → Q

4)

Column-I Column-II
(salt solution in water) (Nature of hydrolysis)

(A) NaCl (P) Cationic hydrolysis only

(B) CH3COONa (Q) Anionic hydrolysis only

(C) NH4CN (R) Both cationic and anionic hydrolysis

(D) CH3COONH4 (S) Does not undergo hydrolysis

(T) pH is independent of initial concentration.

(A) A → PS;B → Q;C → QR;D → TS
(B) A → ST;B → Q;C → RT;D → RT
(C) A → PT;B → R;C → RS;D → PT
(D) A → QR;B → PS;C → RS;D → Q

PART 3 : MATHEMATICS

SECTION-I (i)

1) Consider two fixed points A(1, 0, 0) and P(1, 0, 1). If OA (where 'O' is origin) is rotated through 'O'
in xy-plane by a variable angle θ, to reach a new position OB, then which of the following
statement(s) is(are) correct ?

(A)
Maximum volume of tetrahedron OAPB is .
(B) Maximum volume of tetrahedron OAPB is unity.
(C)
The distance of plane OPB from point A is .
(D) Equation of the plane OPB is (z – x) sinθ + y cos θ = 0.

2) In a triangle ABC points D, E lie on sides AC and AB respectively. M and N are mid points of side
BD and CE respectively. If Δ1 is area of triangle AMN, Δ2 be the area of triangle ADE, Δ be area of
triangle ABC, Δ3 be area of quadrilateral BCDE, Δ4 be area of quadrilateral MNDE. Which of the
following is/are always true ?

(A) 4Δ1 = Δ3
(B) 4Δ1 + Δ2 = Δ
(C) Δ1 = Δ4
(D) 4Δ4 = Δ2 + Δ

3) Let G be a circle of radius R > 0. Let G1, G2, …, Gn be n circles of equal radius r > 0. Suppose each
of the n circles G1, G2, …, Gn touches the circle G externally. Also, for i = 1, 2, …, n − 1, the circle Gi
touches Gi+1 externally, and Gn touches G1 externally. Then, which of the following statements is/are
TRUE?

(A) If n = 4, then
(B) If n = 5, then r < R
(C) If n = 8, then
If n = 12, then
(D)

SECTION-I (ii)

1) A rectangle ABCD of dimension 'a' and '2a' is folded along diagonal BD such that planes ABD and
C'BD are perpendicular to each other. If C point goes to C', then the distance AC' is

(A)
(B)

(C)

(D)

2) Tetrahedron ABCD has side length AB = CD = 12, these edges are perpendicular to each other.
Let E and F be the mid-point of AB and CD respectively, given that EF = 10 and is perpendicular to
both AB and CD then the volume of ABCD is

(A) 200
(B) 240
(C) 280
(D) 320
3) Let n be the number of integral values of x, which satisfy the equation
tan–1x – sin–1x = cos–1x – cot–1x .

Let where are unit vectors and angle between is

then the value of (n + 2 ) is equal to

(A) 10

(B)

(C)

(D) 30

4) Curve ax2 + 2hxy + by2 – 2gx – 2ƒy + c = 0 and a'x2 – 2hxy + (a' + a – b)y2 – 2g'x – 2ƒ'y + c = 0

intersect at 4 concyclic points A, B, C and D. If P is the point , (a+a' ≠ 0), then the

value of is

(A) 5

(B)

(C)

(D)

SECTION-II

1) The centres of two circles C1 and C2 of radii 4 and 9 respectively are at a distance of 15 units from
each other. Let L1 be one direct common tangent to these circles and there are 'n' circles which

touches given both circle and line L. Let r1, r2, ...... rn be the radii of these circles then 18 is
equal to

2) Let where θ is the angle between and . If volume of the

parallelopiped whose coterminous edges are represented by the vectors and

(Where angle between and is taken from the equation 2g(θ)–l = 0) is where p, q ∈ N, then the
least value of p + q is ( & are unit vectors)
3) The shortest distance between (1 – x)2 + (x – y)2 + (y – z)2 + z2 = and 4x + 2y + 4z + 7 = 0 in 3-
dimensional coordinates system is equal to

4) Let y = y(x) be the solution of the differential equation dx = (x + 2) dy,

y(1) = 1. If the domain of y = y(x) is an open interval (α, β), then |α + β| is equal to

5) Let Sk be the area bounded by the curve y = x2 (1 – x)k and the lines x = 0, y = 0 and x = 1 and

equals , (where p, q are co prime). Also . Find the value of

6) The sides of a triangle have the combined equation x2 –3y2 –2xy + 8y – 4 = 0. The third side, which
is variable always passes through the point (–5, –1). If the range of values of the slope of the third

line so that the origin is an interior point of the triangle, lies in the interval (a, b), then find
.

SECTION-I (iii)

1) L1 : 3x + y = 0
L2 : 4x + 3y + 5 = 0
Consider family of straight lines.
L1 + λL2 = 0, λ ∈ R
Match List-I with List-II and select the correct answer using the code given below the list

List-I List-II

thrice of absolute value of y-intercept of line

(P) (1) 2
having slope
(where [.] represent greatest integer function)

Square of maximum distance of point (2, –6) from

(Q) (2) 4
any member of family is

If locus of foot of perpendicular drawn from (0, 0)

(R) to any member of family is x2 + y2 + ax + by = 0, (3) 5
then (a + b) is

If (α, β) be the image of (0, 0) with respect to L2,

(S) (4) 10
then (α2 + β2) is

(5) 13
(A) P → 3;Q → 4;R → 1;S → 2
(B) P → 3;Q → 4;R → 5;S → 2
(C) P → 2;Q → 4;R → 1;S → 3
(D) P → 2;Q → 4;R → 5;S → 3

2) f(x) = x +

List-I List-II

Value of [Sum of coefficients of f(x)] –1 is

(P) (1) 2
(where [ ] → G.I.F.)

(Q) Number of real solutions of f(x) = 0 (2) 3

(R) Number of real solutions of f(x) = sin x (3) 0

(S) Number of real solutions of f(x) = sin |x| (4) 1

(5) 4
(A) P → 1;Q → 4;R → 3;S → 5
(B) P → 4;Q → 3;R → 1;S → 5
(C) P → 4;Q → 3;R → 2;S → 1
(D) P → 3;Q → 4;R → 2;S → 1

3) The function is differentiable and continuous and for all x in the interval [4, 8]

If
Identify correct statements

List - I List - II

(P) (1) 0
No. of solutions of is

(Q) (2) 1
is

(R) (3) 4
is

(S) No. of solutions of f(x) = e–x (4) 3

(5) 8
(A) P → 2;Q → 4;R → 5;S → 2
(B) P → 2;Q → 3;R → 4;S → 5
(C) P → 4;Q → 3;R → 2;S → 1
(D) P → 2;Q → 4;R → 5;S → 1
4) Answer the following by appropriately matching the lists based on the information given
in the paragraph.

Consider 2 differentiable functions ƒ(x), g(x) satisfying and

, (ƒ(x) > 0, ∀ x ∈ R)

List-I List-II

(P) ƒ'(1) (1) –2

(Q) g'(2) (2) 2

(R) (3) 11

(S) (4) 13

(5) 3
Which of the following is the CORRECT combination ?
(A) P → 1;Q → 4;R → 3;S → 1
(B) P → 2;Q → 4;R → 5;S → 1
(C) P → 2;Q → 3;R → 4;S → 1
(D) P → 1;Q → 4;R → 5;S → 2
 ANSWER KEYS

PART 1 : PHYSICS

SECTION-I (i)

Q. 1 2 3
A. C,D A,B,C,D C,D

SECTION-I (ii)

Q. 4 5 6 7
A. A B A C

SECTION-II

Q. 8 9 10 11 12 13
A. 3 2 5 384 4 2

SECTION-I (iii)

Q. 14 15 16 17
A. D C A B

PART 2 : CHEMISTRY

SECTION-I (i)

Q. 18 19 20
A. A,B,C B,C,D A,B,C

SECTION-I (ii)

Q. 21 22 23 24
A. C C B B

SECTION-II

Q. 25 26 27 28 29 30
A. 6 2850 5 73 3 2

SECTION-I (iii)

Q. 31 32 33 34
A. C A B B

PART 3 : MATHEMATICS
 SECTION-I (i)

Q. 35 36 37
A. A,C,D A,B,C C,D

SECTION-I (ii)

Q. 38 39 40 41
A. C B C D

SECTION-II

Q. 42 43 44 45 46 47
A. 1261 5 2 4 11 24

SECTION-I (iii)

Q. 48 49 50 51
A. A D D B
 SOLUTIONS

PART 1 : PHYSICS

1) Explain Question: Question asks about the speed & direction of velocities after an oblique
collision.
Concept: If e = 1 velocities gets exchanged along live of impact
Solution: Sphere A moving with velocity v has a component v/2 along the line joining the
centres of the spheres at the time of collision and another component perpendicular to
the previous direction. After collision the component along the line will interchange i.e. B will
move with v/2 velocity i.e. 4 m/s along the line joining the centres and A moves with
velocity at perpendicular direction to B.
Final Answer: (C,D)

2) Explain Question: Question asks about the speed energy & velocities of a ball after
striking a floor of coefficient of restitution e.
Concept: Along line of impact V = eu
Solution:

Impuse (J) = ΔP = mv sin ϕ – m(–u sinθ)

= m(v sin ϕ + u sinθ)
= m(Vsep + Vapp)

= m(eVapp + Vapp)
= m Vapp (e + 1)
J = mu sin θ(1 + e)
In horizontal direction, momentum is conserved :

u cosθ = v cosϕ or

or
or tan ϕ = e tan θ

in vertical direction,
or v sin ϕ = eu sin θ

final kinetic energy =

 initial kinetic energy =

ratio =
Final Answer: (A,B,C,D)

3) Explain Question: Multiple collisions of elastic nature between 7 particles and final
velocities has been asked
Concept: In elastic collision velocities our exchanged.
Solution: a collides with b after b has collided with c & has come to rest. Similarly when d & e
collide they exchange their velocities after which c & d collide & exchange their velocities.
Finally a is moving leftwards & f & g are moving rightwards.
Final Answer: (C,D)

4) Explain Question: Question asks about de-Broglie wavelength for a moving particle.

Concept:
Solution: 2mu + 0 = 2mV1 + mV2
⇒ 2u = 2V1 + V2

1=
u = V2 – V1
V1 = u/3
Δλ = λ′–λ

=
Final Answer: (A)

5) Explain Question: Question asks the amplitude of SHM in the system when it is forced no
oscillation by radiation pressure.

Concept: and

Solution: Pressure =

Force =

Amplitude =
Final Answer: (B)

6) Explain Question: Question asks about radii of circular path of moving change in uniform
magnetic field.

Concept:
Solution: R =

RP =

Δx = 2 × = 6 × 10 mm = 60 mm.
Final Answer: (A)

7) Explain Question: It has been asked to identify the graph corresponding to Lβ line of x-Ray
spectrum.
Concept:
Solution: For a given value of Z, energy of K–series is more than L–series, also β–line has
more energy as compared to α–line.
Final Answer: (C)

8) Explain Question: Ratio of ω of cylinder in pure rolling with moving surfaces has been
asked.
Concept:
Solution: Since there is no slipping at any interface, the velocities of bottom and upper most
point of lower and upper cylinder are shown in figure.

Angular velocity of upper cylinder = =

Angular velocity of lower cylinder = =

The ratio is
Final Answer: (3)

9) Explain Question: Amplitude of SHM of a block in system of masses having spring and
plank has been asked.
Concept: KXmax = m.a pseudo force
Solution: Viewed from frame of plank

[initial condition]

[at the time of maximum compression]

and
⇒ Friction is static

kA = m1a
Final Answer: (2)

10) Explain Question: Find velocity of observer has been asked if the beat frequency heard
by the observer is given.
Concept: fbeat = f1 – f2
Solution: f = 660 Hz, ν = 330 m/s

f1 = f

f2 = f

f2 – f1 = [ν + u – (ν – u)]

10 = f2 – f1 = [2u]
u = 2.5 m/s
Final Answer: (5)

11) Explain Question: It has bean asked to calculate speed of sound in resonance tube by
resonance column experiment.

Concept:
Solution: ν = 2f (l2 – l1)
ν = 2 × 480 × (70 – 30) × 10–2
ν = 960 × 40 × 10–2
ν = 38400 × 10–2 m/s
ν = 384 m/s
Final Answer: (384)

12) Explain Question: Ratio of intensities of brightest and dimmest fringe has been asked in
an interference experiment.

Concept: & I α A2

Solution: Given

Ratio of intensities,

Now,
Final Answer: (4)
13) Explain Question: It is asked to find no. of beats heard when three different frequencies
are sounded together.
Concept: n = nmax – nmin
Solution: Theory
Final Answer: (2)

14) Explain Question: Effect on different parameters like, radius, angular momentum,
velocity & wavelength has been asked by changing value of h0 me, e0 & e.
Concept: Use the formula of Radius, velocity, velocity is different orbits of Bohr model.

Solution:

Final Answer: (D)

15) Explain Question: Different types of decay has been asked to identify.
Concept: α - decay -
β - decay -
β– decay
Solution: (β+ decay)
(proton decay)

(α-decay)
Final Answer: (C)

16) Explain Question: It has been asked about intensity at different 10 carbon in a YDSE
experiment.

Concept: For maxima ; minima

Solution: Let incident intensity is I0 then reflected intensity is 0.36 I0

At point B phase difference between two waves is

 ⇒
for first maxima (h = 2λ)
Δx = λ

∴ D2 + r2 = 64 D2 ⇒
For Second maxima
Δx = 2λ

⇒ 9r2 + 9D2 = 64D2

9r2 = 55D2 ⇒ ⇒ h = 3λ
For second maxima

⇒ D2 + r2 = 16D2 ⇒
For first maxima

⇒ ⇒
Final Answer: (A)

17) Explain Question: Question asks about the velocity of different points on the periphery of
a pure rolling circular object on fixed surface.
Concept: V = ωR

Solution: C is ICOR & speed of point at a distance r from C is

Final Answer: (B)

PART 2 : CHEMISTRY

18) Explain Question: Find products on complete hydrolysis of aspartame.

Concept: On hydrolysis ester and amides breakdown.
Solution:
Final Answer: (ABC)

19) Explain Question: Identify chiral atom in given compounds.

Concept: Chiral carbon - all four valencies are different.
Solution:

Final Answer: (BCD)

20) Explain Question: Which reaction observed deuterium exchange

Concept: All aldehyde & ketone having α-H shows deuterium exchange.
Solution:

Similarly, all aldehyde/ketone having a-H can undergo deuterium exchange

Final Answer: (ABC)

21) Explain Question: Find Kb for A–

Concept: This question is based on conjugate acid-base pair.
Solution:
HA ⇌ H+ + A –
acid conjugate base
(Ka) (Kb)
∵ Ka × Kb = K w

∴ Kb for A– =
= 2 × 10–-9
 Final Answer:(C)

22)

Explain Question: Question is asking about product of given reaction.

Concept: Halo form reaction
Solution: Methyl ketone gives halofarm with NaOH/X2

Electrolysis of brine NaCl(aq) NaOH + Cl2+H2

Final Answer: (C)

23)

Explain Question: Question is asking to select better pair of reactants to prepare Ph–O–Et.
Concept: This question is based on williamson's ether synthesis.
Solution: Williamson's ether synthesis follows SN2 reaction and for SN2 reaction substrate
should not be arylic or vinylic halide.
To prepare Ph–O–Et. there are two possibilities of reactions.

Williamson's synthesis

I. + Et – Cl →

II. + Ph – Cl
(Aryl halide)

Ph – Cl does not give SN2 So II is not good better pair of reactant is I.

Final Answer: (B)

24) Explain Question: For reversible adiabatic expansion calculate

Concept: For adiabatic process ⇒ PVγ = constant.
Solution:
Reversible adiabatic ideal gas
PVγ = constant
ℓnP + γℓnV = constant
 (Differentiating both sides)
Final Answer: (B)

25) Explain Question: Calculate enthalpy of formation of A+(aq.) using given data.
Concept: Enthalpy of reaction =
Solution:
A+(aq) + B– (aq) → AB(s)
0
ΔfH (kcal/mole) 4x –5x –21.5
0
ΔrH = – 20 = (–21.5) – (4x – 5x)
x = 1.5
0
(ΔfH )A+ = 4x = 6
Final Answer: (6)

26) Explain Question: Calculate for the given reaction

Concept:
ΔG° = ΔH° – TΔS°
Solution:
= 55 kJ/mol, T = 298 K
= 175 J/mol

⇒ = 55000 J/mol – 298 × 175 J/mol

⇒ = 55000 – 52150
⇒ = 2850 J/mol
Final Answer: (2850)

27) Explain Question: Calculate buffer capacity of solution.

Concept: This question is based on buffer solution.
Solution:
Buffer capacity: It is defined as the amount of strong acid or strong base required to change
the pH of one litre buffer solution by one unit.

Buffer capacity (ϕ) =

=5
Final Answer:(5)

28) Explain Question: Calculate Kp for the given reaction

Concept: Total moles at equilibrium (n) = and apply Dalton’s law of partial pressure.
Solution:
 AB2 ⇌ A + 2B
t=0 1 0 0
t = teq 1–α α 2α
n Total = 1 – α + α + 2α = 1 + 2α
From ideal gas eq.
PV = nRT
1.9 × 25 = nT × 0.082 × 300
nT = 1.93
1 + 2α = 1.93

α= = 0.465

⇒ 0.72807
⇒ 0.72854 × 10 ⇒ 73 × 10–2
–2

Final Answer: (73)

29) Explain Question: Calculate total enol products in the given reaction.
Concept: Substitution on acid halide followed by tautomerism.
Solution:

Final Answer: (3)

30) Explain Question: On hydrolysis of given compound how many moles of CO2 obtained.
Concept: Follow β-keto decarboxylation.
Solution:
One mole of the above compound (X) on hydrolysis followed by heating produces 4 moles
of CO2.
Hence, 0.5 M of X produce 2 moles of CO2.
Final Answer: (2)
31) Explain Question: Match the correct option.
Concept: Reaction of nitrogen containing compounds with different reagents.
Solution:

Final Answer: (C)

32) Explain Question: Match with correct property of carbohydrate.
Concept: Match starch, sucrose, lactose & maltose with properties such as mutarotation,
reducing nature & type of glycosidic linkage.
Solution:

(A)
Starch ⇒ It is non-reducing sugar
⇒ Can't show muta rotation
⇒ have α-glycosidic linkage
⇒ At anomeric carbon acetal linkage is present. (A) → QS

(B)
⇒ It is non-reducing sugar and can't show meta rotation.
⇒ It have acetal in L.H.S. and ketal linkage in R.H.S. (B) → QRS

(C) (C) → PRT

(D) Maltose :
 (D) → PST
Final Answer: (A)

33) Explain Question: Match correct option on the basis of given information.
Concept: Based on le-chatelier's principle.
Solution:
(P) On addition of hydrogen reaction shifts in backward direction.
(Q) Process is endothermic so α increases on increasing temperature.
(R) No effect on addition of inert gas at constant volume.
(S) On increasing pressure, volume decreases so concentration of all gases componants
increases.
(T) When α is independent on equlibrium pressure.
Final Answer: (B)

34) Explain Question: Identify effect of hydrolysis on salt solution.

Concept: Hydrolysis of salt of SA + SB can not possible.
Solution:
(A)-(S,T); (B)-(Q); (C)-(R,T); (D)-(R,T)
Final Answer: (B)

PART 3 : MATHEMATICS

35) Explain Question: Assume B in terms of θ. Then obtain volume of tetrahedron in terms of
θ. Also find plane OPB in terms of θ.
Concept: Volume of tetrahedron.
Solution:

Volume of tetrahedron OAPB = | |

= | |=

Also, = = –sinθ – (– cos θ) + (sin θ)

As, = 0 ⇒ – x sin θ + y cos θ + z sin θ = 0

d= = .
Final Answer: (A,C,D)

36) Explain Question: Assume D,E in terms of and obtain M, N by section formula.
Concept: Area of triangle and quadrilateral.
Solution:

Final Answer: (A,B,C)

37) Explain Question: G has radius R. Gi (1 ≤ i ≤ n) touch G externally. Obtain relation

between R and r in terms of n.
Concept: Condition for circles to touch externally.
Solution:
 Final Answer: (C,D)

38) Explain Question: First find foot of perpendicular N on BD from C. Also find CN.
Concept: Foot of perpendicular.
Solution:
AB = CD = a
BC = AD = 2a

N foot of perpendicular on BD drawn from C.

equation of BD in XY plane
and C is (a, 2a)

coordinate of N are

and
Coordinate C'

AC' =
Final Answer: (C)

39) Explain Question: Write volume of tetrahedron as sum of volumes of two terahedrons.
Concept: volume of tetrahedron.
Solution:

Area of ΔAFB =

Volume of tetrahedron ADFB is

Volue of tetrahedron ΔAFBC is

So, total volume is

Final Answer: (B)

40) Explain Question: Solve inverse trigonometric equation. Then find and .
Concept: Cross product.
Solution:
We have
tan–1 x + cot–1 x = sin–1 x + cos–1 x, which is true for all x ∈ [–1, 1]
So, number of integral values of x = 3.

= + , =1=

∴ = (1) (1) sin = = (1)(1) =

⇒ =

⇒ =

⇒ =1+3+
Final Answer: (C)

41) Explain Question: Write family of curves and then apply condition for it be circle.
Concept: Family of curves.
Solution:
Let given curves be S = 0 & S' = 0
So, a circle passing through their points of intersection can be S' + λS = 0
⇒(a' + λa)x2 + (a' + a – b + λb)y2 + (λ – 1)2hxy
–2(g' + λg)x – 2(ƒ' + λƒ)y + c(1 + λ) = 0
So, λ = 1
Now, required circle is
(a + a')x2 + (a + a')y2 – 2x(g + g') – 2y(ƒ + ƒ') + 2c = 0
So, point P is the center of this circle.
Hence, PA = PB = PC = PD = r
Final Answer: (D)

42) Explain Question: Think of different cases satisfying the given condition. Then, find
length of direct tangent.
Concept: Condition for two circles to touch.
Solution:

AB = AC + BC

r=2

AB = AB

AC – BC = AB
r = 50

=
Final Answer: (1261)

43) Explain Question: Find g(θ). Then find volume of parallelopiped.

Concept: Volume of parallelopiped.
Solution:

∴ 2g(θ) = 1 ⇒ 4sin2θ = 1

∴ p + q = 5 is least
Final Answer: (5)

44) Explain Question: Find point satisfying given condition and then find distance of point
form plane.
Concept: Distance of point from plane.
Solution:
Let a = 1 – x
b=x–y
c=y–z
d=z

then a + b + c + d = 1 and a2 + b + c2 + d2 =
⇒ (a – b)2 + (a – c)2 + (a – d)2 + (b – c)2 + (b – d)2 + (c – d)2 = 0
⇒a=b=c=d

So the distance from the point

From the plane 4x + 2y + 4z – 7 = 0 is

Final Answer: (2)

45) Explain Question: Simplify D.E. using substitution y + 1 = Y, x + 2 = X.

Concept: Exact differentials.
Solution:
y + 1 = Y ⇒ dy = dY
x + 2 = X ⇒ dx = dX

(3, 2) →

Let
|x + 2| < eλ
–eλ < x + 2 < eλ
–eλ – 2 < x < eλ – 2
α β
α + β = –4 ⇒ |α + β| = 4
Although x = –2 should be excluded from domain but according to the given problem it will the
most appropriate solution. Final Answer: (4)

46) Explain Question: Find summation using telescopic series. then, find I using by parts.
Concept: integration by parts.
Solution:

Now,

⇒ (p + q) = 7. Ans.

; Put, x – 1 = t2 ⇒ dx = 2t dt
Hence, = 4. Ans.
Final Answer: (11)

47)

Explain Question: Find pair of lines. then find m such that (0, 0) lies inside triangle.
Concept: pair of lines.
Solution:
Equation of pair of straight line is.
x2 – 3y2 – 2xy + 8y – 4 = 0
⇒ x2 + (–2y)x +(–3y2 + 8y –4) = 0

x=

= =y±2
⇒ x = y ± 2(y –1)
⇒ x = y + 2 (y –1) or x = y – 2 (y –1)
⇒ x = 3y – 2 or x = – y +2
Let the equation of straight line passes through point (–5, –1) & of slope m is
y +1 = m (x + 5)
⇒ y + 1 = mx + 5m
Lines passes through point A such that origin is interior part of Δ. We have to form a triangle
using sides x + y = 2, x = 3y –2 & y + 1 = mx + 5x such that origin is the interior. It is
possible only when line passes through point (–5, –1) lies between line L1 & L2

Slope of line L1 = =
Slope of line L2 = – 1
So, slope lies between (–1, 1/5)
Therefore a = – 1 and b = 1/5

∴a+ = – 1 + 52
= – 1 + 25 = 24
Final Answer: (24)

48) Explain Question: Find intersection point of L1 = 0 and L2 = 0. then find line passing
though (1, –3) and satisfying different conditions.
Concept: Family of lines.
Solution:

⇒ λ = ∞ ⇒ L2 itself

⇒ y-int = –
(Q) Maximum distance is between
⇒ Distance between
(1, –3) & (2, –6) ⇒
⇒ Square of max. distance is 10.
(R) Locus of foot of ⊥ from (0, 0) is
(x – 0)(x – 1) + (y – 0)(y + 3) = 0
x2 + y2 – x + 3y = 0 ⇒ a + b = 2
(S) Image of (0, 0) w.r.t. L2
 ⇒
Final Answer: (A)

49) Explain Question: Find f(x) using the given information and then solve the different
options.
Concept: solving f(x) = g(x).
Solution:

f(x) = x + – ...(1)

Let α = ...(2)

β= ...(3)
From (1),
f(x) = x + x3α – xβ ...(4)
From (2) and (4),

α=
⇒ 12α + 5β = 5 ...(5)
From (3) and (5),

β=
⇒ –2α + 15β = 3 ...(6)
Solve (5) and (6),

α= ,β=
From (4),

f(x) =
Final Answer: (D)

50) Explain Question: Find f(x) using given information and then solve different options.
Concept: Integral equation.
Solution:
We know

Now consider
= 1 + 2k . 2 + 4k2

Put

put x = 4, –4 = 2 + c

∴ c = –6

x=4
Final Answer: (A)

51) Explain Question: Find f(x), g(x) using given information. then solve different options.
Concept: integral equation.
Solution:
Differentiating both sides
we get g(x) ƒ(x) = (x2 + 1) (x3 + x)

and
⇒ g(x) = x3 + x ⇒ g'(x) = 3x2 + 1
& ƒ(x) = x2 + 1 ⇒ ƒ'(x) = 2x

=3

Final Answer: (B)