14-09-2025

1001CJA106213250011 JA

PART-1 : PHYSICS

SECTION-I (i)

1) Two rods A and B having same length L = 1.5 m and cross sectional area A = 1 × 10–9 m2, but
different linear coefficient of expansion, αA = 12 × 10–6 /°C and αB = 18 × 10–6 /°C respectively are
joined with an ideal spring with a spring constant K = 200 N/m as shown in figure. Now,
temperature of system is increased by ΔT = 50°C. Initially spring is in its natural length and Youngs
modulus of A and B are YA = 200 GPa and YB = 150 GPa respectively. Then identify the correct

choice(s). (Neglect difference in areal expansion.)

(A) Thermal stress developed in rod A and rod B are equal.

(B) Thermal stress developed in rod A and rod B are unequal.
(C) Compression in spring will be 0.5 mm.
(D) Compression in spring will be 0.25 mm.

2) In the figure shown a uniform rod of mass m and length ℓ is hinged. The rod is released when the

rod makes angle θ = 60° with the vertical.

The angular acceleration of the rod just after release is

(A)

The normal reaction due to the hinge just after release is

(B)

The angular velocity of the rod at the instant it becomes vertical is

(C)

(D)
The normal reaction due to the hinge at the instant the rod becomes vertical is mg

3) In which of the following cases friction cannot be zero for the disc rolling purely on the ground?
(A)

(B)

(C)

(D)

4) A man in an train that was originally at rest. He stands straight and faces the right side of train,
with his legs at horizontal distance ℓ = 0.40 m apart. The centre of gravity of man is at vertical
distance h = 0.9 m above the floor. The train starts accelerating uniformly with a = 1.5 m/s2 on a
level track. The man keeps standing straight.

The effective line of action of resultant force (gravity + pseudo force) shifts sideways by
(A)
.

(B)
The fraction of total body weight transferred between man's leg's is given by .
(C) The percentage of total weight transferred by left to right leg is approximately 34.4%.
The man's entire weight would transfer to his right leg if acceleration of train exceeds about
(D)
2.18 m/s2.

5) A spherical grape of radius R = 2 cm is dried in an oven. After a Time T = 24 hours, the grape has
turned into a spherical raisin of radius R = 1 cm. Assume that the missing volume is entirely due to
water evaporation and all the energy from the oven is used to evaporate the water. The density of
water is ρ = 1000 kg/m3 and the specific latent heat of vaporization is LV = 2.25 × 106 J kg–1. which of
the following statements are correct?

(A) The mass of water evaporated is approximately 26.3 gm

(B) The mass of water evaporated is approximately 29.3 gm
(C) The total energy required to evaporate the water is approximately 66 kJ
(D) The average power supplied by the oven is approximately 0.76 W.

6) The cable Strung between two neighbouring electricity post sag a little. The mass per unit length
of the cable is λ. The distance between the post is L and the maximum sag of the cable is d. Due to
relatively small sag, the tension in the cable can be assumed to be uniform. The cable obey the

hooke's law. Choose the correct statement from the following.

(A)
The approximate value of the Tension is .

(B)
The approximate value of the Tension is .

(C) The approximate formula for calculation of elastic strain energy stored in the cable is (stress)
strain) (volume)
The approximate formula for calculation of elastic strain energy stored int he cable is (stress)
(D)
(strain) (volume)

SECTION-I (ii)

1) A block of mass M1 = 2kg is projected on a smooth wedge of mass M2 = 6kg with an initial
horizontal velocity V0 = 5 m/s as shown in the figure. All the surfaces are smooth and the velocity v
is sufficient so that the block M1 does not leave the contact with the wedge M2.

List-II (in
List-I
SI units)

The maximum height achieved by the Block M1

(I) from the horizontal surface of projection is (P) 2.5
approximately.
 The speed of block M1, when it again comes
(II) back to the horizontal surface of the wedge M2 (Q) 2.0
is

The speed of wedge M2 when the block M1 again

(III) comes back to the horizontal surface of the (R) 1.25
wedge M2 is

When the block M1 is at maximum height, its

(IV) (S) 0.94
velocity is

(T) 0.64

(A) I → Q;II → R;III → S;IV → P

(B) I → S;II → P;III → Q;IV → R
(C) I → S;II → P;III → P;IV → R
(D) I → R;II → Q;III → P;IV → R

2) A uniform hollow cylinder of mass m = 4 kg and radius R = 10 cm rests on a wedge of mass M = 5

kg which is placed on a smooth inclined plane of inclination θ = 30° as shown in the figure. Friction
between the cylinder and the top horizontal surface of wedge is sufficient to prevent slipping of the
cylinder relative to the wedge after the wedge is released from rest. (Take g = 10 m/s2)

List–II
List–I
(in SI units)

(I) The acceleration of the wedge is (P) 3

(II) Friction on cylinder by the wedge is (Q) 10.4

The acceleration of the cylinder relative to

(III) (R) 6
the wedge is

(IV) Normal on cylinder by wedge is (S) 28

(T) 2.56
(A) I → R;II → S;III → T;IV → Q
(B) I → R;II → Q;III → T;IV → S
(C) I → Q;II → S;III → P;IV → R
(D) I → P;II → Q;III → S;IV → T

3) Match the List-I with List-II. (Consider calorimeter has negligible heat capacity)
 List-I List-II

A Hot Block of mass M = 0.20 kg specific heat

capacity S = 350 J/kg-k at temperature. T = 150°C
(I) is dropped into the calorimeter which initially (P) Tf = 0°C
contain the water (m = 100 gm) at 0°C. The system
reaches equilibrium temperature Tf (approx.)

Ice of mass M = 0.18 kg at 0°C is dropped into the

calorimeter which initially contain the water (m =
(II) (Q) Tf = 100°C
400 gm) at 30°C. Final temperature of mixture is
Tf (approx.)

Steam of mass M = 0.061 kg at 100 °C is passed

slowly into the calorimeter which initially contain
(III) (R) Tf = 21.42 °C
the water (m = 400 gm) at 30°C. Final temperature
of the system is Tf (approx.)

Two liquids are mixed in the calorimeter. Liquid (1)

has mass M1 = 0.1 kg specific heat capacity S1 =
(IV) 4200 J/kg-K, T1 = 60°C & Liquid (2) has mass M2 = (S) Tf = 34.94°C
0.15 kg specific heat capacity S2 = 3500 J/kg-K, T2 =
25°C. Find the final temperature Tf (approx.)

(T) Tf = 40.55 °C

(U) Tf = 18.35 °C
(A) I → R;II → P;III → Q;IV → S
(B) I → P;II → Q;III → R;IV → S
(C) I → R;II → P;III → S;IV → T
(D) I → Q;II → R;III → P;IV → T

4) Spherical ball of radius r is placed at the bottom of vertical circular loop of radius r + R as shown
in the figure. If spherical ball is projected with minimum velocity so that it will complete the vertical
circle in the circular loop shown in the figure, match the list-I with list-II for the given physical

quantities. Given m = 1kg, R = 7m, r = 0.1 m, g = 10 m/s2)

List-I List-II (in

SI units)

Kinetic energy of sphere at the top of circular

(I) (P)
loop
 Kinetic energy of sphere at the bottom of circular
(II) (Q)
loop.

Minimum speed imparted to ball at the bottom of

(III) (R)
loop

(IV) Normal force on the ball at the bottom of the loop (S) 189

(T) 48.6

(U) 119
(A) I → P;II → Q;III → U;IV → T
(B) I → U;II → T;III → R;IV → T
(C) I → T;II → S;III → P;IV → R
(D) I → U;II → S;III → P;IV → T

SECTION-II

1) A uniform solid cylinder is placed on a slope fixed to the ground and inclined at an angle θ = 15°
from the horizontal. The axis of the cylinder makes an angle ϕ = 30° with the direction of inclination.
Given that the cylinder rolls without slipping, find the minimum coefficient of static friction µ

between the cylinder and the slope.

2) The co-efficient of thermal expansion of a rod is temperature dependent and is given by the
formula α = aT, where a is constant and T is in °C. If the length of the rod is ℓ at temperature 0°C,
then the temperature at which the length will be 2ℓ is x. The the value of x2 is. Given a = 2 (in SI
unit) and ℓn 2 = 0.69.

3) A copper calorimeter has mass of 180 g and contains 450 g of water and 50 g of ice; all at 0°C.
Dry steam is passed into the calorimeter until a certain temperature (θ) is reached. The mass of the
calorimeter and its contents at the end of the experiment increased by 25 g. Assume no heat loss to
the surrounding and take specific heat capacities of water and copper to be 4200 J kg–1 K–1 and 390 J
kg–1K–1, respectively. Take specific latent heat of fusion and vaporization of water to be 3.36 × 105 J
kg–1 and 2.26 × 106 J kg–1 respectively. The final temperature is.

4) A uniform rod rests against a smooth vertical wall and a rough horizontal surface. A horizontal
force F is applied at the centre of mass of the rod such that the rod is in static equilibrium and the
resultant of F and the weight of the rod intersect at the point P shown in the figure. The angle (in
degree) of friction for friction force between the rod and horizontal surface is (10x)°. Find x value.
5) Roger is creating an ornament that consists of a uniform bar of mass m = 0.20 kg and length L =
2.0 m balancing horizontally on top of a horizontal cylinder of radius R = 1.5 m, with their centres
vertically aligned. He then adds a decorative element of mass M to one end of the bar, causing the
bar to rotate without slipping on the cylinder surface. At equilibrium, the bar is inclined at an angle
θ = 30° to the horizontal. The cylinder remains stationary and does not rotate throughout.

Determine the mass M (in kg).

6) Consider an isolated system of pure water that is supercooled to a temperature of T = –15°C, such
that it remains completely liquid. When the supercooled water is disturbed, some but not all of the
water freezes. Determine the percentage by mass of water that gets frozen.

7) A cylinder is placed in a V-shaped groove, with its axis parallel to the groove. Each side of the
groove makes an angle of θ = 30° with the horizontal. The cylinder has mass M = 500 g and radius R
= 25 cm, and is driven to rotate at a constant angular velocity ω = 30 rad s–1. The coefficient of
friction between the cylinder and each surface is µ = 0.35. The external torque τ (in N-m) required

to rotate the cylinder is

8) A uniform inelastic rope of linear mass density λ = 0.120 kg m–1 and length ℓ = 2.00 m is hung
over a pole of negligible radius, such that both ends start at the same height. Roger pulls one end
downwards with a constant velocity v = 0.500 m s–1. The pole exerts a constant frictional force f =
3.00 N as the rope slides over the pole. Find the acceleration acm (in m/s2) of the centre of mass of
the rope.

PART-2 : CHEMISTRY

SECTION-I (i)

1) Select the correct option:

(A)

Bond length (ℓ1 > ℓ2)

Stability of carbocation
(B)

(C) Order of basic strength < <

(D)
Order of pKa

2) One mole mixture of CH4 & air (containing 80% N2 20% O2 by volume) of a composition such that
when underwent combustion gave maximum heat (assume combustion of only CH4). Then which of
the statement(s) are correct, regarding composition of initial mixture or for final mixture. (X
represents mole fraction)

(A)

(B)

(C)

(D) Data insufficient

3) 1.0 g mixture of CaCO3(s) and glass beads liberate 0.22 g of CO2 upon treatment with excess of
HCl. Glass does not react with HCl. Which of the following statement(s) is/are CORRECT ?
(A) The mass of CaCO3 in the original mixture is 0.5 g
(B) The mass of calcium in the original mixture is 0.2 g
(C) The mass percent of calcium in the original mixture is 40% Ca.
(D) The mass percent of Ca in the original mixture is 20% Ca.

4) Choose the incorrect option(s) :

– +2
(A) 1 mol MnO4 can oxidize 10 mol Fe in acidic medium completely.
–2 +2
(B) 1 mol Cr2O7 can oxidize 4 mol Fe in acidic medium completely.
1 mol Cu2S can be oxidized by 1.3 mol MnO4– in acidic medium completely.
(C)
[Cu2S → Cu+2 + SO2]
2 mol FeS2 can be oxidized by 3 mol Cr2O7–2 ions in acidic medium completely.
(D)
[FeS2 → Fe+3 + SO2]

5) If co-ordinates of a lobe of tetrahedral is (+x, –y, –z) then what are the co-ordinates of other three
lobes of tetrahedral if all lobes are present at corner of cubes (If central atom is placed at origin) ?

(A) (+x, –y, +z)

(B) (–x, –y, +z)
(C) (–x, +y, –z)
(D) (+x, +y, +z)

6) S2F10 disproportionate at 150°C as follows :

S2F10 SF4 + SF6

Select incorrect statement :

(A) Hybridisation of sulphur atom remains unchanged in both product.

(B) Oxidation state of sulphur atom remains unchanged in both product.
(C) Only axial d-orbital(s) is/are used in hybridisation of sulphur in reactant and products.
(D) S2F10 contain maximum 5 atoms in one plane

SECTION-I (ii)

1) Match the list

List-I List-II
(Compounds) (Properties)

(P) (1) Aromatic

(Q) (2) Nonaromatic

 (R) (3) Heterocyclic

(S) (4) Even number of π-bond

(5) Odd number of σ-bond

(A) P → 2,4,5;Q → 2,4;R → 2,5;S → 1,4,5
(B) P → 1,3,5;Q → 2,4,5;R → 2,3,4,5;S → 1,5
(C) P → 1,4,5;Q → 2,5;R → 1,2,5;S → 1
(D) P → 1,3,5;Q → 1,4,5;R → 2,3,5;S → 2,5

2)

List-I List-II

(P) (1) +M

(Q) –OH (2) –M

(R) (3) +I

(S) –CH3 (4) –I

Correct option is :
(A) P → 2,4;Q → 1,4;R → 4;S → 3
(B) P → 2;Q → 1,4;R → 1,3;S → 4
(C) P → 2,4;Q → 2,4;R → 2,4;S → 3
(D) P → 2,3;Q → 1,4;R → 4;S → 1

3) Match the Column.

List-I List-II

(P) Dihydrogen hypophosphate ion (1) All hydrogens are ionizable

Number of acidic hydrogen

(Q) Hydrogen pyrophosphite ion (2)
present is two.

(R) Pyrosulphurous acid (3) sp3 hybridised central atom

Hydrogen peroxymonosulphate Overall Non planar

(S) (4)
ion structure

(5) Ion having peroxy linkage

(A) P → 1,2,3,4;Q → 3,4;R → 1,2,3,4;S → 1,3,4,5
(B) P → 1,3,5;Q → 2,4;R → 1,2,3,5;S → 1,2,3,4
(C) P → 2,4,5;Q → 1,2;R → 3,4,5;S → 2,5
(D) P → 1,2;Q → 1,3;R → 2,3;S → 2,4

4)

List-I List-II

Eq. wt. of underline =

(P) (1) When oxidises into and

Eq. wt. of underline =

When oxidises into
(Q) (2)

Eq. wt. of underline =

(R) (3) When oxidises into

Eq. wt. of underline =

(S) (4) When oxidises into

(5) When oxidises into

The correct match is :
(A) P → 4;Q → 1;R → 3;S → 2
(B) P → 3;Q → 2;R → 1;S → 4
(C) P → 2;Q → 1;R → 4;S → 3
(D) P → 1;Q → 3;R → 2;S → 4

SECTION-II

1) How many compounds are more basic than methyl amine :

(i) Me2NH (ii) Et2NH (iii) NH3 (iv) HN3 (v)

2) The no. of compound with correct IUPAC name is/are :-

(a) 2-Carboxyphenol

(b) 3-Ethyl-4-chloro-5-hydroxybenzenecarbonitrile

(c) 3-Formyl-5-Nitrobenzenecarboxylic acid

(d) 1-Hydroxy-3-methoxy-4-nitrobenzene

(e) 4-Amino-1-nitrobenzene

(f) 3-Methylphenol

(g) 2, 4, 6-Trimethylbenzenecarbonylchloride

3) Calculate the number of resonating structures of anthracene which have no charge separation?

4) 5.7g of bleaching powder was dissolved in 500 ml of water. 25 ml of this solution on treatment
with KI in the presence of HCl liberated iodine, which is reacted with 24.35 ml of N/10 Na2S2O3 for
complete titration. Calculate the % of ‘available’ chlorine in the bleaching powder? [Cl = 35.5, I =
127]

5) When white phosphorous is boiled in alkaline medium, it disproportionate into PH3 and NaH2PO2,
which are produced in a molar ratio of X : 1. Determine X

6)

How many species are forming bonds in their second excited state of central atom :
CH4 , PCl5 , IF5 , XeF4 , ClO3–, SOF4 , BrF5 , SnCl4

7) The sum of oxidation state of Fe in K3[Fe(CN)6] and Cr in CrO5 is "X". Monopositive ion of an
element "Z" has exactly "2X" number of electrons in ultimate shell. If the element belongs to
4th period then number of CORRECT orders among the following is _______.
(i) Zn > Z (Atomic size)
(ii) Z > Zn (IE1)
(iii) Z > Ag (IE1)
(iv) Z > Na (number of unpaired electrons)
(v) Z2O > ZnO (basic nature)
8) For how many of the following species interaction energy E ∝ r–3 (where r is intermolecular
distance)
(i) KF + HF

(ii)
(iii) Acetone + CHCl3
(iv) Benzene + CCl4
(v) I¯ + I2
(vi) Ammoniation of potassium ions
(vii) Rotating dipolar molecules

PART-3 : MATHEMATICS

SECTION-I (i)

1) In a plane rectangular co-ordinate system xRy there are three points , B(–1, 0) and C(1,
0). The distance from point P to line BC is the geometric mean of the distances from this point to
lines AB and AC. Then the locus of point P is

(A) 2x2 + 2y2 + 3y – 2 = 0

(B) 2x2 – 2y2 – 3y + 2 = 0
(C) 8x2 – 17y2 + 12y – 8 = 0
(D) 8x2 + 17y2 – 12y – 8 = 0

2) A and B are the points (2, 0) and (0, 2) respectively. The coordinates of the point P on the line
2x + 3y + 1 = 0 is/are

(A) (7, –5) if |PA – PB| is maximum

(B)
if |PA – PB| is maximum
(C) (7, –5) if |PA – PB| is minimum

(D)
if |PA – PB| is minimum

3) The line L is drawn through the point (1, 1) to intersect L1 : x + 2y = 1 and L2 : x + 2y = 3 at P and
Q respectively. Line perpendicular to L from P intersects L2 at R and line perpendicular to L from Q
intersects L1 and S. Let the area of parallelogram PQRS is least, then which of the following is/are
correct ?

(A) the equation of line L can be y + 3x = 4

(B) the equation of line L can be 3y – x = 2

(C)
the least area of PQRS is square unit
(D) the equation of line L can be 3y – x = 4

4) For fixed natural number n, Δ = , then is divisible by

(A) n
(B) n2 + 4n + 5
(C) n2 + 4n – 5
(D) 2n2

5) If, then a value of satisfies which of the following equations?

(A) 2x2 – x – 1 = 0
(B) x2 – 2x – 3 = 0
(C) 2x2 – 5x– 3 = 0
(D) 2x3 –7x2 + 2x + 3 = 0

6) Let Sn be the sum of the first n terms of the arithmetic sequence b1, b2,.....bn, such that

then

(A) f(1,3,5) = 15
(B) f(2,7,12) < 21
(C) f(1,3,5) = 21
(D) f(2,7,12) < 15

SECTION-I (ii)

1) Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

The system of equation 2x – y + z = 0; x – 2y + z = 0 and λx

(I) (P) 1
– y + 2z = 0 has non-trivial solutions then λ is

The value(s) of c for which the lines x + y = 1,

(II) (c + 2)x + (c + 4)y = 6 and (c + 2)2x + (c + 4)2y = 36 are (Q) 2
concurrent is

The equation 2x2 – 3xy – py2 + x + qy – 1 = 0 represents two

(III) (R) 3
mutually perpendicular lines then |2(p + q)| is

The line λx + µy = 1 is a normal to the circle

(IV) (S) 4
2 2
2x + 2y – 5x + 6y – 1 = 0 then is
 (T) 5
Which of the following is only CORRECT combination ?
(A) I → T;II → Q,S;III → T;IV → Q
(B) I → T;II → R;III → T;IV → Q
(C) I → Q;II → Q,S;III → R,S;IV → P
(D) I → P,Q;II → P;III → Q;IV → S

2) Let α1, β1 (α1 < β1) be roots of the equation x2 – bx + 1 = 0 and α2, β2 (α2 < β2) be the roots of the

equation ax2 + bx + 2 = 0 such that . (a ≠ 0)

Match List-I with List-II and select the correct answer using the code given below the list.

List-I List-II

(I) The value of 'a' equals (P) –4

(II) The value of 'b' equals (Q) 1

(III) The value of (β1 + 2α2) equals (R) 3

(IV) The value of (α1 – 2α2) equals (S) 4

(T) –1
Which of the following is the only CORRECT combination ?
(A) I → T;II → R;III → S;IV → P
(B) I → Q;II → R;III → T;IV → P
(C) I → P;II → S;III → R;IV → Q
(D) I → R;II → T;III → P;IV → Q

3) Match the following List-I and List-II

List-I List-II

(I) (P) isosceles

If , then ΔABC is

(II) (Q) obtuse angle

If , then ΔABC may be

(III) If , then (R) right angle

ΔABC is

(IV) (S) acute angle

If , then ΔABC may be

(T) equilateral
(A) I → Q,S;II → R;III → T;IV → P,R
(B) I → T,R;II → P;III → Q;IV → S
(C) I → R;II → P;III → S;IV → T
(D) I → P;II → R;III → R;IV → P,R
4)

List-I List-II

If sinθ – cos2θ = 0, then cos4θ + cos2θ + 7 is equal

(I) (P) 4
to

(II) If and , then log5N is equal (Q) 9

to

(III) 8 + 3(sin4θ + cos4θ) – 2(sin6θ + cos6θ) is equal to (R) 6

If log22(x – 4) + log22(2 + log2y) = 0 then value of (x

(IV) (S) 7
+ 2y) is equal to

(T) 8
(A) I → T;II → P;III → R;IV → Q
(B) I → P;II → T;III → R;IV → Q
(C) I → T;II → R;III → Q;IV → P
(D) I → T;II → P;III → Q;IV → R

SECTION-II

1)

If and , then the value of (2 + 2x + x2)(5 – 4y + y2) is -

2) Coordinate of any point P are (4, 5). If A and B are variable points on straight lines y = x and y =
2x respectively. Then find minimum value of (PA + PB + AB)2_______

3) A triangle has vertices P = (–8, 5), Q = (–15, –19) and R = (1, –7). The equation of the bisector of
∠P can be written in the form ax + 2y + c = 0, then the value of a + c

4) Given three points A(1, 2), B(5, 7) and C(6, –2). Let P be any point on line segment AC from which
a line is drawn, perpendicular to BC, intersecting line AB at D. If from point P, line be drawn
perpendicular to CD, intersecting AB at (x, y), then x + y equals.

5) If pqr ≠ 0 and system of equations

(p + a)x + by + cz = 0
ax + (q + b)y + cz = 0
ax + by + (r + c)z = 0

has non-trivial solution, then value of is

6) If
 then p is equal to

7) Let α1, α2 be the roots of quadratic equation ax2 + bx + c = 0 and β1, β2 be roots of quadratic
equation px2 + qx + r = 0. If the system of equation α1y +α2z = 0 and β1y + β2z = 0 has non-trivial

solution and (Where λ ∈ R) then λ/4 is equal to :

8) Number of integral value(s) of x such that x2 + 14x + 53 is perfect square of natural number is/are
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I (i)

Q. 1 2 3 4 5 6
A. A,C B,C,D A,C,D A,B,C,D B,C,D B,C

SECTION-I (ii)

Q. 7 8 9 10
A. C B A D

SECTION-II

Q. 11 12 13 14 15 16 17 18
A. 0.23 to 0.26 0.69 22.00 to 22.10 3.00 0.70 to 0.75 18.80 to 19.00 0.43 to 0.46 0.25

PART-2 : CHEMISTRY

SECTION-I (i)

Q. 19 20 21 22 23 24
A. A,D A,B A,B,D A,C,D B,C,D A,B,D

SECTION-I (ii)

Q. 25 26 27 28
A. B A A C

SECTION-II

Q. 29 30 31 32 33 34 35 36
A. 3.00 2.00 4.00 30.30 to 30.40 0.33 5.00 3.00 2.00

PART-3 : MATHEMATICS

SECTION-I (i)

Q. 37 38 39 40 41 42
A. A,C A,D A,B,C A,B A,B,C,D B,D

SECTION-I (ii)

Q. 43 44 45 46
A. A C D D
 SECTION-II

Q. 47 48 49 50 51 52 53 54
A. 2.00 16.40 89.00 12.00 1.00 8.00 0.25 1.00
 SOLUTIONS

PART-1 : PHYSICS

1)

Compression in spring = 0.5 mm

2)

(A) mg sin 60° = α

α=

(B) N2 – mg cos 60° = 0 ⇒ N2 =

mg sin 60 – N1 = m

mg – . = N1

N1 =

N= = =

(C) mg (1 – cos 60°) = =

w=

(D) N – mg =

N= mg
3)

Theoretical

4)
f1 + f2 = ma
N1 + N2 = mg

∴ weight transferred =

5)

6) Correct Answer is (B,C)

7)

WET
(II & III) Using elastic collision concept

2V1 + 6V2 = 10
V1 + 3V2 = 5
V2 – V1 = 5
4V2 = 10

8)

N + ma0sinθ = mg
ma0cosθ – fS = ma
fSR = MR2α
fs = ma
(N + mg) sinθ – fScosθ = Ma0
∴ ma0cosθ = 2ma

and = 6 m/s2

m/s2
fS = N.

9)

(I) MBSB (TB – T) = MWSW (T – TW)

(II) Final temperature is 0°C as ice will not malt completely.

(III) Final temperature is 100°C as steam will not-condense completely.
(IV) M1 S1 (T – T) = M2S2 (T – T2)
0.1 (4200) (60 – T) = 0.15 (3500) (T – 25)
T = 40.55°C

10) ,

KE at bottom =

KE at top

Also (KE)b – (KE)T = mg(2R)

N = 48.6 N

11)
12)

As dℓ = αℓdT

13)

Qloss = Qagain
mSLV + mSLw (100 – T)
= miLf + (mi + mw) SwT + mCSCT
T = 22.06

14)
N2ℓsin30° = fℓcos30°

Angle of friction = 30°

15)
By imposing the condition that the bar does not slip when rotating, we can find x:
x = Rθ
where θ is in radians. We equate the clockwise moment due to mass M with the anti-clockwise
moment due to the mass of the rod. Balancing moments about the contact point, we have

We solve for M and substitute numerical values to obtain:

16) When water freezes. If releases heat. This heat raises the temperature of surrounding
which night rise
above. The freezing of whater, causing the freezing process to half.
Let total mass of water be M and mass of water freezes be m.
Qreleased → Q = mLf
Heat Q causes entire system temperature to rise by ΔT.
Q = MSwΔT
No move water can freeze once. The temperature of system exceeds freezes point Tf. This
occurs. when
ΔT = Tf – Ti .

Hence

17)
 ΣFy = 0
Mg + µNLsinθ = µNRsinθ + µNLcosθ + µNRcosθ
ΣFx = 0
NLsinθ + µNLcosθ + µNRcosθ = NRsinθ

18)

aCM = 0.25 m/s2

PART-2 : CHEMISTRY

19) (3) sp3 N has less E.N. so it is more basic

(4) Acidic strength

20)

CH4 + 2O2 → CO2 + 2H2O

x 2x

if y mole of air present

Total moles = x + 10x

21)
CaCO3 ⇒ x g
Glass bead ⇒ (1 – x)g
CaCO3 + 2HCl ⟶ CO2 + H2O + CaCl2
Xg
Moles of CO2 produced = = 5 × 10–3
Moles of CaCO3 reacted = 5 × 10–3
Weight of CaCO3 reacted = (5 × 10–3) × 100 g = 0.5 g
Weight of CaCO3 in original sample = 0.5 g
Weight of Ca in original sample = 5 × 10–3 × 40 = 0.2 g

% of Ca =

22) Correct answer is options (A,C,D)

23) The correct answer is option (B),(C),(D)

24) The correct answer is option (A),(B),(D)

25)

P is Odd number of σ-bond

Q is Nonaromatic
R is Heterocyclic
S is Aromatic

26)

The correct answer is option (A)

27) The correct answer is option (A)

28)
n = 3 + 8 × 3 = 27

n = 1 + (8 + 0 + 8) × 2 = 33

n = 8 + 8 + 0 + 8 = 24

n = 2 × 2 + 8 × 3 = 28

29) i, ii, v

30)

The correct answer is 2.00.

 f, g

31)

32) Milli eq. of Na2S2O3

This would be the milli eq. of I2 and therefore that of Cl2 (which liberates I2 from Kl).
Millie q. of Cl2 in 500 ml.
Meq. of Cl2 = meq of bleaching powder = Meq of available Cl2 in the bleaching powder.

% of chlorine

33)

34)

IF5, XeF4, ClO3–, SOF4, BrF5

35)

The correct answer is 3.00

36)

(ii)
(iii) Acetone + CHCl3

PART-3 : MATHEMATICS

37)

Equation of AB

AC ⇒ y= –
BC ⇒ y = 0

Distance of P from AB =
Distance of P from AC =
Distance of P from BC = d3 = |y|
According to question d1d2 =
⇒ |16x2 – (3y – 4)2| = 25y2
⇒ Circle S: 2x2 + 2y2 + 3y – 2 = 0 and hyperbola T: 8x2 – 17y2 + 12y – 8 = 0

38) P lies on the line 2x + 3y + 1 = 0 ….. (1)

|PA – PB| is maximum if P, A, B are collinear.
Equation of the line AB is x + y = 2 ….. (2)
P is the point of intersection of (1) and (2) which is (7, – 5)
Equation of perpendicular bisector of AB is
y=x ….. (3)

For minimum value of |PA – PB|, P is the point of intersection of (1) and (3) which is

39)

Area of parallelogram PSQR is least if angle between L & L1 is .

Slope of L1 =
Let slope of L = m

m = –3 or
Line L are y + 3x = 4 or 3y – x = 2

Area of ||gm =

40)
= (n + 1)2 (n + 2).2(n + 3 – n – 2)
= 2nI(n2 + 4n + 5) + 4

41)

42)

{(2b1 + (i – 1)d) (j – k) + (2b1 + (j – 1)d)(k – i) + (2b1 + (k – 1)d)(i – j)}

_____B,D

43) (I)
⇒ 2(–3) + (2 – λ) – 1 + 2λ = 0
–6 + 2 – λ – 1 + 2λ = 0
λ=5

(II)
C2 – C2 – C1

⇒ C = 2, 4
(III) Use abc + 2fgh – af2 – bg2 – ch2 = 0
p=2 & q=3

p=2 &

(IV)

Centre is
 5λ – 6µ = 4

44) and

Hence, roots of the first equation are

and
Also second equation is ax2 + 4x + 2 = 0

put α2 in 2nd equation to get a = –4

45) (I) Since cos A = , we have

or b + c – a = b or c = a2
2 2 2 2 2

Hence c = a and so the ΔABC is isosceles

(II) cos A (sin B – sin C) + (sin 2B – sin 2C) = 0
or cos A (sin B – sin C) + 2 sin (B – C) cos (B + C) = 0
or cos A (sin B – sin C) – 2 cos A sin (B – C) = 0
∴ either cos A = 0 ⇒ A = 90°
or (sin B – sin C) – 2(sin B cos C – cos B sin C) = 0

∴
or a(b – c) – 2 (b2 – c2) = 0
⇒ (b – c) [a – 2 (b + c)] = 0
∴ b – c = 0 or b = c
∴ Isosceles
(III) Combine first and thiral and put the value of cos B

∴
or 4b2 + c2 + a2 – b2 = 2a2 + 2b2
∴ b2 + c2 + a2
∴ ∠A = 90°

(IV) by sine formula

or

or
∴ Either sin (A – B) = 0
 ∴ A = B i.e. Δ is isosceles
or sin2A + sin2 B = sin2C or a2 + b2 = c2
∴ Δ is right angled

46) (I) sinθ = cos2θ

Then cos4θ + cos2θ + 7
= sin2θ + cos2θ + 7
=1 + 7 = 8
(II)

N = (25)2 ⇒ (5)4
log5N = 4

(III)

(IV)
and
x–4=1 2 + log2y = 1

x=5
x + 2y = 6

47) ⇒

⇒
2 2
(2 + 2x + x )(5 – 4y + y )
= (1 + (1 + x)2)(1 + (2 – y)2)

= (1 + tanθ)

48) Reflection of (4, 5) w.r.t lines y = x and y = 2x are (5, 4) and respectively

minimum value of PA + PB + AB = distance between (5,4) and =

49) Use the angle bisector theorem to the angle bisector of ∠P divides QR into segments of

length It follows that and so

P' = The desired answer is the

equation of the line PP' ·PP' has slope , from which the equation to be 11x + 2y + 78 = 0.
Therefore, a + c = 089.

50) P is orthocentre of ΔBCD so line from P perpendicular to CD passes through B

51)
R1 → R1 – R3
R2 → R2 – R3

⇒
c3 → c3 + c2 + c1

expand w.r.t. to 3rd column

4 2
52) We divide LHS by and C1, by , C2 by and C3 by on the RHS to obtain,
Taking limit as we get

[Using ]

53)

α1y + α2z = 0, β1y +β2z = 0 are non trivial solution.

Using componendo and dividendo:

⇒ (α1 + α2)(β1 - β2) = (β1 + β2)(α1 - α2)

⇒ (α1 + α2)2((β1 + β2)2 - 4β1β2) = (β1 + β2)2((α1+ α2)2 - 4α1α2)
Putting valueswe get

⇒λ=1

54) Let x2 + 14x + 53 = k2, k ∈ integer

⇒ x2 + 14x + 53 – k2 = 0 for some x ∈ integer
⇒ (14)2 – 4(53 – k2) = I2, I ∈ integer
⇒ k2 = 4 ⇒ x = –7