18-05-2025
1103CJA101001250023 JA
PART-1 : PHYSICS
SECTION-I (i)
1) The speed (V) of wave on surface of water is given by where λ is the wavelength
of the wave and ρ is density of water, a is a constant and b is a quantity that changes with liquid
temperature. Surface wave of wavelength 30 mm have a speed of 0.240 ms–1. If the temperature of
water changes by 50°C, the speed of waves for same wavelength changes to 0.230 ms–1. Assuming
that the density of water remains constant at 1 x 103 kg m–3.
0
(A) Dimensions of 'a' will be [a] = [M L1T–2]
0
(B) Dimensions of 'b' will be [b] = [M1L T–2]
(C) Change in value of 'b' for temperature change of 50°C will be – 0.22 SI units.
(D) Change in value of 'b' for temperature change of 50°C will be – 0.022 SI units.
2) A rocket is fired from rest at x = 0 and travels along a parabolic trajectory described by y2 =
(12x) m. If the x component of acceleration is m/s2, where t is in seconds.
(A)
The velocity of rocket at t = 2 s is m/s.
(B)
The velocity of rocket at t = 2 s is m/s
(C)
The position of rocket at t = 2 s is m.
(D)
The position of rocket at t = 2 s is .
3) The velocity time graph of a particle moving along x-axis is given as For the given time interval.
Choose the INCORRECT statement(s) :
(A) The magnitude of velocity of particle is decreasing at decreasing rate.
(B) The magnitude of velocity of particle is decreasing at increasing rate.
(C) The particle is on the right side of origin (x-coordinate of position is positive)
(D) The particle is moving along +x-axis.
4) A rocket prototype is fired from ground at time t = 0 and it goes straight up vertically. Take the
launch point as origin and vertically upward direction as positive x-direction. The acceleration of the
0
rocket is given by for 0 < t ≤ t0 ; = –g, t > t ; where . Choose the correct
statement(s):
(A)
The maximum velocity of rocket during up journey is .
(B)
The maximum height attained by rocket from ground is .
(C)
The total time of flight is .
(D)
The total time of flight is .
5) A square platform of side length 8 m is situated in x – z plane such that it is at 16 m from the x-
axis and 8 m from the z-axis as shown in the figure. A particle is projected with velocity
m/s relative to wind from origin and at the same instant the platform starts with
acceleration . Wind is blowing with velocity then select correct
option(s)
Range of v2 (in m/s) so that the particle hits the platform or edge of the platform is given by
(A)
.
Range of v1 (in m/s) so that the particle hits the platform or edge of the platform is given by
(B)
.
(C) Time taken by particle to hit the platform is 4s.
(D) If v1 is 8 m/s and v2 is 7 m/s then particle will hit the platform or edge of the platform.
6) Drag force of a fluid on a body is proportional to the velocity of the body relative to the fluid. A
student drops several small identical stones from different heights over a deep lake and prepares
graphs between speed v of every stone in the water and time t. The graphs can be divided into three
categories as shown here. Which of the following explanations of these graphs appear reasonable?
The first graph is for a stone dropped from a small height and the second is for a stone dropped
(A)
from a large height.
The first graph is for a stone dropped from a large height and the second is for a stone dropped
(B)
from a small height.
The third graph is for a stone dropped from a height sufficient to acquire the speed v0 at the
(C)
instant it enters the water.
(D) The third graph is not possible.
SECTION-I (ii)
Common Content for Question No. 1 to 2
Jerry is walking at a constant speed 7.5 km/hr due west. At t = 0, the was exactly south of Tom's
house at a distance of 1 Km. At this instant, a large number of Tom's friends and Tom himself scatter
in every possible direction from Tom's house in search of Jerry. Each cat walked in a straight line at
a constant speed at 6 km/hr.
1) What will be the closest distance of a cat from Jerry in this search operation?
(A)
(B)
(C)
(D)
2) At what time will the Jerry get nearest to a cat ?
(A) 8 min
(B) 10.67 min
(C) 8.88 min
(D) 10 min
Common Content for Question No. 3 to 4
A policeman is running behind a thief with constant velocity 20 m/s. Velocity of thief is 10 m/s.
Initially separation between police & thief is 1km. Police has a dog which runs at constant speed of
50 m/s. Dog runs from the police to the thief touches it and returns back to the police and then again
runs to the thief and returns to police & goes on repeating the trips till the police catches the thief.
Consider motion of all three along a straight line.
3) Total distance covered by the dog in that part of the trips when it was moving towards the thief.
(A) 1.5 km
(B) 2.5 km
(C) 0.5 km
(D) 3.5 km
4) Total distance covered by the dog in that part of trips when it was moving towards the police is:
(A) 2.5 km
(B) 1.5 km
(C) 0.5 km
(D) 3 km
Common Content for Question No. 5 to 6
AB is an inclined roof and a particle is projected from origin towards the roof such that path of the
particle will just touch the roof once.
5) Particle will touch roof at t = .....
(A) 2s
(B)
(C)
(D)
6) The value of y0 is
(A) 5m
(B) 15m
(C) 20m
(D) 10m
SECTION-II
1)
A man can swim in still water with a speed of 3 m/s. x and y axis with respect to ground are drawn
along and normal to the bank of river flowing to right with a speed of 2 m/s. The man starts
swimming from origin O at t = 0 second. Assume size of man to be negligible. Locus of all the
possible points where man can reach at t = 2 sec is (x – a)2 + y2 = c2. Find value of .
2) The velocity of a particle traveling in a straight line is given by m/s, where time t
is in seconds and t ≥ 0 . If the particle is observed at x = 7m at the instant t = 0, its position x is
expressed as function of time x(t) = kt +ℓe–t/2 +m. Find numerical value of .
3) If and is perpendicular to , then . Find n.
4) Both the cars are accelerating towards right and their initial velocity is also in rightward direction
as shown in figure. Maximum separation between car A and car B (in meters) is 50α. The value of α
is
5) A subway train travels between two of its station stops with the acceleration schedule shown in
the acceleration vs time graph. Then find out the time interval Δt during which the train brakes to
stop with a deceleration of 1 m/s2 is (in sec).
6) Two forces and of equal magnitude produce a resultant of 4 N. When is reversed in
direction and applied along with resultant is of . Find magnitude of in newton.
PART-2 : CHEMISTRY
SECTION-I (i)
1) Which of the following statements is/are correct ?
(A) The second ionization enthalpy of oxygen atom is greater than that of fluorine atom.
(B) The third ionization enthalpy of phosphorus is greater than that of aluminium.
(C) The first ionization enthalpy of aluminium is slightly greater than that of gallium.
(D) The second ionization enthalpy of copper is greater than that of zinc.
2) Which of the following option(s) is/are incorrect ?
(A) Decreasing I.E.2 : F > N > O
(B) Increasing atomic size : Be < B < Li < Na
(C) Electron affinity Cl > F > O > S
(D) Ionisation energy : He < Li
3) Choose the correct statement(s) about Na, Cs, Cl, N
(A) Cs is more metallic than Na but Na is less electropositive than Cs
(B) N has three electrons in p-subshell but Cl has elevan
Anion of Cl is having largest size than cation of Na but cation of Na has smaller size than cation
(C)
of Cs
(D) Except Cl all have +ve ΔHEGE
4) Which of the following Ist ionisation energy order is/are correct
(A) Be < B < C
(B) N < O < F
(C) Mg > Na > Cs
(D) P > S > Ca
5) Which of the following process is endothermic
(A) A2– → A–
(B) A3+ → A2+
(C) A+ → A3+
(D) A+ → A2+
6) How many of the following trend is "INCORRECT" ?
(A) Electron affinity : Se > S > Br > Cℓ
(B) Electronegativity : B > Al > Ga > In
(C) Atomic radii : S > Cℓ > O > F
(D) I.E2 (Be) > I.E2 (Li) > IE1 (Li)
SECTION-I (ii)
Common Content for Question No. 1 to 2
The plane and point at which zero electron density exists is known as nodal plane and nodal point
respectively.
Nodal plane also refers as angular node. Number of angular nodes depends on shape of orbital only
and size of orbital has no role in it.
Based on the comprehension answer the following questions-
1)
Which of the following pair of orbitals contains at least one common nodal plane but doesn't have
same energy in multi electronic atom :-
(A) 3px and 4py
(B) 4dxz and 4dxy
(C) 4dxz and 5py
(D) 3dxz and 3px
2) Select the correct statement -
(A) In orbital 2 nodal planes are in xz and yz plane
(B) and have one common nodal plane
(C) One 4d orbital contains maximum 2 electrons of opposite spin
(D) One 3d orbital contains a total of 10 electrons
Common Content for Question No. 3 to 4
Given graph represent IE1, IE2 and IE3 of two elements M1 and M2 belong to same group of p-block
(atomic mass of M2 > M1 and p, q, r, x, y, z are the IE values of respective elements)
3) Which of the following is CORRECT :
(A) IE2 of M2 > IE2 of M1
(B) 'r' point & 'z' point represent IE3 of M2 & M1 respectively
(C) IE1 + IE2 is higher for M2 as compared to M1
(D) None of these
4) Find ΔH for given reaction M1(g) → + 3e–
(A) 75 eV
(B) 40 eV
(C) 30 eV
(D) 15 eV
Common Content for Question No. 5 to 6
Consider a hypothetical universe, in which 4 quantum number have values as
n = 1, 2, 3..............
0≤ℓ≤n
–ℓ ≤ m ≤ + ℓ (including zero)
s = +1/2, 0, –1/2
Assuming all rules of filling the electrons remains same.
5) How many maximum number of elements can be arranged in 3rd period of periodic table ?
(A) 18
(B) 27
(C) 8
(D) 12
6) How many maximum number of e– can be filled in 3rd shell ?
(A) 32
(B) 18
(C) 27
(D) 48
SECTION-II
1) The number of species among the following, having magnetic moment value of 2.84 BM ________ .
Fe2+, Cr, Ti2+, Mn2+, V3+ , Ni+2 , Cu+2 , Fe+3 , Mn+3 , Pd+2 , Zn+2
2) Maximum possible number of electrons in 41Nb that satisfy n + ℓ + m = 4 is ______.
3) The sum of maximum number of electrons in an atom that can have the quantum numbers as
given in (P) and (Q) respectively
Given : (P) n = 6,
(Q) n = 2, ℓ = 1, , ms =
4) Bond length of A A bond is 124 pm and bond length of B B bond is 174 pm. The bond length
(in pm) of A B bond in AB molecule if percent of ionic character of A B bond is 19.5% is ______.
5) Consider the following Born–Haber’s cycle for formation of MX3(s).
Then calculate value q1, here q1 is
electron affinity of X(g) in kJ/mol.
Given B.E. of X2 = 200 kJ/mole
6) The group number is (a) and period number is (b) of the element with atomic number Z = 100.
Report value of (10a + b).
PART-3 : MATHEMATICS
SECTION-I (i)
1) Suppose α is the smallest & β is the largest integral solution of the inequality ,
then-
(A) |α| > |β|
(B) α + β < 0
(C) αβ < 0
(D) αβ > 0
2) Let ax2 + (b + 2)x + c = 0 and x2 + 5x + 2 = 0 have a common root, where a, b, c ∈ N, then
(A) (b + 2)2 – 4ac > 0
(B) (b + 2)2 – 4ac < 0
(C) minimum value of (a + b + c) is 6.
(D) minimum value of (a + b + c) is 10.
3) Let exactly one root of equation x2 + (k +1)x + 5k = 0 lies in (0,5], then integral value of k can be
-
(A) 0
(B) –1
(C) –2
(D) –3
4) Let , (0 < b < a < c), then
(A) a = 5
(B) b = 4
(C) b + c + a = 21
(D) a + b + c = 20
5) If α, β, γ are roots of the equation x3 – 3x + 1 = 0, then
(A) (α + β) (β + γ) (γ + α) = –1
(B) α2(β + γ) + β2(γ + α) + γ2(α + β) = 3
(C) (α + 1) (β + 1) (γ + 1) = –3
(D) α4 + β4 + γ4 = 18
6) Let the range of a monic quadratic polynomial P(x) with real coefficients is
, then interval of k for which P(x) = 0 has-
(A)
real & unequal roots is
(B)
imaginary roots is
(C)
real & unequal roots is
(D)
equal roots is
SECTION-I (ii)
Common Content for Question No. 1 to 2
Graph of the function ƒ(x) = c + bx – x2 is as shown in figure.
α, β are real roots of ƒ(x) = 0 and pn = αn + βn, n ∈ N
On the basis of above information, answer the following questions :
1) If pn is divisible by 10, then the value of n can be -
(A) 98
(B) 99
(C) 100
(D) 102
2) Maximum value of ƒ(x) is -
(A) 21
(B) 4
(C) 5
(D) 3
Common Content for Question No. 3 to 4
Let a,b,x,y are positive rational numbers and are irrational numbers such that
, where x > y, a2 > b, then
3) The value of x is -
(A)
(B)
(C)
(D)
4) The value of y is
(A)
(B)
(C)
(D)
Common Content for Question No. 5 to 6
Consider , t ∈ R and Q(x) = x2 – 2mx + 6m – 48 where m ∈ R.
5) The sum of all integral values in the range of P(t) is
(A) 18
(B) 20
(C) 21
(D) 22
6) Let Q(x) + 61 ≥ P(t) ∀ x ∈ R. If complete set of values of m is [a, b], then (b + a) is equal to
(A) 2
(B) 4
(C) 6
(D) 8
SECTION-II
1) Find the value of when
2) Given , then the value of is
3) Suppose α and β are distinct roots of x2 – x + 2 = 0 and , then value of
is
4) Let m,n are integers satisfying 3m + 2 = 5n + 3 and 30 < 3m + 2 < 40, then the value of mn is
5) In the equation x5 – 5x4 + 9x3 – 9x2 + 5x – 1 = 0 if p is the sum of real roots and q is the product of
real roots then the value of (p + q) is
6) If a, b, c are the roots of the equation x3 – 2x2 + 1 = 0, then the value of
is equal to
ANSWER KEYS
PART-1 : PHYSICS
SECTION-I (i)
Q. 1 2 3 4 5 6
A. A,B,D A,C A,C A,B,C B,C B,C
SECTION-I (ii)
Q. 7 8 9 10 11 12
A. A B D B B D
SECTION-II
Q. 13 14 15 16 17 18
A. 6 0 1 3 20 3
PART-2 : CHEMISTRY
SECTION-I (i)
Q. 19 20 21 22 23 24
A. A,B,D A,B,C,D A,B,C C,D C,D A,B,D
SECTION-I (ii)
Q. 25 26 27 28 29 30
A. D C D A B D
SECTION-II
Q. 31 32 33 34 35 36
A. 4 11 11 140 180 37
PART-3 : MATHEMATICS
SECTION-I (i)
Q. 37 38 39 40 41 42
A. A,B A,C B,C,D A,B,C A,B,C,D B,C,D
SECTION-I (ii)
Q. 43 44 45 46 47 48
A. B B A B B C
SECTION-II
Q. 49 50 51 52 53 54
A. 5 1 5 84 5 4
SOLUTIONS
PART-1 : PHYSICS
1)
[M L1T–1]2 = [a][L1] =
0
∴ [a] = [M L1T–2]
0
[b] = [M1L T2]
(c) Given data says (in SI units)
(0.240)2 =
0.242 = .........(1)
Similarly,
(0.23)2 = ........(2)
(2) – (1)
(b2 – b1) = (0.23)2 – (0.24)2
Δb = = –0.022kg s–2
9) Time in which police catches thief,
Total distance covered by the dog
= 50 ×100
= 5000 m
= 5 km.
Now, suppose x distance is covered by dog in a trip when it is moving towards the thief and y
when moving towards the police.
Then
Σx + Σy = 5000
Σx - Σy = 2000
2Σx = 7000
Σx = 3500m = 3.5 km
and Σy = 1.5 km
10) Time in which police catches thief,
Total distance covered by the dog
= 50 ×100
= 5000 m
= 5 km.
Now, suppose x distance is covered by dog in a trip when it is moving towards the thief and y
when moving towards the police.
Then
Σx + Σy = 5000
Σx – Σy = 2000
2Σx = 7000
Σx = 3500m = 3.5 km
and Σy = 1.5 km
11)
At the time of touching velocity makes an angle 45° with horizontal in downward direction.
From
OR
Particle will touch roof at time of landing.
So t=
12)
13)
x = (2 + 3 cos θ) × 2
y = (3 sin θ) × 2
⇒ (x – 4)2 + y2 = (6)2
16)
vA = vB (for maximum seperation)
(10 + 2t) = 20 + t
(t = 10)
PART-2 : CHEMISTRY
19)
(A) As removal of second electron takes place from half filled valence shell electron
configuration of S+ i.e. 3s23p3.
(B) I.E(III) of 13Al is 2744 kJ mol–1 where as that of 15P is 2910 kJ mol–1. This is because of higher
nuclear charge in phosphorus.
(C) I.E(I) of Al is 577 kJ mol–1 and that of Ga is 579 kJ mol–1. This may be because of their
similar sizes i.e. 1.25 Å in both.
(D) Cu+ = [Ar] 3d10
Zn+ = [Ar] 3d10 4s1
Electron in 3d10 of Cu+ is closer as compared to electron in 4s1 of Zn+1
20) (A)
21)
Cs is most metallic
N has three electrons in 2p-subshell
Anion of Cl is having largest size than cation of Na
Cl , Na , Cs have –ve EGE
22) Explanation - Let's analyze each option for the ionization energy order:
The species with the lowest nuclear charge and hence the lowest ionization energy is S2-, since
its electrons are least tightly bound by the nucleus.
26)
An orbital can accomodate maximum two electrons with opposite spin.
31) For magnetic moment to be 2.84 BM number of un pair electron must be equal to '2'.
[Fe2+] = [Ar] 3d6→ 4 unparied e–.
[Cr] = [Ar] 4s1 3d5 → 6 unparied e–.
[Ti2+] = [Ar] 3d2→ 2 unparied e–.
[Mn2+] = [Ar] 3d5→ 5 unparied e–.
[V3+] = [Ar] 3d2→ 2 unparied e–
Ni+2 = [Ar] 3d8→ 2 unparied e–
Pd+2 = [Kr] 4d8→ 2 unparied e–
Zn+2 = [Kr] 3d10→ 0 unparied e–
33) n = 6, me = +1 ⇒ 10elΘ l = 0, 1, 2, 3, 4,5
n = 2, l = 1, me = –1, ms = = 1elΘ
Total = 11 elΘ
34)
(Value in pm)
= 62 + 87 – 9 × 1 = 140
35)
36) [Rn]7s25f12
Group number = 3
Block = f
Period = 7
PART-3 : MATHEMATICS
37)
x ∈ (–5,–4) ∪ [–3,1) ⇒ α = –3, β = 0
38) x2 + 5x + 2 = 0 has irrational roots.
ax2 + (b + 2)x + c = 0 has will also be having irrational roots
(b + 2)2 – 4ac > 0 (roots are real)
a = λ; b = 5λ – 2 & c = 2λ
a + b + c = (8λ – 2)
39) ƒ(0) ƒ(5) < 0
5k(25 + (k + 1)5 + 5k) < 0
or 5k(10k + 30) < 0
or k ∈ (–3,0)
∴ k=0 k = –3
2
x +x=0 x2 – 2x – 15 = 0
⇒ x = –1,0 ⇒ (x – 5) (x + 3) = 0
⇒ x = 5, –3
so k = –3
∴ k ∈ [–3,0)
40)
a = 5, b = 4, c = 12
41) We have
α + β + γ = 0, αβγ = –1
& αβ + βγ + γα = –3
(A) (α + β)(β + γ)(γ + α) = –γαβ = 1
(B) α2(–α) + β2(–β) + γ2(–γ)
= –(α3 + β3 + γ3) = –3αβγ = 3
(C) x3 – 3x + 1 = (x – α)(x – β)(x – γ)
put x = –1
(D) x3 – 3x + 1 = 0 ; x = α, β, γ
⇒ x4 – 3x2 + x = 0
Putting x = α, β, γ and adding
α4 + β4 + γ4 = 3(α2 + β2 + γ2) – (α + β + γ)
= 3[(α + β + γ)2 – 2(αβ + βγ + γα)]
= 18
42) a = 1 (∵ monic) ;
- i.e.
⇒ D = 9k2 – 36k – 13 = (3k + 1) (3k – 13)
for real & distinct roots D > 0, for imaginary roots D < 0 for equal roots D = 0.
43)
⇒ b2 = 100 ⇒ (b > 0)
ƒ(7) = 0 ⇒ –49 + 7b + c = 0
ƒ(x) = –x2 + 10x – 21
Roots are 3 and 7
pn = 3n + 7n
for every odd natural number n
pn is divisible by 10
maximum value of ƒ(x) is i.e. 4
44)
⇒ b2 = 100 ⇒ (b > 0)
ƒ(7) = 0 ⇒ –49 + 7b + c = 0
ƒ(x) = –x2 + 10x – 21
Roots are 3 and 7
pn = 3n + 7n
for every odd natural number n
pn is divisible by 10
maximum value of ƒ(x) is i.e. 4
45)
x + y = a b = 4xy
on solving
46)
x+y=a b = 4xy
on solving
47)
P(t) ∈ (1, 6]
(i) Sum of integral value of P(x)
=2+3+4+5+6
= 20
(ii) Q(x) + 61 ≥ P(t) x ∈ R
x2 – 2mx + 6m – 48 + 61 ≥ P(t)
⇒ x2 – 2mx + 6m + 13 ≥ 6
⇒ x2 – 2mx + 6m + 7 ≥ 0
4m2 – 4(6m + 7) ≤ 0
(m – 7)(m + 1) ≤ 0
–1 ≤ m ≤ 7
48)
P(t) ∈ (1, 6]
(i) Sum of integral value of P(x)
=2+3+4+5+6
= 20
(ii) Q(x) + 61 ≥ P(t) x ∈ R
x2 – 2mx + 6m – 48 + 61 ≥ P(t)
⇒ x2 – 2mx + 6m + 13 ≥ 6
⇒ x2 – 2mx + 6m + 7 ≥ 0
4m2 – 4(6m + 7) ≤ 0
(m – 7)(m + 1) ≤ 0
–1 ≤ m ≤ 7
49) ∵ ⇒ ⇒ x2 – 8x + 13 = 0
x – 6x – 2x + 18x + 23 = (x – 8x + 13)(x2 + 2x + 1) + 10 = 10, so that the value of the given
4 3 2 2
expression is
10/2 = 5
50) a(21/3 – 1) = (21/3 – 1)(22/3 + 21/3 + 1)
⇒ ⇒
= 2 – 1 – 3.21/3(21/3 – 1) = 1 – 3.22/3 + 3.21/3
= 3.21/3 – 3 + 3.22/3 + 3 – 6.21/3 + 1 – 3.22/3 + 3.21/3
=1
51) α + β = 1, αβ = 2
α2 + β2 = –3
α3 + β3 = –5
α4 + β4 = 1
α5 + β5 = 11
52) 30 < 5n + 3 < 40 ⇒
⇒ n ∈ (5, 8) ⇒ n = 6 or 7
At n = 6 3m = 5n + 1 ⇒
At n = 7 3m = 36 ⇒ m = 12
∴ mn = 84
53) Sum of the coefficients = 0
⇒ one root is 1
x5 – 5x4 + 9x3 – 9x2 + 5x – 1 = 0
(x – 1)(x4 – 4x3 + 5x2 – 4x + 1) = 0
(1) ⇒ x2 – 3x + 1 = 0
(2) (rejected)
real roots are
54) a + b + c = 2 ; ab + bc + ca = 0 ; abc = –1
= 0 + (ab + bc + ca)2 – 2abc(a + b + c)
= 0 – 2(–1)(2) = 4